[1,1′-Bis(diphenyl­phosphino)cobalto­cenium-κ2P,P′]dichloridoplatinum(II) hexa­fluorido­phosphate

Guan, J.-T.; Zhang, K.-C.; Dai, Z.-Q.

doi:10.1107/S1600536809027925

metal-organic compounds

CRYSTALLOGRAPHIC
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ISSN: 2056-9890

Volume 65| Part 8| August 2009| Page m960

doi:10.1107/S1600536809027925

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[1,1′-Bis(diphenylphosphino)cobaltocenium-κ²P,P′]dichloridoplatinum(II) hexafluoridophosphate

Jin-Tao Guan,^a ^* Kai-Cheng Zhang ^a and Zhi-Qun Dai ^a

^aCollege of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, People's Republic of China
^*Correspondence e-mail: jintaoguan@yahoo.cn

(Received 22 June 2009; accepted 15 July 2009; online 22 July 2009)

The title bimetallic compound, [PtCl₂{Co(C₁₇H₁₄P)₂}]PF₆, was obtained by reaction of 1,1′-bis(diphenylphosphino)cobaltocenium hexafluoridophosphate with bis(acetonitrile)dichloridoplatinum. The Pt^II ion is four-coordinated in a slightly distorted square-planar environment by two P atoms of the 1,1′-bis(diphenylphosphino)cobaltocenium moiety and two Cl atoms. In the crystal structure, molecules are linked by weak C—H⋯F and C—H⋯Cl hydrogen bonds.

Related literature

For background to cobaltocene derivatives applied as catalysts, see: Brasse et al. (2000 ); Yu et al. (2007 ). For the structure of dichloro [1,1′-bis(diphenylphosphino)ferrocene], see: Corain et al. (1989 ). For 1,1′-bis(diphenylphosphino)cobaltocenium tetrafluoridoborate, see: Hou et al. (2007 ).

Experimental

Crystal data

[CoPt(C₁₇H₁₄P)₂Cl₂]PF₆
M_r = 968.39
Triclinic, $[P \overline 1]$
a = 8.9730 (1) Å
b = 10.8770 (1) Å
c = 19.7670 (1) Å
α = 94.9780 (1)°
β = 102.4230 (1)°
γ = 114.2320 (1)°
V = 1684.54 (3) Å³
Z = 2
Mo Kα radiation
μ = 5.00 mm⁻¹
T = 293 K
0.20 × 0.10 × 0.10 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 2004 ) T_min = 0.435, T_max = 0.635
17964 measured reflections
7506 independent reflections
6245 reflections with I > 2σ(I)
R_int = 0.080

Refinement

R[F² > 2σ(F²)] = 0.040
wR(F²) = 0.092
S = 1.00
7506 reflections
424 parameters
H-atom parameters constrained
Δρ_max = 1.98 e Å⁻³
Δρ_min = −1.19 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C3—H3⋯F2ⁱ	0.98	2.32	3.190 (11)	148
C4—H4⋯Cl1ⁱⁱ	0.98	2.80	3.448 (7)	124
C7—H7⋯F5	0.98	2.55	3.513 (14)	168
C12—H12⋯F6ⁱⁱⁱ	0.93	2.54	3.267 (11)	135
C14—H14⋯Cl2ⁱⁱⁱ	0.93	2.79	3.497 (8)	134
C16—H16⋯Cl1	0.93	2.80	3.454 (7)	128
C22—H22⋯F5	0.93	2.51	3.311 (11)	145
Symmetry codes: (i) -x+1, -y+1, -z+2; (ii) x-1, y, z; (iii) x-1, y-1, z.

Data collection: SMART (Bruker, 2001 ); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809027925/jh2085sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536809027925/jh2085Isup2.hkl

checkCIF report

Comment top

Cobaltocene derivatives have been applied as catalysts in cross-coupling reactions (Brasse et al., 2000). As part of our investigations of new catalysts, we have focused our attention on cobaltocenium compounds. Some complexes, such as 1,1'-bis(diphenylphosphino)cobaltocenium tetrafluoridoborate, have been obtained and reported(Hou et al., 2007). Herein, we report the structure of the title compound, (I) (Fig. 1), which is very similar to the complex dichloro [1,1'-bis(diphenylphosphino)ferrocene] (Corain et al., 1989). The PtÎI^ metal ion is in an essentially square-planar environment defined by the two Cl atoms and the two P atoms. The angle between the plane P—Pt—P and the plane Cl—Pt—Cl is 4.0 (3)°. The bond angle of the two P atoms at the Pt atom is 100.64 (5)°, with the two Cl atoms it is 86.08 (5)°. The two substituted Cp rings are staggered and are essentially parallel with an interplanar angle of 3.62 (2)°. The crystal structure contains non-bonded C—H···F and C—H···Cl interactions (Fig.2).

Related literature top

For background to cobaltocene derivatives applied as catalysts, see: Brasse et al. (2000); Yu et al. (2007). For the structure of dichloro [1,1'-bis(diphenylphosphino)ferrocene], see: Corain et al. (1989). For 1,1'-bis(diphenylphosphino)cobaltocenium tetrafluoridoborate, see: Hou et al. (2007).

Experimental top

A mixture of 1,1'-bis(dipehnylphosphio)cobaltocenium hexafluoridophosphate (70.2 mg, 0.1 mmol) and bis(acetonitrile)dichloroplatinum (34.8 mg, 0.1 mmol) in CH₂Cl₂(10 ml) was stirred for 4 h. The precipitate formed was separated by filtration and washed with Et₂O and water, and dried under vacuum to give an yellow powder (85.2 mg). Crystals appropriate for data collection were obtained by slow evaporation from a CH₃NO₂ solution at 293 K.

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXS97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

	Fig. 1. The molecular structure of (I), with atom labels and 50% probability displacement ellipsoids for non-H atoms. H atoms are omitted for clarity.
	Fig. 2. Hydrogen bonding interactions in (I).H atoms not involved in hydrogen bonding have been omitted.

