Figure 4
Illustrations of the topological analysis for (I). (a) A schematic representation of the connectivities of the {CoII(COO−)2(teaH3)} units, showing the detailed hydrogen-bonding interactions (dashed green lines). H atoms not involved in these interactions have been omitted for clarity. (b) The final supramolecular topology constructed from the intercrossed square skeletons (bold parts with two different colours). [Symmetry codes: (iv) −x + 2, −y, −z + 1; (v) −x + , −y + , z + ; (vi) x − , −y − , z − ; (vii) x − , −y + , z − ; (viii) −x + , y + , −z − ; (ix) x − 1, y, z − 1; (x) −x, −y, −z − 1.] |