catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]

Tan, Y.-H.; Li, Y.; Ji, F.-M.; Xiong, T.-T.; Xia, L.-B.

doi:10.1107/S1600536807067827

metal-organic compounds

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ISSN: 2056-9890

Volume 64| Part 2| February 2008| Page m274

doi:10.1107/S1600536807067827

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catena-Poly[[tetraaquacobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]

Yu-Hui Tan,^a ^* Yin-bao Li,^a Fa-Ming Ji,^b Ting-Ting Xiong ^b and Li-Bin Xia ^b

^aDepartment of Pharmacy, Gannan Medical University, Ganzhou 341000, People's Republic of China, and ^bDepartment of Materials and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, People's Republic of China
^*Correspondence e-mail: tyxcn@163.com

(Received 19 November 2007; accepted 19 December 2007; online 4 January 2008)

In the title compound, [Co(C₁₄H₈N₂O₆)(H₂O)₄]_n, each 5,5′-diazenediylbis(2-hydroxybenzoato) ligand acts as a dicarboxylate bridge, leading to the formation of polymeric chains running in the [ $[\overline{1}]$ 10] direction. The Co atom is hexacoordinated in a distorted octahedral geometry by six O atoms [Co—O = 2.039 (4)–2.115 (4) Å] from two ligands and four water molecules. Intermolecular O—H⋯O and O—H⋯N hydrogen bonds build up a three-dimensional supramolecular structure.

Related literature

For related literature, see: Klotz (2005 ); Tang, Tan & Cao (2007 ); Tang, Tan, Chen et al. (2007 ); Tang, Yang et al. (2007 ); Riordan & Blair (1979 ).

Experimental

Crystal data

[Co(C₁₄H₈N₂O₆)(H₂O)₄]
M_r = 431.22
Monoclinic, P 2₁ /c
a = 9.5152 (14) Å
b = 11.2452 (17) Å
c = 16.194 (2) Å
β = 106.687 (2)°
V = 1659.8 (4) Å³
Z = 4
Mo Kα radiation
μ = 1.09 mm⁻¹
T = 296 (2) K
0.10 × 0.08 × 0.08 mm

Data collection

Bruker SMART APEX CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2000 ) T_min = 0.898, T_max = 0.917
11094 measured reflections
3427 independent reflections
1976 reflections with I > 2σ(I)
R_int = 0.062

Refinement

R[F² > 2σ(F²)] = 0.049
wR(F²) = 0.133
S = 0.94
3427 reflections
246 parameters
H-atom parameters constrained
Δρ_max = 0.50 e Å⁻³
Δρ_min = −0.44 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1WA⋯O6ⁱ	0.82	1.89	2.667 (5)	157
O1W—H1WB⋯N1ⁱⁱ	0.82	2.08	2.871 (5)	161
O2W—H2WA⋯O2	0.82	1.84	2.629 (5)	161
O3W—H3WA⋯O2ⁱ	0.82	1.88	2.682 (4)	167
O3W—H3WB⋯O4ⁱⁱⁱ	0.81	2.23	2.899 (5)	141
O4W—H4WA⋯N2ⁱ	0.82	2.35	3.074 (5)	148
O4W—H4WB⋯O6^iv	0.82	1.88	2.665 (4)	159
O3—H3A⋯O1	0.82	1.80	2.521 (5)	147
O4—H4A⋯O5	0.82	1.82	2.541 (4)	147
Symmetry codes: (i) $[-x+1, y-{\script{1\over 2}}, -z+{\script{1\over 2}}]$ ; (ii) -x+1, -y+1, -z; (iii) -x, -y+1, -z; (iv) x+1, y-1, z.

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003 ); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536807067827/dn2293sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536807067827/dn2293Isup2.hkl

checkCIF report

Comment top

Olsalazine - 3,3-azobis(6-hydroxybenzoic acid) - has been widely used to prevent and treat the inflammatory bowel diseases, such as ulcerative colitis (Klotz, 2005). In previous work, we have synthesized a serial of Zn (Tang, Tan, Chen & Cao, 2007), Cd and Co (Tang, Yang et al., 2007) complexes with phenanthroline as auxiliary ligand. Also we have reported a Mn complex of olsalazine(Tang, Tan & Cao, 2007), however the cobalt complex with single olsalazine as building block have not been reported yet, Here we reported the crystal structure of the title compound, (I)- a new cobalt complex of olsalazine.

