catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]

Yang, M.-H.

doi:10.1107/S1600536808031619

metal-organic compounds

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ISSN: 2056-9890

Volume 64| Part 11| November 2008| Page m1358

doi:10.1107/S1600536808031619

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catena-Poly[[[bis[aquanickel(II)]bis(μ-pyridine-2,6-dicarboxylato N-oxide)]-μ-1,2-di-4-pyridylethane] tetrahydrate]

Ming-Hua Yang ^a ^*

^aDepartment of Chemistry, Lishui University, Lishui 323000, People's Republic of China
^*Correspondence e-mail: zjlsxyhx@126.com

(Received 25 September 2008; accepted 30 September 2008; online 4 October 2008)

In the title compound, {[Ni₂(C₇H₃NO₅)₂(C₁₂H₁₂N₂)(H₂O)₂]·4H₂O}_n, two Ni^II ions, two tridentate pyridine-2,6-dicarboxylate N-oxide ligands and two coordinated water molecules form centrosymmetric dinuclear units, which are further bridged by centrosymmetric 1,2-di-4-pyridylethane ligands into polymeric chains along [210]. Each Ni^II ion has a distorted square-pyramidal environment, with the basal plane formed by three O [Ni—O = 1.9290 (16)–1.9588 (10) Å] and one N [Ni—N = 1.9828 (18) Å] atoms and the apical position occupied by the water molecule [Ni—O = 2.2643 (11) Å]. The water molecules are involved in the formation of O—H⋯O hydrogen bonds.

Related literature

For related literature, see: Laine et al. (1995a ,b ); Lin et al. (2006 ); Nathan et al. (1985 ). For a related structure, see: Wen et al. (2005 ).

Experimental

Crystal data

[Ni₂(C₇H₃NO₅)₂(C₁₂H₁₂N₂)(H₂O)₂]·4H₂O
M_r = 771.96
Triclinic, $[P \overline 1]$
a = 8.2803 (16) Å
b = 10.3542 (15) Å
c = 11.1326 (16) Å
α = 113.727 (2)°
β = 104.282 (2)°
γ = 100.255 (2)°
V = 804.4 (2) Å³
Z = 1
Mo Kα radiation
μ = 1.25 mm⁻¹
T = 298 (2) K
0.25 × 0.19 × 0.16 mm

Data collection

Bruker APEXII area-detector diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ) T_min = 0.745, T_max = 0.825
4146 measured reflections
2850 independent reflections
2180 reflections with I > 2σ(I)
R_int = 0.033

Refinement

R[F² > 2σ(F²)] = 0.028
wR(F²) = 0.063
S = 0.83
2850 reflections
199 parameters
H-atom parameters constrained
Δρ_max = 0.35 e Å⁻³
Δρ_min = −0.29 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1W⋯O3Wⁱ	0.85	1.99	2.8144 (15)	162
O1W—H2W⋯O2ⁱ	0.86	1.98	2.824 (2)	168
O3W—H6W⋯O5ⁱ	0.85	1.94	2.7791 (13)	170
O3W—H5W⋯O2W	0.86	2.44	2.8527 (13)	110
O2W—H3W⋯O2	0.84	2.15	2.976 (2)	167
O2W—H4W⋯O3Wⁱⁱ	0.84	1.97	2.7985 (14)	169
Symmetry codes: (i) -x, -y, -z+1; (ii) -x, -y+1, -z+1.

Data collection: APEX2 (Bruker, 2004 ); cell refinement: APEX2; data reduction: APEX2; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEPIII (Burnett & Johnson, 1996 ), ORTEP-3 for Windows (Farrugia, 1997 ) and PLATON (Spek, 2003 ); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808031619/cv2458sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536808031619/cv2458Isup2.hkl

checkCIF report

Comment top

The complexation of metal ions by dicarboxylate acid (pyridine-2,6-dicarboxylic acid) has been extensively studied (Laine et al., 1995a,b). Owing to the unique ability of the ligand to form stable chelates with various coordination modes and its biological activity, many crystal structures have been determined. Pyridine-2,6-dicarboxylic acid N-oxide (pydco), has limited steric hindrance and weak stacking interactions and can offer possibilities to form complicated coordination polymers through polycarboxylate ligands. However, the coordination chemistry and structural properties of metal polymers containing pydco ligands have seldom been documented to date (Nathan et al., 1985; Lin et al., 2006; Wen et al., 2005). In this paper, we report the synthesis and crystal structure of the title compound, (I).