[1,1'-Bis(diphenylphosphino)cobaltocenium- κ²P,P']dichloridoplatinum(II) hexafluoridophosphate top

Crystal data top

[CoPt(C₁₇H₁₄P)₂Cl₂]PF₆	Z = 2
M_r = 968.39	F(000) = 940
Triclinic, P1	D_x = 1.909 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.9730 (1) Å	Cell parameters from 7129 reflections
b = 10.8770 (1) Å	θ = 2.5–27.4°
c = 19.7670 (1) Å	µ = 5.00 mm⁻¹
α = 94.9780 (1)°	T = 293 K
β = 102.4230 (1)°	Block, yellow
γ = 114.2320 (1)°	0.20 × 0.10 × 0.10 mm
V = 1684.54 (3) Å³

Data collection top

Bruker SMART CCD area-detector diffractometer	7506 independent reflections
Radiation source: fine-focus sealed tube	6245 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.080
ϕ and ω scans	θ_max = 27.5°, θ_min = 1.1°
Absorption correction: multi-scan (SADABS; Sheldrick, 2004)	h = −11→11
T_min = 0.435, T_max = 0.635	k = −13→13
17964 measured reflections	l = −25→25

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.092	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.0412P)² + 0.1224P] where P = (F_o² + 2F_c²)/3
7506 reflections	(Δ/σ)_max = 0.027
424 parameters	Δρ_max = 1.98 e Å⁻³
0 restraints	Δρ_min = −1.19 e Å⁻³

Crystal data top

[CoPt(C₁₇H₁₄P)₂Cl₂]PF₆	γ = 114.2320 (1)°
M_r = 968.39	V = 1684.54 (3) Å³
Triclinic, P1	Z = 2
a = 8.9730 (1) Å	Mo Kα radiation
b = 10.8770 (1) Å	µ = 5.00 mm⁻¹
c = 19.7670 (1) Å	T = 293 K
α = 94.9780 (1)°	0.20 × 0.10 × 0.10 mm
β = 102.4230 (1)°

