trans-Dichloridobis(2-methyl­aniline-κN)palladium(II)

Bon, V.; Dudko, A.; Orysyk, S.; Pekhnyo, V.

doi:10.1107/S1600536809008472

metal-organic compounds

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Volume 65| Part 4| April 2009| Page m396

doi:10.1107/S1600536809008472

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trans-Dichloridobis(2-methylaniline-κN)palladium(II)

V. Bon,^a ^* A. Dudko,^a S. Orysyk ^a and V. Pekhnyo ^a

^aV.I. Vernadskii Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv 03680, Ukraine
^*Correspondence e-mail: bon@ionc.kiev.ua

(Received 25 February 2009; accepted 8 March 2009; online 14 March 2009)

In the title compound, [PdCl₂(C₇H₉N)₂], the Pd atom is situated on an inversion centre and displays a distorted square-planar coordination environment. The crystal structure displays weak intermolecular N—H⋯Cl hydrogen bonding.

Related literature

For the cytostatic and antitumoral activity of Pd complexes with N-containing organic ligands, see: Casas et al. (2008 ); Curic et al. (1996 ). For related structures, see: Baldovino-Pantaleon et al. (2007 ); Navarro–Ranninger et al. (1987 ); Vogels et al. (1999 ). For bond-length data, see: Allen et al. (1987 ).

Experimental

Crystal data

[PdCl₂(C₇H₉N)₂]
M_r = 391.60
Monoclinic, P 2₁ /c
a = 12.1841 (3) Å
b = 8.0653 (2) Å
c = 7.5407 (2) Å
β = 97.346 (2)°
V = 734.93 (3) Å³
Z = 2
Mo Kα radiation
μ = 1.61 mm⁻¹
T = 173 K
0.17 × 0.16 × 0.04 mm

Data collection

Bruker APEXII CCD diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2005 ) T_min = 0.777, T_max = 0.932
8179 measured reflections
1502 independent reflections
1118 reflections with I > 2σ(I)
R_int = 0.074

Refinement

R[F² > 2σ(F²)] = 0.034
wR(F²) = 0.060
S = 1.03
1502 reflections
97 parameters
2 restraints
H atoms treated by a mixture of independent and constrained refinement
Δρ_max = 0.48 e Å⁻³
Δρ_min = −0.66 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1N⋯Cl1ⁱ	0.85 (2)	2.71 (3)	3.410 (4)	141 (3)
N1—H2N⋯Cl1ⁱⁱ	0.90 (2)	2.43 (3)	3.319 (4)	172 (3)
Symmetry codes: (i) $[x, -y+{\script{3\over 2}}, z+{\script{1\over 2}}]$ ; (ii) $[-x, y-{\script{1\over 2}}, -z+{\script{1\over 2}}]$ .

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT (Bruker, 2005); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: publCIF (Westrip, 2009 ).

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809008472/rk2132sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536809008472/rk2132Isup2.hkl

checkCIF report

Comment top

Palladium complex compounds with N–containing organic ligands attract constant scientific interest due to its cytostatic and antitumoral activity (Curic et al., 1996; Casas et al., 2008). Asymmetric unit of title compound contains half of a molecule, other one generates by the symmetry operator of inversion centre (Fig. 1). Pd atom shows a square–planar geometry of coordination environment, which contain two chlorine atoms in trans–position and a two amino groups of o–toluidine. Bond lengths and angles have normal values (Allen et al., 1987). The crystal structure displays week intermolecular N—H···Cl hydrogen bonding (Table 1) creating the layered structure (Fig. 2).

Related literature top

For the cytostatic and antitumoral activity of Pd complexes with N-containing organic ligands, see: Casas et al. (2008); Curic et al. (1996). For related structures, see: Baldovino-Pantaleon et al. (2007); Navarro–Ranninger et al. (1987); Vogels et al. (1999). For bond-length data, see: Allen et al. (1987).

