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Figure 4
A selection of cyclic motifs, emerging from the various linking interactions between neighbouring cations. The representation of atoms and bonds is as in Fig. 3 . (a) R44(18), R43(21) and R42(24) rings formed within the chains of Ge1 cations aligned along the a axis. (b)/(c) The R42(8) motif observed for the Ge2⋯Ge2 and Ge1⋯Ge1 interactions, respectively. (d)/(e) The R42(16), R42(12) and R42(24) rings observed for the interlinking of Ge1. (f) Complex R86(24) rings, observed for the Ge2⋯Ge2 interconnection, comprising four ammonium groups, four water molecules and two chloride anions. Atoms and bonds are represented as in Fig. 2 . (The symmetry codes correspond to those listed in Table 2 and in Figs. 2 and 3 .) |


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