catena-Poly[[[bis­(N,N-dimethyl­formamide)iron(II)]-{μ-2,2′-bis­(diphenyl­phosphino­yl)-N,N′-[(1R,2R)-cyclo­hexane-1,2-di­yl]dibenzamide}] bis­(perchlorate) N,N-dimethyl­formamide disolvate]

Ferrell, G.R.; Moore, C.; Rheingold, A.L.; Daley, C.J.A.

doi:10.1107/S1600536809045188

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 2 Perspective view of the polymeric cationic portion of the title structure showing three Fe^II centers and the coordination geometry of the oxidized Trost ligand ((1R,2R)-(+)-1,2- diaminocyclohexane-N,N′-bis(2′-diphenyloxophosphinobenzoyl)) that bridges adjacent Fe^II centers in the polymer. H-atoms, co-solvated DMF, and ClO₄⁻ anions are not displayed for clarity. Thermal ellipsoids are drawn at 30% probability.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 65| Part 12| November 2009| Pages m1512-m1513

doi:10.1107/S1600536809045188

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