Aqua­bis(o-vanillinato-κ2O,O′)nickel(II)

Wang, Q.; Wang, D.-Q.

doi:10.1107/S1600536807068183

metal-organic compounds

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ISSN: 2056-9890

Volume 64| Part 2| February 2008| Page m298

doi:10.1107/S1600536807068183

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Aquabis(o-vanillinato-κ²O,O′)nickel(II)

Qiang Wang ^a and Da-Qi Wang ^a ^*

^aCollege of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China
^*Correspondence e-mail: wdq4899@163.com

(Received 11 November 2007; accepted 21 December 2007; online 4 January 2008)

The Ni^II atom in the title complex, aquabis(2-formyl-6-methoxyphenolato-κ²O,O′)nickel(II), [Ni(C₈H₇O₃)₂(H₂O)], is five-coordinated by four O atoms from two o-vanillinate ligands and one water molecule in a slightly distorted square-pyramidal geometry (τ = 0.06). In the crystal structure, the molecules are linked into dimers by intermolecular O—H⋯O hydrogen bonds.

Related literature

For general background, see: Meyer et al. (1982 ); Soules et al. (1988 ); Edwards et al. (1992 ); Asokan et al. (1998 ). For calculation of the τ parameter, see: Addison et al. (1984 ).

Experimental

Crystal data

[Ni(C₈H₇O₃)₂(H₂O)]
M_r = 379.00
Monoclinic, P 2₁ /c
a = 9.4569 (14) Å
b = 15.8320 (19) Å
c = 11.1372 (18) Å
β = 97.729 (2)°
V = 1652.3 (4) Å³
Z = 4
Mo Kα radiation
μ = 1.21 mm⁻¹
T = 298 (2) K
0.43 × 0.40 × 0.15 mm

Data collection

Siemens SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ) T_min = 0.625, T_max = 0.840
8178 measured reflections
2909 independent reflections
1462 reflections with I > 2σ(I)
R_int = 0.083

Refinement

R[F² > 2σ(F²)] = 0.061
wR(F²) = 0.157
S = 1.00
2909 reflections
199 parameters
3 restraints
H-atom parameters constrained
Δρ_max = 0.54 e Å⁻³
Δρ_min = −1.08 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O7—H2⋯O2ⁱ	0.85	2.21	2.899 (5)	139
O7—H2⋯O3ⁱ	0.85	2.21	2.929 (6)	143
O7—H3⋯O5ⁱ	0.85	2.17	2.907 (5)	146
O7—H3⋯O6ⁱ	0.85	2.25	2.906 (5)	134
Symmetry code: (i) -x+1, -y+2, -z+1.

Data collection: SMART (Siemens, 1996 ); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 1997 ); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536807068183/bv2085sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536807068183/bv2085Isup2.hkl

checkCIF report

Comment top

The structural and magnetic properties of binuclear and polymetallic nickel(II) complexes with various bridging ligands have received considerable attention in the past three decades (Meyer et al., 1982; Soules et al., 1988; Edwards et al., 1992; Asokan et al., 1998). In this paper, we report here the synthesis and crystal structure of the title complex, a new nickel complex.

The molecular structure of the title complex, (I), is shown in Fig.1. The Ni^II atom is five-coordinated in which four oxygen O(1), O(2), O(4), O(5) atoms from two o-vanillin ligands and one water molecule in a slightly distorted square pyramidal geometry, the tau value is 0.06 (Addison et al., 1984). NI(1), O(1), C(1), C(2), C(3), O(2) and Ni(1),O(4), C(9), C(10), C(11), O(5) form two six-membered chelating rings, which are essentially coplanar with a dihedral angle of 6.7 (0.19)°.

As seen in Fig. 2, the molecules are linked into dimers by intermolecular O—H···O hydrogen bonds (Table 1).

Related literature top

For general background, see: Meyer et al. (1982); Soules et al. (1988); Edwards et al. (1992); Asokan et al. (1998). For calculation of τ parameter, see: Addison et al. 1984.

