Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate

Xie, Q.-F.; Huang, M.-L.; Chen, Y.-M.

doi:10.1107/S1600536809047564

metal-organic compounds

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 65| Part 12| December 2009| Page m1660

doi:10.1107/S1600536809047564

Open

access

Bis{μ-1,3-bis[2-(5-bromo-2-oxidobenzylideneamino)ethyl]-2-(5-bromo-2-oxidophenyl)-1,3-imidazolidine}dineodymium(III) N,N-dimethylformamide hexasolvate

Qing-Fan Xie,^a Miao-Ling Huang ^a ^* and Yan-Min Chen ^a

^aDepartment of Chemistry and Science of Life, Quanzhou Normal University, Fujian 362000, People's Republic of China
^*Correspondence e-mail: hml301@163.com

(Received 31 October 2009; accepted 10 November 2009; online 21 November 2009)

In the title centrosymmetric dinuclear complex, [Nd₂(C₂₇H₂₄Br₃N₄O₃)₂]·6C₃H₇NO, the Nd^III ion is coordinated in a slightly distorted square-antiprismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis[2-(5-bromo-2-oxidobenzylamino)ethyl]-2-(5-bromo-2-oxidophenyl)-1,3-imidazolidine ligands. The Nd⋯Nd separation is 4.5012 (12) Å.

Related literature

For general background to tripodal ligands, see: Bian et al. (2008 ); Palaniandavar et al. (2006 ); Velusamy et al. (2004 ). For related structures, see: Fondo et al. (2005 ); Xie et al. (2009 ); Yang et al. (1995 ).

Experimental

Crystal data

[Nd₂(C₂₇H₂₄Br₃N₄O₃)₂]·6C₃H₇NO
M_r = 2111.46
Monoclinic, P 2₁ /c
a = 14.624 (6) Å
b = 22.460 (4) Å
c = 13.663 (4) Å
β = 101.133 (6)°
V = 4403 (2) Å³
Z = 2
Mo Kα radiation
μ = 3.95 mm⁻¹
T = 296 K
0.25 × 0.23 × 0.22 mm

Data collection

Bruke APEXII CCD diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ) T_min = 0.438, T_max = 0.477
25933 measured reflections
8078 independent reflections
5119 reflections with I > 2σ(I)
R_int = 0.057

Refinement

R[F² > 2σ(F²)] = 0.046
wR(F²) = 0.120
S = 1.02
8078 reflections
484 parameters
62 restraints
H-atom parameters constrained
Δρ_max = 0.84 e Å⁻³
Δρ_min = −0.78 e Å⁻³

Table 1
Selected bond lengths (Å)

Nd1—O1ⁱ	2.341 (4)
Nd1—O2	2.344 (4)
Nd1—O3	2.448 (4)
Nd1—O3ⁱ	2.467 (4)
Nd1—N1ⁱ	2.616 (5)
Nd1—N2ⁱ	2.864 (4)
Nd1—N3	2.896 (5)
Nd1—N4	2.627 (5)
Symmetry code: (i) -x+2, -y+1, -z+2.

Data collection: APEX2 (Bruker, 2007 ); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809047564/hy2250sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536809047564/hy2250Isup2.hkl

checkCIF report

Comment top

As the rare-earth ions have unique electronic structures and bonding characteristics, the formation of complexes has managed to maintain its unique electromagnetic nature of light. Tripodal ligand has a semi-rigid structure. It can provide a number of service sites to form thermodynamically stable complexes, and its three side chains are free to flip to form a suitable cavity size to include different guest molecules or ions. Furthermore, the researches of tripodal ligands and their complexes are very active at present (Bian et al., 2008; Palaniandavar et al., 2006; Velusamy et al., 2004).

The molecular diagram of the title compound is presented in Fig. 1. The structure is composed of a dimeric [Nd₂(brapi)₂] molecule [brapi = 2-(2'-hydroxy-5'-bromophenyl)-1,3-bis[3'-aza-4'-(2''-hydroxy- 5''-bromophenyl)-prop-4'-en-1'-yl]-1,3-imidazolidine], with eight-coordinated Nd^III ions linked by two bridging O atoms from the phenolic hydroxyl groups, and six N,N-dimethylformamide (DMF) molecules. The coordination geometry around the Nd^III ion may be described as distorted square antiprismatic, with one square plane being defined by O2, O3, N3, N4 [the torsion angle is 3.07 (17)°] and the other defined by O1, O3, N2, N1 [the torsion angle is 2.03 (16)°]. The coordination to the metal of the O atoms and N atoms results in the bond lengths of C—O [1.328 (8)–1.364 (7) Å] and C—N [1.301 (7)–1.527 (7) Å] are longer than those in the ligand (Fondo et al., 2005) and in complexes [Ce₂(brapi)₂].2DMF (Xie et al., 2009) and [La₂(brapi)₂].2CHCl₃ (Yang et al., 1995). The bond lengths of Nd—O (Table 1) are similar to those in the complexes [Ce₂(brapi)₂].2DMF and [La₂(brapi)₂].2CHCl₃. It can be seen that there is an intermolecular C—H···O hydrogen bond between the DMF molecule and the ligand. The solvent DMF molecules play a role in stablizing the crystal structure.

Related literature top

For general background to tripodal ligands, see: Bian et al. (2008); Palaniandavar et al. (2006); Velusamy et al. (2004). For related structures, see: Fondo et al. (2005); Xie et al. (2009); Yang et al. (1995).

Experimental top

A mixture of H₃brapi (1 mmol), Nd(NO₃)₃.6H₂O (1 mmol) and DMF (12 ml) was sealed in a 18 ml Teflon-lined stainless steel reactor and heated in an oven at 353 K for 5 d, and then slowly cooled to room temperature. Orange hexagonal prism crystals of the title complex were collected.

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

Fig. 1. The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level. [Symmetry codes: (i) -x+2, -y+1, -z+2.]

