Bis[4-(2-hydroxy­benzyl­ideneamino)benzoato-κO]tetrakis­(methanol-κO)manganese(II)

Zhong, M.; Lin, J.-H.; Shang, J.; Huang, T.-H.; Wang, X.-J.

doi:10.1107/S160053680901681X

metal-organic compounds

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ISSN: 2056-9890

Volume 65| Part 6| June 2009| Page m634

doi:10.1107/S160053680901681X

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Bis[4-(2-hydroxybenzylideneamino)benzoato-κO]tetrakis(methanol-κO)manganese(II)

Min Zhong,^a ^* Jia-Huang Lin,^a Jing Shang,^a Ting-Hong Huang ^a and Xiu-Jian Wang ^a

^aSchool of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China
^*Correspondence e-mail: zhongmin0310@yahoo.com.cn

(Received 3 April 2009; accepted 5 May 2009; online 14 May 2009)

In the title mononuclear complex, [Mn(C₁₄H₁₀NO₃)₂(CH₃OH)₄], the Mn^II atom, lying on an inversion centre, exhibits a distorted octahedral geometry, defined by two O atoms from two monodentate ligands and four O atoms from four methanol molecules. The crystal structure involves intramolecular O—H⋯N and O—H⋯O and intermolecular O—H⋯O hydrogen bonds.

Related literature

For general background, see: Deeth (2008 ); Dubois et al. (2008 ); Huang et al. (2004 ).

Experimental

Crystal data

[Mn(C₁₄H₁₀NO₃)₂(CH₄O)₄]
M_r = 663.57
Monoclinic, P 2₁ /c
a = 15.0341 (6) Å
b = 11.8819 (4) Å
c = 8.8178 (3) Å
β = 98.912 (4)°
V = 1556.14 (10) Å³
Z = 2
Mo Kα radiation
μ = 0.49 mm⁻¹
T = 293 K
0.6 × 0.6 × 0.3 mm

Data collection

Oxford Diffraction Gemini S Ultra diffractometer
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006 $[Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England.]$ ) T_min = 0.823, T_max = 1.000 (expected range = 0.711–0.865)
10167 measured reflections
3374 independent reflections
2008 reflections with I > 2σ(I)
R_int = 0.032

Refinement

R[F² > 2σ(F²)] = 0.039
wR(F²) = 0.102
S = 0.92
3374 reflections
205 parameters
H-atom parameters constrained
Δρ_max = 0.55 e Å⁻³
Δρ_min = −0.31 e Å⁻³

Table 1
Selected bond lengths (Å)

Mn1—O3	2.1275 (15)
Mn1—O5	2.1803 (13)
Mn1—O4	2.2023 (14)

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1—H1A⋯N1	0.85	1.83	2.619 (2)	153
O4—H4B⋯O2ⁱ	0.85	1.84	2.621 (2)	151
O5—H5B⋯O2	0.85	1.83	2.618 (2)	153
Symmetry code: (i) $[-x+1, y+{\script{1\over 2}}, -z+{\script{1\over 2}}]$ .

Data collection: CrysAlis CCD (Oxford Diffraction, 2006 $[Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England.]$ ); cell refinement: CrysAlis RED (Oxford Diffraction, 2006 $[Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England.]$ ); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008) and Mercury (Macrae et al., 2006 ); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks I, New_Global_Publ_Block. DOI: 10.1107/S160053680901681X/hy2192sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S160053680901681X/hy2192Isup2.hkl

checkCIF report

Comment top

General molecular mechanics method for transition metal carboxylates and the multiple coordination modes in manganese(II) complexes have been reported recently (Deeth, 2008). Information on the structures of manganese(II) carboxylates continues to be collected, and at the same time new applications of such complexes are being discovered in magnetic properties, potential biological significance and ferrimagnet (Huang et al., 2004). The chemistry of organo-manganese(II) complexes of Schiff base has stemmed from the reported biocidal and catalytic activities of organo-manganese(II) compounds (Dubois et al., 2008). We report here a new monomeric manganese(II) compound, which contains the Schiff base ligand, N-(4-carboxyphenyl)salicylideneimine (Fig.1). The Mn^II atom has a distorted octahedral geometry (Table 1). There exist intra- and intermolecular hydrogen bonds in the crystal structure (Table 2). The intermolecular hydrogen bonds is used to form a two-dimensional supramolecular network (Fig. 2).

