Bis[μ-methyl­enebis(diphenyl­phosphine)]bis­[(5-nitro-1,10-phenanthroline)silver(I)] bis­(hexa­fluoridoanti­monate)

Yin, G.

doi:10.1107/S1600536807067013

metal-organic compounds

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Volume 64| Part 1| January 2008| Page m264

https://doi.org/10.1107/S1600536807067013

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Bis[μ-methylenebis(diphenylphosphine)]bis[(5-nitro-1,10-phenanthroline)silver(I)] bis(hexafluoridoantimonate)

Gangqiang Yin ^a ^*

^aDepartment of Chemistry, Guangdong Medical College, Zhanjiang 524023, People's Republic of China.
^*Correspondence e-mail: yingq666@sohu.com

(Received 15 November 2007; accepted 14 December 2007; online 21 December 2007)

In the title compound, [Ag₂(C₁₂H₇N₃O₂)₂(C₂₅H₂₂P₂)₂](SbF₆)₂, the two Ag^I atoms are bridged by the two methylenebis(diphenylphosphine) ligands and an eight-membered centrosymmetric metallacyclic ring is formed. The metal atom exhibits a distorted tetrahedral coordination geometry, coordinated by two P atoms of the bridging ligands and two N atoms of the chelating 5-nitro-1,10-phenanthroline ligand. The latter ligand shows minor disorder, adopting two orientations with site occupancy factors of 0.84 and 0.16.

Related literature

For related literature, see: Ho & Bau (1983 ); Smith & Cagle (1947 ).

Experimental

Crystal data

[Ag₂(C₁₂H₇N₃O₂)₂(C₂₅H₂₂P₂)₂](SbF₆)₂
M_r = 1906.38
Monoclinic, P 2₁ /n
a = 12.8034 (7) Å
b = 23.3993 (10) Å
c = 13.5580 (11) Å
β = 117.936 (2)°
V = 3588.5 (4) Å³
Z = 2
Mo Kα radiation
μ = 1.46 mm⁻¹
T = 293 (2) K
0.35 × 0.35 × 0.28 mm

Data collection

Rigaku Mercury 70 CCD diffractometer
Absorption correction: multi-scan (CrystalClear; Rigaku, 2000 ) T_min = 0.816, T_max = 1.000 (expected range = 0.543–0.665)
22441 measured reflections
6301 independent reflections
5851 reflections with I > 2σ(I)
R_int = 0.026

Refinement

R[F² > 2σ(F²)] = 0.030
wR(F²) = 0.060
S = 1.11
6301 reflections
623 parameters
486 restraints
H-atom parameters constrained
Δρ_max = 0.66 e Å⁻³
Δρ_min = −0.70 e Å⁻³

Table 1
Selected geometric parameters (Å, °)

Ag—N1	2.392 (6)
Ag—P2	2.3982 (7)
Ag—P1	2.4491 (7)
Ag—N2	2.451 (5)

N1—Ag—P2	115.8 (3)
N1—Ag—P1	100.1 (3)
P2—Ag—P1	144.11 (3)
N1—Ag—N2	68.51 (15)
P2—Ag—N2	103.1 (2)
P1—Ag—N2	90.9 (2)

Data collection: CrystalClear (Rigaku, 2000); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1999 ); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks I, global. DOI: https://doi.org/10.1107/S1600536807067013/gk2121sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536807067013/gk2121Isup2.hkl

checkCIF report

Comment top

The title compound, [Ag₂(methylenebis(diphenylphosphine))₂(5-nitro-1,10-phenanthroline)₂]. (SbF₆)₂, is formed by self-assembly between the metal diphosphine compound [Ag₂(methylenebis(diphenylphosphine))₂](SbF₆)₂ and 5-nitro-1,10-phenanthroline. In the crystal structure, the complex cation exists as a centrosymmetric dimer. Perspective view of the title compound is given in Fig. 1. The two methylenebis(diphenylphosphine) molecules bridge two Ag(5-nitro-1,10-phenanthroline) moieties to form an eight-membered Ag2P4C2 metallacyclic ring with the 5-nitro-1,10-phenanthroline ligand chelating Ag atoms. The P1—Ag—P2 angle of 144.11 (3)° is much larger than the N1—Ag—N2 angle of 68.59 (10)°, indicating a distorted tetrahedral coordination geometry around the silver atom.

Related literature top

For related literature, see: Ho & Bau (1983); Smith & Cagle (1947).

Experimental top

[Ag₂(methylenebis(diphenylphosphine))₂](SbF₆)₂ (Ho & Bau,1983) and 5-nitro-1,10-phenanthroline (Smith & Cagle, 1947) were prepared according to the literature procedures. The title compound was prepared by reacting 0.25 mmol of [Ag₂(bis(diphenylphosphino)₂](SbF₆)₂ with 0.5 mmol 5-nitro-1,10-phenanthroline in 15 ml CH₃CN at room temperature for 1 h. The resulting mixture was evaporated to dryness using Schlenk techniques. The solid product was recrystallized from a mixture of 15 ml CH₂Cl₂ and 10 ml CH₃OH giving yellow crystals suitable for X-ray analysis.

Structure description top

For related literature, see: Ho & Bau (1983); Smith & Cagle (1947).

Computing details top

Data collection: CrystalClear (Rigaku, 2000); cell refinement: CrystalClear (Rigaku, 2000); data reduction: CrystalClear (Rigaku, 2000); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1999); software used to prepare material for publication: SHELXTL (Bruker, 1999).

Figures top

	Fig. 1. ORTEP view of the title compound with the atomic numbering scheme. Displacement ellipsoids were drawn at the 30% probability level and all hydrogen atoms were omitted for clarity. Atoms with the suffix A were generated by the symmetery operation -x, -y, 2 - z.
	Fig. 2. Crystal packing of the title compound

Bis[µ-methylenebis(diphenylphosphine)]bis[(5-nitro-1,10- phenanthroline)silver(I)] bis(hexafluoridoantimonate) top

Crystal data top

[Ag₂(C₁₂H₇N₃O₂)₂(C₂₅H₂₂P₂)₂](SbF₆)₂	F(000) = 1880
M_r = 1906.38	D_x = 1.764 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 7865 reflections
a = 12.8034 (7) Å	θ = 3.0–25.0°
b = 23.3993 (10) Å	µ = 1.46 mm⁻¹
c = 13.5580 (11) Å	T = 293 K
β = 117.936 (2)°	Prism, yellow
V = 3588.5 (4) Å³	0.35 × 0.35 × 0.28 mm
Z = 2