Bis{µ-1,3-bis[2-(5-bromo-2-oxidobenzylideneamino)ethyl]-2-(5-bromo-2- oxidophenyl)-1,3-imidazolidine}dineodymium(III) N,N-dimethylformamide hexasolvate top

Crystal data top

[Nd₂(C₂₇H₂₄Br₃N₄O₃)₂]·6C₃H₇NO	F(000) = 2092
M_r = 2111.46	D_x = 1.593 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 3640 reflections
a = 14.624 (6) Å	θ = 2.3–20.3°
b = 22.460 (4) Å	µ = 3.95 mm⁻¹
c = 13.663 (4) Å	T = 296 K
β = 101.133 (6)°	Prism, orange
V = 4403 (2) Å³	0.25 × 0.23 × 0.22 mm
Z = 2

Data collection top

Bruke APEXII CCD diffractometer	8078 independent reflections
Radiation source: fine-focus sealed tube	5119 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.057
ϕ and ω scans	θ_max = 25.5°, θ_min = 2.3°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −17→13
T_min = 0.438, T_max = 0.477	k = −27→27
25933 measured reflections	l = −16→16

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.046	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.120	H-atom parameters constrained
S = 1.02	w = 1/[σ²(F_o²) + (0.0539P)² + 1.2941P] where P = (F_o² + 2F_c²)/3
8078 reflections	(Δ/σ)_max = 0.001
484 parameters	Δρ_max = 0.84 e Å⁻³
62 restraints	Δρ_min = −0.78 e Å⁻³

Crystal data top

[Nd₂(C₂₇H₂₄Br₃N₄O₃)₂]·6C₃H₇NO	V = 4403 (2) Å³
M_r = 2111.46	Z = 2
Monoclinic, P2₁/c	Mo Kα radiation
a = 14.624 (6) Å	µ = 3.95 mm⁻¹
b = 22.460 (4) Å	T = 296 K
c = 13.663 (4) Å	0.25 × 0.23 × 0.22 mm
β = 101.133 (6)°

Data collection top

Bruke APEXII CCD diffractometer	8078 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	5119 reflections with I > 2σ(I)
T_min = 0.438, T_max = 0.477	R_int = 0.057
25933 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.046	62 restraints
wR(F²) = 0.120	H-atom parameters constrained
S = 1.02	Δρ_max = 0.84 e Å⁻³
8078 reflections	Δρ_min = −0.78 e Å⁻³
484 parameters