Related literature top

For general background, see: Deeth (2008); Dubois et al. (2008); Huang et al. (2004).

Experimental top

Manganese(II) acetate tetrahydrate (0.049 g, 0.2 mmol) was dissolved in 8 ml deionized water, giving a transparent solution (A), and N-(4-carboxyphenyl)salicylideneimine (0.097 g, 0.4 mmol) was dissolved in 10 ml me thanol (B). Then solution B was mixed with A and a suspension was obtained. Ammonia was added to the above mixture dropwise under magnetic stirring until pH value is neutral. The resulting suspension was transferred into a 25 ml Teflon-lined stainless-steel autoclave. The autoclave was sealed and maintained at 363 K for 12 h under autogenous pressure. After the reaction was completed, the resulting colourless block crystals were collected by filtration.

Computing details top

Data collection: CrysAlis CCD (Oxford Diffraction, 2006); cell refinement: CrysAlis RED (Oxford Diffraction, 2006); data reduction: CrysAlis RED (Oxford Diffraction, 2006); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008) and Mercury (Macrae et al., 2006); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

	Fig. 1. Molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level. H atoms have been omitted for clarity. [Symmetry code: (i) -x + 1, -y, -z.]
	Fig. 2. Crystal packing of the title compound, showing hydrogen bonds (dashed lines).

Bis[4-(2-hydroxybenzylideneamino)benzoato-κO]tetrakis(methanol- κO)manganese(II) top

Crystal data top

[Mn(C₁₄H₁₀NO₃)₂(CH₄O)₄]	F(000) = 694
M_r = 663.57	D_x = 1.416 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 3622 reflections
a = 15.0341 (6) Å	θ = 2.7–29.8°
b = 11.8819 (4) Å	µ = 0.49 mm⁻¹
c = 8.8178 (3) Å	T = 293 K
β = 98.912 (4)°	Block, colorless
V = 1556.14 (10) Å³	0.6 × 0.6 × 0.3 mm
Z = 2

Data collection top

Oxford Diffraction Gemini S Ultra diffractometer	3374 independent reflections
Radiation source: Enhance (Mo) X-ray Source	2008 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.032
Detector resolution: 16.0855 pixels mm^-1	θ_max = 27.0°, θ_min = 2.7°
ω scans	h = −19→16
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006)	k = −15→14
T_min = 0.823, T_max = 1.000	l = −11→11
10167 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.039	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.102	H-atom parameters constrained
S = 0.92	w = 1/[σ²(F_o²) + (0.058P)²] where P = (F_o² + 2F_c²)/3
3374 reflections	(Δ/σ)_max < 0.001
205 parameters	Δρ_max = 0.55 e Å⁻³
0 restraints	Δρ_min = −0.31 e Å⁻³

Crystal data top

[Mn(C₁₄H₁₀NO₃)₂(CH₄O)₄]	V = 1556.14 (10) Å³
M_r = 663.57	Z = 2
Monoclinic, P2₁/c	Mo Kα radiation
a = 15.0341 (6) Å	µ = 0.49 mm⁻¹
b = 11.8819 (4) Å	T = 293 K
c = 8.8178 (3) Å	0.6 × 0.6 × 0.3 mm
β = 98.912 (4)°

Data collection top

Oxford Diffraction Gemini S Ultra diffractometer	3374 independent reflections
Absorption correction: multi-scan (CrysAlis RED; Oxford Diffraction, 2006)	2008 reflections with I > 2σ(I)
T_min = 0.823, T_max = 1.000	R_int = 0.032
10167 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.039	0 restraints
wR(F²) = 0.102	H-atom parameters constrained
S = 0.92	Δρ_max = 0.55 e Å⁻³
3374 reflections	Δρ_min = −0.31 e Å⁻³
205 parameters

