Aqua­bis(isonicotinamide-κN1)bis­(4-methyl­benzoato)-κO;κ2O,O′-cadmium(II) monohydrate

Necefoğlu, H.; Çimen, E.; Tercan, B.; Süzen, Y.; Hökelek, T.

doi:10.1107/S1600536810008366

metal-organic compounds

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ISSN: 2056-9890

Volume 66| Part 4| April 2010| Pages m392-m393

doi:10.1107/S1600536810008366

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Aquabis(isonicotinamide-κN¹)bis(4-methylbenzoato)-κO;κ²O,O′-cadmium(II) monohydrate

Hacali Necefoğlu,^a Efdal Çimen,^a Barış Tercan,^b Yasemin Süzen ^c and Tuncer Hökelek ^d ^*

^aDepartment of Chemistry, Kafkas University, 36100 Kars, Turkey, ^bDepartment of Physics, Karabük University, 78050 Karabük, Turkey, ^cDepartment of Chemistry, Faculty of Science, Anadolu University, 26470 Yenibağlar, Eskişehir, Turkey, and ^dDepartment of Physics, Hacettepe University, 06800 Beytepe, Ankara, Turkey
^*Correspondence e-mail: merzifon@hacettepe.edu.tr

(Received 1 March 2010; accepted 4 March 2010; online 13 March 2010)

In the crystal structure of the title compound, [Cd(C₈H₇O₂)₂(C₆H₆N₂O)₂(H₂O)]·H₂O, the Cd^II cation is coordinated by two 4-methylbenzoate (PMB) anions, two isonicotinamide (INA) ligands and one water molecule in a distorted octahedral CdN₂O₄ geometry. One of PMB ions acts as a bidentate ligand while the other and the two INA are monodentate ligands. An O—H⋯O hydrogen bond links the uncoordinated water molecule to the carboxyl groups of the complex. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 10.28 (11) and 21.24 (9)°, while the two benzene rings and the two pyridine rings are oriented at dihedral angles of 6.90 (4) and 88.64 (4)°, respectively. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a supramolecular structure. A π–π contact between the benzene rings [centroid–centroid distance = 3.911 (1) Å] may further stabilize the crystal structure. Weak C—H⋯π interactions involving the pyridine rings also occur in the crystal structure.

Related literature

For niacin, see: Krishnamachari (1974 ) and for the nicotinic acid derivative N,N-diethylnicotinamide, see: Bigoli et al. (1972 ). For related structures, see: Greenaway et al. (1984 ); Hökelek & Necefoğlu (1996 ); Hökelek et al. (2009a ,b ,c ,d ).

Experimental

Crystal data

[Cd(C₈H₇O₂)₂(C₆H₆N₂O)₂(H₂O)]·H₂O
M_r = 662.97
Triclinic, $[P \overline 1]$
a = 9.5032 (2) Å
b = 12.3543 (3) Å
c = 13.6134 (3) Å
α = 78.278 (3)°
β = 69.776 (2)°
γ = 71.746 (3)°
V = 1416.18 (6) Å³
Z = 2
Mo Kα radiation
μ = 0.83 mm⁻¹
T = 102 K
0.40 × 0.20 × 0.15 mm

Data collection

Bruker Kappa APEXII CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2005 ) T_min = 0.819, T_max = 0.881
25922 measured reflections
7154 independent reflections
6962 reflections with I > 2σ(I)
R_int = 0.021

Refinement

R[F² > 2σ(F²)] = 0.020
wR(F²) = 0.053
S = 1.14
7154 reflections
404 parameters
H atoms treated by a mixture of independent and constrained refinement
Δρ_max = 0.56 e Å⁻³
Δρ_min = −0.38 e Å⁻³

Table 1
Selected bond lengths (Å)

Cd1—O1	2.2478 (11)
Cd1—O3	2.4263 (11)
Cd1—O4	2.3794 (11)
Cd1—O7	2.2947 (11)
Cd1—N1	2.3295 (12)
Cd1—N3	2.3671 (13)

Table 2
Hydrogen-bond geometry (Å, °)