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Nd1	1.09682 (2)	0.516119 (15)	0.91542 (2)	0.04309 (12)
O1	0.8295 (3)	0.57032 (18)	1.1258 (3)	0.0549 (12)
O2	1.1124 (3)	0.61662 (18)	0.8752 (3)	0.0551 (11)
O3	0.9518 (3)	0.55074 (16)	0.9608 (3)	0.0453 (10)
O4	0.7262 (6)	0.4034 (4)	0.5864 (6)	0.143 (3)
O5	0.9895 (8)	0.6783 (5)	0.4013 (8)	0.214 (4)
O6	0.4457 (4)	0.4441 (2)	0.1416 (4)	0.0840 (16)
N1	0.7226 (4)	0.4679 (2)	1.0519 (4)	0.0458 (13)
N2	0.8233 (3)	0.44465 (19)	0.8871 (3)	0.0408 (12)
N3	0.9378 (4)	0.4633 (2)	0.7851 (3)	0.0451 (13)
N4	1.0965 (4)	0.5268 (2)	0.7239 (4)	0.0512 (14)
N5	0.6314 (6)	0.4532 (5)	0.4580 (6)	0.111 (3)
N6	0.9545 (6)	0.6979 (3)	0.5551 (7)	0.109 (2)
N7	0.4382 (5)	0.3491 (3)	0.0826 (4)	0.0726 (18)
Br1	0.50063 (7)	0.64057 (4)	1.32131 (8)	0.1009 (3)
Br2	1.33362 (7)	0.75756 (4)	0.61348 (6)	0.0850 (3)
Br3	0.65268 (7)	0.68123 (4)	0.66156 (8)	0.1146 (4)
C1	0.7576 (5)	0.5835 (3)	1.1687 (5)	0.0470 (16)
C2	0.6724 (5)	0.5486 (3)	1.1534 (5)	0.0490 (16)
C3	0.5970 (5)	0.5677 (3)	1.1966 (5)	0.0617 (19)
H3	0.5415	0.5463	1.1833	0.074*
C4	0.6030 (5)	0.6180 (3)	1.2590 (5)	0.0628 (19)
C5	0.6870 (6)	0.6513 (3)	1.2762 (5)	0.067 (2)
H5	0.6925	0.6845	1.3176	0.080*
C6	0.7615 (5)	0.6349 (3)	1.2319 (5)	0.068 (2)
H6	0.8154	0.6579	1.2437	0.081*
C7	0.6587 (5)	0.4961 (3)	1.0878 (5)	0.0477 (16)
H7	0.5982	0.4816	1.0702	0.057*
C8	0.6907 (5)	0.4201 (3)	0.9770 (4)	0.0504 (17)
H8A	0.6237	0.4152	0.9677	0.060*
H8B	0.7201	0.3826	0.9996	0.060*
C9	0.7180 (4)	0.4389 (3)	0.8787 (4)	0.0477 (16)
H9A	0.6943	0.4097	0.8277	0.057*
H9B	0.6889	0.4768	0.8578	0.057*
C10	0.8680 (5)	0.3849 (3)	0.8719 (5)	0.0569 (18)
H10A	0.8961	0.3677	0.9357	0.068*
H10B	0.8215	0.3574	0.8374	0.068*
C11	0.9415 (5)	0.3967 (3)	0.8102 (5)	0.0585 (19)
H11A	0.9291	0.3732	0.7494	0.070*
H11B	1.0027	0.3861	0.8475	0.070*
C12	0.9465 (5)	0.4751 (3)	0.6783 (4)	0.0545 (18)
H12A	0.9173	0.5129	0.6572	0.065*
H12B	0.9132	0.4443	0.6359	0.065*
C13	1.0481 (5)	0.4765 (3)	0.6639 (5)	0.0579 (18)
H13A	1.0788	0.4392	0.6858	0.070*
H13B	1.0501	0.4821	0.5939	0.070*
C14	1.1301 (5)	0.5694 (3)	0.6763 (5)	0.0592 (19)
H14	1.1281	0.5637	0.6085	0.071*
C15	1.1575 (5)	0.6467 (3)	0.8157 (5)	0.0525 (17)
C16	1.1705 (5)	0.6250 (3)	0.7199 (5)	0.0533 (17)
C17	1.2211 (5)	0.6604 (3)	0.6599 (5)	0.0606 (19)
H17	1.2278	0.6466	0.5975	0.073*
C18	1.2598 (5)	0.7148 (3)	0.6938 (5)	0.0606 (19)
C19	1.2454 (5)	0.7379 (3)	0.7859 (5)	0.0606 (19)
H19	1.2693	0.7750	0.8076	0.073*
C20	1.1950 (5)	0.7048 (3)	0.8445 (5)	0.0584 (18)
H20	1.1855	0.7210	0.9044	0.070*
C21	0.8421 (5)	0.4808 (3)	0.7978 (4)	0.0476 (16)
H21	0.7977	0.4681	0.7384	0.057*
C22	0.8863 (4)	0.5795 (3)	0.8925 (4)	0.0472 (16)
C23	0.8291 (4)	0.5476 (3)	0.8122 (4)	0.0449 (15)
C24	0.7604 (5)	0.5790 (3)	0.7447 (5)	0.0568 (18)
H24	0.7224	0.5586	0.6931	0.068*
C25	0.7488 (5)	0.6406 (3)	0.7547 (6)	0.068 (2)
C26	0.8068 (5)	0.6723 (3)	0.8294 (6)	0.071 (2)
H26	0.8011	0.7134	0.8334	0.086*
C27	0.8741 (5)	0.6418 (3)	0.8990 (5)	0.0614 (19)
H27	0.9113	0.6630	0.9502	0.074*
C28	0.6559 (9)	0.4070 (6)	0.5211 (8)	0.117 (4)
H28	0.6154	0.3747	0.5142	0.140*
C29	0.5455 (9)	0.4509 (6)	0.3801 (10)	0.199 (7)
H29A	0.5119	0.4150	0.3876	0.298*
H29B	0.5619	0.4513	0.3153	0.298*
H29C	0.5071	0.4847	0.3867	0.298*
C30	0.6919 (8)	0.5047 (5)	0.4636 (8)	0.129 (4)
H30A	0.7489	0.4969	0.5100	0.193*
H30B	0.6614	0.5386	0.4856	0.193*
H30C	0.7056	0.5126	0.3989	0.193*
C31	1.0027 (9)	0.7059 (5)	0.4841 (9)	0.128 (3)
H31	1.0503	0.7340	0.4955	0.153*
C32	0.9706 (8)	0.7371 (5)	0.6416 (7)	0.127 (3)
H32A	0.9884	0.7138	0.7012	0.191*
H32B	0.9145	0.7587	0.6446	0.191*
H32C	1.0194	0.7647	0.6362	0.191*
C33	0.8992 (10)	0.6434 (6)	0.5505 (11)	0.198 (5)
H33A	0.8369	0.6512	0.5155	0.297*
H33B	0.8976	0.6302	0.6170	0.297*
H33C	0.9269	0.6131	0.5161	0.297*
C34	0.4033 (6)	0.4034 (3)	0.0944 (5)	0.068 (2)
H34	0.3417	0.4105	0.0639	0.081*