Data collection top

Rigaku Mercury 70 CCD diffractometer	6301 independent reflections
Radiation source: fine-focus sealed tube	5851 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.026
Detector resolution: 14.6306 pixels mm^-1	θ_max = 25.0°, θ_min = 3.0°
ω scans	h = −15→15
Absorption correction: multi-scan (CrystalClear; Rigaku, 2000)	k = −27→26
T_min = 0.816, T_max = 1.000	l = −16→15
22441 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.060	H-atom parameters constrained
S = 1.11	w = 1/[σ²(F_o²) + (0.0186P)² + 5.1P] where P = (F_o² + 2F_c²)/3
6301 reflections	(Δ/σ)_max = 0.002
623 parameters	Δρ_max = 0.66 e Å⁻³
486 restraints	Δρ_min = −0.70 e Å⁻³

Crystal data top

[Ag₂(C₁₂H₇N₃O₂)₂(C₂₅H₂₂P₂)₂](SbF₆)₂	V = 3588.5 (4) Å³
M_r = 1906.38	Z = 2
Monoclinic, P2₁/n	Mo Kα radiation
a = 12.8034 (7) Å	µ = 1.46 mm⁻¹
b = 23.3993 (10) Å	T = 293 K
c = 13.5580 (11) Å	0.35 × 0.35 × 0.28 mm
β = 117.936 (2)°

Data collection top

Rigaku Mercury 70 CCD diffractometer	6301 independent reflections
Absorption correction: multi-scan (CrystalClear; Rigaku, 2000)	5851 reflections with I > 2σ(I)
T_min = 0.816, T_max = 1.000	R_int = 0.026
22441 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.030	486 restraints
wR(F²) = 0.060	H-atom parameters constrained
S = 1.11	Δρ_max = 0.66 e Å⁻³
6301 reflections	Δρ_min = −0.70 e Å⁻³
623 parameters