Experimental top

The 5 ml of 0.02 M chloroform o–toluidine solution was poured into the test–tube. The other reactant, 5 ml 0.01 M water solution of K₂PdCl₄ was carefully added on the top of the organic part. The sealed test–tube with double–layer mixture was put in a dark place. Two weeks later, the yellow plate shape crystals were grown in the chloroform part of the solution.

Computing details top

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT (Bruker, 2005); data reduction: SAINT (Bruker, 2005); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: publCIF (Westrip, 2009).

Figures top

	Fig. 1. Molecular structure of the title compound with the atom numbering scheme. Displacement ellipsoids are drawn at 50% probability lervel. H atoms are presented as a small spheres of arbitrary radius. Symmetry code: (i) -x, 1-y, -z.
	Fig. 2. Crystal packing of title compound, projection along b axis. Dashed lines indicate hydrogen bonds [Symmetry code: (i) -x, y-1/2, 1/2-z; (ii) x, 3/2-y, 1/2+z].

trans-Dichloridobis(2-methylaniline-κN)palladium(II) top

Crystal data top

[PdCl₂(C₇H₉N)₂]	F(000) = 392
M_r = 391.60	D_x = 1.770 Mg m⁻³
Monoclinic, P2₁/c	Melting point: 560 K
Hall symbol: -P 2ybc	Mo Kα radiation, λ = 0.71073 Å
a = 12.1841 (3) Å	Cell parameters from 1337 reflections
b = 8.0653 (2) Å	θ = 3.0–22.5°
c = 7.5407 (2) Å	µ = 1.61 mm⁻¹
β = 97.346 (2)°	T = 173 K
V = 734.93 (3) Å³	Plate, yellow
Z = 2	0.17 × 0.16 × 0.04 mm

Data collection top

Bruker APEXII CCD diffractometer	1502 independent reflections
Radiation source: Fine–focus sealed tube	1118 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.074
Detector resolution: 8.26 pixels mm^-1	θ_max = 26.4°, θ_min = 1.7°
ϕ and ω scans	h = −15→15
Absorption correction: multi-scan (SADABS; Bruker, 2005)	k = −10→10
T_min = 0.777, T_max = 0.932	l = −9→9
8179 measured reflections

Refinement top

Refinement on F²	Primary atom site location: Direct
Least-squares matrix: Full	Secondary atom site location: Difmap
R[F² > 2σ(F²)] = 0.034	Hydrogen site location: Geom
wR(F²) = 0.060	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ²(F_o²) + (0.0118P)² + 0.6868P] where P = (F_o² + 2F_c²)/3
1502 reflections	(Δ/σ)_max < 0.001
97 parameters	Δρ_max = 0.48 e Å⁻³
2 restraints	Δρ_min = −0.66 e Å⁻³

Crystal data top

[PdCl₂(C₇H₉N)₂]	V = 734.93 (3) Å³
M_r = 391.60	Z = 2
Monoclinic, P2₁/c	Mo Kα radiation
a = 12.1841 (3) Å	µ = 1.61 mm⁻¹
b = 8.0653 (2) Å	T = 173 K
c = 7.5407 (2) Å	0.17 × 0.16 × 0.04 mm
β = 97.346 (2)°

Data collection top

Bruker APEXII CCD diffractometer	1502 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 2005)	1118 reflections with I > 2σ(I)
T_min = 0.777, T_max = 0.932	R_int = 0.074
8179 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.034	2 restraints
wR(F²) = 0.060	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	Δρ_max = 0.48 e Å⁻³
1502 reflections	Δρ_min = −0.66 e Å⁻³
97 parameters