Cg3 and Cg4 are the centroids of the N1/C17-C21 and N3/C23-C27 rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N2—H21⋯O5ⁱ	0.85 (2)	2.05 (2)	2.8990 (19)	177 (2)
N2—H22⋯O6ⁱⁱ	0.87 (3)	2.10 (3)	2.948 (2)	163 (2)
N4—H41⋯O8ⁱⁱⁱ	0.87 (2)	1.99 (2)	2.822 (2)	160 (2)
N4—H42⋯O6^iv	0.86 (2)	2.05 (2)	2.8979 (18)	171 (2)
O7—H71⋯O2^v	0.79 (3)	1.93 (3)	2.7186 (19)	175 (2)
O7—H72⋯O3ⁱⁱ	0.80 (3)	1.97 (3)	2.7690 (18)	174 (3)
O8—H81⋯O4	0.79 (3)	2.21 (3)	2.8767 (18)	143 (3)
O8—H82⋯O1	0.80 (3)	1.93 (3)	2.7269 (18)	169 (3)
C6—H6⋯Cg4^vi	0.93	2.82	3.720 (2)	163
C14—H14⋯Cg3^vii	0.93	2.78	3.6840 (19)	164
Symmetry codes: (i) -x+1, -y+1, -z-1; (ii) -x, -y, -z; (iii) -x, -y, -z+1; (iv) -x, -y-1, -z+1; (v) -x+1, -y, -z; (vi) x+1, y, z; (vii) x-1, y, z.

Data collection: APEX2 (Bruker, 2007 ); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ); software used to prepare material for publication: WinGX (Farrugia, 1999 ) and PLATON (Spek, 2009 ).

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810008366/xu2732sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536810008366/xu2732Isup2.hkl

checkCIF report

Comment top

As a part of our ongoing investigation on transition metal complexes of nicotinamide (NA), one form of niacin (Krishnamachari, 1974), and/or the nicotinic acid derivative N,N-diethylnicotinamide (DENA), an important respiratory stimulant (Bigoli et al., 1972), the title compound was synthesized and its crystal structure is reported herein.

The title compound, (I), is a monomeric complex, where the Cd^II ion is surrounded by two 4-methylbenzoate (PMB) and two isonicotinamide (INA) ligands and one water molecule. One of the PMB ions acts as a bidentate ligand, while the other PMB and two INA are monodentate ligands. The crystal structures of similar complexes of Cd^II, Co^II, Mn^II and Zn^II ions, [Cd(C₈H₅O₃)₂(C₆H₆N₂O)₂(H₂O)].H₂O, (II) (Hökelek et al., 2009a), [Co(C₉H₁₀NO₂)₂(C₆H₆N₂O)(H₂O)₂], (III) (Hökelek et al., 2009b), [Mn(C₉H₁₀NO₂)₂(C₆H₆N₂O)(H₂O)₂], (IV) (Hökelek et al., 2009c), [Zn₂(DENA)₂(C₇H₅O₃)₄].2H₂O, (V) (Hökelek & Necefoğlu, 1996) and [Zn(C₈H₈NO₂)₂(C₆H₆N₂O)₂].H₂O, (VI) (Hökelek et al., 2009d) have also been reported. In (II), the two benzoate ions are coordinated to the Cd atom as bidentate ligands. In the other structures one of the benzoate ligands acts as a bidentate ligand, while the other is monodentate ligand.

In the title compound (Fig. 1), the average Cd—O bond length (Table 1) is 2.3371 (11) Å and the Cd atom is displaced out of the least-squares planes of the carboxylate groups (O1/C1/O2) and (O3/C9/O4) by 0.2697 (1) Å and 0.0105 (1) Å, respectively. The dihedral angle between the planar carboxylate groups and the adjacent benzene rings A (C2—C7) and B (C10—C15) are 10.28 (11)° and 21.24 (9)°, respectively, while those between rings A, B, C (N1/C17—C21) and D (N3/C23—C27) are A/B = 6.90 (4), A/C = 63.11 (5), A/D = 76.86 (4), B/C = 62.69 (5), B/D = 83.75 (4) and C/D = 88.64 (4) °. The intramolecular O—H···O hydrogen bonds (Table 2) link the water molecules to the carboxylate groups (O1/C1/O2) and (O3/C9/O4). In (I), the O3—Cd1—O4 angle is 54.71 (4)°. The corresponding O—M—O (where M is a metal) angles are 52.91 (4)° and 53.96 (4)° in (II), 60.70 (4)° in (III), 58.45 (9)° in (IV), 58.3 (3)° in (V), 60.03 (6)° in (VI) and 55.2 (1)° in [Cu(Asp)₂(py)₂] (where Asp is acetylsalicylate and py is pyridine) [(VII); Greenaway et al., 1984].