C35	0.3825 (8)	0.3037 (4)	0.0193 (7)	0.127 (4)
H35A	0.3209	0.3188	−0.0050	0.190*
H35B	0.3788	0.2683	0.0578	0.190*
H35C	0.4116	0.2945	−0.0361	0.190*
C36	0.5326 (6)	0.3332 (4)	0.1312 (7)	0.103 (3)
H36A	0.5697	0.3262	0.0816	0.154*
H36B	0.5310	0.2977	0.1701	0.154*
H36C	0.5594	0.3651	0.1741	0.154*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Nd1	0.0450 (2)	0.0465 (2)	0.03667 (18)	−0.00268 (17)	0.00517 (14)	−0.00282 (15)
O1	0.049 (3)	0.050 (3)	0.068 (3)	−0.004 (2)	0.018 (2)	−0.007 (2)
O2	0.068 (3)	0.050 (3)	0.049 (3)	0.001 (2)	0.017 (2)	0.003 (2)
O3	0.047 (3)	0.045 (2)	0.040 (2)	0.003 (2)	0.001 (2)	−0.0026 (18)
O4	0.129 (7)	0.168 (7)	0.116 (6)	−0.006 (5)	−0.015 (5)	−0.020 (5)
O5	0.231 (8)	0.236 (8)	0.191 (6)	−0.015 (6)	0.082 (6)	−0.048 (6)
O6	0.078 (4)	0.063 (3)	0.104 (4)	−0.008 (3)	0.002 (3)	−0.014 (3)
N1	0.047 (3)	0.048 (3)	0.042 (3)	−0.002 (3)	0.008 (2)	−0.005 (2)
N2	0.040 (3)	0.041 (3)	0.041 (3)	0.002 (2)	0.006 (2)	−0.008 (2)
N3	0.052 (3)	0.045 (3)	0.038 (3)	0.003 (2)	0.010 (2)	−0.006 (2)
N4	0.057 (4)	0.055 (3)	0.042 (3)	−0.006 (3)	0.008 (3)	−0.007 (2)
N5	0.101 (7)	0.152 (8)	0.072 (5)	0.000 (6)	−0.003 (5)	−0.010 (5)
N6	0.124 (5)	0.093 (4)	0.115 (5)	−0.005 (4)	0.038 (4)	−0.018 (4)
N7	0.083 (5)	0.061 (4)	0.068 (4)	0.007 (3)	0.002 (4)	0.006 (3)
Br1	0.0759 (6)	0.1142 (8)	0.1206 (8)	0.0082 (5)	0.0388 (6)	−0.0435 (6)
Br2	0.0998 (7)	0.0696 (5)	0.0893 (6)	−0.0105 (5)	0.0274 (5)	0.0242 (4)
Br3	0.1152 (8)	0.0817 (6)	0.1245 (8)	0.0199 (6)	−0.0330 (7)	0.0376 (6)
C1	0.042 (4)	0.048 (4)	0.051 (4)	0.002 (3)	0.010 (3)	−0.001 (3)
C2	0.047 (4)	0.049 (4)	0.052 (4)	0.003 (3)	0.013 (3)	−0.006 (3)
C3	0.066 (5)	0.063 (4)	0.053 (4)	−0.003 (4)	0.002 (4)	−0.004 (3)
C4	0.061 (5)	0.065 (5)	0.065 (5)	0.008 (4)	0.018 (4)	−0.010 (4)
C5	0.078 (6)	0.054 (4)	0.070 (5)	−0.001 (4)	0.018 (4)	−0.020 (4)
C6	0.065 (5)	0.061 (5)	0.077 (5)	−0.003 (4)	0.014 (4)	−0.017 (4)
C7	0.048 (4)	0.043 (3)	0.052 (4)	−0.009 (3)	0.008 (3)	0.001 (3)
C8	0.047 (4)	0.046 (4)	0.057 (4)	−0.004 (3)	0.004 (3)	−0.012 (3)
C9	0.049 (4)	0.046 (4)	0.045 (4)	−0.004 (3)	0.003 (3)	−0.009 (3)
C10	0.071 (5)	0.042 (4)	0.061 (4)	0.002 (3)	0.019 (4)	−0.004 (3)
C11	0.064 (5)	0.044 (4)	0.064 (4)	0.001 (3)	0.005 (4)	−0.009 (3)
C12	0.064 (5)	0.063 (4)	0.033 (3)	−0.009 (3)	0.002 (3)	−0.007 (3)
C13	0.068 (5)	0.066 (4)	0.040 (3)	−0.010 (4)	0.009 (3)	−0.012 (3)
C14	0.073 (5)	0.068 (5)	0.037 (4)	0.003 (4)	0.012 (4)	−0.001 (3)
C15	0.057 (5)	0.050 (4)	0.046 (4)	0.008 (3)	−0.001 (3)	0.004 (3)
C16	0.060 (5)	0.050 (4)	0.050 (4)	0.000 (3)	0.010 (3)	0.005 (3)
C17	0.072 (5)	0.064 (4)	0.047 (4)	0.004 (4)	0.015 (4)	0.004 (3)
C18	0.063 (5)	0.057 (4)	0.060 (4)	−0.002 (4)	0.007 (4)	0.016 (4)
C19	0.072 (5)	0.043 (4)	0.065 (5)	0.002 (4)	0.009 (4)	0.007 (3)
C20	0.072 (5)	0.052 (4)	0.050 (4)	0.008 (4)	0.008 (4)	0.000 (3)
C21	0.056 (4)	0.052 (4)	0.032 (3)	−0.005 (3)	0.000 (3)	−0.004 (3)
C22	0.050 (4)	0.042 (3)	0.049 (4)	−0.002 (3)	0.009 (3)	−0.005 (3)
C23	0.050 (4)	0.043 (3)	0.040 (3)	−0.004 (3)	0.005 (3)	0.004 (3)
C24	0.057 (5)	0.063 (4)	0.045 (4)	−0.004 (4)	−0.005 (3)	0.004 (3)
C25	0.063 (5)	0.058 (4)	0.078 (5)	0.004 (4)	0.000 (4)	0.018 (4)
C26	0.079 (6)	0.039 (4)	0.090 (6)	0.005 (4)	0.001 (5)	0.007 (4)
C27	0.068 (5)	0.045 (4)	0.068 (5)	−0.002 (4)	0.005 (4)	−0.006 (3)
C28	0.116 (10)	0.164 (11)	0.078 (7)	−0.033 (9)	0.036 (7)	−0.039 (8)
C29	0.161 (13)	0.227 (15)	0.164 (12)	−0.055 (11)	−0.080 (10)	0.009 (11)
C30	0.131 (10)	0.120 (9)	0.125 (9)	−0.021 (8)	0.003 (8)	−0.019 (7)
C31	0.140 (6)	0.117 (6)	0.132 (6)	−0.012 (5)	0.040 (5)	−0.015 (5)
C32	0.143 (7)	0.123 (6)	0.115 (6)	0.015 (6)	0.022 (6)	−0.009 (5)
C33	0.200 (9)	0.201 (8)	0.205 (8)	−0.080 (7)	0.072 (7)	−0.001 (7)
C34	0.073 (5)	0.058 (5)	0.070 (5)	0.007 (4)	0.008 (4)	0.011 (4)
C35	0.180 (11)	0.069 (6)	0.115 (8)	−0.020 (6)	−0.012 (8)	−0.022 (5)
C36	0.104 (8)	0.084 (6)	0.120 (8)	0.017 (5)	0.020 (6)	0.017 (5)

