Two metastable high hydrates of energetic material 3,3′,5,5′-tetra­nitro-4,4′-bi­pyrazole

Domasevitch, K.V.; Krautscheid, H.

doi:10.1107/S2053229624003346

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 1
Crystallization of H₂Tnbpz·nH₂O as a result of prototropic dismutation of hydrogen bipyrazolates (M = Na). The postulated aggregation of the H(Tnpbz)⁻ anions by extensive mutual NO₂/NO₂ interactions and hydration of the pyrazole sites are well reflected by the structures of the metastable high hydrates (1) and (2).

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 80| Part 5| May 2024| Pages 166-176

https://doi.org/10.1107/S2053229624003346

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