In the crystal structure, intramolecular O—H···O and intermolecular O—H···O and N—H···O hydrogen bonds (Table 2) link the molecules into a supramolecular structure, in which they may be effective in the stabilization of the structure. The π–π contact between the benzene rings, Cg1—Cg2ⁱ, [symmetry code (i): 1 + x, y, z, where Cg1 and Cg2 are the centroids of rings A (C2—C7) and B (C10—C15)] may further stabilize the structure, with centroid-centroid distance of 3.911 (1) Å. There also exists two weak C—H···π interactions involving the pyridine rings C and D (Table 2).

Related literature top

For niacin, see: Krishnamachari (1974) and for the nicotinic acid derivative N,N-diethylnicotinamide, see: Bigoli et al. (1972). For related structures, see: Greenaway et al. (1984); Hökelek & Necefoğlu (1996); Hökelek et al. (2009a,b,c,d).

Experimental top

The title compound was prepared by the reaction of 3CdSO₄.8H₂O (1.29 g, 5 mmol) in H₂O (40 ml) and INA (1.22 g, 10 mmol) in H₂O (15 ml) with sodium 4-methylbenzoate (1.58 g, 10 mmol) in H₂O (350 ml). The mixture was filtered and set aside to crystallize at ambient temperature for one week, giving colorless single crystals.

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999) and PLATON (Spek, 2009).

Figures top

Fig. 1. The molecular structure of the title molecule with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Dashed lines indicate the hydrogen-bondings.

Aquabis(isonicotinamide-κN¹)bis(4-methylbenzoato)- κO;κ²O,O'-cadmium(II) monohydrate top

Crystal data top

[Cd(C₈H₇O₂)₂(C₆H₆N₂O)₂(H₂O)]·H₂O	Z = 2
M_r = 662.97	F(000) = 676
Triclinic, P1	D_x = 1.555 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.5032 (2) Å	Cell parameters from 8576 reflections
b = 12.3543 (3) Å	θ = 2.4–28.3°
c = 13.6134 (3) Å	µ = 0.83 mm⁻¹
α = 78.278 (3)°	T = 102 K
β = 69.776 (2)°	Block, colorless
γ = 71.746 (3)°	0.40 × 0.20 × 0.15 mm
V = 1416.18 (6) Å³

Data collection top

Bruker Kappa APEXII CCD area-detector diffractometer	7154 independent reflections
Radiation source: fine-focus sealed tube	6962 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.021
ϕ and ω scans	θ_max = 28.6°, θ_min = 1.6°
Absorption correction: multi-scan (SADABS; Bruker, 2005)	h = −12→12
T_min = 0.819, T_max = 0.881	k = −16→16
25922 measured reflections	l = −18→18

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.020	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.053	H atoms treated by a mixture of independent and constrained refinement
S = 1.14	w = 1/[σ²(F_o²) + (0.0175P)² + 1.1925P] where P = (F_o² + 2F_c²)/3
7154 reflections	(Δ/σ)_max = 0.001
404 parameters	Δρ_max = 0.56 e Å⁻³
0 restraints	Δρ_min = −0.38 e Å⁻³

Crystal data top

[Cd(C₈H₇O₂)₂(C₆H₆N₂O)₂(H₂O)]·H₂O	γ = 71.746 (3)°
M_r = 662.97	V = 1416.18 (6) Å³
Triclinic, P1	Z = 2
a = 9.5032 (2) Å	Mo Kα radiation
b = 12.3543 (3) Å	µ = 0.83 mm⁻¹
c = 13.6134 (3) Å	T = 102 K
α = 78.278 (3)°	0.40 × 0.20 × 0.15 mm
β = 69.776 (2)°