Experimental top

Amounts of 304.3 mg (2 mmol) of o-vanillin and 80.00 mg (2 mmol) of NaOH were stirred into 30 ml absolute ethanol under room room temperature for 20 minutes, nickel chloride hexahydrate in the amount of 237.7 mg (1 mmol) was added, and the mixture was heated with stirring for 7 h and then filtered. The well shaped green polyhedral crystals of [Ni (C₈H₇O₃)₂H₂O] for structure determination and characterization were separated from the mother liquor by slow evaporation at room temperature after two weeks.

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 1997); software used to prepare material for publication: SHELXTL (Sheldrick, 1997).

Figures top

	Fig. 1. The structure of the title complex, showing 30% probability displacement ellipsoids and the atom-numbering scheme.
	Fig. 2. The crystal packing of the title compound, viewed approximately along the bc plane.

aquabis(2-formyl-6-methoxyphenolato-κ²O,O')nickel(II) top

Crystal data top

[Ni(C₈H₇O₃)₂(H₂O)]	F(000) = 784
M_r = 379.00	D_x = 1.524 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 1614 reflections
a = 9.4569 (14) Å	θ = 2.5–27.7°
b = 15.8320 (19) Å	µ = 1.21 mm⁻¹
c = 11.1372 (18) Å	T = 298 K
β = 97.729 (2)°	Block, green
V = 1652.3 (4) Å³	0.43 × 0.40 × 0.15 mm
Z = 4

Data collection top

Siemens SMART CCD area-detector diffractometer	2909 independent reflections
Radiation source: fine-focus sealed tube	1462 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.083
ϕ and ω scans	θ_max = 25.0°, θ_min = 2.2°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −11→11
T_min = 0.625, T_max = 0.840	k = −10→18
8178 measured reflections	l = −13→12

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.062	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.157	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.0683P)²] where P = (F_o² + 2F_c²)/3
2909 reflections	(Δ/σ)_max < 0.001
199 parameters	Δρ_max = 0.54 e Å⁻³
3 restraints	Δρ_min = −1.09 e Å⁻³

Crystal data top

[Ni(C₈H₇O₃)₂(H₂O)]	V = 1652.3 (4) Å³
M_r = 379.00	Z = 4
Monoclinic, P2₁/c	Mo Kα radiation
a = 9.4569 (14) Å	µ = 1.21 mm⁻¹
b = 15.8320 (19) Å	T = 298 K
c = 11.1372 (18) Å	0.43 × 0.40 × 0.15 mm
β = 97.729 (2)°