In (I) (Fig. 1), each Ni^II atom is coordinated by three oxygen atoms from the carboxylato groups and one N-oxide entity from two pydco anions and one N atom from bridging 1,2-di-4-pyridylethane (bpa) ligand to form the basal plane, and further it coordinated by one apical oxygen atom from one water molecule to form a quasi-square pyramidal environment. Each carboxylato group is coordinated to the Ni atom in a monodentate fashion and the two carboxyl groups are out of coplanarity with the correspondingly linking pyridine rings, with the dihedral angles between them being ca 46° and 39°, respectively. They are very different from those in the free H₂pydco, in which the carboxyl groups are found to be essentially coplanar with the pyridine rings. Owing to the monodentate coordination modes of carboxylate groups, a binuclear [Ni₂(pydco)₂] unit was formed. Finally, bpa ligands connect the dimeric units into polymeric zigzag chain.

The crystalline water molecules contribute to intermolecular O—H···O hydrogen bonds (Table 1), which stabilize the crystal packing.

Related literature top

For related structures, see: Laine et al. (1995a,b); Lin et al. (2006); Nathan et al. (1985); Wen et al. (2005).

Experimental top

Ni(AC)₂ (25 mg, 0.07 mmol), H₂pydco (31 mg, 0.15 mmol), bpa (19 mg, 0.09 mmol) were added in a solvent of acetonitrile, the mixture was heated for two hours under reflux. during the process stirring and influx were required. The resultant was kept at room temperature for six weeks, when single crystals were obtained.

Computing details top

Data collection: APEX2 (Bruker, 2004); cell refinement: APEX2 (Bruker, 2004); data reduction: APEX2 (Bruker, 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEPIII (Burnett & Johnson, 1996), ORTEP-3 for Windows (Farrugia, 1997) and PLATON (Spek, 2003); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top

Fig. 1. A portion of the crystal structure of (I) showing the atomic numbering scheme and 40% probability displacement ellipsoids [symmetry codes: (i) -x, -y, 2 - z; (ii) -x, -y, 1 - z' (iii) -x, 1 - y, 1 - z].

catena-Poly[[[bis[aquanickel(II)]bis(µ-pyridine-2,6-dicarboxylato N-oxide)]-µ-1,2-di-4-pyridylethane] tetrahydrate] top

Crystal data top

[Ni₂(C₇H₃NO₅)₂(C₁₂H₁₂N₂)(H₂O)₂]·4H₂O	Z = 1
M_r = 771.96	F(000) = 398
Triclinic, P1	D_x = 1.594 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.2803 (16) Å	Cell parameters from 2850 reflections
b = 10.3542 (15) Å	θ = 2.1–25.2°
c = 11.1326 (16) Å	µ = 1.25 mm⁻¹
α = 113.727 (2)°	T = 298 K
β = 104.282 (2)°	Block, green
γ = 100.255 (2)°	0.25 × 0.19 × 0.16 mm
V = 804.4 (2) Å³

Data collection top

Bruker APEXII area-detector diffractometer	2850 independent reflections
Radiation source: fine-focus sealed tube	2180 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.033
ϕ and ω scans	θ_max = 25.2°, θ_min = 2.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −9→9
T_min = 0.745, T_max = 0.825	k = −12→12
4146 measured reflections	l = −13→12

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.028	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.063	H-atom parameters constrained
S = 0.83	w = 1/[σ²(F_o²) + (0.0269P)² + 0.19P] where P = (F_o² + 2F_c²)/3
2850 reflections	(Δ/σ)_max < 0.001
199 parameters	Δρ_max = 0.35 e Å⁻³
0 restraints	Δρ_min = −0.29 e Å⁻³