Data collection top

Bruker Kappa APEXII CCD area-detector diffractometer	7154 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 2005)	6962 reflections with I > 2σ(I)
T_min = 0.819, T_max = 0.881	R_int = 0.021
25922 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.020	0 restraints
wR(F²) = 0.053	H atoms treated by a mixture of independent and constrained refinement
S = 1.14	Δρ_max = 0.56 e Å⁻³
7154 reflections	Δρ_min = −0.38 e Å⁻³
404 parameters

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Cd1	0.141608 (11)	0.121190 (8)	0.094078 (7)	0.00977 (3)
O1	0.21408 (12)	0.17237 (9)	0.21480 (8)	0.0153 (2)
O2	0.43486 (13)	0.06777 (9)	0.11883 (8)	0.0158 (2)
O3	−0.09543 (12)	0.15690 (9)	0.04849 (8)	0.0150 (2)
O4	−0.08901 (13)	0.26914 (10)	0.15327 (9)	0.0164 (2)
O5	0.56683 (13)	0.41643 (10)	−0.38584 (9)	0.0199 (2)
O6	−0.03527 (14)	−0.40999 (9)	0.37641 (9)	0.0178 (2)
O7	0.25490 (14)	−0.02091 (10)	−0.01623 (9)	0.0183 (2)
H71	0.345 (3)	−0.038 (2)	−0.0464 (19)	0.030 (6)*
H72	0.214 (3)	−0.064 (2)	−0.0261 (18)	0.028 (6)*
O8	−0.06722 (16)	0.23407 (12)	0.36356 (10)	0.0224 (2)
H81	−0.115 (3)	0.252 (2)	0.323 (2)	0.039 (7)*
H82	0.021 (3)	0.216 (2)	0.326 (2)	0.039 (7)*
N1	0.24879 (15)	0.23682 (11)	−0.05300 (10)	0.0131 (2)
N2	0.32591 (17)	0.46852 (14)	−0.40532 (11)	0.0222 (3)
H21	0.355 (3)	0.502 (2)	−0.4672 (19)	0.029 (6)*
H22	0.235 (3)	0.4542 (19)	−0.3832 (18)	0.027 (6)*
N3	0.06838 (15)	−0.03017 (11)	0.21984 (10)	0.0139 (2)
N4	0.02873 (16)	−0.36600 (12)	0.50561 (10)	0.0162 (2)
H41	0.056 (2)	−0.3201 (18)	0.5322 (17)	0.022 (5)*
H42	0.020 (2)	−0.4306 (19)	0.5415 (16)	0.019 (5)*
C1	0.35814 (17)	0.12189 (12)	0.19750 (11)	0.0122 (3)
C2	0.43118 (17)	0.12606 (13)	0.27780 (11)	0.0138 (3)
C3	0.34802 (19)	0.19738 (14)	0.35725 (13)	0.0190 (3)
H3	0.2493	0.2439	0.3587	0.023*
C4	0.4114 (2)	0.19972 (16)	0.43464 (13)	0.0223 (3)
H4	0.3544	0.2478	0.4874	0.027*
C5	0.55876 (19)	0.13100 (15)	0.43413 (12)	0.0196 (3)
C6	0.64170 (19)	0.06017 (15)	0.35394 (13)	0.0208 (3)
H6	0.7406	0.0138	0.3523	0.025*
C7	0.57917 (18)	0.05760 (14)	0.27640 (12)	0.0174 (3)
H7	0.6364	0.0099	0.2233	0.021*
C8	0.6266 (2)	0.13244 (18)	0.51874 (14)	0.0276 (4)
H8A	0.7263	0.0775	0.5079	0.041*
H8B	0.5582	0.1132	0.5865	0.041*
H8C	0.6384	0.2075	0.5157	0.041*
C9	−0.16048 (17)	0.24072 (12)	0.10406 (11)	0.0123 (3)