Data collection top

Siemens SMART CCD area-detector diffractometer	2909 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	1462 reflections with I > 2σ(I)
T_min = 0.625, T_max = 0.840	R_int = 0.083
8178 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.062	3 restraints
wR(F²) = 0.157	H-atom parameters constrained
S = 1.00	Δρ_max = 0.54 e Å⁻³
2909 reflections	Δρ_min = −1.09 e Å⁻³
199 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Ni1	0.67982 (8)	0.96568 (5)	0.38774 (6)	0.0453 (3)
O1	0.8808 (4)	0.9428 (2)	0.4415 (3)	0.0453 (3)
O2	0.6193 (4)	0.8834 (2)	0.4980 (3)	0.0513 (11)
O3	0.4899 (6)	0.7887 (3)	0.6400 (4)	0.0692 (14)
O4	0.7481 (4)	1.0350 (2)	0.2593 (3)	0.0453 (3)
O5	0.4873 (4)	0.9690 (2)	0.3093 (3)	0.0496 (11)
O6	0.2167 (5)	0.9542 (3)	0.2415 (4)	0.0608 (12)
O7	0.6836 (4)	1.0859 (2)	0.5067 (3)	0.0453 (3)
H2	0.6050	1.1043	0.4699	0.068*
H3	0.6619	1.0821	0.5782	0.068*
C1	0.9283 (7)	0.8990 (4)	0.5329 (6)	0.0616 (19)
H1	1.0270	0.8976	0.5528	0.074*
C2	0.8499 (7)	0.8524 (4)	0.6073 (6)	0.0543 (18)
C3	0.7005 (7)	0.8465 (4)	0.5862 (6)	0.0475 (16)
C4	0.6359 (9)	0.7939 (4)	0.6677 (6)	0.0586 (19)
C5	0.7127 (11)	0.7527 (5)	0.7618 (7)	0.082 (3)
H5	0.6664	0.7188	0.8126	0.098*
C6	0.8604 (11)	0.7610 (5)	0.7822 (8)	0.090 (3)
H6	0.9123	0.7333	0.8474	0.108*
C7	0.9297 (9)	0.8095 (5)	0.7074 (7)	0.075 (2)
H7	1.0285	0.8147	0.7214	0.090*
C8	0.4138 (9)	0.7343 (4)	0.7120 (7)	0.093 (3)
H8A	0.4531	0.6784	0.7123	0.139*
H8B	0.3149	0.7327	0.6783	0.139*
H8C	0.4225	0.7554	0.7935	0.139*
C9	0.6688 (7)	1.0686 (4)	0.1745 (5)	0.0551 (17)
H9	0.7142	1.1025	0.1231	0.066*
C10	0.5204 (7)	1.0624 (4)	0.1462 (5)	0.0465 (16)
C11	0.4375 (7)	1.0112 (3)	0.2125 (5)	0.0419 (15)
C12	0.2881 (7)	1.0062 (4)	0.1720 (6)	0.0490 (16)
C13	0.2275 (8)	1.0497 (4)	0.0718 (6)	0.0614 (19)
H13	0.1302	1.0444	0.0462	0.074*
C14	0.3087 (9)	1.1010 (4)	0.0087 (6)	0.071 (2)
H14	0.2659	1.1308	−0.0585	0.086*
C15	0.4511 (9)	1.1083 (4)	0.0442 (6)	0.064 (2)
H15	0.5047	1.1438	0.0014	0.077*
C16	0.0696 (7)	0.9382 (5)	0.2025 (7)	0.088 (3)
H16A	0.0191	0.9909	0.1918	0.132*
H16B	0.0309	0.9050	0.2625	0.132*
H16C	0.0594	0.9081	0.1271	0.132*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ni1	0.0487 (5)	0.0459 (5)	0.0406 (5)	−0.0023 (4)	0.0037 (3)	0.0054 (4)
O1	0.0487 (5)	0.0459 (5)	0.0406 (5)	−0.0023 (4)	0.0037 (3)	0.0054 (4)
O2	0.058 (3)	0.050 (2)	0.044 (3)	0.012 (2)	−0.001 (2)	0.014 (2)
O3	0.092 (4)	0.050 (3)	0.069 (3)	−0.006 (3)	0.026 (3)	0.013 (2)
O4	0.0487 (5)	0.0459 (5)	0.0406 (5)	−0.0023 (4)	0.0037 (3)	0.0054 (4)
O5	0.055 (3)	0.048 (2)	0.045 (2)	−0.005 (2)	0.003 (2)	0.012 (2)
O6	0.051 (3)	0.074 (3)	0.055 (3)	−0.011 (3)	0.001 (2)	0.005 (2)
O7	0.0487 (5)	0.0459 (5)	0.0406 (5)	−0.0023 (4)	0.0037 (3)	0.0054 (4)
C1	0.054 (5)	0.065 (5)	0.060 (5)	0.010 (4)	−0.013 (4)	0.001 (4)
C2	0.062 (5)	0.048 (4)	0.052 (4)	0.018 (4)	0.002 (4)	0.002 (3)
C3	0.063 (5)	0.039 (4)	0.041 (4)	0.010 (3)	0.010 (4)	−0.007 (3)
C4	0.091 (6)	0.040 (4)	0.046 (4)	0.008 (4)	0.014 (4)	0.001 (3)
C5	0.135 (8)	0.061 (5)	0.052 (5)	0.020 (5)	0.017 (5)	0.013 (4)
C6	0.113 (8)	0.075 (6)	0.080 (6)	0.036 (6)	0.008 (6)	0.004 (5)
C7	0.075 (6)	0.083 (6)	0.063 (5)	0.023 (5)	−0.008 (4)	0.007 (5)
C8	0.137 (8)	0.058 (5)	0.094 (6)	−0.015 (5)	0.051 (6)	0.007 (4)
C9	0.059 (5)	0.057 (4)	0.049 (4)	−0.004 (4)	0.007 (4)	0.006 (3)
C10	0.059 (5)	0.040 (3)	0.039 (4)	0.004 (3)	0.001 (3)	0.005 (3)
C11	0.056 (5)	0.034 (3)	0.034 (4)	0.002 (3)	0.000 (3)	−0.003 (3)
C12	0.056 (5)	0.045 (4)	0.046 (4)	0.000 (3)	0.003 (4)	−0.002 (3)
C13	0.068 (5)	0.068 (5)	0.045 (4)	0.009 (4)	−0.005 (4)	0.009 (4)
C14	0.090 (6)	0.063 (5)	0.055 (5)	0.007 (5)	−0.015 (4)	0.011 (4)
C15	0.092 (6)	0.052 (4)	0.047 (4)	−0.008 (4)	0.008 (4)	0.004 (3)
C16	0.047 (5)	0.122 (7)	0.092 (6)	−0.008 (5)	0.001 (4)	0.012 (5)