Special details top

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R–factor wR and goodness of fit S are based on F², conventional R–factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R–factors(gt) etc. and is not relevant to the choice of reflections for refinement. R–factors based on F² are statistically about twice as large as those based on F, and R–factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pd1	0.0000	0.5000	0.0000	0.01692 (12)
Cl1	0.06040 (8)	0.77044 (11)	0.02411 (13)	0.0222 (2)
N1	0.1118 (3)	0.4372 (4)	0.2186 (5)	0.0192 (8)
H1N	0.130 (3)	0.526 (4)	0.276 (5)	0.024 (12)*
H2N	0.071 (3)	0.386 (4)	0.294 (5)	0.025 (12)*
C1	0.2062 (3)	0.3358 (5)	0.1906 (5)	0.0216 (9)
C2	0.3051 (4)	0.4060 (6)	0.1573 (6)	0.0300 (11)
C3	0.3912 (3)	0.2990 (6)	0.1258 (6)	0.0330 (11)
H3	0.4596	0.3446	0.1015	0.040*
C4	0.3790 (4)	0.1308 (6)	0.1291 (6)	0.0390 (12)
H4	0.4387	0.0612	0.1073	0.047*
C5	0.2808 (4)	0.0614 (6)	0.1639 (6)	0.0352 (12)
H5	0.2722	−0.0556	0.1653	0.042*
C6	0.1949 (3)	0.1643 (5)	0.1967 (5)	0.0271 (10)
H6	0.1275	0.1174	0.2238	0.032*
C7	0.3210 (4)	0.5894 (6)	0.1537 (7)	0.0432 (14)
H7A	0.2701	0.6373	0.0560	0.065*
H7B	0.3974	0.6142	0.1350	0.065*
H7C	0.3060	0.6370	0.2677	0.065*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pd1	0.0189 (2)	0.0155 (2)	0.0169 (2)	0.0004 (2)	0.00446 (15)	−0.0002 (2)
Cl1	0.0272 (5)	0.0174 (5)	0.0222 (5)	−0.0014 (4)	0.0033 (4)	0.0008 (4)
N1	0.0228 (18)	0.0170 (17)	0.019 (2)	−0.0008 (14)	0.0066 (16)	−0.0040 (16)
C1	0.022 (2)	0.025 (2)	0.017 (2)	0.0002 (17)	0.0021 (18)	0.0009 (17)
C2	0.029 (3)	0.039 (3)	0.022 (3)	0.000 (2)	0.004 (2)	0.000 (2)
C3	0.022 (2)	0.044 (3)	0.033 (3)	0.007 (2)	0.004 (2)	−0.004 (2)
C4	0.034 (3)	0.047 (3)	0.036 (3)	0.014 (2)	0.003 (2)	−0.012 (2)
C5	0.041 (3)	0.030 (2)	0.033 (3)	0.006 (2)	0.000 (2)	−0.005 (2)
C6	0.025 (2)	0.034 (3)	0.022 (3)	0.0000 (19)	0.0007 (19)	0.0015 (19)
C7	0.031 (3)	0.035 (3)	0.063 (4)	0.001 (2)	0.002 (3)	0.005 (3)

Geometric parameters (Å, º) top

Pd1—N1	2.063 (3)	C3—C4	1.365 (6)
Pd1—N1ⁱ	2.063 (3)	C3—H3	0.9500
Pd1—Cl1ⁱ	2.3017 (9)	C4—C5	1.376 (6)
Pd1—Cl1	2.3017 (9)	C4—H4	0.9500
N1—C1	1.449 (5)	C5—C6	1.382 (5)
N1—H1N	0.85 (2)	C5—H5	0.9500
N1—H2N	0.90 (2)	C6—H6	0.9500
C1—C2	1.383 (5)	C7—H7A	0.9800
C1—C6	1.392 (5)	C7—H7B	0.9800
C2—C3	1.402 (6)	C7—H7C	0.9800
C2—C7	1.492 (5)