Data collection top

Bruker SMART CCD area-detector diffractometer	7506 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 2004)	6245 reflections with I > 2σ(I)
T_min = 0.435, T_max = 0.635	R_int = 0.080
17964 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.040	0 restraints
wR(F²) = 0.092	H-atom parameters constrained
S = 1.00	Δρ_max = 1.98 e Å⁻³
7506 reflections	Δρ_min = −1.19 e Å⁻³
424 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1	0.39843 (2)	0.173677 (19)	0.691223 (10)	0.02720 (8)
C1	0.1265 (6)	0.0476 (5)	0.8029 (3)	0.0310 (11)
C2	0.1575 (7)	0.0917 (6)	0.8766 (3)	0.0393 (13)
H2	0.2662	0.1217	0.9124	0.047*
C3	0.0069 (7)	0.0887 (6)	0.8896 (3)	0.0402 (14)
H3	−0.0069	0.1162	0.9355	0.048*
C4	−0.1191 (7)	0.0395 (6)	0.8243 (3)	0.0385 (13)
H4	−0.2358	0.0284	0.8171	0.046*
C5	−0.0475 (6)	0.0153 (5)	0.7704 (3)	0.0335 (12)
H5	−0.1066	−0.0182	0.7199	0.040*
C6	0.1783 (7)	0.3358 (5)	0.7545 (3)	0.0313 (11)
C7	0.2929 (8)	0.3902 (6)	0.8247 (3)	0.0453 (15)
H7	0.4113	0.4042	0.8385	0.054*
C8	0.2032 (11)	0.4171 (7)	0.8706 (4)	0.061 (2)
H8	0.2486	0.4506	0.9218	0.074*
C9	0.0375 (11)	0.3835 (7)	0.8310 (4)	0.060 (2)
H9	−0.0523	0.3899	0.8496	0.072*
C10	0.0197 (8)	0.3319 (6)	0.7586 (3)	0.0462 (15)
H10	−0.0830	0.3002	0.7191	0.055*
C11	0.1492 (7)	−0.1487 (5)	0.7122 (3)	0.0350 (12)
C12	0.0321 (8)	−0.2418 (6)	0.7413 (3)	0.0507 (16)
H12	0.0269	−0.2148	0.7864	0.061*
C13	−0.0751 (8)	−0.3725 (7)	0.7043 (4)	0.0605 (19)
H13	−0.1526	−0.4341	0.7241	0.073*
C14	−0.0672 (8)	−0.4123 (6)	0.6369 (4)	0.0574 (18)
H14	−0.1420	−0.5001	0.6109	0.069*
C15	0.0499 (8)	−0.3231 (7)	0.6084 (4)	0.0519 (16)
H15	0.0562	−0.3515	0.5638	0.062*
C16	0.1584 (7)	−0.1917 (6)	0.6453 (3)	0.0409 (14)
H16	0.2376	−0.1316	0.6257	0.049*
C17	0.4359 (7)	0.0302 (6)	0.8356 (3)	0.0373 (13)
C18	0.4344 (8)	−0.0865 (7)	0.8568 (3)	0.0513 (16)
H18	0.3546	−0.1725	0.8305	0.062*
C19	0.5543 (11)	−0.0755 (10)	0.9187 (4)	0.073 (2)
H19	0.5538	−0.1545	0.9335	0.088*
C20	0.6699 (10)	0.0491 (11)	0.9567 (4)	0.074 (3)
H20	0.7482	0.0555	0.9978	0.089*
C21	0.6736 (8)	0.1670 (10)	0.9353 (4)	0.068 (2)
H21	0.7538	0.2524	0.9622	0.081*
C22	0.5600 (7)	0.1594 (7)	0.8746 (3)	0.0495 (16)
H22	0.5650	0.2392	0.8594	0.059*
C23	0.0296 (6)	0.1815 (5)	0.6113 (3)	0.0295 (11)
C24	−0.0224 (7)	0.0419 (6)	0.5888 (3)	0.0367 (13)
H24	0.0462	0.0008	0.6067	0.044*
C25	−0.1782 (7)	−0.0353 (6)	0.5390 (3)	0.0433 (14)
H25	−0.2142	−0.1290	0.5245	0.052*
C26	−0.2803 (7)	0.0236 (7)	0.5108 (3)	0.0494 (17)
H26	−0.3833	−0.0292	0.4769	0.059*
C27	−0.2286 (8)	0.1602 (7)	0.5332 (3)	0.0497 (16)
H27	−0.2978	0.2006	0.5146	0.060*
C28	−0.0737 (7)	0.2407 (6)	0.5835 (3)	0.0419 (14)
H28	−0.0399	0.3340	0.5982	0.050*
C29	0.3237 (7)	0.4478 (6)	0.6492 (3)	0.0360 (12)
C30	0.3094 (8)	0.4536 (6)	0.5787 (3)	0.0458 (15)
H30	0.2458	0.3736	0.5445	0.055*
C31	0.3895 (9)	0.5784 (8)	0.5587 (4)	0.0591 (19)
H31	0.3807	0.5818	0.5112	0.071*
C32	0.4826 (9)	0.6979 (7)	0.6099 (4)	0.063 (2)
H32	0.5356	0.7819	0.5967	0.075*
C33	0.4963 (9)	0.6918 (7)	0.6794 (4)	0.0629 (19)
H33	0.5592	0.7720	0.7136	0.075*
C34	0.4184 (8)	0.5689 (6)	0.6996 (3)	0.0513 (16)
H34	0.4289	0.5664	0.7472	0.062*
Cl1	0.57300 (18)	0.06097 (16)	0.69406 (8)	0.0458 (4)
Cl2	0.5467 (2)	0.30193 (16)	0.61893 (9)	0.0502 (4)
Co1	0.08481 (9)	0.21409 (8)	0.82014 (4)	0.03369 (17)
P1	0.27781 (16)	0.02746 (14)	0.75901 (7)	0.0295 (3)
P2	0.23250 (16)	0.28380 (13)	0.67663 (7)	0.0285 (3)
F1	0.7096 (13)	0.6711 (9)	0.8492 (4)	0.209 (4)
F4	0.9060 (8)	0.6276 (8)	0.9842 (3)	0.129 (2)
F3	0.6545 (11)	0.6101 (15)	0.9389 (5)	0.255 (6)
F5	0.7334 (12)	0.4950 (8)	0.8797 (7)	0.265 (6)
F2	0.8821 (13)	0.7923 (8)	0.9449 (5)	0.230 (5)
F6	0.9614 (11)	0.6650 (12)	0.8885 (4)	0.211 (5)
P3	0.8058 (3)	0.6409 (2)	0.91318 (10)	0.0653 (5)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.02182 (10)	0.02686 (12)	0.03064 (12)	0.00777 (8)	0.00884 (8)	0.00572 (8)
C1	0.030 (3)	0.028 (3)	0.037 (3)	0.012 (2)	0.013 (2)	0.012 (2)
C2	0.036 (3)	0.054 (4)	0.029 (3)	0.019 (3)	0.010 (2)	0.012 (3)
C3	0.045 (3)	0.048 (4)	0.036 (3)	0.022 (3)	0.021 (3)	0.018 (3)
C4	0.032 (3)	0.041 (3)	0.046 (3)	0.014 (2)	0.017 (3)	0.014 (3)
C5	0.033 (3)	0.032 (3)	0.032 (3)	0.010 (2)	0.010 (2)	0.005 (2)
C6	0.037 (3)	0.024 (3)	0.035 (3)	0.012 (2)	0.014 (2)	0.008 (2)
C7	0.046 (3)	0.031 (3)	0.038 (3)	0.001 (3)	0.008 (3)	−0.002 (3)
C8	0.094 (6)	0.037 (4)	0.043 (4)	0.016 (4)	0.028 (4)	0.000 (3)
C9	0.089 (6)	0.057 (5)	0.067 (5)	0.047 (4)	0.049 (4)	0.020 (4)
C10	0.052 (4)	0.044 (4)	0.059 (4)	0.029 (3)	0.026 (3)	0.024 (3)
C11	0.035 (3)	0.030 (3)	0.043 (3)	0.016 (2)	0.015 (2)	0.007 (2)
C12	0.060 (4)	0.032 (3)	0.059 (4)	0.014 (3)	0.030 (3)	0.008 (3)
C13	0.056 (4)	0.042 (4)	0.081 (5)	0.012 (3)	0.036 (4)	0.010 (4)
C14	0.045 (4)	0.029 (3)	0.085 (5)	0.008 (3)	0.015 (4)	−0.003 (3)
C15	0.049 (4)	0.046 (4)	0.055 (4)	0.017 (3)	0.017 (3)	−0.003 (3)
C16	0.034 (3)	0.038 (3)	0.048 (3)	0.012 (3)	0.014 (3)	0.006 (3)
C17	0.033 (3)	0.055 (4)	0.036 (3)	0.026 (3)	0.013 (2)	0.018 (3)
C18	0.055 (4)	0.060 (4)	0.057 (4)	0.036 (3)	0.023 (3)	0.027 (3)
C19	0.074 (5)	0.115 (8)	0.068 (5)	0.064 (5)	0.032 (4)	0.059 (5)
C20	0.052 (4)	0.142 (9)	0.049 (4)	0.057 (5)	0.018 (4)	0.042 (5)
C21	0.038 (4)	0.111 (7)	0.043 (4)	0.029 (4)	0.003 (3)	0.005 (4)
C22	0.041 (3)	0.061 (4)	0.047 (4)	0.026 (3)	0.009 (3)	0.005 (3)
C23	0.029 (3)	0.032 (3)	0.028 (3)	0.014 (2)	0.007 (2)	0.007 (2)
C24	0.034 (3)	0.038 (3)	0.039 (3)	0.016 (2)	0.011 (2)	0.008 (2)
C25	0.039 (3)	0.035 (3)	0.042 (3)	0.006 (3)	0.009 (3)	−0.006 (3)
C26	0.028 (3)	0.067 (5)	0.040 (3)	0.011 (3)	0.006 (3)	−0.003 (3)
C27	0.037 (3)	0.067 (5)	0.052 (4)	0.033 (3)	0.006 (3)	0.012 (3)
C28	0.038 (3)	0.040 (3)	0.049 (4)	0.023 (3)	0.007 (3)	0.002 (3)
C29	0.034 (3)	0.032 (3)	0.041 (3)	0.013 (2)	0.012 (2)	0.012 (2)
C30	0.051 (4)	0.042 (4)	0.048 (4)	0.020 (3)	0.019 (3)	0.015 (3)
C31	0.066 (4)	0.065 (5)	0.060 (4)	0.032 (4)	0.028 (4)	0.034 (4)
C32	0.058 (4)	0.041 (4)	0.092 (6)	0.017 (3)	0.029 (4)	0.036 (4)
C33	0.065 (5)	0.034 (4)	0.070 (5)	0.006 (3)	0.012 (4)	0.010 (3)
C34	0.051 (4)	0.037 (4)	0.050 (4)	0.007 (3)	0.008 (3)	0.013 (3)
Cl1	0.0384 (7)	0.0527 (9)	0.0572 (9)	0.0263 (7)	0.0193 (7)	0.0171 (7)
Cl2	0.0529 (9)	0.0433 (9)	0.0666 (10)	0.0201 (7)	0.0379 (8)	0.0221 (7)
Co1	0.0351 (4)	0.0350 (4)	0.0317 (4)	0.0140 (3)	0.0140 (3)	0.0054 (3)
P1	0.0275 (6)	0.0304 (7)	0.0321 (7)	0.0127 (6)	0.0101 (6)	0.0091 (6)
P2	0.0282 (6)	0.0246 (7)	0.0307 (7)	0.0088 (5)	0.0100 (6)	0.0055 (5)
F1	0.269 (10)	0.196 (9)	0.115 (5)	0.133 (8)	−0.088 (6)	−0.008 (5)
F4	0.119 (5)	0.172 (6)	0.091 (4)	0.062 (4)	0.013 (3)	0.053 (4)
F3	0.122 (6)	0.457 (19)	0.210 (9)	0.118 (9)	0.102 (7)	0.085 (10)
F5	0.172 (8)	0.088 (6)	0.445 (17)	0.039 (5)	−0.002 (10)	−0.082 (8)
F2	0.255 (11)	0.105 (6)	0.217 (9)	0.073 (6)	−0.119 (8)	−0.031 (6)
F6	0.165 (7)	0.350 (15)	0.138 (6)	0.101 (8)	0.091 (6)	0.074 (8)
P3	0.0571 (11)	0.0653 (14)	0.0542 (11)	0.0153 (10)	0.0056 (9)	0.0014 (10)