Special details top

Experimental. 2007–03-05 # Formatted by publCIF

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ag	0.023652 (17)	−0.075515 (9)	1.091671 (17)	0.01867 (6)
P1	−0.17901 (6)	−0.06326 (3)	0.94206 (6)	0.01775 (16)
P2	0.19380 (6)	−0.02588 (3)	1.22857 (6)	0.01697 (15)
C21	−0.2634 (2)	−0.00996 (12)	0.9721 (2)	0.0216 (6)
C22	−0.3864 (3)	−0.00586 (13)	0.9110 (3)	0.0247 (7)
H22A	−0.4286	−0.0325	0.8555	0.030*
C23	−0.4457 (3)	0.03785 (14)	0.9330 (3)	0.0326 (8)
H23A	−0.5274	0.0409	0.8913	0.039*
C24	−0.3838 (3)	0.07685 (15)	1.0167 (3)	0.0401 (9)
H24A	−0.4241	0.1059	1.0315	0.048*
C25	−0.2625 (3)	0.07299 (15)	1.0786 (3)	0.0385 (8)
H25A	−0.2211	0.0992	1.1351	0.046*
C26	−0.2027 (3)	0.02995 (13)	1.0562 (3)	0.0280 (7)
H26A	−0.1209	0.0276	1.0977	0.034*
C31	−0.2520 (2)	−0.13177 (12)	0.9320 (2)	0.0205 (6)
C32	−0.2280 (2)	−0.17707 (13)	0.8787 (2)	0.0253 (7)
H32A	−0.1866	−0.1703	0.8389	0.030*
C33	−0.2651 (3)	−0.23201 (13)	0.8845 (3)	0.0313 (8)
H33A	−0.2483	−0.2620	0.8491	0.038*
C34	−0.3271 (3)	−0.24197 (14)	0.9432 (3)	0.0357 (8)
H34A	−0.3513	−0.2789	0.9480	0.043*
C35	−0.3532 (3)	−0.19762 (15)	0.9945 (3)	0.0351 (8)
H35A	−0.3960	−0.2046	1.0329	0.042*
C36	−0.3163 (2)	−0.14242 (14)	0.9894 (3)	0.0274 (7)
H36A	−0.3343	−0.1126	1.0242	0.033*
C41	0.1816 (2)	−0.02647 (12)	1.3574 (2)	0.0200 (6)
C42	0.2094 (3)	−0.07752 (14)	1.4183 (3)	0.0275 (7)
H42A	0.2376	−0.1085	1.3948	0.033*
C43	0.1952 (3)	−0.08225 (15)	1.5130 (3)	0.0330 (8)
H43A	0.2131	−0.1165	1.5525	0.040*
C44	0.1546 (3)	−0.03626 (16)	1.5490 (3)	0.0353 (8)
H44A	0.1466	−0.0393	1.6135	0.042*
C45	0.1261 (3)	0.01406 (15)	1.4896 (3)	0.0352 (8)
H45A	0.0983	0.0449	1.5138	0.042*
C46	0.1388 (3)	0.01893 (13)	1.3932 (3)	0.0261 (7)
H46A	0.1185	0.0529	1.3528	0.031*
C51	0.3399 (2)	−0.05683 (13)	1.2753 (2)	0.0206 (6)
C52	0.3518 (3)	−0.10922 (13)	1.2338 (3)	0.0283 (7)
H52A	0.2852	−0.1281	1.1808	0.034*
C53	0.4631 (3)	−0.13370 (15)	1.2712 (3)	0.0389 (9)
H53A	0.4709	−0.1688	1.2430	0.047*
C54	0.5617 (3)	−0.10585 (16)	1.3500 (3)	0.0371 (8)
H54A	0.6360	−0.1223	1.3751	0.044*
C55	0.5510 (3)	−0.05397 (16)	1.3916 (3)	0.0349 (8)
H55A	0.6182	−0.0352	1.4439	0.042*
C56	0.4403 (2)	−0.02935 (14)	1.3558 (3)	0.0262 (7)
H56A	0.4332	0.0054	1.3856	0.031*
C61	−0.2118 (2)	−0.04967 (12)	0.7965 (2)	0.0206 (6)
H61A	−0.1595	−0.0726	0.7791	0.025*
H61B	−0.2924	−0.0613	0.7469	0.025*
C1	0.0907 (6)	−0.1990 (2)	1.0194 (7)	0.0286 (12)	0.842 (4)
H1A	0.1206	−0.1748	0.9843	0.034*	0.842 (4)
C2	0.0947 (6)	−0.2583 (2)	1.0054 (5)	0.0438 (16)	0.842 (4)
H2A	0.1270	−0.2729	0.9619	0.053*	0.842 (4)
C3	0.0510 (5)	−0.2940 (2)	1.0557 (5)	0.0445 (16)	0.842 (4)
H3A	0.0541	−0.3332	1.0471	0.053*	0.842 (4)
C4	0.0010 (5)	−0.2723 (2)	1.1206 (4)	0.0338 (12)	0.842 (4)
C5	−0.0497 (5)	−0.3045 (2)	1.1798 (5)	0.0424 (17)	0.842 (4)
C6	−0.1018 (4)	−0.2802 (2)	1.2341 (4)	0.0427 (13)	0.842 (4)
H6A	−0.1364	−0.3033	1.2666	0.051*	0.842 (4)
C7	−0.1057 (5)	−0.2198 (2)	1.2435 (4)	0.0323 (12)	0.842 (4)
C8	−0.1592 (4)	−0.1931 (2)	1.3008 (4)	0.0411 (12)	0.842 (4)
H8A	−0.1969	−0.2146	1.3324	0.049*	0.842 (4)
C9	−0.1552 (5)	−0.1351 (2)	1.3094 (4)	0.0417 (12)	0.842 (4)
H9A	−0.1903	−0.1165	1.3468	0.050*	0.842 (4)
C10	−0.0977 (5)	−0.1041 (2)	1.2612 (5)	0.0326 (13)	0.842 (4)
H10A	−0.0943	−0.0646	1.2690	0.039*	0.842 (4)
C11	−0.0517 (5)	−0.18563 (19)	1.1947 (5)	0.0235 (10)	0.842 (4)
C12	0.0005 (7)	−0.2113 (2)	1.1323 (5)	0.0251 (11)	0.842 (4)
N1	0.0456 (9)	−0.1765 (2)	1.0812 (9)	0.0238 (10)	0.842 (4)
N2	−0.0478 (8)	−0.12770 (18)	1.2050 (7)	0.0233 (10)	0.842 (4)
N3	−0.0420 (4)	−0.36777 (18)	1.1863 (4)	0.0676 (16)	0.842 (4)
O1	−0.0046 (4)	−0.39241 (17)	1.1320 (6)	0.121 (3)	0.842 (4)
O2	−0.0729 (8)	−0.3919 (2)	1.2455 (8)	0.095 (3)	0.842 (4)
C1'	0.110 (4)	−0.1903 (13)	1.011 (4)	0.023 (3)	0.158 (4)
H1'A	0.1420	−0.1628	0.9842	0.027*	0.158 (4)
C2'	0.116 (3)	−0.2481 (13)	0.987 (3)	0.027 (4)	0.158 (4)
H2'A	0.1480	−0.2585	0.9405	0.032*	0.158 (4)
C3'	0.075 (3)	−0.2885 (12)	1.031 (3)	0.028 (4)	0.158 (4)
H3'A	0.0816	−0.3269	1.0173	0.034*	0.158 (4)
C4'	0.023 (3)	−0.2733 (11)	1.098 (3)	0.024 (3)	0.158 (4)
C5'	−0.026 (2)	−0.3121 (10)	1.149 (2)	0.026 (4)	0.158 (4)
H5'A	−0.0234	−0.3511	1.1372	0.031*	0.158 (4)
C6'	−0.074 (3)	−0.2941 (10)	1.210 (3)	0.032 (4)	0.158 (4)
C7'	−0.086 (3)	−0.2346 (9)	1.228 (3)	0.026 (3)	0.158 (4)
C8'	−0.129 (2)	−0.2136 (10)	1.299 (2)	0.031 (4)	0.158 (4)
H8'A	−0.1587	−0.2390	1.3318	0.037*	0.158 (4)
C9'	−0.127 (3)	−0.1569 (10)	1.320 (2)	0.031 (3)	0.158 (4)
H9'A	−0.1576	−0.1433	1.3656	0.038*	0.158 (4)
C10'	−0.079 (3)	−0.1187 (11)	1.271 (3)	0.031 (3)	0.158 (4)
H10B	−0.0756	−0.0798	1.2862	0.037*	0.158 (4)
C11'	−0.034 (3)	−0.1943 (10)	1.185 (3)	0.025 (3)	0.158 (4)
C12'	0.012 (4)	−0.2131 (11)	1.114 (3)	0.022 (3)	0.158 (4)
N1'	0.059 (6)	−0.1739 (13)	1.072 (5)	0.020 (3)	0.158 (4)
N2'	−0.038 (5)	−0.1379 (11)	1.204 (4)	0.023 (3)	0.158 (4)
N3'	−0.1201 (15)	−0.3401 (8)	1.2576 (16)	0.040 (3)	0.158 (4)
O2'	−0.1967 (14)	−0.3283 (7)	1.2810 (14)	0.049 (3)	0.158 (4)
O1'	−0.091 (4)	−0.3889 (11)	1.259 (4)	0.033 (3)	0.158 (4)
Sb	0.035784 (19)	0.195912 (9)	1.342401 (19)	0.03131 (7)
F1	−0.0552 (2)	0.15895 (13)	1.3963 (3)	0.0868 (9)
F2	−0.09810 (19)	0.23510 (10)	1.2379 (2)	0.0632 (7)