In (I), the Co atom is hexacoordinated (Fig. 1) by two O atoms from two L ligands (H₂L=3,3-azo-bis(6-hydroxybenzoic acid)) cis to each other and four water molecules in a distorted octahedral geometry. Each ligand L acts as a carboxylate bridge, that leads to the formation of polymeric chain running in the [-110] direction. Intermolecular O—H···O and O—H···N hydrogen bonds build up a three dimensional supramolecular structure (Table 1).

Related literature top

For related literature, see: Klotz (2005); Tang, Tan & Cao (2007); Tang, Tan, Chen et al. (2007); Tang, Yang et al. (2007); Riordan & Blair (1979).

Computing details top

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT (Bruker, 2000); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: SHELXL97 (Sheldrick, 1997).

Figures top

Fig. 1. Partial view of the polymeric chain in (I), showing the atom-labelling-scheme. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity. [Symmetry codes: (i) x + 1, y - 1, z; (ii) x - 1, y + 1, z]

catena-Poly[[tetraaquacobalt(II)]-µ-2,2'-dihydroxy-5,5'- diazenediyldibenzoato] top

Crystal data top

[Co(C₁₄H₈N₂O₆)(H₂O)₄]	F(000) = 884
M_r = 431.22	D_x = 1.726 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 935 reflections
a = 9.5152 (14) Å	θ = 2.2–26°
b = 11.2452 (17) Å	µ = 1.10 mm⁻¹
c = 16.194 (2) Å	T = 296 K
β = 106.687 (2)°	Block, red
V = 1659.8 (4) Å³	0.10 × 0.08 × 0.08 mm
Z = 4

Data collection top

Bruker SMART APEX CCD area-detector diffractometer	3427 independent reflections
Radiation source: fine-focus sealed tube	1976 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.062
ϕ and ω scans	θ_max = 26.4°, θ_min = 1.8°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −11→11
T_min = 0.898, T_max = 0.918	k = −14→14
11094 measured reflections	l = −19→20

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.049	H-atom parameters constrained
wR(F²) = 0.133	w = 1/[σ²(F_o²) + (0.0717P)²] where P = (F_o² + 2F_c²)/3
S = 0.94	(Δ/σ)_max = 0.001
3427 reflections	Δρ_max = 0.50 e Å⁻³
246 parameters	Δρ_min = −0.44 e Å⁻³
0 restraints	Extinction correction: SHELXL97 (Sheldrick, 1997), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0050 (11)

Crystal data top

[Co(C₁₄H₈N₂O₆)(H₂O)₄]	V = 1659.8 (4) Å³
M_r = 431.22	Z = 4
Monoclinic, P2₁/c	Mo Kα radiation
a = 9.5152 (14) Å	µ = 1.10 mm⁻¹
b = 11.2452 (17) Å	T = 296 K
c = 16.194 (2) Å	0.10 × 0.08 × 0.08 mm
β = 106.687 (2)°

