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Figure 2 (Left) Schlegel diagram showing the IUPAC lowest-locants for the cage carbon atoms. The C2 axis passes through the center of the hexagon with C19 and C41 and bisects the C30—C50 bond. The CF3 groups are attached to the cage carbon atoms depicted as black circles. Also shown is the ribbon of meta- and para-C6(CF3)2 edge-sharing hexagons (the two meta-C6(CF3)2 hexagons are indicated with the letter m). (Right) The structure showing the atom numbers for the CF3 groups and the network of F⋯F contacts between CF3 groups that share the same hexagon. |