F3	0.12724 (18)	0.23192 (9)	1.28696 (18)	0.0447 (5)
F4	0.0682 (2)	0.25534 (10)	1.4442 (2)	0.0624 (7)
F5	0.0064 (2)	0.13675 (9)	1.23847 (18)	0.0559 (6)
F6	0.16940 (18)	0.15634 (9)	1.44683 (17)	0.0461 (5)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag	0.01518 (11)	0.01797 (12)	0.02097 (11)	−0.00183 (8)	0.00690 (9)	−0.00001 (9)
P1	0.0148 (3)	0.0175 (4)	0.0195 (4)	−0.0012 (3)	0.0069 (3)	0.0020 (3)
P2	0.0140 (3)	0.0155 (4)	0.0193 (4)	−0.0006 (3)	0.0060 (3)	0.0015 (3)
C21	0.0220 (14)	0.0207 (16)	0.0236 (15)	0.0009 (12)	0.0119 (13)	0.0042 (12)
C22	0.0219 (15)	0.0260 (17)	0.0288 (16)	−0.0009 (13)	0.0141 (13)	0.0049 (13)
C23	0.0249 (16)	0.037 (2)	0.041 (2)	0.0085 (15)	0.0203 (15)	0.0085 (16)
C24	0.044 (2)	0.034 (2)	0.054 (2)	0.0089 (17)	0.0326 (19)	−0.0018 (18)
C25	0.0392 (19)	0.035 (2)	0.045 (2)	−0.0055 (16)	0.0229 (17)	−0.0149 (17)
C26	0.0250 (15)	0.0286 (17)	0.0316 (17)	−0.0025 (14)	0.0142 (14)	−0.0036 (14)
C31	0.0122 (13)	0.0225 (16)	0.0190 (14)	−0.0032 (12)	0.0007 (11)	0.0047 (12)
C32	0.0190 (14)	0.0256 (17)	0.0229 (16)	−0.0019 (13)	0.0027 (13)	0.0019 (13)
C33	0.0229 (16)	0.0212 (17)	0.0294 (17)	−0.0023 (13)	−0.0048 (14)	0.0023 (14)
C34	0.0225 (16)	0.0249 (18)	0.0349 (19)	−0.0070 (14)	−0.0071 (15)	0.0109 (15)
C35	0.0212 (16)	0.043 (2)	0.0323 (18)	−0.0082 (15)	0.0050 (14)	0.0169 (16)
C36	0.0175 (14)	0.0321 (18)	0.0274 (16)	−0.0026 (13)	0.0062 (13)	0.0065 (14)
C41	0.0125 (13)	0.0241 (16)	0.0199 (14)	−0.0032 (12)	0.0047 (12)	0.0002 (12)
C42	0.0230 (15)	0.0291 (18)	0.0303 (17)	0.0016 (13)	0.0125 (14)	0.0067 (14)
C43	0.0233 (16)	0.043 (2)	0.0299 (17)	−0.0013 (15)	0.0099 (14)	0.0136 (16)
C44	0.0332 (18)	0.052 (2)	0.0255 (17)	−0.0073 (17)	0.0174 (15)	0.0033 (16)
C45	0.0382 (19)	0.038 (2)	0.0373 (19)	−0.0051 (16)	0.0239 (16)	−0.0075 (16)
C46	0.0263 (16)	0.0243 (17)	0.0310 (17)	−0.0030 (13)	0.0161 (14)	0.0007 (13)
C51	0.0165 (13)	0.0235 (16)	0.0209 (15)	0.0007 (12)	0.0080 (12)	0.0062 (12)
C52	0.0208 (15)	0.0215 (17)	0.0403 (19)	−0.0008 (13)	0.0124 (14)	−0.0002 (14)
C53	0.0352 (19)	0.0238 (18)	0.061 (2)	0.0089 (15)	0.0247 (18)	0.0045 (17)
C54	0.0205 (16)	0.043 (2)	0.047 (2)	0.0121 (15)	0.0152 (16)	0.0166 (17)
C55	0.0158 (15)	0.048 (2)	0.0332 (18)	−0.0019 (15)	0.0055 (14)	0.0064 (16)
C56	0.0196 (15)	0.0296 (18)	0.0288 (16)	−0.0015 (13)	0.0108 (13)	−0.0024 (14)
C61	0.0222 (14)	0.0162 (15)	0.0237 (15)	−0.0003 (12)	0.0111 (13)	0.0000 (12)
C1	0.026 (3)	0.029 (3)	0.026 (2)	0.005 (2)	0.0082 (18)	−0.001 (2)
C2	0.047 (3)	0.035 (3)	0.039 (3)	0.012 (3)	0.011 (2)	−0.007 (3)
C3	0.047 (3)	0.021 (2)	0.038 (3)	0.011 (2)	−0.002 (2)	−0.006 (2)
C4	0.028 (3)	0.0185 (19)	0.028 (3)	0.0031 (17)	−0.0086 (17)	0.0019 (18)
C5	0.035 (3)	0.017 (2)	0.037 (4)	−0.007 (2)	−0.015 (2)	0.014 (2)
C6	0.033 (2)	0.039 (3)	0.032 (2)	−0.013 (2)	−0.0048 (18)	0.017 (2)
C7	0.026 (2)	0.040 (3)	0.018 (2)	−0.014 (2)	0.0001 (17)	0.007 (2)
C8	0.034 (3)	0.064 (4)	0.024 (2)	−0.023 (2)	0.0132 (19)	0.002 (2)
C9	0.037 (3)	0.060 (3)	0.033 (2)	−0.018 (2)	0.020 (2)	−0.011 (2)
C10	0.030 (3)	0.042 (3)	0.029 (2)	−0.012 (2)	0.017 (2)	−0.011 (2)
C11	0.016 (2)	0.028 (2)	0.0144 (18)	−0.0046 (17)	−0.0025 (14)	0.0035 (17)
C12	0.020 (2)	0.0213 (18)	0.020 (3)	−0.0026 (16)	−0.0031 (16)	0.0098 (17)
N1	0.019 (3)	0.0228 (18)	0.022 (3)	0.0015 (16)	0.0032 (14)	−0.0027 (16)
N2	0.022 (2)	0.025 (2)	0.0200 (16)	−0.008 (2)	0.0071 (15)	−0.002 (2)
N3	0.038 (2)	0.026 (2)	0.081 (3)	−0.008 (2)	−0.020 (2)	0.018 (2)
O1	0.086 (3)	0.023 (2)	0.269 (8)	0.004 (2)	0.097 (4)	0.008 (3)
O2	0.114 (7)	0.034 (3)	0.066 (5)	−0.031 (3)	−0.016 (3)	0.030 (3)
C1'	0.024 (5)	0.024 (5)	0.023 (5)	0.004 (5)	0.014 (4)	−0.001 (4)
C2'	0.029 (6)	0.025 (6)	0.029 (5)	0.001 (5)	0.016 (5)	0.001 (5)
C3'	0.033 (6)	0.023 (5)	0.030 (6)	0.007 (5)	0.016 (5)	−0.004 (5)
C4'	0.023 (5)	0.020 (4)	0.023 (5)	0.001 (4)	0.007 (4)	0.003 (4)
C5'	0.024 (5)	0.019 (5)	0.025 (6)	−0.004 (5)	0.003 (5)	0.007 (5)
C6'	0.028 (5)	0.028 (5)	0.029 (5)	−0.007 (5)	0.004 (5)	0.010 (5)
C7'	0.021 (4)	0.032 (5)	0.019 (4)	−0.006 (4)	0.004 (4)	0.003 (4)
C8'	0.025 (5)	0.039 (6)	0.023 (5)	−0.011 (5)	0.007 (5)	0.000 (5)
C9'	0.028 (5)	0.046 (5)	0.025 (4)	−0.012 (5)	0.016 (4)	−0.005 (5)
C10'	0.028 (5)	0.037 (5)	0.026 (4)	−0.012 (5)	0.012 (4)	−0.003 (5)
C11'	0.021 (4)	0.022 (4)	0.019 (4)	−0.010 (4)	−0.001 (4)	0.005 (4)
C12'	0.019 (4)	0.022 (4)	0.019 (5)	0.002 (4)	0.004 (4)	−0.001 (4)
N1'	0.020 (5)	0.022 (4)	0.019 (5)	−0.005 (4)	0.009 (4)	0.006 (4)
N2'	0.022 (5)	0.033 (5)	0.017 (4)	−0.008 (5)	0.010 (4)	−0.002 (5)
N3'	0.040 (5)	0.039 (5)	0.043 (5)	−0.007 (5)	0.021 (4)	0.018 (5)
O2'	0.045 (6)	0.043 (6)	0.053 (6)	−0.007 (5)	0.019 (5)	0.020 (5)
O1'	0.039 (5)	0.038 (6)	0.036 (6)	−0.006 (5)	0.030 (5)	0.015 (5)
Sb	0.03320 (12)	0.02695 (13)	0.03999 (14)	0.00654 (9)	0.02232 (11)	0.00912 (10)
F1	0.0786 (18)	0.091 (2)	0.119 (2)	−0.0047 (16)	0.0694 (19)	0.0431 (19)
F2	0.0377 (12)	0.0606 (16)	0.0893 (18)	0.0241 (11)	0.0282 (13)	0.0301 (14)
F3	0.0464 (12)	0.0476 (13)	0.0557 (13)	0.0058 (10)	0.0370 (11)	0.0089 (10)
F4	0.0965 (19)	0.0479 (14)	0.0622 (15)	0.0149 (13)	0.0533 (15)	−0.0061 (12)
F5	0.0565 (14)	0.0377 (12)	0.0437 (13)	0.0067 (11)	−0.0013 (11)	−0.0024 (10)
F6	0.0489 (12)	0.0339 (11)	0.0392 (12)	0.0060 (10)	0.0070 (10)	0.0053 (9)