Geometric parameters (Å, º) top

Pt1—P2	2.2525 (14)	C15—H15	0.9300
Pt1—P1	2.2533 (13)	C16—H16	0.9300
Pt1—Cl2	2.3235 (13)	C17—C18	1.366 (8)
Pt1—Cl1	2.3473 (15)	C17—C22	1.403 (8)
C1—C2	1.424 (7)	C17—P1	1.828 (5)
C1—C5	1.432 (7)	C18—C19	1.403 (9)
C1—P1	1.833 (5)	C18—H18	0.9300
C1—Co1	2.010 (5)	C19—C20	1.346 (12)
C2—C3	1.416 (8)	C19—H19	0.9300
C2—Co1	2.025 (6)	C20—C21	1.374 (11)
C2—H2	0.9800	C20—H20	0.9300
C3—C4	1.409 (8)	C21—C22	1.367 (9)
C3—Co1	2.046 (5)	C21—H21	0.9300
C3—H3	0.9800	C22—H22	0.9300
C4—C5	1.415 (7)	C23—C28	1.381 (8)
C4—Co1	2.049 (5)	C23—C24	1.390 (8)
C4—H4	0.9800	C23—P2	1.816 (5)
C5—Co1	2.018 (5)	C24—C25	1.388 (8)
C5—H5	0.9800	C24—H24	0.9300
C6—C10	1.426 (8)	C25—C26	1.373 (9)
C6—C7	1.441 (8)	C25—H25	0.9300
C6—P2	1.823 (5)	C26—C27	1.361 (9)
C6—Co1	1.999 (5)	C26—H26	0.9300
C7—C8	1.420 (9)	C27—C28	1.394 (8)
C7—Co1	2.032 (5)	C27—H27	0.9300
C7—H7	0.9800	C28—H28	0.9300
C8—C9	1.400 (10)	C29—C30	1.381 (8)
C8—Co1	2.058 (6)	C29—C34	1.391 (8)
C8—H8	0.9800	C29—P2	1.818 (5)
C9—C10	1.441 (9)	C30—C31	1.390 (9)
C9—Co1	2.057 (7)	C30—H30	0.9300
C9—H9	0.9800	C31—C32	1.389 (10)
C10—Co1	2.011 (6)	C31—H31	0.9300
C10—H10	0.9800	C32—C33	1.364 (9)
C11—C16	1.394 (7)	C32—H32	0.9300
C11—C12	1.396 (7)	C33—C34	1.372 (8)
C11—P1	1.810 (6)	C33—H33	0.9300
C12—C13	1.369 (9)	C34—H34	0.9300
C12—H12	0.9300	F1—P3	1.512 (7)
C13—C14	1.392 (9)	F4—P3	1.550 (6)
C13—H13	0.9300	F3—P3	1.472 (7)
C14—C15	1.369 (9)	F5—P3	1.472 (8)
C14—H14	0.9300	F2—P3	1.511 (8)
C15—C16	1.377 (8)	F6—P3	1.507 (7)