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Mn1	0.5000	0.0000	0.0000	0.02171 (15)
O1	1.09324 (11)	0.03911 (14)	0.80222 (19)	0.0404 (4)
H1A	1.0420	0.0210	0.7533	0.048*
O2	0.57922 (10)	−0.20216 (13)	0.26345 (18)	0.0350 (4)
O3	0.60735 (10)	−0.03061 (12)	0.18268 (17)	0.0291 (4)
N1	0.94227 (12)	−0.06941 (15)	0.7155 (2)	0.0295 (5)
C1	1.11213 (15)	−0.0410 (2)	0.9117 (3)	0.0303 (6)
C2	1.19528 (16)	−0.0391 (2)	1.0049 (3)	0.0360 (6)
H2A	1.2378	0.0151	0.9904	0.043*
C3	1.21437 (16)	−0.1187 (2)	1.1196 (3)	0.0397 (6)
H3A	1.2704	−0.1177	1.1815	0.048*
C4	1.15283 (15)	−0.1989 (2)	1.1442 (3)	0.0377 (6)
H4A	1.1665	−0.2511	1.2229	0.045*
C5	1.07051 (15)	−0.2014 (2)	1.0510 (3)	0.0332 (6)
H5A	1.0288	−0.2561	1.0675	0.040*
C6	1.04831 (14)	−0.12450 (18)	0.9335 (2)	0.0276 (5)
C7	0.96278 (15)	−0.13309 (19)	0.8321 (3)	0.0306 (5)
H7A	0.9215	−0.1870	0.8529	0.037*
C8	0.86185 (14)	−0.08573 (19)	0.6112 (2)	0.0269 (5)
C9	0.81878 (14)	−0.18938 (19)	0.5844 (3)	0.0312 (6)
H9A	0.8412	−0.2524	0.6402	0.037*
C10	0.74265 (14)	−0.19842 (19)	0.4748 (3)	0.0299 (5)
H10A	0.7137	−0.2675	0.4587	0.036*
C11	0.70884 (14)	−0.10594 (17)	0.3887 (2)	0.0225 (5)
C12	0.75350 (15)	−0.00380 (18)	0.4146 (2)	0.0259 (5)
H12A	0.7322	0.0587	0.3567	0.031*
C13	0.82848 (15)	0.00641 (19)	0.5241 (2)	0.0279 (5)
H13A	0.8572	0.0757	0.5401	0.033*
C14	0.62646 (14)	−0.11436 (18)	0.2699 (2)	0.0234 (5)
O4	0.42496 (10)	0.08439 (12)	0.16313 (16)	0.0306 (4)
H4B	0.4371	0.1543	0.1666	0.037*
O5	0.43893 (10)	−0.15779 (11)	0.05698 (16)	0.0271 (4)
H5B	0.4791	−0.1938	0.1163	0.033*
C15	0.42208 (19)	0.0436 (2)	0.3134 (3)	0.0436 (7)
H15A	0.3862	0.0932	0.3650	0.065*
H15B	0.4821	0.0403	0.3695	0.065*
H15C	0.3960	−0.0303	0.3075	0.065*
C16	0.39223 (16)	−0.23800 (19)	−0.0468 (3)	0.0368 (6)
H16A	0.3730	−0.2999	0.0103	0.055*
H16B	0.4316	−0.2651	−0.1145	0.055*
H16C	0.3406	−0.2029	−0.1058	0.055*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Mn1	0.0265 (3)	0.0162 (2)	0.0218 (3)	−0.0006 (2)	0.00172 (19)	0.0002 (2)
O1	0.0353 (10)	0.0405 (10)	0.0447 (11)	−0.0090 (8)	0.0041 (8)	0.0001 (9)
O2	0.0365 (9)	0.0240 (9)	0.0407 (10)	−0.0064 (7)	−0.0061 (8)	0.0091 (8)
O3	0.0313 (9)	0.0259 (9)	0.0282 (9)	−0.0022 (7)	−0.0011 (7)	0.0067 (7)
N1	0.0296 (11)	0.0303 (11)	0.0282 (10)	−0.0001 (9)	0.0029 (9)	−0.0037 (9)
C1	0.0333 (14)	0.0307 (13)	0.0272 (12)	0.0057 (10)	0.0061 (11)	−0.0047 (11)
C2	0.0260 (13)	0.0373 (14)	0.0454 (15)	−0.0033 (11)	0.0077 (12)	−0.0122 (12)
C3	0.0247 (14)	0.0523 (17)	0.0392 (15)	0.0064 (12)	−0.0040 (11)	−0.0083 (13)
C4	0.0366 (14)	0.0417 (15)	0.0331 (14)	0.0070 (12)	0.0002 (12)	0.0001 (12)
C5	0.0286 (13)	0.0352 (14)	0.0354 (14)	−0.0022 (11)	0.0035 (11)	−0.0022 (12)
C6	0.0223 (12)	0.0336 (13)	0.0271 (12)	0.0010 (10)	0.0044 (10)	−0.0069 (11)
C7	0.0304 (13)	0.0313 (13)	0.0302 (13)	−0.0033 (10)	0.0053 (11)	−0.0027 (11)
C8	0.0245 (12)	0.0312 (13)	0.0249 (12)	−0.0004 (10)	0.0036 (10)	−0.0059 (10)
C9	0.0293 (13)	0.0247 (13)	0.0373 (14)	0.0055 (10)	−0.0015 (11)	0.0034 (11)
C10	0.0293 (13)	0.0226 (12)	0.0355 (14)	−0.0011 (10)	−0.0022 (11)	−0.0010 (11)
C11	0.0252 (12)	0.0214 (11)	0.0225 (11)	0.0003 (9)	0.0086 (10)	−0.0014 (9)
C12	0.0330 (12)	0.0224 (11)	0.0223 (11)	0.0000 (11)	0.0043 (9)	0.0032 (10)
C13	0.0336 (13)	0.0244 (12)	0.0251 (11)	−0.0048 (11)	0.0025 (10)	−0.0020 (11)
C14	0.0276 (12)	0.0201 (12)	0.0237 (11)	0.0025 (10)	0.0075 (10)	−0.0001 (10)
O4	0.0433 (10)	0.0183 (8)	0.0317 (9)	0.0003 (7)	0.0105 (7)	−0.0017 (7)
O5	0.0306 (8)	0.0180 (8)	0.0309 (9)	−0.0023 (7)	−0.0010 (7)	0.0019 (7)
C15	0.070 (2)	0.0313 (13)	0.0339 (14)	−0.0014 (13)	0.0207 (14)	0.0006 (12)
C16	0.0417 (15)	0.0264 (13)	0.0415 (15)	−0.0077 (11)	0.0041 (12)	−0.0096 (11)