Geometric parameters (Å, º) top

Ag—N1	2.392 (6)	C1—N1	1.329 (5)
Ag—P2	2.3982 (7)	C1—C2	1.404 (6)
Ag—N1'	2.38 (3)	C1—H1A	0.9300
Ag—N2'	2.49 (3)	C2—C3	1.353 (7)
Ag—P1	2.4491 (7)	C2—H2A	0.9300
Ag—N2	2.451 (5)	C3—C4	1.403 (7)
P1—C21	1.817 (3)	C3—H3A	0.9300
P1—C31	1.828 (3)	C4—C12	1.437 (5)
P1—C61	1.843 (3)	C4—C5	1.457 (8)
P2—C51	1.821 (3)	C5—C6	1.330 (7)
P2—C41	1.825 (3)	C5—N3	1.483 (6)
P2—C61ⁱ	1.835 (3)	C6—C7	1.424 (7)
C21—C26	1.395 (4)	C6—H6A	0.9300
C21—C22	1.398 (4)	C7—C8	1.400 (7)
C22—C23	1.387 (4)	C7—C11	1.408 (5)
C22—H22A	0.9300	C8—C9	1.359 (7)
C23—C24	1.381 (5)	C8—H8A	0.9300
C23—H23A	0.9300	C9—C10	1.395 (6)
C24—C25	1.380 (5)	C9—H9A	0.9300
C24—H24A	0.9300	C10—N2	1.322 (5)
C25—C26	1.383 (4)	C10—H10A	0.9300
C25—H25A	0.9300	C11—N2	1.361 (5)
C26—H26A	0.9300	C11—C12	1.432 (6)
C31—C36	1.395 (4)	C12—N1	1.361 (5)
C31—C32	1.396 (4)	N3—O2	1.191 (8)
C32—C33	1.385 (4)	N3—O1	1.198 (7)
C32—H32A	0.9300	C1'—N1'	1.325 (17)
C33—C34	1.382 (5)	C1'—C2'	1.405 (17)
C33—H33A	0.9300	C1'—H1'A	0.9300
C34—C35	1.376 (5)	C2'—C3'	1.350 (18)
C34—H34A	0.9300	C2'—H2'A	0.9300
C35—C36	1.388 (4)	C3'—C4'	1.397 (17)
C35—H35A	0.9300	C3'—H3'A	0.9300
C36—H36A	0.9300	C4'—C12'	1.440 (16)
C41—C46	1.383 (4)	C4'—C5'	1.447 (17)
C41—C42	1.400 (4)	C5'—C6'	1.322 (19)
C42—C43	1.384 (4)	C5'—H5'A	0.9300
C42—H42A	0.9300	C6'—C7'	1.435 (18)
C43—C44	1.379 (5)	C6'—N3'	1.50 (3)
C43—H43A	0.9300	C7'—C8'	1.387 (17)
C44—C45	1.376 (5)	C7'—C11'	1.429 (16)
C44—H44A	0.9300	C8'—C9'	1.357 (18)
C45—C46	1.396 (4)	C8'—H8'A	0.9300
C45—H45A	0.9300	C9'—C10'	1.417 (17)
C46—H46A	0.9300	C9'—H9'A	0.9300
C51—C52	1.386 (4)	C10'—N2'	1.324 (17)
C51—C56	1.394 (4)	C10'—H10B	0.9300
C52—C53	1.392 (4)	C11'—N2'	1.349 (16)
C52—H52A	0.9300	C11'—C12'	1.420 (16)
C53—C54	1.376 (5)	C12'—N1'	1.354 (16)
C53—H53A	0.9300	N3'—O2'	1.197 (16)
C54—C55	1.372 (5)	N3'—O1'	1.197 (19)
C54—H54A	0.9300	Sb—F1	1.853 (2)
C55—C56	1.390 (4)	Sb—F3	1.8630 (19)
C55—H55A	0.9300	Sb—F4	1.864 (2)
C56—H56A	0.9300	Sb—F2	1.874 (2)
C61—P2ⁱ	1.835 (3)	Sb—F6	1.8759 (19)
C61—H61A	0.9700	Sb—F5	1.883 (2)
C61—H61B	0.9700