Data collection top

Bruker SMART APEX CCD area-detector diffractometer	3427 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 2000)	1976 reflections with I > 2σ(I)
T_min = 0.898, T_max = 0.918	R_int = 0.062
11094 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.049	0 restraints
wR(F²) = 0.133	H-atom parameters constrained
S = 0.94	Δρ_max = 0.50 e Å⁻³
3427 reflections	Δρ_min = −0.44 e Å⁻³
246 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Co1	0.71433 (7)	0.14001 (5)	0.21254 (4)	0.0333 (2)
O1W	0.8824 (4)	0.2527 (3)	0.2134 (2)	0.0515 (9)
H1WA	0.9251	0.3002	0.2506	0.077*
H1WB	0.8799	0.2780	0.1654	0.077*
O2W	0.6621 (4)	0.2503 (3)	0.3053 (2)	0.0537 (10)
H2WA	0.5912	0.2842	0.2726	0.080*
H2WB	0.6352	0.2127	0.3415	0.080*
O3W	0.5405 (4)	0.0277 (3)	0.2068 (2)	0.0575 (10)
H3WA	0.5494	−0.0263	0.2418	0.086*
H3WB	0.5144	0.0028	0.1579	0.086*
O4W	0.8418 (4)	0.0398 (3)	0.31539 (19)	0.0455 (9)
H4WA	0.8933	0.0663	0.3610	0.068*
H4WB	0.8900	−0.0006	0.2912	0.068*
N2	0.0915 (4)	0.6415 (3)	0.0012 (2)	0.0366 (9)
N1	0.1224 (4)	0.6059 (3)	−0.0651 (2)	0.0374 (10)
O1	0.5775 (4)	0.2345 (3)	0.10743 (19)	0.0402 (8)
O2	0.4732 (4)	0.3607 (3)	0.1776 (2)	0.0542 (10)
O3	0.5168 (4)	0.2395 (3)	−0.0547 (2)	0.0609 (11)
H3A	0.5587	0.2174	−0.0055	0.091*
O4	−0.3150 (4)	1.0087 (3)	−0.0450 (2)	0.0533 (10)
H4A	−0.3126	1.0395	0.0012	0.080*
O5	−0.2290 (4)	1.0400 (3)	0.1171 (2)	0.0455 (9)
O6	−0.0537 (4)	0.9267 (3)	0.2009 (2)	0.0637 (12)
C1	0.4906 (5)	0.3199 (4)	0.1097 (3)	0.0358 (11)
C2	0.4027 (5)	0.3698 (4)	0.0249 (3)	0.0326 (10)
C3	0.4191 (6)	0.3262 (4)	−0.0520 (3)	0.0399 (12)
C4	0.3349 (6)	0.3724 (4)	−0.1303 (3)	0.0523 (15)
H4	0.3427	0.3408	−0.1819	0.063*
C5	0.2420 (5)	0.4632 (4)	−0.1309 (3)	0.0441 (13)
H5	0.1885	0.4954	−0.1835	0.053*
C6	0.2240 (5)	0.5101 (4)	−0.0547 (3)	0.0346 (11)
C7	0.3054 (5)	0.4617 (4)	0.0228 (3)	0.0356 (11)
H7	0.2944	0.4914	0.0742	0.043*
C8	−0.0120 (5)	0.7371 (4)	−0.0142 (3)	0.0348 (11)
C9	−0.1058 (5)	0.7662 (4)	−0.0956 (3)	0.0414 (12)
H9	−0.1024	0.7229	−0.1439	0.050*
C10	−0.2027 (6)	0.8587 (4)	−0.1037 (3)	0.0446 (12)
H10	−0.2621	0.8798	−0.1580	0.054*
C11	−0.2134 (5)	0.9212 (4)	−0.0320 (3)	0.0386 (12)
C12	−0.1231 (5)	0.8923 (4)	0.0500 (3)	0.0351 (11)
C13	−0.0236 (6)	0.8005 (4)	0.0566 (3)	0.0419 (12)
H13	0.0377	0.7808	0.1108	0.050*
C14	−0.1338 (5)	0.9566 (4)	0.1286 (3)	0.0403 (12)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Co1	0.0379 (4)	0.0295 (3)	0.0312 (3)	0.0035 (3)	0.0078 (3)	0.0014 (3)
O1W	0.060 (2)	0.055 (2)	0.0364 (19)	−0.0171 (19)	0.0088 (17)	−0.0010 (17)
O2W	0.061 (3)	0.060 (2)	0.040 (2)	0.023 (2)	0.0160 (18)	0.0057 (17)
O3W	0.054 (2)	0.061 (2)	0.047 (2)	−0.015 (2)	−0.0007 (17)	0.0173 (19)
O4W	0.054 (2)	0.044 (2)	0.0359 (18)	0.0113 (17)	0.0085 (16)	−0.0011 (15)
N2	0.042 (2)	0.0304 (19)	0.035 (2)	0.0096 (19)	0.0072 (18)	0.0031 (19)
N1	0.039 (3)	0.036 (2)	0.038 (2)	0.0101 (18)	0.0122 (18)	0.0017 (17)
O1	0.048 (2)	0.0362 (18)	0.0361 (18)	0.0122 (16)	0.0121 (16)	0.0027 (15)
O2	0.070 (3)	0.055 (2)	0.0340 (18)	0.028 (2)	0.0094 (18)	−0.0057 (17)
O3	0.080 (3)	0.062 (2)	0.042 (2)	0.045 (2)	0.019 (2)	0.0083 (18)
O4	0.061 (2)	0.052 (2)	0.0403 (19)	0.0296 (19)	0.0029 (17)	−0.0053 (17)
O5	0.054 (2)	0.0407 (19)	0.0385 (19)	0.0189 (18)	0.0075 (16)	−0.0045 (16)
O6	0.079 (3)	0.067 (3)	0.035 (2)	0.043 (2)	0.0014 (19)	−0.0079 (19)
C1	0.039 (3)	0.030 (2)	0.037 (3)	0.004 (2)	0.008 (2)	0.004 (2)
C2	0.036 (3)	0.031 (2)	0.030 (2)	0.002 (2)	0.009 (2)	0.003 (2)
C3	0.043 (3)	0.035 (3)	0.045 (3)	0.014 (2)	0.018 (2)	0.000 (2)
C4	0.071 (4)	0.052 (3)	0.033 (3)	0.025 (3)	0.014 (3)	0.003 (3)
C5	0.050 (3)	0.045 (3)	0.035 (3)	0.017 (3)	0.008 (2)	0.006 (2)
C6	0.041 (3)	0.028 (2)	0.035 (3)	0.007 (2)	0.012 (2)	0.001 (2)
C7	0.043 (3)	0.031 (2)	0.037 (3)	0.003 (2)	0.017 (2)	0.004 (2)
C8	0.036 (3)	0.030 (2)	0.039 (3)	0.010 (2)	0.012 (2)	0.001 (2)
C9	0.045 (3)	0.047 (3)	0.031 (3)	0.010 (2)	0.009 (2)	−0.005 (2)
C10	0.055 (3)	0.048 (3)	0.026 (2)	0.015 (3)	0.004 (2)	0.004 (2)
C11	0.041 (3)	0.033 (2)	0.039 (3)	0.006 (2)	0.006 (2)	0.001 (2)
C12	0.037 (3)	0.032 (3)	0.033 (2)	0.005 (2)	0.004 (2)	−0.0027 (19)
C13	0.050 (3)	0.037 (3)	0.034 (3)	0.014 (2)	0.003 (2)	−0.002 (2)
C14	0.038 (3)	0.039 (3)	0.038 (3)	0.012 (2)	0.003 (2)	−0.002 (2)

