Figure 9
Packing diagram for (III), showing the cyclic tetramer formation through the combination of π–π and C—H⋯π interactions. The extension of the tetramers into a one-dimensional ribbon by C—H⋯O interactions and into a two-dimensional network by C—H⋯π interactions is illustrated. Intermolecular interactions are shown as dashed lines and H atoms not involved in these interactions have been omitted for clarity. Ring centroids are indicated with solid circles. [Symmetry codes: (i) −x + 1, −y + 1, −z + 2; (ii) x + 1, y, z; (iii) x, y, z + 1; (v) −x + 1, −y + 2, −z + 1.] |