Geometric parameters (Å, º) top

Ni1—O5	1.912 (4)	C5—H5	0.9300
Ni1—O2	1.929 (4)	C6—C7	1.364 (10)
Ni1—O1	1.949 (4)	C6—H6	0.9300
Ni1—O4	1.978 (4)	C7—H7	0.9300
Ni1—O7	2.316 (3)	C8—H8A	0.9600
O1—C1	1.263 (7)	C8—H8B	0.9600
O2—C3	1.301 (7)	C8—H8C	0.9600
O3—C4	1.377 (8)	C9—C10	1.400 (8)
O3—C8	1.434 (7)	C9—H9	0.9300
O4—C9	1.244 (6)	C10—C11	1.405 (8)
O5—C11	1.302 (6)	C10—C15	1.431 (8)
O6—C12	1.369 (7)	C11—C12	1.426 (8)
O6—C16	1.423 (7)	C12—C13	1.370 (8)
O7—H2	0.8502	C13—C14	1.375 (9)
O7—H3	0.8502	C13—H13	0.9300
C1—C2	1.395 (9)	C14—C15	1.357 (9)
C1—H1	0.9300	C14—H14	0.9300
C2—C3	1.404 (8)	C15—H15	0.9300
C2—C7	1.431 (9)	C16—H16A	0.9600
C3—C4	1.428 (8)	C16—H16B	0.9600
C4—C5	1.359 (9)	C16—H16C	0.9600
C5—C6	1.391 (10)