Geometric parameters (Å, º) top

Nd1—O1ⁱ	2.341 (4)	C9—H9B	0.9700
Nd1—O2	2.344 (4)	C10—C11	1.512 (9)
Nd1—O3	2.448 (4)	C10—H10A	0.9700
Nd1—O3ⁱ	2.467 (4)	C10—H10B	0.9700
Nd1—N1ⁱ	2.616 (5)	C11—H11A	0.9700
Nd1—N2ⁱ	2.864 (4)	C11—H11B	0.9700
Nd1—N3	2.896 (5)	C12—C13	1.537 (9)
Nd1—N4	2.627 (5)	C12—H12A	0.9700
O1—C1	1.333 (7)	C12—H12B	0.9700
O1—Nd1ⁱ	2.341 (4)	C13—H13A	0.9700
O2—C15	1.328 (8)	C13—H13B	0.9700
O3—C22	1.364 (7)	C14—C16	1.459 (9)
O3—Nd1ⁱ	2.467 (4)	C14—H14	0.9300
O4—C28	1.227 (12)	C15—C20	1.441 (9)
O5—C31	1.272 (12)	C15—C16	1.442 (9)
O6—C34	1.217 (8)	C16—C17	1.446 (9)
N1—C7	1.301 (7)	C17—C18	1.388 (9)
N1—C8	1.494 (7)	C17—H17	0.9300
N1—Nd1ⁱ	2.616 (5)	C18—C19	1.414 (9)
N2—C10	1.525 (7)	C19—C20	1.401 (9)
N2—C9	1.527 (7)	C19—H19	0.9300
N2—C21	1.533 (7)	C20—H20	0.9300
N2—Nd1ⁱ	2.864 (4)	C21—C23	1.529 (8)
N3—C21	1.496 (8)	C21—H21	0.9800
N3—C12	1.512 (7)	C22—C27	1.415 (8)
N3—C11	1.533 (7)	C22—C23	1.436 (8)
N4—C14	1.304 (8)	C23—C24	1.415 (8)
N4—C13	1.492 (7)	C24—C25	1.403 (9)
N5—C28	1.353 (13)	C24—H24	0.9300
N5—C30	1.448 (12)	C25—C26	1.391 (9)
N5—C29	1.483 (12)	C26—C27	1.408 (9)
N6—C31	1.317 (12)	C26—H26	0.9300
N6—C32	1.456 (11)	C27—H27	0.9300
N6—C33	1.461 (13)	C28—H28	0.9300
N7—C34	1.343 (9)	C29—H29A	0.9600
N7—C36	1.457 (9)	C29—H29B	0.9600
N7—C35	1.476 (9)	C29—H29C	0.9600
Br1—C4	1.928 (7)	C30—H30A	0.9600
Br2—C18	1.936 (7)	C30—H30B	0.9600
Br3—C25	1.933 (7)	C30—H30C	0.9600
C1—C6	1.435 (8)	C31—H31	0.9300
C1—C2	1.453 (9)	C32—H32A	0.9600
C2—C3	1.414 (9)	C32—H32B	0.9600
C2—C7	1.471 (8)	C32—H32C	0.9600
C3—C4	1.409 (9)	C33—H33A	0.9600
C3—H3	0.9300	C33—H33B	0.9600
C4—C5	1.418 (9)	C33—H33C	0.9600
C5—C6	1.394 (10)	C34—H34	0.9300
C5—H5	0.9300	C35—H35A	0.9600
C6—H6	0.9300	C35—H35B	0.9600
C7—H7	0.9300	C35—H35C	0.9600
C8—C9	1.531 (8)	C36—H36A	0.9600
C8—H8A	0.9700	C36—H36B	0.9600
C8—H8B	0.9700	C36—H36C	0.9600
C9—H9A	0.9700