Geometric parameters (Å, º) top

Co1—O1W	2.037 (3)	O5—C14	1.280 (5)
Co1—O3W	2.062 (3)	O5—Co1ⁱⁱ	2.103 (3)
Co1—O4W	2.087 (3)	O6—C14	1.245 (5)
Co1—O5ⁱ	2.103 (3)	C1—C2	1.497 (6)
Co1—O1	2.110 (3)	C2—C7	1.381 (6)
Co1—O2W	2.115 (3)	C2—C3	1.388 (6)
O1W—H1WA	0.8195	C3—C4	1.391 (7)
O1W—H1WB	0.8219	C4—C5	1.349 (6)
O2W—H2WA	0.8220	C4—H4	0.9300
O2W—H2WB	0.8212	C5—C6	1.397 (6)
O3W—H3WA	0.8183	C5—H5	0.9300
O3W—H3WB	0.8089	C6—C7	1.383 (6)
O4W—H4WA	0.8158	C7—H7	0.9300
O4W—H4WB	0.8205	C8—C13	1.383 (6)
N2—N1	1.257 (5)	C8—C9	1.401 (6)
N2—C8	1.430 (6)	C9—C10	1.371 (6)
N1—C6	1.426 (6)	C9—H9	0.9300
O1—C1	1.275 (5)	C10—C11	1.385 (6)
O2—C1	1.245 (5)	C10—H10	0.9300
O3—C3	1.357 (5)	C11—C12	1.398 (6)
O3—H3A	0.8200	C12—C13	1.383 (6)
O4—C11	1.353 (5)	C12—C14	1.493 (6)
O4—H4A	0.8200	C13—H13	0.9300