P2—Pt1—P1	100.63 (5)	C25—C24—C23	119.1 (5)
P2—Pt1—Cl2	88.81 (5)	C25—C24—H24	120.5
P1—Pt1—Cl2	170.32 (5)	C23—C24—H24	120.5
P2—Pt1—Cl1	173.88 (5)	C26—C25—C24	121.5 (6)
P1—Pt1—Cl1	84.37 (5)	C26—C25—H25	119.3
Cl2—Pt1—Cl1	86.08 (5)	C24—C25—H25	119.3
C2—C1—C5	106.8 (4)	C27—C26—C25	119.1 (6)
C2—C1—P1	126.3 (4)	C27—C26—H26	120.5
C5—C1—P1	126.8 (4)	C25—C26—H26	120.5
C2—C1—Co1	69.9 (3)	C26—C27—C28	121.0 (6)
C5—C1—Co1	69.5 (3)	C26—C27—H27	119.5
P1—C1—Co1	128.0 (3)	C28—C27—H27	119.5
C3—C2—C1	108.9 (5)	C23—C28—C27	119.8 (6)
C3—C2—Co1	70.4 (3)	C23—C28—H28	120.1
C1—C2—Co1	68.8 (3)	C27—C28—H28	120.1
C3—C2—H2	125.5	C30—C29—C34	118.9 (5)
C1—C2—H2	125.5	C30—C29—P2	120.7 (4)
Co1—C2—H2	125.5	C34—C29—P2	120.2 (4)
C4—C3—C2	107.5 (5)	C29—C30—C31	120.3 (6)
C4—C3—Co1	70.0 (3)	C29—C30—H30	119.8
C2—C3—Co1	68.9 (3)	C31—C30—H30	119.8
C4—C3—H3	126.3	C32—C31—C30	119.7 (6)
C2—C3—H3	126.3	C32—C31—H31	120.2
Co1—C3—H3	126.3	C30—C31—H31	120.2
C3—C4—C5	109.0 (5)	C33—C32—C31	119.8 (6)
C3—C4—Co1	69.7 (3)	C33—C32—H32	120.1
C5—C4—Co1	68.5 (3)	C31—C32—H32	120.1
C3—C4—H4	125.5	C32—C33—C34	120.8 (7)
C5—C4—H4	125.5	C32—C33—H33	119.6
Co1—C4—H4	125.5	C34—C33—H33	119.6
C4—C5—C1	107.8 (5)	C33—C34—C29	120.4 (6)
C4—C5—Co1	70.8 (3)	C33—C34—H34	119.8
C1—C5—Co1	68.9 (3)	C29—C34—H34	119.8
C4—C5—H5	126.1	C6—Co1—C1	107.7 (2)
C1—C5—H5	126.1	C6—Co1—C10	41.7 (2)
Co1—C5—H5	126.1	C1—Co1—C10	134.9 (2)
C10—C6—C7	107.2 (5)	C6—Co1—C5	111.5 (2)
C10—C6—P2	127.8 (4)	C1—Co1—C5	41.7 (2)
C7—C6—P2	125.0 (4)	C10—Co1—C5	109.1 (2)
C10—C6—Co1	69.6 (3)	C6—Co1—C2	134.9 (2)
C7—C6—Co1	70.3 (3)	C1—Co1—C2	41.3 (2)
P2—C6—Co1	125.5 (3)	C10—Co1—C2	175.8 (2)
C8—C7—C6	108.0 (6)	C5—Co1—C2	69.1 (2)
C8—C7—Co1	70.7 (4)	C6—Co1—C7	41.9 (2)
C6—C7—Co1	67.8 (3)	C1—Co1—C7	111.7 (2)
C8—C7—H7	126.0	C10—Co1—C7	69.6 (3)
C6—C7—H7	126.0	C5—Co1—C7	142.6 (2)
Co1—C7—H7	126.0	C2—Co1—C7	109.3 (3)
C9—C8—C7	108.8 (6)	C6—Co1—C3	175.5 (2)
C9—C8—Co1	70.1 (4)	C1—Co1—C3	69.5 (2)
C7—C8—Co1	68.7 (3)	C10—Co1—C3	142.8 (2)
C9—C8—H8	125.6	C5—Co1—C3	68.9 (2)
C7—C8—H8	125.6	C2—Co1—C3	40.7 (2)
Co1—C8—H8	125.6	C7—Co1—C3	135.3 (2)
C8—C9—C10	108.2 (6)	C6—Co1—C4	142.7 (2)
C8—C9—Co1	70.1 (4)	C1—Co1—C4	69.0 (2)
C10—C9—Co1	67.5 (3)	C10—Co1—C4	113.4 (2)
C8—C9—H9	125.9	C5—Co1—C4	40.7 (2)
C10—C9—H9	125.9	C2—Co1—C4	68.0 (2)
Co1—C9—H9	125.9	C7—Co1—C4	175.4 (2)
C6—C10—C9	107.8 (6)	C3—Co1—C4	40.2 (2)
C6—C10—Co1	68.7 (3)	C6—Co1—C9	69.7 (2)
C9—C10—Co1	71.0 (4)	C1—Co1—C9	176.4 (2)
C6—C10—H10	126.1	C10—Co1—C9	41.5 (3)
C9—C10—H10	126.1	C5—Co1—C9	136.4 (3)
Co1—C10—H10	126.1	C2—Co1—C9	142.3 (3)
C16—C11—C12	119.0 (5)	C7—Co1—C9	68.2 (3)
C16—C11—P1	120.9 (4)	C3—Co1—C9	113.3 (2)
C12—C11—P1	120.0 (4)	C4—Co1—C9	111.4 (3)
C13—C12—C11	120.8 (6)	C6—Co1—C8	69.6 (2)
C13—C12—H12	119.6	C1—Co1—C8	142.3 (3)
C11—C12—H12	119.6	C10—Co1—C8	68.9 (3)
C12—C13—C14	119.4 (6)	C5—Co1—C8	175.9 (3)
C12—C13—H13	120.3	C2—Co1—C8	113.2 (3)
C14—C13—H13	120.3	C7—Co1—C8	40.6 (2)
C15—C14—C13	120.4 (6)	C3—Co1—C8	110.4 (2)
C15—C14—H14	119.8	C4—Co1—C8	136.2 (2)
C13—C14—H14	119.8	C9—Co1—C8	39.8 (3)
C14—C15—C16	120.5 (6)	C11—P1—C17	108.6 (3)
C14—C15—H15	119.8	C11—P1—C1	98.9 (2)
C16—C15—H15	119.8	C17—P1—C1	99.8 (2)
C15—C16—C11	119.9 (5)	C11—P1—Pt1	114.09 (18)
C15—C16—H16	120.0	C17—P1—Pt1	111.89 (17)
C11—C16—H16	120.0	C1—P1—Pt1	121.89 (17)
C18—C17—C22	119.8 (6)	C23—P2—C29	105.9 (2)
C18—C17—P1	123.0 (5)	C23—P2—C6	104.9 (2)
C22—C17—P1	117.2 (5)	C29—P2—C6	100.4 (2)
C17—C18—C19	119.5 (7)	C23—P2—Pt1	112.19 (18)
C17—C18—H18	120.2	C29—P2—Pt1	115.15 (18)
C19—C18—H18	120.2	C6—P2—Pt1	116.92 (18)
C20—C19—C18	120.1 (8)	F5—P3—F3	89.2 (7)
C20—C19—H19	119.9	F5—P3—F6	88.5 (6)
C18—C19—H19	119.9	F3—P3—F6	176.5 (7)
C19—C20—C21	120.8 (7)	F5—P3—F2	177.7 (7)
C19—C20—H20	119.6	F3—P3—F2	92.5 (7)
C21—C20—H20	119.6	F6—P3—F2	89.9 (6)
C22—C21—C20	120.4 (8)	F5—P3—F1	91.4 (6)
C22—C21—H21	119.8	F3—P3—F1	86.0 (6)
C20—C21—H21	119.8	F6—P3—F1	96.7 (6)
C21—C22—C17	119.4 (7)	F2—P3—F1	87.1 (5)
C21—C22—H22	120.3	F5—P3—F4	95.7 (6)
C17—C22—H22	120.3	F3—P3—F4	91.4 (5)
C28—C23—C24	119.5 (5)	F6—P3—F4	86.2 (4)
C28—C23—P2	120.8 (4)	F2—P3—F4	85.9 (4)
C24—C23—P2	119.7 (4)	F1—P3—F4	172.4 (5)