Crystal data top

[Ni₂(C₇H₃NO₅)₂(C₁₂H₁₂N₂)(H₂O)₂]·4H₂O	γ = 100.255 (2)°
M_r = 771.96	V = 804.4 (2) Å³
Triclinic, P1	Z = 1
a = 8.2803 (16) Å	Mo Kα radiation
b = 10.3542 (15) Å	µ = 1.25 mm⁻¹
c = 11.1326 (16) Å	T = 298 K
α = 113.727 (2)°	0.25 × 0.19 × 0.16 mm
β = 104.282 (2)°

Data collection top

Bruker APEXII area-detector diffractometer	2850 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	2180 reflections with I > 2σ(I)
T_min = 0.745, T_max = 0.825	R_int = 0.033
4146 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.028	0 restraints
wR(F²) = 0.063	H-atom parameters constrained
S = 0.83	Δρ_max = 0.35 e Å⁻³
2850 reflections	Δρ_min = −0.29 e Å⁻³
199 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Ni1	0.19610 (4)	0.10188 (3)	0.85792 (3)	0.03124 (11)
O1	0.0912 (2)	0.1451 (2)	0.70832 (19)	0.0473 (5)
O2	−0.1257 (2)	0.1548 (2)	0.5550 (2)	0.0600 (6)
O3	−0.03449 (19)	0.0177 (2)	0.85274 (17)	0.0433 (4)
N1	0.4335 (2)	0.2138 (2)	0.8837 (2)	0.0376 (5)
N2	−0.1753 (2)	−0.0555 (2)	0.7358 (2)	0.0354 (5)
C1	−0.0673 (3)	0.1028 (3)	0.6318 (3)	0.0401 (6)
C2	−0.2011 (3)	−0.0227 (3)	0.6272 (3)	0.0368 (6)
C3	−0.3544 (3)	−0.1043 (3)	0.5128 (3)	0.0489 (7)
H3	−0.3736	−0.0847	0.4369	0.059*
C4	−0.4795 (4)	−0.2144 (3)	0.5092 (3)	0.0570 (8)
H4	−0.5824	−0.2686	0.4315	0.068*
C5	−0.4508 (3)	−0.2433 (3)	0.6215 (3)	0.0492 (7)
H5	−0.5343	−0.3172	0.6205	0.059*
C6	−0.2980 (3)	−0.1624 (3)	0.7350 (3)	0.0366 (6)
C8	0.5711 (3)	0.1727 (3)	0.9306 (3)	0.0490 (7)
H8	0.5514	0.0953	0.9529	0.059*
C9	0.7394 (3)	0.2397 (3)	0.9470 (3)	0.0507 (7)
H9	0.8307	0.2077	0.9798	0.061*
C10	0.7726 (3)	0.3553 (3)	0.9144 (3)	0.0436 (6)
C11	0.9551 (3)	0.4316 (3)	0.9304 (3)	0.0518 (7)
H11A	1.0234	0.3635	0.9215	0.062*
H11B	0.9488	0.4587	0.8559	0.062*
C12	0.6307 (3)	0.3995 (3)	0.8690 (3)	0.0479 (7)
H12	0.6474	0.4782	0.8482	0.058*
C13	0.46548 (10)	0.32671 (9)	0.85477 (8)	0.0442 (7)
H13	0.3722	0.3577	0.8236	0.053*
O1W	0.22201 (10)	−0.11885 (9)	0.72089 (8)	0.0584 (5)
H1W	0.1610	−0.1939	0.7212	0.088*
H2W	0.2045	−0.1367	0.6357	0.088*
O2W	0.15515 (10)	0.41900 (9)	0.61420 (8)	0.0944 (8)
H3W	0.0828	0.3364	0.5887	0.142*
H4W	0.1122	0.489	0.6354	0.142*