N1—Ag—P2	115.8 (3)	N1—C1—C2	122.1 (5)
N1—Ag—N1'	6.2 (7)	N1—C1—H1A	119.0
P2—Ag—N1'	113.8 (17)	C2—C1—H1A	119.0
N1—Ag—N2'	62.3 (6)	C3—C2—C1	119.4 (5)
P2—Ag—N2'	104.1 (13)	C3—C2—H2A	120.3
N1'—Ag—N2'	68.3 (7)	C1—C2—H2A	120.3
N1—Ag—P1	100.1 (3)	C2—C3—C4	120.7 (4)
P2—Ag—P1	144.11 (3)	C2—C3—H3A	119.6
N1'—Ag—P1	101.7 (17)	C4—C3—H3A	119.6
N2'—Ag—P1	93.4 (14)	C3—C4—C12	117.1 (4)
N1—Ag—N2	68.51 (15)	C3—C4—C5	127.6 (4)
P2—Ag—N2	103.1 (2)	C12—C4—C5	115.2 (5)
N1'—Ag—N2	74.5 (6)	C6—C5—C4	123.5 (4)
N2'—Ag—N2	6.3 (7)	C6—C5—N3	115.5 (6)
P1—Ag—N2	90.9 (2)	C4—C5—N3	121.0 (6)
C21—P1—C31	106.38 (13)	C5—C6—C7	121.5 (5)
C21—P1—C61	105.11 (13)	C5—C6—H6A	119.2
C31—P1—C61	102.66 (13)	C7—C6—H6A	119.2
C21—P1—Ag	113.91 (10)	C8—C7—C11	118.9 (4)
C31—P1—Ag	105.39 (9)	C8—C7—C6	122.7 (4)
C61—P1—Ag	121.90 (9)	C11—C7—C6	118.4 (5)
C51—P2—C41	101.49 (13)	C9—C8—C7	118.9 (4)
C51—P2—C61ⁱ	104.48 (13)	C9—C8—H8A	120.5
C41—P2—C61ⁱ	104.99 (13)	C7—C8—H8A	120.5
C51—P2—Ag	119.29 (10)	C8—C9—C10	119.0 (5)
C41—P2—Ag	106.43 (9)	C8—C9—H9A	120.5
C61ⁱ—P2—Ag	118.08 (10)	C10—C9—H9A	120.5
C26—C21—C22	118.7 (3)	N2—C10—C9	123.8 (5)
C26—C21—P1	118.7 (2)	N2—C10—H10A	118.1
C22—C21—P1	122.5 (2)	C9—C10—H10A	118.1
C23—C22—C21	120.1 (3)	N2—C11—C7	121.3 (4)
C23—C22—H22A	119.9	N2—C11—C12	118.2 (4)
C21—C22—H22A	119.9	C7—C11—C12	120.5 (4)
C24—C23—C22	120.2 (3)	N1—C12—C4	120.8 (5)
C24—C23—H23A	119.9	N1—C12—C11	118.5 (4)
C22—C23—H23A	119.9	C4—C12—C11	120.7 (4)
C25—C24—C23	120.4 (3)	C1—N1—C12	119.8 (4)
C25—C24—H24A	119.8	C1—N1—Ag	121.8 (4)
C23—C24—H24A	119.8	C12—N1—Ag	118.1 (3)
C24—C25—C26	119.7 (3)	C10—N2—C11	118.0 (4)
C24—C25—H25A	120.1	C10—N2—Ag	125.2 (3)
C26—C25—H25A	120.1	C11—N2—Ag	116.0 (3)
C25—C26—C21	120.9 (3)	O2—N3—O1	122.8 (6)
C25—C26—H26A	119.5	O2—N3—C5	118.7 (7)
C21—C26—H26A	119.5	O1—N3—C5	118.6 (6)
C36—C31—C32	118.9 (3)	N1'—C1'—C2'	122 (2)
C36—C31—P1	122.0 (2)	N1'—C1'—H1'A	119.1
C32—C31—P1	118.4 (2)	C2'—C1'—H1'A	119.1
C33—C32—C31	120.7 (3)	C3'—C2'—C1'	119 (2)
C33—C32—H32A	119.6	C3'—C2'—H2'A	120.3
C31—C32—H32A	119.6	C1'—C2'—H2'A	120.3
C34—C33—C32	119.6 (3)	C2'—C3'—C4'	120.9 (19)
C34—C33—H33A	120.2	C2'—C3'—H3'A	119.6
C32—C33—H33A	120.2	C4'—C3'—H3'A	119.6
C35—C34—C33	120.4 (3)	C3'—C4'—C12'	117.0 (16)
C35—C34—H34A	119.8	C3'—C4'—C5'	126.3 (18)
C33—C34—H34A	119.8	C12'—C4'—C5'	116.6 (16)
C34—C35—C36	120.5 (3)	C6'—C5'—C4'	123 (2)
C34—C35—H35A	119.8	C6'—C5'—H5'A	118.7
C36—C35—H35A	119.8	C4'—C5'—H5'A	118.7
C35—C36—C31	119.9 (3)	C5'—C6'—C7'	122 (2)
C35—C36—H36A	120.1	C5'—C6'—N3'	115.7 (19)
C31—C36—H36A	120.1	C7'—C6'—N3'	121.9 (18)
C46—C41—C42	118.8 (3)	C8'—C7'—C6'	124.6 (17)
C46—C41—P2	123.7 (2)	C8'—C7'—C11'	117.2 (16)
C42—C41—P2	117.3 (2)	C6'—C7'—C11'	117.6 (17)
C43—C42—C41	120.5 (3)	C9'—C8'—C7'	121.4 (18)
C43—C42—H42A	119.7	C9'—C8'—H8'A	119.3
C41—C42—H42A	119.7	C7'—C8'—H8'A	119.3
C44—C43—C42	120.0 (3)	C8'—C9'—C10'	118.9 (18)
C44—C43—H43A	120.0	C8'—C9'—H9'A	120.5
C42—C43—H43A	120.0	C10'—C9'—H9'A	120.5
C45—C44—C43	120.1 (3)	N2'—C10'—C9'	121 (2)
C45—C44—H44A	119.9	N2'—C10'—H10B	119.7
C43—C44—H44A	119.9	C9'—C10'—H10B	119.7
C44—C45—C46	120.2 (3)	N2'—C11'—C7'	120.3 (17)
C44—C45—H45A	119.9	N2'—C11'—C12'	119.5 (16)
C46—C45—H45A	119.9	C7'—C11'—C12'	120.0 (17)
C41—C46—C45	120.3 (3)	N1'—C12'—C4'	120.5 (17)
C41—C46—H46A	119.8	N1'—C12'—C11'	118.7 (17)
C45—C46—H46A	119.8	C4'—C12'—C11'	120.3 (17)
C52—C51—C56	119.3 (3)	C1'—N1'—C12'	120 (2)
C52—C51—P2	120.1 (2)	C1'—N1'—Ag	121.4 (17)
C56—C51—P2	120.6 (2)	C12'—N1'—Ag	117.8 (15)
C51—C52—C53	120.3 (3)	C10'—N2'—C11'	121.4 (19)
C51—C52—H52A	119.9	C10'—N2'—Ag	124.1 (16)
C53—C52—H52A	119.9	C11'—N2'—Ag	114.3 (14)
C54—C53—C52	119.8 (3)	O2'—N3'—O1'	120.1 (19)
C54—C53—H53A	120.1	O2'—N3'—C6'	118.5 (18)
C52—C53—H53A	120.1	O1'—N3'—C6'	121 (2)
C55—C54—C53	120.4 (3)	F1—Sb—F3	179.02 (13)
C55—C54—H54A	119.8	F1—Sb—F4	91.09 (13)
C53—C54—H54A	119.8	F3—Sb—F4	89.86 (10)
C54—C55—C56	120.3 (3)	F1—Sb—F2	90.32 (12)
C54—C55—H55A	119.8	F3—Sb—F2	89.92 (10)
C56—C55—H55A	119.8	F4—Sb—F2	90.14 (12)
C55—C56—C51	119.8 (3)	F1—Sb—F6	89.50 (11)
C55—C56—H56A	120.1	F3—Sb—F6	90.25 (9)
C51—C56—H56A	120.1	F4—Sb—F6	90.09 (10)
P2ⁱ—C61—P1	112.26 (15)	F2—Sb—F6	179.72 (11)
P2ⁱ—C61—H61A	109.2	F1—Sb—F5	90.56 (14)
P1—C61—H61A	109.2	F3—Sb—F5	88.49 (10)
P2ⁱ—C61—H61B	109.2	F4—Sb—F5	178.33 (11)
P1—C61—H61B	109.2	F2—Sb—F5	90.13 (11)
H61A—C61—H61B	107.9	F6—Sb—F5	89.65 (9)