C5—C1—C2—C3	−0.8 (6)	C3—C2—Co1—C1	−120.5 (5)
P1—C1—C2—C3	−177.8 (4)	C3—C2—Co1—C10	−147 (3)
Co1—C1—C2—C3	59.1 (4)	C1—C2—Co1—C10	−27 (4)
C5—C1—C2—Co1	−59.9 (3)	C3—C2—Co1—C5	−81.5 (4)
P1—C1—C2—Co1	123.0 (4)	C1—C2—Co1—C5	39.0 (3)
C1—C2—C3—C4	1.5 (7)	C3—C2—Co1—C7	138.4 (4)
Co1—C2—C3—C4	59.6 (4)	C1—C2—Co1—C7	−101.2 (3)
C1—C2—C3—Co1	−58.1 (4)	C1—C2—Co1—C3	120.5 (5)
C2—C3—C4—C5	−1.6 (7)	C3—C2—Co1—C4	−37.6 (3)
Co1—C3—C4—C5	57.3 (4)	C1—C2—Co1—C4	82.9 (3)
C2—C3—C4—Co1	−58.9 (4)	C3—C2—Co1—C9	59.3 (6)
C3—C4—C5—C1	1.1 (6)	C1—C2—Co1—C9	179.7 (4)
Co1—C4—C5—C1	59.2 (3)	C3—C2—Co1—C8	94.8 (4)
C3—C4—C5—Co1	−58.1 (4)	C1—C2—Co1—C8	−144.7 (3)
C2—C1—C5—C4	−0.2 (6)	C8—C7—Co1—C6	119.8 (6)
P1—C1—C5—C4	176.8 (4)	C8—C7—Co1—C1	−147.6 (4)
Co1—C1—C5—C4	−60.4 (4)	C6—C7—Co1—C1	92.7 (4)
C2—C1—C5—Co1	60.2 (4)	C8—C7—Co1—C10	80.9 (5)
P1—C1—C5—Co1	−122.8 (4)	C6—C7—Co1—C10	−38.8 (3)
C10—C6—C7—C8	0.7 (6)	C8—C7—Co1—C5	176.0 (4)
P2—C6—C7—C8	−179.6 (4)	C6—C7—Co1—C5	56.2 (5)
Co1—C6—C7—C8	−59.5 (4)	C8—C7—Co1—C2	−103.4 (4)
C10—C6—C7—Co1	60.1 (4)	C6—C7—Co1—C2	136.8 (3)
P2—C6—C7—Co1	−120.1 (4)	C8—C7—Co1—C3	−65.3 (6)
C6—C7—C8—C9	−1.0 (7)	C6—C7—Co1—C3	174.9 (3)
Co1—C7—C8—C9	−58.7 (5)	C8—C7—Co1—C4	−50 (3)
C6—C7—C8—Co1	57.7 (4)	C6—C7—Co1—C4	−170 (3)
C7—C8—C9—C10	1.0 (8)	C8—C7—Co1—C9	36.4 (4)
Co1—C8—C9—C10	−56.9 (5)	C6—C7—Co1—C9	−83.4 (4)
C7—C8—C9—Co1	57.9 (5)	C6—C7—Co1—C8	−119.8 (6)
C7—C6—C10—C9	−0.1 (6)	C4—C3—Co1—C6	−132 (3)
P2—C6—C10—C9	−179.8 (4)	C2—C3—Co1—C6	−14 (3)
Co1—C6—C10—C9	60.5 (4)	C4—C3—Co1—C1	−81.5 (4)
C7—C6—C10—Co1	−60.6 (4)	C2—C3—Co1—C1	37.4 (3)
P2—C6—C10—Co1	119.7 (4)	C4—C3—Co1—C10	57.4 (6)
C8—C9—C10—C6	−0.6 (7)	C2—C3—Co1—C10	176.2 (4)
Co1—C9—C10—C6	−59.0 (4)	C4—C3—Co1—C5	−36.7 (3)
C8—C9—C10—Co1	58.5 (5)	C2—C3—Co1—C5	82.1 (4)
C16—C11—C12—C13	−1.5 (10)	C4—C3—Co1—C2	−118.9 (5)
P1—C11—C12—C13	175.0 (6)	C4—C3—Co1—C7	178.1 (4)
C11—C12—C13—C14	−0.2 (11)	C2—C3—Co1—C7	−63.0 (5)
C12—C13—C14—C15	1.8 (11)	C2—C3—Co1—C4	118.9 (5)
C13—C14—C15—C16	−1.7 (11)	C4—C3—Co1—C9	96.0 (4)
C14—C15—C16—C11	0.0 (10)	C2—C3—Co1—C9	−145.1 (4)
C12—C11—C16—C15	1.6 (9)	C4—C3—Co1—C8	138.9 (4)
P1—C11—C16—C15	−174.9 (5)	C2—C3—Co1—C8	−102.2 (4)
C22—C17—C18—C19	1.9 (9)	C3—C4—Co1—C6	174.5 (4)
P1—C17—C18—C19	−176.2 (5)	C5—C4—Co1—C6	53.3 (5)
C17—C18—C19—C20	−0.1 (10)	C3—C4—Co1—C1	82.6 (4)
C18—C19—C20—C21	−0.7 (11)	C5—C4—Co1—C1	−38.6 (3)
C19—C20—C21—C22	−0.4 (11)	C3—C4—Co1—C10	−146.3 (4)
C20—C21—C22—C17	2.1 (10)	C5—C4—Co1—C10	92.5 (4)
C18—C17—C22—C21	−2.9 (9)	C3—C4—Co1—C5	121.2 (5)
P1—C17—C22—C21	175.3 (5)	C3—C4—Co1—C2	38.0 (3)
C28—C23—C24—C25	−0.5 (8)	C5—C4—Co1—C2	−83.2 (4)
P2—C23—C24—C25	179.7 (4)	C3—C4—Co1—C7	−17 (3)
C23—C24—C25—C26	1.2 (8)	C5—C4—Co1—C7	−138 (3)
C24—C25—C26—C27	−1.3 (9)	C5—C4—Co1—C3	−121.2 (5)
C25—C26—C27—C28	0.7 (9)	C3—C4—Co1—C9	−101.3 (4)
C24—C23—C28—C27	0.0 (8)	C5—C4—Co1—C9	137.5 (4)
P2—C23—C28—C27	179.8 (4)	C3—C4—Co1—C8	−63.0 (5)
C26—C27—C28—C23	−0.1 (9)	C5—C4—Co1—C8	175.9 (4)
C34—C29—C30—C31	0.5 (9)	C8—C9—Co1—C6	−82.1 (4)
P2—C29—C30—C31	−175.5 (5)	C10—C9—Co1—C6	38.4 (4)
C29—C30—C31—C32	−0.8 (10)	C8—C9—Co1—C1	−126 (4)
C30—C31—C32—C33	0.7 (11)	C10—C9—Co1—C1	−5 (4)
C31—C32—C33—C34	−0.3 (12)	C8—C9—Co1—C10	−120.5 (6)
C32—C33—C34—C29	0.0 (11)	C8—C9—Co1—C5	177.6 (3)
C30—C29—C34—C33	−0.1 (10)	C10—C9—Co1—C5	−61.9 (5)
P2—C29—C34—C33	175.9 (5)	C8—C9—Co1—C2	56.6 (6)
C10—C6—Co1—C1	139.1 (4)	C10—C9—Co1—C2	177.2 (4)
C7—C6—Co1—C1	−103.0 (4)	C8—C9—Co1—C7	−37.1 (4)
P2—C6—Co1—C1	16.5 (4)	C10—C9—Co1—C7	83.4 (4)
C7—C6—Co1—C10	117.9 (5)	C8—C9—Co1—C3	94.3 (4)
P2—C6—Co1—C10	−122.6 (5)	C10—C9—Co1—C3	−145.2 (4)
C10—C6—Co1—C5	95.0 (4)	C8—C9—Co1—C4	137.9 (4)
C7—C6—Co1—C5	−147.2 (4)	C10—C9—Co1—C4	−101.6 (4)
P2—C6—Co1—C5	−27.6 (4)	C10—C9—Co1—C8	120.5 (6)
C10—C6—Co1—C2	176.4 (4)	C9—C8—Co1—C6	82.4 (4)
C7—C6—Co1—C2	−65.7 (5)	C7—C8—Co1—C6	−38.2 (4)
P2—C6—Co1—C2	53.8 (5)	C9—C8—Co1—C1	175.2 (3)