C10	−0.32334 (17)	0.30742 (12)	0.10992 (12)	0.0130 (3)
C11	−0.41385 (18)	0.37317 (13)	0.19319 (12)	0.0166 (3)
H11	−0.3706	0.3785	0.2432	0.020*
C12	−0.56823 (19)	0.43074 (14)	0.20192 (13)	0.0195 (3)
H12	−0.6280	0.4732	0.2584	0.023*
C13	−0.63418 (18)	0.42543 (13)	0.12678 (13)	0.0177 (3)
C14	−0.54103 (18)	0.36423 (13)	0.04114 (13)	0.0176 (3)
H14	−0.5822	0.3633	−0.0114	0.021*
C15	−0.38809 (18)	0.30477 (13)	0.03297 (12)	0.0152 (3)
H15	−0.3283	0.2629	−0.0240	0.018*
C16	−0.80317 (19)	0.48229 (16)	0.13748 (15)	0.0257 (4)
H16A	−0.8456	0.5324	0.1920	0.039*
H16B	−0.8590	0.4248	0.1551	0.039*
H16C	−0.8127	0.5259	0.0721	0.039*
C17	0.16137 (17)	0.33676 (13)	−0.08530 (12)	0.0152 (3)
H17	0.0612	0.3651	−0.0419	0.018*
C18	0.21389 (18)	0.39975 (13)	−0.18067 (12)	0.0166 (3)
H18	0.1500	0.4686	−0.2009	0.020*
C19	0.36446 (17)	0.35759 (13)	−0.24544 (11)	0.0134 (3)
C20	0.45742 (18)	0.25694 (13)	−0.20997 (12)	0.0153 (3)
H20	0.5599	0.2288	−0.2501	0.018*
C21	0.39564 (18)	0.19876 (13)	−0.11404 (12)	0.0148 (3)
H21A	0.4582	0.1308	−0.0911	0.018*
C22	0.42827 (18)	0.41740 (13)	−0.35244 (12)	0.0154 (3)
C23	0.01222 (18)	−0.10290 (13)	0.19260 (12)	0.0153 (3)
H23	−0.0121	−0.0849	0.1296	0.018*
C24	−0.01121 (18)	−0.20371 (13)	0.25425 (12)	0.0158 (3)
H24	−0.0495	−0.2523	0.2325	0.019*
C25	0.02332 (17)	−0.23100 (12)	0.34907 (11)	0.0125 (3)
C26	0.07689 (18)	−0.15443 (13)	0.37961 (12)	0.0160 (3)
H26	0.0976	−0.1688	0.4437	0.019*
C27	0.09879 (18)	−0.05607 (13)	0.31243 (12)	0.0156 (3)
H27	0.1363	−0.0057	0.3326	0.019*
C28	0.00343 (17)	−0.34324 (12)	0.41280 (11)	0.0131 (3)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Cd1	0.01036 (5)	0.01012 (5)	0.00874 (5)	−0.00363 (4)	−0.00264 (4)	0.00016 (3)
O1	0.0118 (5)	0.0192 (5)	0.0162 (5)	−0.0038 (4)	−0.0054 (4)	−0.0029 (4)
O2	0.0165 (5)	0.0163 (5)	0.0152 (5)	−0.0032 (4)	−0.0054 (4)	−0.0038 (4)
O3	0.0122 (5)	0.0160 (5)	0.0169 (5)	−0.0018 (4)	−0.0048 (4)	−0.0040 (4)
O4	0.0142 (5)	0.0201 (5)	0.0177 (5)	−0.0041 (4)	−0.0076 (4)	−0.0034 (4)
O5	0.0164 (5)	0.0272 (6)	0.0148 (5)	−0.0095 (5)	−0.0039 (4)	0.0046 (4)
O6	0.0239 (6)	0.0157 (5)	0.0185 (5)	−0.0105 (4)	−0.0098 (4)	0.0023 (4)
O7	0.0141 (5)	0.0195 (6)	0.0213 (6)	−0.0072 (5)	0.0013 (4)	−0.0100 (4)
O8	0.0184 (6)	0.0347 (7)	0.0148 (5)	−0.0063 (5)	−0.0039 (5)	−0.0075 (5)
N1	0.0138 (6)	0.0132 (6)	0.0125 (6)	−0.0055 (5)	−0.0033 (5)	0.0003 (4)
