view article
Figure 4
Fragment of the solid-state structure of 1 (displacement ellipsoids are drawn at the 50% probability level), showing the inter­molecular inter­actions in the tetra­molecular fragment and their analogy with the respective crystal structures of Ph2Te2 (green), PhTeI2Me (violet) and the bis­organotellurenyl selenides (4MeO-C6H4Te)2Se and Fe(C5H4Te)2Te2Se (orange). Selected inter­molecular distances in 1 (Å): Te1⋯I1i = 3.942 (1), I2⋯Te1i = 3.971 (1), I2⋯Te2ii = 3.992 (1), Te2⋯C4ii = 3.66 (1), Te2⋯C3ii = 3.422 (9), Te2⋯C2ii = 3.566 (8) and Te2⋯Se1iii = 3.512 (1). Selected angles (°): Se1—Te1⋯I1i = 171.40 (3), C7ii⋯Te2ii—I2 = 166.4 (2), Te1—I2—Te2ii = 97.72 (2), Se1ii—Te2ii⋯C3 = 174.9 (2), C7—Te2⋯Se1iii = 94.6 (2), Te1—Se1⋯Te2iii = 152.87 (4), Te2iii⋯Se1iii—Te2 = 99.22 (3) and Se1—Te2⋯Se1iii = 80.78 (3). [Symmetry codes: (i) x, −y + [{3\over 2}], z − [{1\over 2}]; (ii) x, y, z − 1; (iii) −x + 1, −y + 1, −z + 3.]

Journal logoSTRUCTURAL
CHEMISTRY
ISSN: 2053-2296
Volume 76| Part 6| June 2020| Pages 579-584
https://doi.org/10.1107/S2053229620006166
Follow Acta Cryst. C
Sign up for e-alerts
E-alerts
Follow Acta Cryst. on Twitter
Twitter
Follow us on facebook
Facebook
Sign up for RSS feeds
RSS