O5—Ni1—O2	87.93 (16)	C6—C7—C2	119.8 (8)
O5—Ni1—O1	167.31 (16)	C6—C7—H7	120.1
O2—Ni1—O1	92.25 (16)	C2—C7—H7	120.1
O5—Ni1—O4	92.17 (16)	O3—C8—H8A	109.5
O2—Ni1—O4	171.17 (16)	O3—C8—H8B	109.5
O1—Ni1—O4	85.73 (16)	H8A—C8—H8B	109.5
O5—Ni1—O7	100.30 (15)	O3—C8—H8C	109.5
O2—Ni1—O7	99.99 (14)	H8A—C8—H8C	109.5
O1—Ni1—O7	92.17 (14)	H8B—C8—H8C	109.5
O4—Ni1—O7	88.68 (14)	O4—C9—C10	128.7 (6)
C1—O1—Ni1	125.2 (4)	O4—C9—H9	115.7
C3—O2—Ni1	126.1 (4)	C10—C9—H9	115.7
C4—O3—C8	118.3 (6)	C9—C10—C11	122.4 (6)
C9—O4—Ni1	124.3 (4)	C9—C10—C15	118.8 (6)
C11—O5—Ni1	127.5 (4)	C11—C10—C15	118.8 (6)
C12—O6—C16	118.1 (5)	O5—C11—C10	124.5 (6)
Ni1—O7—H2	93.5	O5—C11—C12	117.7 (5)
Ni1—O7—H3	119.4	C10—C11—C12	117.8 (6)
H2—O7—H3	99.8	O6—C12—C13	125.4 (6)
O1—C1—C2	127.6 (6)	O6—C12—C11	113.5 (5)
O1—C1—H1	116.2	C13—C12—C11	121.2 (6)
C2—C1—H1	116.2	C12—C13—C14	120.8 (7)
C1—C2—C3	122.6 (6)	C12—C13—H13	119.6
C1—C2—C7	116.6 (7)	C14—C13—H13	119.6
C3—C2—C7	120.8 (7)	C15—C14—C13	120.2 (7)
O2—C3—C2	125.1 (6)	C15—C14—H14	119.9
O2—C3—C4	118.8 (6)	C13—C14—H14	119.9
C2—C3—C4	116.1 (6)	C14—C15—C10	121.2 (6)
C5—C4—O3	124.0 (7)	C14—C15—H15	119.4
C5—C4—C3	122.7 (8)	C10—C15—H15	119.4
O3—C4—C3	113.2 (6)	O6—C16—H16A	109.5
C4—C5—C6	120.0 (8)	O6—C16—H16B	109.5
C4—C5—H5	120.0	H16A—C16—H16B	109.5
C6—C5—H5	120.0	O6—C16—H16C	109.5
C7—C6—C5	120.6 (8)	H16A—C16—H16C	109.5
C7—C6—H6	119.7	H16B—C16—H16C	109.5
C5—C6—H6	119.7

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O7—H2···O2ⁱ	0.85	2.21	2.899 (5)	139
O7—H2···O3ⁱ	0.85	2.21	2.929 (6)	143
O7—H3···O5ⁱ	0.85	2.17	2.907 (5)	146
O7—H3···O6ⁱ	0.85	2.25	2.906 (5)	134

Symmetry code: (i) −x+1, −y+2, −z+1.

Experimental details

Crystal data
Chemical formula	[Ni(C₈H₇O₃)₂(H₂O)]
M_r	379.00
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	298
a, b, c (Å)	9.4569 (14), 15.8320 (19), 11.1372 (18)
β (°)	97.729 (2)
V (Å³)	1652.3 (4)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	1.21
Crystal size (mm)	0.43 × 0.40 × 0.15

Data collection
Diffractometer	Siemens SMART CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Sheldrick, 1996)
T_min, T_max	0.625, 0.840
No. of measured, independent and observed [I > 2σ(I)] reflections	8178, 2909, 1462
R_int	0.083
(sin θ/λ)_max (Å⁻¹)	0.595

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.062, 0.157, 1.00
No. of reflections	2909
No. of parameters	199
No. of restraints	3
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.54, −1.09

Computer programs: SMART (Siemens, 1996), SAINT (Siemens, 1996), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 1997).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O7—H2···O2ⁱ	0.85	2.21	2.899 (5)	138.5
O7—H2···O3ⁱ	0.85	2.21	2.929 (6)	142.6
O7—H3···O5ⁱ	0.85	2.17	2.907 (5)	145.7
O7—H3···O6ⁱ	0.85	2.25	2.906 (5)	134.0

Symmetry code: (i) −x+1, −y+2, −z+1.

Acknowledgements

The authors acknowledge the financial support of the Shandong Province Science Foundation, and the State Key Laboratory of Crystalline Materials, Shandong University, People's Republic of China.

References

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