Geometric parameters (Å, º) top

Mn1—O3	2.1275 (15)	C7—H7A	0.9300
Mn1—O3ⁱ	2.1275 (15)	C8—C13	1.386 (3)
Mn1—O5ⁱ	2.1802 (13)	C8—C9	1.394 (3)
Mn1—O5	2.1803 (13)	C9—C10	1.383 (3)
Mn1—O4	2.2023 (14)	C9—H9A	0.9300
Mn1—O4ⁱ	2.2023 (14)	C10—C11	1.387 (3)
O1—C1	1.354 (3)	C10—H10A	0.9300
O1—H1A	0.8500	C11—C12	1.389 (3)
O2—C14	1.258 (2)	C11—C14	1.496 (3)
O3—C14	1.263 (2)	C12—C13	1.372 (3)
N1—C7	1.275 (3)	C12—H12A	0.9300
N1—C8	1.415 (3)	C13—H13A	0.9300
C1—C2	1.386 (3)	O4—C15	1.418 (3)
C1—C6	1.414 (3)	O4—H4B	0.8500
C2—C3	1.382 (3)	O5—C16	1.428 (2)
C2—H2A	0.9300	O5—H5B	0.8500
C3—C4	1.369 (3)	C15—H15A	0.9600
C3—H3A	0.9300	C15—H15B	0.9600
C4—C5	1.376 (3)	C15—H15C	0.9600
C4—H4A	0.9300	C16—H16A	0.9600
C5—C6	1.383 (3)	C16—H16B	0.9600
C5—H5A	0.9300	C16—H16C	0.9600
C6—C7	1.452 (3)