O1ⁱ—Nd1—O2	132.23 (16)	C10—C11—H11A	110.3
O1ⁱ—Nd1—O3	141.78 (14)	N3—C11—H11A	110.3
O2—Nd1—O3	83.19 (14)	C10—C11—H11B	110.3
O1ⁱ—Nd1—O3ⁱ	82.36 (14)	N3—C11—H11B	110.3
O2—Nd1—O3ⁱ	143.18 (14)	H11A—C11—H11B	108.5
O3—Nd1—O3ⁱ	68.98 (14)	N3—C12—C13	113.0 (5)
O1ⁱ—Nd1—N1ⁱ	70.04 (15)	N3—C12—H12A	109.0
O2—Nd1—N1ⁱ	76.54 (15)	C13—C12—H12A	109.0
O3—Nd1—N1ⁱ	143.92 (14)	N3—C12—H12B	109.0
O3ⁱ—Nd1—N1ⁱ	112.44 (14)	C13—C12—H12B	109.0
O1ⁱ—Nd1—N4	75.43 (15)	H12A—C12—H12B	107.8
O2—Nd1—N4	70.15 (15)	N4—C13—C12	108.2 (5)
O3—Nd1—N4	112.86 (14)	N4—C13—H13A	110.0
O3ⁱ—Nd1—N4	142.50 (14)	C12—C13—H13A	110.0
N1ⁱ—Nd1—N4	87.97 (16)	N4—C13—H13B	110.0
O1ⁱ—Nd1—N2ⁱ	111.02 (14)	C12—C13—H13B	110.0
O2—Nd1—N2ⁱ	83.34 (14)	H13A—C13—H13B	108.4
O3—Nd1—N2ⁱ	83.07 (13)	N4—C14—C16	125.9 (6)
O3ⁱ—Nd1—N2ⁱ	70.15 (13)	N4—C14—H14	117.1
N1ⁱ—Nd1—N2ⁱ	65.33 (14)	C16—C14—H14	117.1
N4—Nd1—N2ⁱ	146.32 (15)	O2—C15—C20	120.1 (6)
O1ⁱ—Nd1—N3	82.21 (14)	O2—C15—C16	123.5 (6)
O2—Nd1—N3	110.68 (14)	C20—C15—C16	116.4 (6)
O3—Nd1—N3	69.76 (13)	C15—C16—C17	120.0 (6)
O3ⁱ—Nd1—N3	82.46 (13)	C15—C16—C14	123.1 (6)
N1ⁱ—Nd1—N3	145.60 (14)	C17—C16—C14	116.8 (6)
N4—Nd1—N3	65.05 (15)	C18—C17—C16	121.0 (6)
N2ⁱ—Nd1—N3	146.97 (14)	C18—C17—H17	119.5
O1ⁱ—Nd1—Nd1ⁱ	113.20 (11)	C16—C17—H17	119.5
O2—Nd1—Nd1ⁱ	114.57 (11)	C17—C18—C19	119.9 (6)
O3—Nd1—Nd1ⁱ	34.64 (9)	C17—C18—Br2	118.9 (5)
O3ⁱ—Nd1—Nd1ⁱ	34.34 (9)	C19—C18—Br2	121.2 (5)
N1ⁱ—Nd1—Nd1ⁱ	136.13 (11)	C20—C19—C18	120.0 (6)
N4—Nd1—Nd1ⁱ	135.87 (12)	C20—C19—H19	120.0
N2ⁱ—Nd1—Nd1ⁱ	73.76 (10)	C18—C19—H19	120.0
N3—Nd1—Nd1ⁱ	73.20 (10)	C19—C20—C15	122.5 (6)
C1—O1—Nd1ⁱ	136.9 (4)	C19—C20—H20	118.7
C15—O2—Nd1	135.7 (4)	C15—C20—H20	118.7
C22—O3—Nd1	120.3 (4)	N3—C21—C23	114.6 (5)
C22—O3—Nd1ⁱ	120.0 (4)	N3—C21—N2	105.6 (4)
Nd1—O3—Nd1ⁱ	111.02 (14)	C23—C21—N2	111.8 (5)
C7—N1—C8	117.1 (5)	N3—C21—H21	108.2
C7—N1—Nd1ⁱ	130.1 (4)	C23—C21—H21	108.2
C8—N1—Nd1ⁱ	112.8 (4)	N2—C21—H21	108.2
C10—N2—C9	111.6 (4)	O3—C22—C27	120.3 (5)
C10—N2—C21	102.1 (4)	O3—C22—C23	121.0 (5)
C9—N2—C21	108.6 (4)	C27—C22—C23	118.7 (6)
C10—N2—Nd1ⁱ	107.0 (3)	C24—C23—C22	118.9 (6)
C9—N2—Nd1ⁱ	108.6 (3)	C24—C23—C21	119.8 (5)
C21—N2—Nd1ⁱ	118.9 (3)	C22—C23—C21	121.3 (5)
C21—N3—C12	108.8 (5)	C25—C24—C23	120.9 (6)
C21—N3—C11	102.9 (5)	C25—C24—H24	119.6
C12—N3—C11	112.4 (5)	C23—C24—H24	119.6
C21—N3—Nd1	118.6 (3)	C26—C25—C24	120.6 (6)
C12—N3—Nd1	108.3 (4)	C26—C25—Br3	120.2 (5)
C11—N3—Nd1	105.8 (3)	C24—C25—Br3	119.2 (5)
C14—N4—C13	117.8 (5)	C25—C26—C27	119.6 (6)
C14—N4—Nd1	129.4 (4)	C25—C26—H26	120.2
C13—N4—Nd1	112.8 (4)	C27—C26—H26	120.2
C28—N5—C30	119.7 (9)	C26—C27—C22	121.2 (6)
C28—N5—C29	120.8 (11)	C26—C27—H27	119.4
C30—N5—C29	119.4 (10)	C22—C27—H27	119.4
C31—N6—C32	119.4 (10)	O4—C28—N5	126.5 (11)
C31—N6—C33	116.9 (10)	O4—C28—H28	116.7
C32—N6—C33	122.9 (10)	N5—C28—H28	116.7
C34—N7—C36	121.1 (7)	N5—C29—H29A	109.5
C34—N7—C35	121.2 (7)	N5—C29—H29B	109.5
C36—N7—C35	117.6 (7)	H29A—C29—H29B	109.5
O1—C1—C6	120.1 (6)	N5—C29—H29C	109.5
O1—C1—C2	122.9 (5)	H29A—C29—H29C	109.5
C6—C1—C2	117.0 (6)	H29B—C29—H29C	109.5
C3—C2—C1	119.5 (6)	N5—C30—H30A	109.5
C3—C2—C7	118.1 (6)	N5—C30—H30B	109.5
C1—C2—C7	122.2 (6)	H30A—C30—H30B	109.5
C4—C3—C2	122.2 (7)	N5—C30—H30C	109.5
C4—C3—H3	118.9	H30A—C30—H30C	109.5
C2—C3—H3	118.9	H30B—C30—H30C	109.5
C3—C4—C5	118.4 (7)	O5—C31—N6	125.3 (12)
C3—C4—Br1	121.0 (6)	O5—C31—H31	117.3
C5—C4—Br1	120.6 (5)	N6—C31—H31	117.3
C6—C5—C4	120.8 (6)	N6—C32—H32A	109.5
C6—C5—H5	119.6	N6—C32—H32B	109.5
C4—C5—H5	119.6	H32A—C32—H32B	109.5
C5—C6—C1	122.0 (7)	N6—C32—H32C	109.5
C5—C6—H6	119.0	H32A—C32—H32C	109.5
C1—C6—H6	119.0	H32B—C32—H32C	109.5
N1—C7—C2	126.6 (6)	N6—C33—H33A	109.5
N1—C7—H7	116.7	N6—C33—H33B	109.5
C2—C7—H7	116.7	H33A—C33—H33B	109.5
N1—C8—C9	107.7 (5)	N6—C33—H33C	109.5
N1—C8—H8A	110.2	H33A—C33—H33C	109.5
C9—C8—H8A	110.2	H33B—C33—H33C	109.5
N1—C8—H8B	110.2	O6—C34—N7	125.4 (7)
C9—C8—H8B	110.2	O6—C34—H34	117.3
H8A—C8—H8B	108.5	N7—C34—H34	117.3
N2—C9—C8	112.8 (5)	N7—C35—H35A	109.5
N2—C9—H9A	109.0	N7—C35—H35B	109.5
C8—C9—H9A	109.0	H35A—C35—H35B	109.5
N2—C9—H9B	109.0	N7—C35—H35C	109.5
C8—C9—H9B	109.0	H35A—C35—H35C	109.5
H9A—C9—H9B	107.8	H35B—C35—H35C	109.5
C11—C10—N2	107.0 (5)	N7—C36—H36A	109.5
C11—C10—H10A	110.3	N7—C36—H36B	109.5
N2—C10—H10A	110.3	H36A—C36—H36B	109.5
C11—C10—H10B	110.3	N7—C36—H36C	109.5
N2—C10—H10B	110.3	H36A—C36—H36C	109.5
H10A—C10—H10B	108.6	H36B—C36—H36C	109.5
C10—C11—N3	107.3 (5)

