A phase transition caught in mid-course: independent and concomitant analyses of the monoclinic and triclinic structures of (nBu4N)[Co(orotate)2(bipy)]·3H2O

Castro, M.; Falvello, L.R.; Forcén-Vázquez, E.; Guerra, P.; Al-Kenany, N.A.; Martínez, G.; Tomás, M.

doi:10.1107/S2053229617010841

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 9
(a) The anion and (b) the ⁿBu₄N⁺ cation from monoclinic phase (2d) of the multicrystal of (ⁿBu₄N)[cis-Co(Or)₂(bipy)]·3H₂O. Non-H atoms are represented by 50% probability displacement ellipsoids in both parts. For the ⁿBu₄N⁺cation in part (b), the major-disorder component (C22A—C23A) is shown for one ⁿBu group and the minor component (C22Bⁱⁱ—C23Bⁱⁱ) is shown for its symmetry relative. [Symmetry codes: (i) −x + $[{1\over 2}]$ , y, −z + $[{3\over 2}]$ ; (ii) −x + $[{3\over 2}]$ , y, −z + $[{3\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 73| Part 9| September 2017| Pages 731-742

https://doi.org/10.1107/S2053229617010841

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