O3W	0.03080 (10)	0.37588 (9)	0.33371 (8)	0.0875 (7)
H6W	0.0820	0.3592	0.2741	0.131*
H5W	0.1116	0.4510	0.4044	0.131*
C7	−0.25478 (10)	−0.18425 (9)	0.86469 (8)	0.0374 (6)
O4	−0.28538 (10)	−0.09359 (9)	0.96606 (8)	0.0401 (4)
O5	−0.19822 (10)	−0.28825 (9)	0.85957 (8)	0.0540 (5)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ni1	0.02697 (17)	0.0386 (2)	0.03728 (19)	0.00914 (13)	0.01384 (14)	0.02526 (16)
O1	0.0408 (10)	0.0605 (12)	0.0545 (12)	0.0133 (9)	0.0172 (9)	0.0406 (11)
O2	0.0654 (13)	0.0709 (14)	0.0579 (13)	0.0196 (11)	0.0122 (10)	0.0495 (12)
O3	0.0302 (9)	0.0632 (12)	0.0351 (10)	0.0041 (8)	0.0070 (8)	0.0286 (9)
N1	0.0335 (11)	0.0434 (13)	0.0472 (13)	0.0122 (10)	0.0175 (10)	0.0297 (11)
N2	0.0296 (11)	0.0454 (13)	0.0341 (12)	0.0114 (10)	0.0107 (10)	0.0218 (11)
C1	0.0484 (16)	0.0430 (16)	0.0361 (15)	0.0176 (13)	0.0183 (13)	0.0219 (13)
C2	0.0388 (14)	0.0456 (16)	0.0335 (14)	0.0180 (12)	0.0152 (12)	0.0221 (13)
C3	0.0471 (16)	0.0630 (19)	0.0386 (16)	0.0170 (15)	0.0102 (14)	0.0285 (15)
C4	0.0403 (16)	0.073 (2)	0.0413 (17)	0.0064 (15)	0.0009 (14)	0.0243 (16)
C5	0.0403 (15)	0.0570 (19)	0.0440 (17)	0.0067 (13)	0.0102 (13)	0.0241 (15)
C6	0.0319 (13)	0.0431 (16)	0.0374 (15)	0.0096 (12)	0.0129 (12)	0.0219 (13)
C8	0.0419 (15)	0.0528 (18)	0.070 (2)	0.0182 (13)	0.0246 (15)	0.0413 (16)
C9	0.0376 (15)	0.0531 (18)	0.070 (2)	0.0172 (13)	0.0220 (14)	0.0340 (16)
C10	0.0384 (14)	0.0430 (16)	0.0456 (16)	0.0072 (12)	0.0191 (13)	0.0172 (14)
C11	0.0420 (16)	0.0497 (18)	0.0549 (18)	0.0048 (13)	0.0224 (14)	0.0172 (14)
C12	0.0497 (16)	0.0403 (16)	0.0560 (18)	0.0061 (13)	0.0202 (14)	0.0270 (15)
C13	0.0400 (15)	0.0445 (16)	0.0553 (17)	0.0127 (13)	0.0167 (13)	0.0305 (15)
O1W	0.0732 (13)	0.0580 (13)	0.0531 (12)	0.0221 (11)	0.0286 (11)	0.0301 (11)
O2W	0.1038 (19)	0.0682 (16)	0.113 (2)	0.0268 (14)	0.0349 (16)	0.0454 (15)
O3W	0.127 (2)	0.0742 (16)	0.0925 (17)	0.0440 (15)	0.0679 (16)	0.0463 (14)
C7	0.0256 (13)	0.0449 (17)	0.0418 (16)	0.0028 (12)	0.0102 (12)	0.0249 (14)
O4	0.0350 (9)	0.0520 (11)	0.0420 (10)	0.0147 (8)	0.0165 (8)	0.0278 (9)
O5	0.0675 (13)	0.0502 (12)	0.0608 (13)	0.0252 (10)	0.0269 (11)	0.0360 (11)