C10—C6—Co1—C7	−117.9 (5)	C7—C8—Co1—C1	54.6 (6)
P2—C6—Co1—C7	119.5 (5)	C9—C8—Co1—C10	37.7 (4)
C10—C6—Co1—C3	−171 (3)	C7—C8—Co1—C10	−82.9 (4)
C7—C6—Co1—C3	−53 (3)	C9—C8—Co1—C5	−24 (3)
P2—C6—Co1—C3	66 (3)	C7—C8—Co1—C5	−144 (3)
C10—C6—Co1—C4	60.7 (5)	C9—C8—Co1—C2	−146.3 (4)
C7—C6—Co1—C4	178.6 (4)	C7—C8—Co1—C2	93.1 (4)
P2—C6—Co1—C4	−61.8 (5)	C9—C8—Co1—C7	120.6 (6)
C10—C6—Co1—C9	−38.2 (4)	C9—C8—Co1—C3	−102.4 (4)
C7—C6—Co1—C9	79.6 (4)	C7—C8—Co1—C3	137.0 (4)
P2—C6—Co1—C9	−160.8 (5)	C9—C8—Co1—C4	−64.5 (5)
C10—C6—Co1—C8	−80.8 (4)	C7—C8—Co1—C4	174.9 (4)
C7—C6—Co1—C8	37.1 (4)	C7—C8—Co1—C9	−120.6 (6)
P2—C6—Co1—C8	156.6 (5)	C16—C11—P1—C17	−111.8 (5)
C2—C1—Co1—C6	139.5 (3)	C12—C11—P1—C17	71.7 (5)
C5—C1—Co1—C6	−102.8 (3)	C16—C11—P1—C1	144.6 (5)
P1—C1—Co1—C6	18.6 (4)	C12—C11—P1—C1	−31.8 (6)
C2—C1—Co1—C10	177.4 (3)	C16—C11—P1—Pt1	13.7 (5)
C5—C1—Co1—C10	−64.9 (4)	C12—C11—P1—Pt1	−162.8 (5)
P1—C1—Co1—C10	56.4 (5)	C18—C17—P1—C11	−8.5 (5)
C2—C1—Co1—C5	−117.8 (4)	C22—C17—P1—C11	173.3 (4)
P1—C1—Co1—C5	121.3 (5)	C18—C17—P1—C1	94.4 (5)
C5—C1—Co1—C2	117.8 (4)	C22—C17—P1—C1	−83.8 (4)
P1—C1—Co1—C2	−120.9 (5)	C18—C17—P1—Pt1	−135.3 (4)
C2—C1—Co1—C7	95.0 (3)	C22—C17—P1—Pt1	46.5 (5)
C5—C1—Co1—C7	−147.2 (3)	C2—C1—P1—C11	126.1 (5)
P1—C1—Co1—C7	−25.9 (4)	C5—C1—P1—C11	−50.4 (5)
C2—C1—Co1—C3	−36.9 (3)	Co1—C1—P1—C11	−142.0 (4)
C5—C1—Co1—C3	80.9 (3)	C2—C1—P1—C17	15.4 (5)
P1—C1—Co1—C3	−157.8 (4)	C5—C1—P1—C17	−161.1 (5)
C2—C1—Co1—C4	−80.0 (3)	Co1—C1—P1—C17	107.2 (4)
C5—C1—Co1—C4	37.7 (3)	C2—C1—P1—Pt1	−108.2 (5)
P1—C1—Co1—C4	159.1 (4)	C5—C1—P1—Pt1	75.3 (5)
C2—C1—Co1—C9	−178 (4)	Co1—C1—P1—Pt1	−16.3 (4)
C5—C1—Co1—C9	−60 (4)	P2—Pt1—P1—C11	104.7 (2)
P1—C1—Co1—C9	62 (4)	Cl2—Pt1—P1—C11	−62.6 (4)
C2—C1—Co1—C8	60.2 (5)	Cl1—Pt1—P1—C11	−71.8 (2)
C5—C1—Co1—C8	178.0 (4)	P2—Pt1—P1—C17	−131.6 (2)
P1—C1—Co1—C8	−60.7 (5)	Cl2—Pt1—P1—C17	61.1 (4)
C9—C10—Co1—C6	−118.8 (6)	Cl1—Pt1—P1—C17	51.9 (2)
C6—C10—Co1—C1	−61.7 (5)	P2—Pt1—P1—C1	−13.8 (2)
C9—C10—Co1—C1	179.5 (4)	Cl2—Pt1—P1—C1	178.9 (3)
C6—C10—Co1—C5	−101.2 (3)	Cl1—Pt1—P1—C1	169.7 (2)
C9—C10—Co1—C5	140.0 (4)	C28—C23—P2—C29	−39.1 (5)
C6—C10—Co1—C2	−37 (4)	C24—C23—P2—C29	140.6 (4)
C9—C10—Co1—C2	−156 (3)	C28—C23—P2—C6	66.5 (5)
C6—C10—Co1—C7	39.0 (3)	C24—C23—P2—C6	−113.7 (4)
C9—C10—Co1—C7	−79.8 (4)	C28—C23—P2—Pt1	−165.6 (4)
C6—C10—Co1—C3	178.9 (4)	C24—C23—P2—Pt1	14.2 (4)
C9—C10—Co1—C3	60.0 (6)	C30—C29—P2—C23	−39.7 (5)
C6—C10—Co1—C4	−144.8 (3)	C34—C29—P2—C23	144.4 (5)
C9—C10—Co1—C4	96.4 (4)	C30—C29—P2—C6	−148.6 (5)
C6—C10—Co1—C9	118.8 (6)	C34—C29—P2—C6	35.5 (5)
C6—C10—Co1—C8	82.6 (4)	C30—C29—P2—Pt1	84.9 (5)
C9—C10—Co1—C8	−36.2 (4)	C34—C29—P2—Pt1	−91.0 (5)
C4—C5—Co1—C6	−148.5 (3)	C10—C6—P2—C23	−15.8 (5)
C1—C5—Co1—C6	92.7 (3)	C7—C6—P2—C23	164.4 (4)
C4—C5—Co1—C1	118.8 (4)	Co1—C6—P2—C23	74.8 (4)
C4—C5—Co1—C10	−104.0 (4)	C10—C6—P2—C29	93.9 (5)
C1—C5—Co1—C10	137.3 (3)	C7—C6—P2—C29	−85.8 (5)
C4—C5—Co1—C2	80.1 (3)	Co1—C6—P2—C29	−175.4 (3)
C1—C5—Co1—C2	−38.7 (3)	C10—C6—P2—Pt1	−140.8 (4)
C4—C5—Co1—C7	174.9 (4)	C7—C6—P2—Pt1	39.4 (5)
C1—C5—Co1—C7	56.1 (5)	Co1—C6—P2—Pt1	−50.2 (4)
C4—C5—Co1—C3	36.3 (3)	P1—Pt1—P2—C23	−77.79 (17)
C1—C5—Co1—C3	−82.5 (3)	Cl2—Pt1—P2—C23	100.09 (17)
C1—C5—Co1—C4	−118.8 (4)	Cl1—Pt1—P2—C23	66.8 (5)
C4—C5—Co1—C9	−65.8 (4)	P1—Pt1—P2—C29	160.9 (2)
C1—C5—Co1—C9	175.4 (3)	Cl2—Pt1—P2—C29	−21.2 (2)
C4—C5—Co1—C8	−44 (3)	Cl1—Pt1—P2—C29	−54.4 (5)
C1—C5—Co1—C8	−163 (3)	P1—Pt1—P2—C6	43.48 (19)
C3—C2—Co1—C6	178.5 (3)	Cl2—Pt1—P2—C6	−138.64 (19)
C1—C2—Co1—C6	−61.0 (4)	Cl1—Pt1—P2—C6	−171.9 (5)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C3—H3···F2ⁱ	0.98	2.32	3.190 (11)	148
C4—H4···Cl1ⁱⁱ	0.98	2.80	3.448 (7)	124
C7—H7···F5	0.98	2.55	3.513 (14)	168
C12—H12···F6ⁱⁱⁱ	0.93	2.54	3.267 (11)	135
C14—H14···Cl2ⁱⁱⁱ	0.93	2.79	3.497 (8)	134
C16—H16···Cl1	0.93	2.80	3.454 (7)	128
C22—H22···F5	0.93	2.51	3.311 (11)	145