N1—Pd1—N1ⁱ	180.0	C4—C3—C2	121.5 (4)
N1—Pd1—Cl1ⁱ	90.13 (10)	C4—C3—H3	119.2
N1ⁱ—Pd1—Cl1ⁱ	89.87 (10)	C2—C3—H3	119.2
N1—Pd1—Cl1	89.88 (10)	C3—C4—C5	120.5 (4)
N1ⁱ—Pd1—Cl1	90.13 (10)	C3—C4—H4	119.8
Cl1ⁱ—Pd1—Cl1	180.0	C5—C4—H4	119.8
C1—N1—Pd1	118.6 (3)	C4—C5—C6	119.1 (4)
C1—N1—H1N	113 (3)	C4—C5—H5	120.4
Pd1—N1—H1N	108 (3)	C6—C5—H5	120.4
C1—N1—H2N	110 (2)	C5—C6—C1	120.7 (4)
Pd1—N1—H2N	105 (3)	C5—C6—H6	119.7
H1N—N1—H2N	101 (4)	C1—C6—H6	119.7
C2—C1—C6	120.3 (4)	C2—C7—H7A	109.5
C2—C1—N1	121.5 (4)	C2—C7—H7B	109.5
C6—C1—N1	118.2 (4)	H7A—C7—H7B	109.5
C1—C2—C3	117.8 (4)	C2—C7—H7C	109.5
C1—C2—C7	121.8 (4)	H7A—C7—H7C	109.5
C3—C2—C7	120.4 (4)	H7B—C7—H7C	109.5

Cl1ⁱ—Pd1—N1—C1	70.4 (3)	C1—C2—C3—C4	−0.5 (7)
Cl1—Pd1—N1—C1	−109.6 (3)	C7—C2—C3—C4	179.7 (5)
Pd1—N1—C1—C2	90.5 (4)	C2—C3—C4—C5	0.0 (7)
Pd1—N1—C1—C6	−89.0 (4)	C3—C4—C5—C6	−0.5 (7)
C6—C1—C2—C3	1.6 (6)	C4—C5—C6—C1	1.5 (7)
N1—C1—C2—C3	−177.9 (4)	C2—C1—C6—C5	−2.1 (7)
C6—C1—C2—C7	−178.7 (4)	N1—C1—C6—C5	177.4 (4)
N1—C1—C2—C7	1.9 (7)

Symmetry code: (i) −x, −y+1, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1N···Cl1ⁱⁱ	0.85 (2)	2.71 (3)	3.410 (4)	141 (3)
N1—H2N···Cl1ⁱⁱⁱ	0.90 (2)	2.43 (3)	3.319 (4)	172 (3)

Symmetry codes: (ii) x, −y+3/2, z+1/2; (iii) −x, y−1/2, −z+1/2.

Experimental details

Crystal data
Chemical formula	[PdCl₂(C₇H₉N)₂]
M_r	391.60
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	173
a, b, c (Å)	12.1841 (3), 8.0653 (2), 7.5407 (2)
β (°)	97.346 (2)
V (Å³)	734.93 (3)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	1.61
Crystal size (mm)	0.17 × 0.16 × 0.04

Data collection
Diffractometer	Bruker APEXII CCD diffractometer
Absorption correction	Multi-scan (SADABS; Bruker, 2005)
T_min, T_max	0.777, 0.932
No. of measured, independent and observed [I > 2σ(I)] reflections	8179, 1502, 1118
R_int	0.074
(sin θ/λ)_max (Å⁻¹)	0.625

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.034, 0.060, 1.03
No. of reflections	1502
No. of parameters	97
No. of restraints	2
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
Δρ_max, Δρ_min (e Å⁻³)	0.48, −0.66

Computer programs: APEX2 (Bruker, 2005), SAINT (Bruker, 2005), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008), publCIF (Westrip, 2009).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1N···Cl1ⁱ	0.85 (2)	2.71 (3)	3.410 (4)	141 (3)
N1—H2N···Cl1ⁱⁱ	0.90 (2)	2.43 (3)	3.319 (4)	172 (3)

Symmetry codes: (i) x, −y+3/2, z+1/2; (ii) −x, y−1/2, −z+1/2.

References

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CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 65| Part 4| April 2009| Page m396

doi:10.1107/S1600536809008472

Open

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