N1—Ag—P1—C21	143.06 (17)	C61ⁱ—P2—C51—C56	46.3 (3)
P2—Ag—P1—C21	−39.37 (11)	Ag—P2—C51—C56	−179.1 (2)
N1'—Ag—P1—C21	149.1 (6)	C56—C51—C52—C53	−0.9 (5)
N2'—Ag—P1—C21	80.6 (6)	P2—C51—C52—C53	−178.5 (3)
N2—Ag—P1—C21	74.73 (15)	C51—C52—C53—C54	0.3 (5)
N1—Ag—P1—C31	26.83 (17)	C52—C53—C54—C55	−0.3 (5)
P2—Ag—P1—C31	−155.60 (10)	C53—C54—C55—C56	1.0 (5)
N1'—Ag—P1—C31	32.9 (6)	C54—C55—C56—C51	−1.6 (5)
N2'—Ag—P1—C31	−35.7 (6)	C52—C51—C56—C55	1.6 (4)
N2—Ag—P1—C31	−41.50 (15)	P2—C51—C56—C55	179.2 (2)
N1—Ag—P1—C61	−89.21 (17)	C21—P1—C61—P2ⁱ	49.57 (18)
P2—Ag—P1—C61	88.35 (12)	C31—P1—C61—P2ⁱ	160.67 (15)
N1'—Ag—P1—C61	−83.2 (6)	Ag—P1—C61—P2ⁱ	−81.92 (16)
N2'—Ag—P1—C61	−151.7 (6)	C2—C1—N1—Ag	−174.5 (6)
N2—Ag—P1—C61	−157.54 (15)	C4—C12—N1—Ag	174.2 (5)
N1—Ag—P2—C51	24.36 (19)	C11—C12—N1—Ag	−3.4 (11)
N1'—Ag—P2—C51	17.9 (7)	P2—Ag—N1—C1	−85.9 (8)
N2'—Ag—P2—C51	90.1 (8)	N1'—Ag—N1—C1	−14 (18)
P1—Ag—P2—C51	−152.97 (11)	N2'—Ag—N1—C1	−178.9 (18)
N2—Ag—P2—C51	96.58 (17)	P1—Ag—N1—C1	92.5 (8)
N1—Ag—P2—C41	−89.44 (18)	N2—Ag—N1—C1	179.5 (9)
N1'—Ag—P2—C41	−95.8 (7)	P2—Ag—N1—C12	100.1 (7)
N2'—Ag—P2—C41	−23.7 (8)	N1'—Ag—N1—C12	172 (19)
P1—Ag—P2—C41	93.23 (11)	N2'—Ag—N1—C12	7.1 (17)
N2—Ag—P2—C41	−17.21 (16)	P1—Ag—N1—C12	−81.5 (8)
N1—Ag—P2—C61ⁱ	152.98 (18)	N2—Ag—N1—C12	5.5 (7)
N1'—Ag—P2—C61ⁱ	146.6 (7)	C9—C10—N2—C11	−0.7 (11)
N2'—Ag—P2—C61ⁱ	−141.2 (8)	C9—C10—N2—Ag	168.8 (5)
P1—Ag—P2—C61ⁱ	−24.35 (12)	C7—C11—N2—C10	−0.9 (11)
N2—Ag—P2—C61ⁱ	−134.79 (17)	C12—C11—N2—C10	178.9 (7)
C31—P1—C21—C26	133.8 (2)	C7—C11—N2—Ag	−171.3 (5)
C61—P1—C21—C26	−117.8 (2)	C12—C11—N2—Ag	8.5 (9)
Ag—P1—C21—C26	18.2 (3)	N1—Ag—N2—C10	−176.9 (8)
C31—P1—C21—C22	−49.0 (3)	P2—Ag—N2—C10	70.2 (7)
C61—P1—C21—C22	59.4 (3)	N1'—Ag—N2—C10	−178.3 (19)
Ag—P1—C21—C22	−164.7 (2)	N2'—Ag—N2—C10	170 (15)
C26—C21—C22—C23	1.1 (4)	P1—Ag—N2—C10	−76.4 (7)
P1—C21—C22—C23	−176.0 (2)	N1—Ag—N2—C11	−7.2 (6)
C21—C22—C23—C24	−1.2 (5)	P2—Ag—N2—C11	−120.1 (6)
C22—C23—C24—C25	0.5 (5)	N1'—Ag—N2—C11	−8.7 (18)
C23—C24—C25—C26	0.3 (6)	N2'—Ag—N2—C11	−20 (14)
C24—C25—C26—C21	−0.4 (5)	P1—Ag—N2—C11	93.2 (6)
C22—C21—C26—C25	−0.3 (5)	C6—C5—N3—O2	−6.1 (8)
P1—C21—C26—C25	176.9 (3)	C4—C5—N3—O2	171.9 (7)
C21—P1—C31—C36	−27.8 (3)	C6—C5—N3—O1	174.2 (5)
C61—P1—C31—C36	−138.0 (2)	C4—C5—N3—O1	−7.8 (7)
Ag—P1—C31—C36	93.5 (2)	N1—Ag—N1'—C1'	169 (23)
C21—P1—C31—C32	161.8 (2)	P2—Ag—N1'—C1'	−81 (5)
C61—P1—C31—C32	51.7 (2)	N2'—Ag—N1'—C1'	−177 (5)
Ag—P1—C31—C32	−76.9 (2)	P1—Ag—N1'—C1'	94 (5)
C36—C31—C32—C33	−1.3 (4)	N2—Ag—N1'—C1'	−179 (5)
P1—C31—C32—C33	169.4 (2)	N1—Ag—N1'—C12'	−3 (15)
C31—C32—C33—C34	0.3 (4)	P2—Ag—N1'—C12'	107 (4)
C32—C33—C34—C35	0.8 (4)	N2'—Ag—N1'—C12'	10 (4)
C33—C34—C35—C36	−0.9 (5)	P1—Ag—N1'—C12'	−79 (5)
C34—C35—C36—C31	−0.1 (4)	N2—Ag—N1'—C12'	9 (4)
C32—C31—C36—C35	1.2 (4)	C9'—C10'—N2'—C11'	−4 (7)
P1—C31—C36—C35	−169.2 (2)	C9'—C10'—N2'—Ag	171 (3)
C51—P2—C41—C46	135.8 (2)	C7'—C11'—N2'—C10'	6 (7)
C61ⁱ—P2—C41—C46	27.2 (3)	C12'—C11'—N2'—C10'	−179 (5)
Ag—P2—C41—C46	−98.7 (2)	C7'—C11'—N2'—Ag	−169 (3)
C51—P2—C41—C42	−48.9 (2)	C12'—C11'—N2'—Ag	6 (6)
C61ⁱ—P2—C41—C42	−157.5 (2)	N1—Ag—N2'—C10'	178 (5)
Ag—P2—C41—C42	76.5 (2)	P2—Ag—N2'—C10'	66 (4)
C46—C41—C42—C43	−0.5 (4)	N1'—Ag—N2'—C10'	177 (5)
P2—C41—C42—C43	−176.0 (2)	P1—Ag—N2'—C10'	−82 (4)
C41—C42—C43—C44	−0.7 (5)	N2—Ag—N2'—C10'	−15 (11)
C42—C43—C44—C45	1.2 (5)	N1—Ag—N2'—C11'	−7 (3)
C43—C44—C45—C46	−0.4 (5)	P2—Ag—N2'—C11'	−119 (4)
C42—C41—C46—C45	1.3 (4)	N1'—Ag—N2'—C11'	−8 (4)
P2—C41—C46—C45	176.5 (2)	P1—Ag—N2'—C11'	93 (4)
C44—C45—C46—C41	−0.8 (5)	N2—Ag—N2'—C11'	160 (17)
C41—P2—C51—C52	114.9 (3)	C5'—C6'—N3'—O2'	−156 (3)
C61ⁱ—P2—C51—C52	−136.2 (2)	C7'—C6'—N3'—O2'	23 (4)
Ag—P2—C51—C52	−1.6 (3)	C5'—C6'—N3'—O1'	16 (5)
C41—P2—C51—C56	−62.7 (3)	C7'—C6'—N3'—O1'	−166 (4)