Geometric parameters (Å, º) top

Ni1—O3	1.9290 (16)	C8—C9	1.373 (3)
Ni1—O1	1.9373 (16)	C8—H8	0.9300
Ni1—O4ⁱ	1.9588 (10)	C9—C10	1.386 (3)
Ni1—N1	1.9828 (18)	C9—H9	0.9300
Ni1—O1W	2.2643 (11)	C10—C12	1.390 (3)
O1—C1	1.258 (3)	C10—C11	1.506 (3)
O2—C1	1.230 (3)	C11—C11ⁱⁱ	1.501 (5)
O3—N2	1.331 (2)	C11—H11A	0.9700
N1—C13	1.3332 (19)	C11—H11B	0.9700
N1—C8	1.345 (3)	C12—C13	1.376 (3)
N2—C6	1.358 (3)	C12—H12	0.9300
N2—C2	1.361 (3)	C13—H13	0.9300
C1—C2	1.525 (3)	O1W—H1W	0.85
C2—C3	1.379 (3)	O1W—H2W	0.86
C3—C4	1.377 (4)	O2W—H3W	0.84
C3—H3	0.9300	O2W—H4W	0.84
C4—C5	1.375 (3)	O3W—H6W	0.85
C4—H4	0.9300	O3W—H5W	0.86
C5—C6	1.371 (3)	C7—O5	1.2351 (14)
C5—H5	0.9300	C7—O4	1.2618 (12)
C6—C7	1.517 (3)	O4—Ni1ⁱ	1.9588 (10)

O3—Ni1—O1	89.83 (7)	N2—C6—C5	120.3 (2)
O3—Ni1—O4ⁱ	86.14 (5)	N2—C6—C7	116.2 (2)
O1—Ni1—O4ⁱ	167.38 (6)	C5—C6—C7	123.6 (3)
O3—Ni1—N1	172.23 (8)	N1—C8—C9	123.1 (2)
O1—Ni1—N1	90.76 (7)	N1—C8—H8	118.5
O4ⁱ—Ni1—N1	91.65 (6)	C9—C8—H8	118.5
O3—Ni1—O1W	94.95 (6)	C8—C9—C10	119.7 (2)
O1—Ni1—O1W	97.00 (6)	C8—C9—H9	120.2
O4ⁱ—Ni1—O1W	95.30 (6)	C10—C9—H9	120.2
N1—Ni1—O1W	92.67 (6)	C9—C10—C12	117.0 (2)
C1—O1—Ni1	129.11 (16)	C9—C10—C11	121.5 (2)
N2—O3—Ni1	123.58 (13)	C12—C10—C11	121.5 (2)
C13—N1—C8	117.39 (17)	C11ⁱⁱ—C11—C10	111.5 (3)
C13—N1—Ni1	123.82 (12)	C11ⁱⁱ—C11—H11A	109.3
C8—N1—Ni1	118.78 (15)	C10—C11—H11A	109.3
O3—N2—C6	114.80 (18)	C11ⁱⁱ—C11—H11B	109.3
O3—N2—C2	123.49 (19)	C10—C11—H11B	109.3
C6—N2—C2	121.6 (2)	H11A—C11—H11B	108.0
O2—C1—O1	124.3 (2)	C13—C12—C10	120.0 (2)
O2—C1—C2	115.3 (2)	C13—C12—H12	120.0
O1—C1—C2	120.5 (2)	C10—C12—H12	120.0
N2—C2—C3	118.2 (2)	N1—C13—C12	122.78 (15)
N2—C2—C1	121.5 (2)	N1—C13—H13	118.6
C3—C2—C1	120.3 (2)	C12—C13—H13	118.6
C4—C3—C2	121.1 (2)	Ni1—O1W—H1W	115.3
C4—C3—H3	119.5	Ni1—O1W—H2W	114.2
C2—C3—H3	119.5	H1W—O1W—H2W	108.3
C5—C4—C3	119.4 (3)	H3W—O2W—H4W	113.1
C5—C4—H4	120.3	H6W—O3W—H5W	99.6
C3—C4—H4	120.3	O5—C7—O4	127.3 (1)
C6—C5—C4	119.5 (2)	O5—C7—C6	117.9 (2)
C6—C5—H5	120.3	O4—C7—C6	114.9 (2)
C4—C5—H5	120.3	C7—O4—Ni1ⁱ	114.7 (1)

Symmetry codes: (i) −x, −y, −z+2; (ii) −x+2, −y+1, −z+2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W···O3Wⁱⁱⁱ	0.85	1.99	2.8144 (15)	162
O1W—H2W···O2ⁱⁱⁱ	0.86	1.98	2.824 (2)	168
O3W—H6W···O5ⁱⁱⁱ	0.85	1.94	2.7791 (13)	170
O3W—H5W···O2W	0.86	2.44	2.8527 (13)	110
O2W—H3W···O2	0.84	2.15	2.976 (2)	167
O2W—H4W···O3W^iv	0.84	1.97	2.7985 (14)	169

Symmetry codes: (iii) −x, −y, −z+1; (iv) −x, −y+1, −z+1.

