Complexes of 2,4,6-tri­hydroxy­benzoic acid: effects of intra­molecular hydro­gen bonding on ligand geometry and metal binding modes

Abrahams, B.F.; Commons, C.J.; Hudson, T.A.; Sanches Arlt, R.; Ahl, R.; Carajias, E.D.; Chan, J.W.K.; Guo, Z.; Hill, R.E.; McGinty, A.; Peters, N.L.; Poon, J.Y.P.; Qu, J.; Qu, J.; Rochette, E.E.; Walkear, C.; Wang, H.; Wu, H.; Xu, C.; Zhang, J.

doi:10.1107/S2053229622009901

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 13
The structure of [Ca₂(H₃thba)₂(H₂O)₁₀][H₃thba]₂·4H₂O (8), showing (a) the [Ca₂(H₃thba)₂(H₂O)₁₀]²⁺ dimer with the carboxylate group of the H₃thba⁻ anion acting in a bridging bidentate mode and (b) interleaved coordinated H₃thba⁻ anions (brown bonds) and uncoordinated anions (green bonds) arranged to form stacks. Colour code: Ca green, O red, C black and H pale pink.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 78| Part 11| November 2022| Pages 653-670

https://doi.org/10.1107/S2053229622009901

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