Symmetry codes: (i) −x+1, −y+1, −z+2; (ii) x−1, y, z; (iii) x−1, y−1, z.

Experimental details

Crystal data
Chemical formula	[CoPt(C₁₇H₁₄P)₂Cl₂]PF₆
M_r	968.39
Crystal system, space group	Triclinic, P1
Temperature (K)	293
a, b, c (Å)	8.9730 (1), 10.8770 (1), 19.7670 (1)
α, β, γ (°)	94.9780 (1), 102.4230 (1), 114.2320 (1)
V (Å³)	1684.54 (3)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	5.00
Crystal size (mm)	0.20 × 0.10 × 0.10

Data collection
Diffractometer	Bruker SMART CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Sheldrick, 2004)
T_min, T_max	0.435, 0.635
No. of measured, independent and observed [I > 2σ(I)] reflections	17964, 7506, 6245
R_int	0.080
(sin θ/λ)_max (Å⁻¹)	0.650

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.040, 0.092, 1.00
No. of reflections	7506
No. of parameters	424
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	1.98, −1.19

Computer programs: SMART (Bruker, 2001), SAINT (Bruker, 2001), SHELXS97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C3—H3···F2ⁱ	0.98	2.32	3.190 (11)	148
C4—H4···Cl1ⁱⁱ	0.98	2.80	3.448 (7)	124
C7—H7···F5	0.98	2.55	3.513 (14)	168
C12—H12···F6ⁱⁱⁱ	0.93	2.54	3.267 (11)	135
C14—H14···Cl2ⁱⁱⁱ	0.93	2.79	3.497 (8)	134
C16—H16···Cl1	0.93	2.80	3.454 (7)	128
C22—H22···F5	0.93	2.51	3.311 (11)	145

Symmetry codes: (i) −x+1, −y+1, −z+2; (ii) x−1, y, z; (iii) x−1, y−1, z.

Acknowledgements

The authors acknowledge financial support from the National Natural Science Foundation of China (No. 20572029), the New Century Excellent Talents in Universities (NCET-04–0743) and the Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China (No. 705039).

References

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