O1W—Co1—O3W	177.81 (14)	C3—C2—C1	120.9 (4)
O1W—Co1—O4W	93.15 (13)	O3—C3—C2	122.5 (4)
O3W—Co1—O4W	88.88 (13)	O3—C3—C4	117.4 (4)
O1W—Co1—O5ⁱ	88.37 (14)	C2—C3—C4	120.2 (4)
O3W—Co1—O5ⁱ	90.63 (15)	C5—C4—C3	119.6 (4)
O4W—Co1—O5ⁱ	94.86 (12)	C5—C4—H4	120.2
O1W—Co1—O1	89.64 (14)	C3—C4—H4	120.2
O3W—Co1—O1	88.33 (13)	C4—C5—C6	121.7 (4)
O4W—Co1—O1	177.14 (13)	C4—C5—H5	119.2
O5ⁱ—Co1—O1	84.59 (12)	C6—C5—H5	119.2
O1W—Co1—O2W	88.52 (15)	C7—C6—C5	118.3 (4)
O3W—Co1—O2W	92.42 (15)	C7—C6—N1	126.0 (4)
O4W—Co1—O2W	87.20 (13)	C5—C6—N1	115.6 (4)
O5ⁱ—Co1—O2W	176.36 (14)	C2—C7—C6	120.9 (4)
O1—Co1—O2W	93.49 (13)	C2—C7—H7	119.6
Co1—O1W—H1WA	129.4	C6—C7—H7	119.6
Co1—O1W—H1WB	113.6	C13—C8—C9	118.6 (4)
H1WA—O1W—H1WB	110.0	C13—C8—N2	117.2 (4)
Co1—O2W—H2WA	97.5	C9—C8—N2	124.1 (4)
Co1—O2W—H2WB	112.9	C10—C9—C8	119.8 (4)
H2WA—O2W—H2WB	109.5	C10—C9—H9	120.1
Co1—O3W—H3WA	120.1	C8—C9—H9	120.1
Co1—O3W—H3WB	105.9	C9—C10—C11	120.9 (4)
H3WA—O3W—H3WB	111.2	C9—C10—H10	119.5
Co1—O4W—H4WA	125.8	C11—C10—H10	119.5
Co1—O4W—H4WB	101.2	O4—C11—C10	117.4 (4)
H4WA—O4W—H4WB	111.2	O4—C11—C12	122.3 (4)
N1—N2—C8	114.1 (3)	C10—C11—C12	120.3 (4)
N2—N1—C6	117.2 (4)	C13—C12—C11	117.9 (4)
C1—O1—Co1	127.7 (3)	C13—C12—C14	120.5 (4)
C3—O3—H3A	109.5	C11—C12—C14	121.6 (4)
C11—O4—H4A	109.5	C8—C13—C12	122.5 (4)
C14—O5—Co1ⁱⁱ	127.3 (3)	C8—C13—H13	118.8
O2—C1—O1	123.7 (4)	C12—C13—H13	118.8
O2—C1—C2	119.4 (4)	O6—C14—O5	123.4 (4)
O1—C1—C2	116.9 (4)	O6—C14—C12	119.9 (4)
C7—C2—C3	119.3 (4)	O5—C14—C12	116.7 (4)
C7—C2—C1	119.8 (4)

Symmetry codes: (i) x+1, y−1, z; (ii) x−1, y+1, z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1WA···O6ⁱⁱⁱ	0.82	1.89	2.667 (5)	157
O1W—H1WB···N1^iv	0.82	2.08	2.871 (5)	161
O2W—H2WA···O2	0.82	1.84	2.629 (5)	161
O3W—H3WA···O2ⁱⁱⁱ	0.82	1.88	2.682 (4)	167
O3W—H3WB···O4^v	0.81	2.23	2.899 (5)	141
O4W—H4WA···N2ⁱⁱⁱ	0.82	2.35	3.074 (5)	148
O4W—H4WB···O6ⁱ	0.82	1.88	2.665 (4)	159
O3—H3A···O1	0.82	1.80	2.521 (5)	147
O4—H4A···O5	0.82	1.82	2.541 (4)	147

Symmetry codes: (i) x+1, y−1, z; (iii) −x+1, y−1/2, −z+1/2; (iv) −x+1, −y+1, −z; (v) −x, −y+1, −z.