O1ⁱ—Nd1—O2—C15	7.2 (6)	C3—C2—C7—N1	−170.8 (6)
O3—Nd1—O2—C15	−156.6 (5)	C1—C2—C7—N1	14.0 (10)
O3ⁱ—Nd1—O2—C15	163.1 (5)	C7—N1—C8—C9	117.0 (6)
N1ⁱ—Nd1—O2—C15	53.5 (5)	Nd1ⁱ—N1—C8—C9	−60.6 (5)
N4—Nd1—O2—C15	−39.2 (5)	C10—N2—C9—C8	85.1 (6)
N2ⁱ—Nd1—O2—C15	119.7 (5)	C21—N2—C9—C8	−163.2 (4)
N3—Nd1—O2—C15	−91.2 (5)	Nd1ⁱ—N2—C9—C8	−32.6 (5)
Nd1ⁱ—Nd1—O2—C15	−171.6 (5)	N1—C8—C9—N2	62.4 (6)
O1ⁱ—Nd1—O3—C22	−103.7 (4)	C9—N2—C10—C11	139.9 (5)
O2—Nd1—O3—C22	56.8 (4)	C21—N2—C10—C11	24.1 (6)
O3ⁱ—Nd1—O3—C22	−147.8 (5)	Nd1ⁱ—N2—C10—C11	−101.5 (5)
N1ⁱ—Nd1—O3—C22	112.6 (4)	N2—C10—C11—N3	−2.2 (6)
N4—Nd1—O3—C22	−8.3 (4)	C21—N3—C11—C10	−21.2 (6)
N2ⁱ—Nd1—O3—C22	140.9 (4)	C12—N3—C11—C10	−138.1 (5)
N3—Nd1—O3—C22	−58.2 (4)	Nd1—N3—C11—C10	103.9 (5)
Nd1ⁱ—Nd1—O3—C22	−147.8 (5)	C21—N3—C12—C13	163.0 (5)
O1ⁱ—Nd1—O3—Nd1ⁱ	44.1 (3)	C11—N3—C12—C13	−83.7 (6)
O2—Nd1—O3—Nd1ⁱ	−155.44 (16)	Nd1—N3—C12—C13	32.8 (6)
O3ⁱ—Nd1—O3—Nd1ⁱ	0.0	C14—N4—C13—C12	−118.4 (6)
N1ⁱ—Nd1—O3—Nd1ⁱ	−99.6 (2)	Nd1—N4—C13—C12	60.2 (6)
N4—Nd1—O3—Nd1ⁱ	139.49 (15)	N3—C12—C13—N4	−62.7 (7)
N2ⁱ—Nd1—O3—Nd1ⁱ	−71.36 (15)	C13—N4—C14—C16	173.0 (6)
N3—Nd1—O3—Nd1ⁱ	89.54 (16)	Nd1—N4—C14—C16	−5.3 (10)
O1ⁱ—Nd1—N3—C21	156.1 (4)	Nd1—O2—C15—C20	−145.5 (5)
O2—Nd1—N3—C21	−71.6 (4)	Nd1—O2—C15—C16	35.8 (9)
O3—Nd1—N3—C21	2.5 (4)	O2—C15—C16—C17	−179.6 (6)
O3ⁱ—Nd1—N3—C21	72.8 (4)	C20—C15—C16—C17	1.7 (9)
N1ⁱ—Nd1—N3—C21	−168.0 (3)	O2—C15—C16—C14	3.9 (10)
N4—Nd1—N3—C21	−126.4 (4)	C20—C15—C16—C14	−174.8 (6)
N2ⁱ—Nd1—N3—C21	39.1 (5)	N4—C14—C16—C15	−16.1 (11)
Nd1ⁱ—Nd1—N3—C21	38.9 (3)	N4—C14—C16—C17	167.3 (7)
O1ⁱ—Nd1—N3—C12	−79.4 (4)	C15—C16—C17—C18	1.5 (10)
O2—Nd1—N3—C12	52.9 (4)	C14—C16—C17—C18	178.2 (6)
O3—Nd1—N3—C12	127.0 (4)	C16—C17—C18—C19	−3.6 (10)
O3ⁱ—Nd1—N3—C12	−162.7 (4)	C16—C17—C18—Br2	176.0 (5)
N1ⁱ—Nd1—N3—C12	−43.5 (5)	C17—C18—C19—C20	2.4 (10)
N4—Nd1—N3—C12	−1.9 (4)	Br2—C18—C19—C20	−177.2 (5)
N2ⁱ—Nd1—N3—C12	163.6 (3)	C18—C19—C20—C15	1.0 (10)
Nd1ⁱ—Nd1—N3—C12	163.4 (4)	O2—C15—C20—C19	178.3 (6)
O1ⁱ—Nd1—N3—C11	41.3 (4)	C16—C15—C20—C19	−2.9 (10)
O2—Nd1—N3—C11	173.6 (4)	C12—N3—C21—C23	−80.3 (6)
O3—Nd1—N3—C11	−112.3 (4)	C11—N3—C21—C23	160.4 (5)
O3ⁱ—Nd1—N3—C11	−42.0 (4)	Nd1—N3—C21—C23	44.0 (5)
N1ⁱ—Nd1—N3—C11	77.3 (4)	C12—N3—C21—N2	156.3 (4)
N4—Nd1—N3—C11	118.8 (4)	C11—N3—C21—N2	36.9 (5)
N2ⁱ—Nd1—N3—C11	−75.7 (4)	Nd1—N3—C21—N2	−79.4 (4)
Nd1ⁱ—Nd1—N3—C11	−75.9 (3)	C10—N2—C21—N3	−38.3 (5)
O1ⁱ—Nd1—N4—C14	−123.5 (6)	C9—N2—C21—N3	−156.2 (4)
O2—Nd1—N4—C14	22.8 (6)	Nd1ⁱ—N2—C21—N3	79.1 (4)
O3—Nd1—N4—C14	96.0 (6)	C10—N2—C21—C23	−163.5 (5)
O3ⁱ—Nd1—N4—C14	−179.2 (5)	C9—N2—C21—C23	78.5 (5)
N1ⁱ—Nd1—N4—C14	−53.6 (6)	Nd1ⁱ—N2—C21—C23	−46.2 (6)
N2ⁱ—Nd1—N4—C14	−17.4 (7)	Nd1—O3—C22—C27	−105.6 (6)
N3—Nd1—N4—C14	148.4 (6)	Nd1ⁱ—O3—C22—C27	109.5 (6)
Nd1ⁱ—Nd1—N4—C14	128.0 (5)	Nd1—O3—C22—C23	73.8 (7)
O1ⁱ—Nd1—N4—C13	58.1 (4)	Nd1ⁱ—O3—C22—C23	−71.1 (6)
O2—Nd1—N4—C13	−155.6 (5)	O3—C22—C23—C24	178.3 (6)
O3—Nd1—N4—C13	−82.4 (4)	C27—C22—C23—C24	−2.3 (9)
O3ⁱ—Nd1—N4—C13	2.5 (5)	O3—C22—C23—C21	−2.6 (9)
N1ⁱ—Nd1—N4—C13	128.0 (4)	C27—C22—C23—C21	176.8 (6)
N2ⁱ—Nd1—N4—C13	164.3 (4)	N3—C21—C23—C24	121.4 (6)
N3—Nd1—N4—C13	−30.0 (4)	N2—C21—C23—C24	−118.5 (6)
Nd1ⁱ—Nd1—N4—C13	−50.3 (5)	N3—C21—C23—C22	−57.7 (7)
Nd1ⁱ—O1—C1—C6	144.0 (5)	N2—C21—C23—C22	62.5 (7)
Nd1ⁱ—O1—C1—C2	−37.2 (9)	C22—C23—C24—C25	0.9 (10)
O1—C1—C2—C3	−176.0 (6)	C21—C23—C24—C25	−178.2 (6)
C6—C1—C2—C3	2.9 (9)	C23—C24—C25—C26	2.1 (11)
O1—C1—C2—C7	−0.9 (9)	C23—C24—C25—Br3	−179.1 (5)
C6—C1—C2—C7	178.0 (6)	C24—C25—C26—C27	−3.6 (12)
C1—C2—C3—C4	−3.6 (10)	Br3—C25—C26—C27	177.6 (6)
C7—C2—C3—C4	−178.9 (6)	C25—C26—C27—C22	2.2 (12)
C2—C3—C4—C5	1.8 (10)	O3—C22—C27—C26	−179.8 (6)
C2—C3—C4—Br1	−177.1 (5)	C23—C22—C27—C26	0.7 (10)
C3—C4—C5—C6	0.5 (11)	C30—N5—C28—O4	0.9 (17)
Br1—C4—C5—C6	179.5 (6)	C29—N5—C28—O4	178.1 (12)
C4—C5—C6—C1	−1.1 (11)	C32—N6—C31—O5	−173.4 (12)
O1—C1—C6—C5	178.3 (6)	C33—N6—C31—O5	17.0 (19)
C2—C1—C6—C5	−0.6 (10)	C36—N7—C34—O6	2.7 (12)
C8—N1—C7—C2	−172.8 (6)	C35—N7—C34—O6	−176.7 (8)
Nd1ⁱ—N1—C7—C2	4.4 (9)