O3—Mn1—O3ⁱ	180.00 (10)	C13—C8—C9	119.0 (2)
O3—Mn1—O5ⁱ	91.39 (5)	C13—C8—N1	116.85 (19)
O3ⁱ—Mn1—O5ⁱ	88.61 (5)	C9—C8—N1	124.0 (2)
O3—Mn1—O5	88.61 (5)	C10—C9—C8	120.0 (2)
O3ⁱ—Mn1—O5	91.39 (5)	C10—C9—H9A	120.0
O5ⁱ—Mn1—O5	180.00 (7)	C8—C9—H9A	120.0
O3—Mn1—O4	89.34 (6)	C9—C10—C11	121.0 (2)
O3ⁱ—Mn1—O4	90.66 (6)	C9—C10—H10A	119.5
O5ⁱ—Mn1—O4	92.04 (5)	C11—C10—H10A	119.5
O5—Mn1—O4	87.96 (5)	C10—C11—C12	118.4 (2)
O3—Mn1—O4ⁱ	90.66 (6)	C10—C11—C14	121.60 (19)
O3ⁱ—Mn1—O4ⁱ	89.34 (6)	C12—C11—C14	120.02 (19)
O5ⁱ—Mn1—O4ⁱ	87.96 (5)	C13—C12—C11	121.1 (2)
O5—Mn1—O4ⁱ	92.04 (5)	C13—C12—H12A	119.4
O4—Mn1—O4ⁱ	180.00 (7)	C11—C12—H12A	119.4
C1—O1—H1A	104.9	C12—C13—C8	120.5 (2)
C14—O3—Mn1	132.05 (14)	C12—C13—H13A	119.7
C7—N1—C8	121.23 (19)	C8—C13—H13A	119.7
O1—C1—C2	118.8 (2)	O2—C14—O3	123.5 (2)
O1—C1—C6	121.2 (2)	O2—C14—C11	119.14 (19)
C2—C1—C6	120.0 (2)	O3—C14—C11	117.32 (18)
C3—C2—C1	119.3 (2)	C15—O4—Mn1	123.20 (14)
C3—C2—H2A	120.4	C15—O4—H4B	109.7
C1—C2—H2A	120.4	Mn1—O4—H4B	109.9
C4—C3—C2	121.6 (2)	C16—O5—Mn1	127.52 (13)
C4—C3—H3A	119.2	C16—O5—H5B	106.9
C2—C3—H3A	119.2	Mn1—O5—H5B	106.9
C3—C4—C5	119.2 (2)	O4—C15—H15A	109.5
C3—C4—H4A	120.4	O4—C15—H15B	109.5
C5—C4—H4A	120.4	H15A—C15—H15B	109.5
C4—C5—C6	121.6 (2)	O4—C15—H15C	109.5
C4—C5—H5A	119.2	H15A—C15—H15C	109.5
C6—C5—H5A	119.2	H15B—C15—H15C	109.5
C5—C6—C1	118.4 (2)	O5—C16—H16A	109.5
C5—C6—C7	120.2 (2)	O5—C16—H16B	109.5
C1—C6—C7	121.4 (2)	H16A—C16—H16B	109.5
N1—C7—C6	122.4 (2)	O5—C16—H16C	109.5
N1—C7—H7A	118.8	H16A—C16—H16C	109.5
C6—C7—H7A	118.8	H16B—C16—H16C	109.5

O5ⁱ—Mn1—O3—C14	−173.33 (18)	C8—C9—C10—C11	1.0 (3)
O5—Mn1—O3—C14	6.67 (18)	C9—C10—C11—C12	0.3 (3)
O4—Mn1—O3—C14	94.64 (19)	C9—C10—C11—C14	−179.90 (18)
O4ⁱ—Mn1—O3—C14	−85.36 (19)	C10—C11—C12—C13	−1.0 (3)
O1—C1—C2—C3	178.3 (2)	C14—C11—C12—C13	179.17 (18)
C6—C1—C2—C3	−0.6 (3)	C11—C12—C13—C8	0.4 (3)
C1—C2—C3—C4	−0.5 (4)	C9—C8—C13—C12	0.8 (3)
C2—C3—C4—C5	1.0 (4)	N1—C8—C13—C12	176.55 (18)
C3—C4—C5—C6	−0.2 (3)	Mn1—O3—C14—O2	−1.2 (3)
C4—C5—C6—C1	−0.9 (3)	Mn1—O3—C14—C11	−179.75 (12)
C4—C5—C6—C7	176.7 (2)	C10—C11—C14—O2	10.7 (3)
O1—C1—C6—C5	−177.6 (2)	C12—C11—C14—O2	−169.4 (2)
C2—C1—C6—C5	1.3 (3)	C10—C11—C14—O3	−170.6 (2)
O1—C1—C6—C7	4.8 (3)	C12—C11—C14—O3	9.2 (3)
C2—C1—C6—C7	−176.2 (2)	O3—Mn1—O4—C15	−41.12 (17)
C8—N1—C7—C6	174.53 (19)	O3ⁱ—Mn1—O4—C15	138.88 (17)
C5—C6—C7—N1	−174.7 (2)	O5ⁱ—Mn1—O4—C15	−132.49 (17)
C1—C6—C7—N1	2.8 (3)	O5—Mn1—O4—C15	47.51 (17)
C7—N1—C8—C13	157.1 (2)	O3—Mn1—O5—C16	−142.12 (16)
C7—N1—C8—C9	−27.4 (3)	O3ⁱ—Mn1—O5—C16	37.88 (16)
C13—C8—C9—C10	−1.5 (3)	O4—Mn1—O5—C16	128.49 (16)
N1—C8—C9—C10	−176.92 (19)	O4ⁱ—Mn1—O5—C16	−51.51 (16)