Experimental details

Crystal data
Chemical formula	[Co(C₁₄H₈N₂O₆)(H₂O)₄]
M_r	431.22
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	296
a, b, c (Å)	9.5152 (14), 11.2452 (17), 16.194 (2)
β (°)	106.687 (2)
V (Å³)	1659.8 (4)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	1.10
Crystal size (mm)	0.10 × 0.08 × 0.08

Data collection
Diffractometer	Bruker SMART APEX CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Bruker, 2000)
T_min, T_max	0.898, 0.918
No. of measured, independent and observed [I > 2σ(I)] reflections	11094, 3427, 1976
R_int	0.062
(sin θ/λ)_max (Å⁻¹)	0.625

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.049, 0.133, 0.94
No. of reflections	3427
No. of parameters	246
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.50, −0.44

Computer programs: SMART (Bruker, 2000), SAINT (Bruker, 2000), SHELXS97 (Sheldrick, 1997), SHELXL97 (Sheldrick, 1997), PLATON (Spek, 2003).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1WA···O6ⁱ	0.82	1.89	2.667 (5)	156.9
O1W—H1WB···N1ⁱⁱ	0.82	2.08	2.871 (5)	161.4
O2W—H2WA···O2	0.82	1.84	2.629 (5)	161.4
O3W—H3WA···O2ⁱ	0.82	1.88	2.682 (4)	166.9
O3W—H3WB···O4ⁱⁱⁱ	0.81	2.23	2.899 (5)	140.6
O4W—H4WA···N2ⁱ	0.82	2.35	3.074 (5)	147.9
O4W—H4WB···O6^iv	0.82	1.88	2.665 (4)	159.1
O3—H3A···O1	0.82	1.80	2.521 (5)	146.6
O4—H4A···O5	0.82	1.82	2.541 (4)	146.6

Symmetry codes: (i) −x+1, y−1/2, −z+1/2; (ii) −x+1, −y+1, −z; (iii) −x, −y+1, −z; (iv) x+1, y−1, z.

Acknowledgements

This work was supported by the Gannan Medical University Masters Development Foundation.

References

Bruker (2000). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Klotz, U. (2005). Dig. Liver Dis. 37, 381–388. Web of Science CrossRef PubMed CAS Google Scholar
Riordan, J. E. & Blair, H. S. (1979). Polymer, 20, 196–202. CrossRef CAS Google Scholar
Sheldrick, G. M. (1997). SHELXS97 and SHELXL97. University of Göttingen, Germany. Google Scholar
Spek, A. L. (2003). J. Appl. Cryst. 36, 7–13. Web of Science CrossRef CAS IUCr Journals Google Scholar
Tang, Y.-Z., Tan, Y.-H. & Cao, Y.-W. (2007). Acta Cryst. E63, m1175–m1176. Web of Science CSD CrossRef IUCr Journals Google Scholar
Tang, Y. Z., Tan, Y. H., Chen, S. H. & Cao, Y. W. (2007). Z. Anorg. Allg. Chem. 633, 332–335. Web of Science CSD CrossRef CAS Google Scholar
Tang, Y. Z., Yang, S. P., Tan, Y. H., Chen, S. H., Cao, Y. W. & Wang, P. (2007). Chin. J. Inorg. Chem. 23, 70–74. CAS Google Scholar

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Volume 64| Part 2| February 2008| Page m274

doi:10.1107/S1600536807067827

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metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-di­hydroxy-5,5′-diazenediyldibenzoato]

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

Acknowledgements

References

metal-organic compounds

catena-Poly[[tetraaquacobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]