Symmetry code: (i) −x+2, −y+1, −z+2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C21—H21···O4	0.98	2.58	3.514 (10)	159

Experimental details

Crystal data
Chemical formula	[Nd₂(C₂₇H₂₄Br₃N₄O₃)₂]·6C₃H₇NO
M_r	2111.46
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	296
a, b, c (Å)	14.624 (6), 22.460 (4), 13.663 (4)
β (°)	101.133 (6)
V (Å³)	4403 (2)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	3.95
Crystal size (mm)	0.25 × 0.23 × 0.22

Data collection
Diffractometer	Bruke APEXII CCD diffractometer
Absorption correction	Multi-scan (SADABS; Sheldrick, 1996)
T_min, T_max	0.438, 0.477
No. of measured, independent and observed [I > 2σ(I)] reflections	25933, 8078, 5119
R_int	0.057
(sin θ/λ)_max (Å⁻¹)	0.606

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.046, 0.120, 1.02
No. of reflections	8078
No. of parameters	484
No. of restraints	62
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.84, −0.78

Computer programs: APEX2 (Bruker, 2007), SAINT (Bruker, 2007), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

Selected bond lengths (Å) top

Nd1—O1ⁱ	2.341 (4)	Nd1—N1ⁱ	2.616 (5)
Nd1—O2	2.344 (4)	Nd1—N2ⁱ	2.864 (4)
Nd1—O3	2.448 (4)	Nd1—N3	2.896 (5)
Nd1—O3ⁱ	2.467 (4)	Nd1—N4	2.627 (5)

Symmetry code: (i) −x+2, −y+1, −z+2.

Acknowledgements

This work was supported by the Education Department Foundation of Fujian Province of China (grant Nos. JA08212 and 2008 F5053).

References

Bian, Z. Y., Sumi, K., Furue, M., Sato, S., Koike, K. & Ishitani, O. (2008). Inorg. Chem. 47, 10801–10803. Web of Science CrossRef PubMed CAS Google Scholar
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Fondo, M., Deibe, A. M. G., Ocampo, N., Bermejo, M. R. & Sanmartín, J. (2005). Z. Anorg. Allg. Chem. 631, 2041–2045. Web of Science CSD CrossRef CAS Google Scholar
Palaniandavar, M., Velusamy, M. & Mayilmurugan, R. (2006). J. Chem. Sci. 118, 601–610. Web of Science CrossRef CAS Google Scholar
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany. Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Velusamy, M., Mayilmurugan, R. & Palaniandavar, M. (2004). Inorg. Chem. 43, 6284–6293. Web of Science CSD CrossRef PubMed CAS Google Scholar
Xie, Q.-F., Huang, M.-L. & Chen, Y.-M. (2009). Chin. J. Inorg. Chem. 25, 1539–1544. CAS Google Scholar
Yang, L.-W., Liu, S., Wong, E., Rettig, S. J. & Orvig, C. (1995). Inorg. Chem. 34, 2164–2178. CrossRef CAS Web of Science Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 65| Part 12| December 2009| Page m1660

doi:10.1107/S1600536809047564

Open

access

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Bis{μ-1,3-bis­­[2-(5-bromo-2-oxido­benzyl­­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-di­methyl­formamide hexa­solvate

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

Acknowledgements

References

metal-organic compounds

Bis{μ-1,3-bis[2-(5-bromo-2-oxidobenzylideneamino)ethyl]-2-(5-bromo-2-oxidophenyl)-1,3-imidazolidine}dineodymium(III) N,N-dimethylformamide hexasolvate