Symmetry code: (i) −x, −y, −z+2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C35—H35A···F4ⁱⁱ	0.93	2.54	3.409 (4)	155
C46—H46A···F5	0.93	2.50	3.398 (4)	163

Symmetry code: (ii) −x−1/2, y−1/2, −z+5/2.

Experimental details

Crystal data
Chemical formula	[Ag₂(C₁₂H₇N₃O₂)₂(C₂₅H₂₂P₂)₂](SbF₆)₂
M_r	1906.38
Crystal system, space group	Monoclinic, P2₁/n
Temperature (K)	293
a, b, c (Å)	12.8034 (7), 23.3993 (10), 13.5580 (11)
β (°)	117.936 (2)
V (Å³)	3588.5 (4)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	1.46
Crystal size (mm)	0.35 × 0.35 × 0.28

Data collection
Diffractometer	Rigaku Mercury 70 CCD
Absorption correction	Multi-scan (CrystalClear; Rigaku, 2000)
T_min, T_max	0.816, 1.000
No. of measured, independent and observed [I > 2σ(I)] reflections	22441, 6301, 5851
R_int	0.026
(sin θ/λ)_max (Å⁻¹)	0.595

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.030, 0.060, 1.11
No. of reflections	6301
No. of parameters	623
No. of restraints	486
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.66, −0.70

Computer programs: CrystalClear (Rigaku, 2000), SHELXS97 (Sheldrick, 1997), SHELXL97 (Sheldrick, 1997), SHELXTL (Bruker, 1999).

Selected geometric parameters (Å, º) top

Ag—N1	2.392 (6)	Ag—P1	2.4491 (7)
Ag—P2	2.3982 (7)	Ag—N2	2.451 (5)

N1—Ag—P2	115.8 (3)	N1—Ag—N2	68.51 (15)
N1—Ag—P1	100.1 (3)	P2—Ag—N2	103.1 (2)
P2—Ag—P1	144.11 (3)	P1—Ag—N2	90.9 (2)

References

Bruker (1999). SHELXTL. Version 5.10. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Ho, D. M. & Bau, R. (1983). Inorg. Chem. 22, 4073–4079. CSD CrossRef CAS Web of Science Google Scholar
Rigaku (2000). CrystalClear. Version 1.3.6. Rigaku Corporation, Tokyo, Japan. Google Scholar
Sheldrick, G. M. (1997). SHELXS97 and SHELXL97. University of Göttingen, Germany. Google Scholar
Smith, G. F. & Cagle, F. W. M. (1947). J. Org. Chem. 12, 781–784. CrossRef PubMed CAS Web of Science Google Scholar

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