Symmetry code: (i) −x+1, −y, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1—H1A···N1	0.85	1.83	2.619 (2)	153
O4—H4B···O2ⁱⁱ	0.85	1.84	2.621 (2)	151
O5—H5B···O2	0.85	1.83	2.618 (2)	153

Symmetry code: (ii) −x+1, y+1/2, −z+1/2.

Experimental details

Crystal data
Chemical formula	[Mn(C₁₄H₁₀NO₃)₂(CH₄O)₄]
M_r	663.57
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	293
a, b, c (Å)	15.0341 (6), 11.8819 (4), 8.8178 (3)
β (°)	98.912 (4)
V (Å³)	1556.14 (10)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	0.49
Crystal size (mm)	0.6 × 0.6 × 0.3

Data collection
Diffractometer	Oxford Diffraction Gemini S Ultra diffractometer
Absorption correction	Multi-scan (CrysAlis RED; Oxford Diffraction, 2006)
T_min, T_max	0.823, 1.000
No. of measured, independent and observed [I > 2σ(I)] reflections	10167, 3374, 2008
R_int	0.032
(sin θ/λ)_max (Å⁻¹)	0.639

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.039, 0.102, 0.92
No. of reflections	3374
No. of parameters	205
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.55, −0.31

Computer programs: CrysAlis CCD (Oxford Diffraction, 2006), CrysAlis RED (Oxford Diffraction, 2006), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008) and Mercury (Macrae et al., 2006), SHELXTL (Sheldrick, 2008).

Selected bond lengths (Å) top

Mn1—O3	2.1275 (15)	Mn1—O4	2.2023 (14)
Mn1—O5	2.1803 (13)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1—H1A···N1	0.85	1.83	2.619 (2)	153
O4—H4B···O2ⁱ	0.85	1.84	2.621 (2)	151
O5—H5B···O2	0.85	1.83	2.618 (2)	153

Symmetry code: (i) −x+1, y+1/2, −z+1/2.

Acknowledgements

This work was supported by the Natural Science Foundation of Guangxi Province of China (grant No. 0832100).

References

Deeth, R. J. (2008). Inorg. Chem. 47, 6711–6725. Web of Science CrossRef PubMed CAS Google Scholar
Dubois, L., Pécaut, J., Charlot, M.-F., Baffert, C., Collomb, M.-N., Deronzier, A. & Latour, J.-M. (2008). Chem. Eur. J. 14, 3013–3025. Web of Science CSD CrossRef PubMed CAS Google Scholar
Huang, D., Wang, W., Zhang, X., Chen, C., Chen, F., Liu, Q., Liao, D., Li, L. & Sun, L. (2004). Eur. J. Inorg. Chem. pp. 1454–1464. Web of Science CSD CrossRef Google Scholar
Macrae, C. F., Edgington, P. R., McCabe, P., Pidcock, E., Shields, G. P., Taylor, R., Towler, M. & van de Streek, J. (2006). J. Appl. Cryst. 39, 453–457. Web of Science CrossRef CAS IUCr Journals Google Scholar
Oxford Diffraction (2006). CrysAlis CCD and CrysAlis RED. Oxford Diffraction Ltd, Abingdon, England. Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar

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Volume 65| Part 6| June 2009| Page m634

doi:10.1107/S160053680901681X

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metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Bis[4-(2-hy­droxy­benzyl­­idene­amino)benzoato-κO]tetra­kis­­(methanol-κO)manganese(II)

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

Acknowledgements

References

metal-organic compounds

Bis[4-(2-hydroxybenzylideneamino)benzoato-κO]tetrakis(methanol-κO)manganese(II)