Experimental details

Crystal data
Chemical formula	[Ni₂(C₇H₃NO₅)₂(C₁₂H₁₂N₂)(H₂O)₂]·4H₂O
M_r	771.96
Crystal system, space group	Triclinic, P1
Temperature (K)	298
a, b, c (Å)	8.2803 (16), 10.3542 (15), 11.1326 (16)
α, β, γ (°)	113.727 (2), 104.282 (2), 100.255 (2)
V (Å³)	804.4 (2)
Z	1
Radiation type	Mo Kα
µ (mm⁻¹)	1.25
Crystal size (mm)	0.25 × 0.19 × 0.16

Data collection
Diffractometer	Bruker APEXII area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Sheldrick, 1996)
T_min, T_max	0.745, 0.825
No. of measured, independent and observed [I > 2σ(I)] reflections	4146, 2850, 2180
R_int	0.033
(sin θ/λ)_max (Å⁻¹)	0.599

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.028, 0.063, 0.83
No. of reflections	2850
No. of parameters	199
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.35, −0.29

Computer programs: APEX2 (Bruker, 2004), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), ORTEPIII (Burnett & Johnson, 1996), ORTEP-3 for Windows (Farrugia, 1997) and PLATON (Spek, 2003).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W···O3Wⁱ	0.85	1.99	2.8144 (15)	162.0
O1W—H2W···O2ⁱ	0.86	1.98	2.824 (2)	167.5
O3W—H6W···O5ⁱ	0.85	1.94	2.7791 (13)	169.6
O3W—H5W···O2W	0.86	2.44	2.8527 (13)	110.4
O2W—H3W···O2	0.84	2.15	2.976 (2)	167.4
O2W—H4W···O3Wⁱⁱ	0.84	1.97	2.7985 (14)	169.0

Symmetry codes: (i) −x, −y, −z+1; (ii) −x, −y+1, −z+1.

Acknowledgements

The author is grateful to the Natural Science Foundation of Zhejiang Province for financial support (grant No. Y407081).

References

Bruker (2004). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Burnett, M. N. & Johnson, C. K. (1996). ORTEPIII. Report ORNL-6895. Oak Ridge National Laboratory, Tennessee, USA. Google Scholar
Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565. CrossRef IUCr Journals Google Scholar
Laine, P., Gourdon, A. & Launay, J.-P. (1995a). Inorg. Chem. 34, 5129–5137. CSD CrossRef CAS Web of Science Google Scholar
Laine, P., Gourdon, A. & Launay, J.-P. (1995b). Inorg. Chem. 34, 5138–5149. CrossRef CAS Web of Science Google Scholar
Lin, J.-G., Zhu, H.-Z., Wen, L.-L., Tian, Z.-F. & Meng, Q.-J. Z. (2006). Z. Anorg. Allg. Chem. 632, 689–694. Google Scholar
Nathan, L. C., Doyle, C. A., Mooring, A. M., Zapien, D. C., Larsen, S. K. & Pierpont, C. G. (1985). Inorg. Chem. 24, 2763–2766. CSD CrossRef CAS Web of Science Google Scholar
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany. Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Spek, A. L. (2003). J. Appl. Cryst. 36, 7–13. Web of Science CrossRef CAS IUCr Journals Google Scholar
Wen, L.-L., Dang, D.-B., Duan, C.-Y., Li, Y.-Z., Tian, Z.-F. & Meng, Q.-J. (2005). Inorg. Chem. 44, 7161–7170. Web of Science CSD CrossRef PubMed CAS Google Scholar

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Volume 64| Part 11| November 2008| Page m1358

doi:10.1107/S1600536808031619

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metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

catena-Poly[[[bis­­[aqua­nickel(II)]bis­­(μ-pyridine-2,6-di­carboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

Acknowledgements

References

metal-organic compounds

catena-Poly[[[bis[aquanickel(II)]bis(μ-pyridine-2,6-dicarboxylato N-oxide)]-μ-1,2-di-4-pyridylethane] tetrahydrate]