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Figure 1
The crystal structures for I (top) and II (bottom). The left panel shows the dimeric fragments, with displacement ellipsoids at the 30% probability level. The orientation emphasizes the conformation of the centrosymmetric end-to-end azide bridge. The right panel shows part of the crystal packing, with a polyhedral representation for the metal centres. The orientation emphasizes the inter-chain π–π inter­actions between dmbpy ligands.

Journal logoSTRUCTURAL
CHEMISTRY
ISSN: 2053-2296
Volume 78| Part 8| August 2022| Pages 449-454
https://doi.org/10.1107/S2053229622006908
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