Figure 2
Individual crystal packing of molecules A, B and C in compound 1. (a) View slightly off-set from the a axis, showing the near linear (θ = 167.8°) alignment of tail-to-tail C13C—H13C⋯O6C intrastrand contacts and interdigitation interactions through interstrand donor propargylic H9A (green) and H9B (blue) atoms with acceptor dioxolanyl atoms O6C (red) and ether atoms O3C (red), respectively; measurement of very weak engagement between interstrand donor proparygyl H9C (red) and acceptor propargylic ether atoms O2A (green) is not shown here, but discussed in Section 3.2.3. (b) View along the c axis showing the parallel, unidirectional and tail-to-tail arrangements of strands of outstretched molecules A (green) and B (blue), and the orthogonal tail-to-tail arrangement of strands of molecules C (red), all with acetylenic donor C13—H13⋯O6 dioxolanyl acceptor contacts; the positions of atoms C5 and H9 are also shown for reference purposes. Generic atom labels without symmetry codes have been used. |