Figure 3
Sections of the hydrogen-bonding pattern in (I). (a)/(b) The layers parallel to the ab plane formed by the interlinking of symmetry-related cations of Ge1 and Ge2, respectively. (c) A layer parallel to the bc plane formed by the mutual interlinking of the cations of Ge1 and Ge2. The colour code is as used in Fig. 2. In addition, the chloride counter-anions are shown as green spheres and N—H⋯Cl and O—H⋯Cl hydrogen bonds are represented as thin broken green lines. Weak C—H⋯Cl and C—H⋯O contacts are shown as thin broken black lines. C– and N-bonded H atoms, as well as ammonium groups, which are not involved in the intermolecular hydrogen-bonding scheme shown explicitly in the figure have been omitted for clarity. [The symmetry codes correspond to those listed in Table 2; additionally: (x) x + 1, y, z; (xi) x + 1, y − 1, z; (xii) x + 2, y − 1, z; (xiv) x, y + 1, z; (xvii) x − 1, y + 1, z; (xviii) x + 1, y − 1, z − 1; (xix) x − 1, y, z; (xx) −x + 1, −y, −z; (xxi) −x, −y + 1, −z.] |