N2	0.0179 (7)	0.0322 (8)	0.0158 (6)	−0.0125 (6)	−0.0065 (5)	0.0105 (6)
N3	0.0152 (6)	0.0144 (6)	0.0121 (6)	−0.0049 (5)	−0.0038 (5)	−0.0006 (4)
N4	0.0225 (7)	0.0131 (6)	0.0147 (6)	−0.0078 (5)	−0.0072 (5)	0.0024 (5)
C1	0.0128 (6)	0.0106 (6)	0.0138 (6)	−0.0055 (5)	−0.0045 (5)	0.0017 (5)
C2	0.0135 (6)	0.0162 (7)	0.0128 (6)	−0.0060 (5)	−0.0045 (5)	0.0001 (5)
C3	0.0157 (7)	0.0226 (8)	0.0205 (7)	−0.0035 (6)	−0.0068 (6)	−0.0063 (6)
C4	0.0224 (8)	0.0292 (9)	0.0190 (8)	−0.0074 (7)	−0.0063 (6)	−0.0091 (6)
C5	0.0207 (8)	0.0278 (8)	0.0155 (7)	−0.0132 (7)	−0.0078 (6)	0.0014 (6)
C6	0.0142 (7)	0.0299 (9)	0.0190 (7)	−0.0055 (6)	−0.0079 (6)	0.0006 (6)
C7	0.0146 (7)	0.0223 (8)	0.0145 (7)	−0.0037 (6)	−0.0044 (6)	−0.0022 (6)
C8	0.0299 (9)	0.0432 (11)	0.0195 (8)	−0.0202 (8)	−0.0128 (7)	0.0018 (7)
C9	0.0119 (6)	0.0136 (6)	0.0109 (6)	−0.0049 (5)	−0.0029 (5)	0.0016 (5)
C10	0.0114 (6)	0.0124 (6)	0.0157 (7)	−0.0038 (5)	−0.0049 (5)	−0.0002 (5)
C11	0.0158 (7)	0.0173 (7)	0.0183 (7)	−0.0032 (6)	−0.0067 (6)	−0.0042 (6)
C12	0.0162 (7)	0.0189 (7)	0.0209 (8)	−0.0012 (6)	−0.0037 (6)	−0.0057 (6)
C13	0.0130 (7)	0.0150 (7)	0.0246 (8)	−0.0029 (5)	−0.0067 (6)	−0.0004 (6)
C14	0.0169 (7)	0.0159 (7)	0.0241 (8)	−0.0038 (6)	−0.0119 (6)	−0.0019 (6)
C15	0.0151 (7)	0.0136 (7)	0.0177 (7)	−0.0028 (5)	−0.0064 (6)	−0.0027 (5)
C16	0.0142 (7)	0.0257 (9)	0.0352 (10)	0.0002 (6)	−0.0095 (7)	−0.0039 (7)
C17	0.0117 (6)	0.0170 (7)	0.0145 (7)	−0.0040 (5)	−0.0029 (5)	0.0015 (5)
C18	0.0143 (7)	0.0164 (7)	0.0162 (7)	−0.0037 (6)	−0.0051 (6)	0.0044 (6)
C19	0.0151 (7)	0.0151 (7)	0.0114 (6)	−0.0072 (5)	−0.0047 (5)	0.0018 (5)
C20	0.0143 (7)	0.0154 (7)	0.0136 (7)	−0.0040 (5)	−0.0017 (5)	−0.0008 (5)
C21	0.0154 (7)	0.0129 (7)	0.0144 (7)	−0.0029 (5)	−0.0042 (5)	0.0002 (5)
C22	0.0174 (7)	0.0161 (7)	0.0123 (6)	−0.0073 (6)	−0.0035 (5)	0.0019 (5)
C23	0.0190 (7)	0.0170 (7)	0.0115 (6)	−0.0071 (6)	−0.0059 (5)	0.0009 (5)
C24	0.0216 (7)	0.0152 (7)	0.0132 (7)	−0.0082 (6)	−0.0058 (6)	−0.0012 (5)
C25	0.0124 (6)	0.0117 (6)	0.0123 (6)	−0.0037 (5)	−0.0033 (5)	0.0012 (5)
C26	0.0202 (7)	0.0171 (7)	0.0142 (7)	−0.0088 (6)	−0.0088 (6)	0.0028 (5)
C27	0.0203 (7)	0.0154 (7)	0.0145 (7)	−0.0091 (6)	−0.0073 (6)	0.0014 (5)
C28	0.0111 (6)	0.0128 (6)	0.0136 (6)	−0.0036 (5)	−0.0025 (5)	0.0009 (5)

Geometric parameters (Å, º) top

Cd1—O1	2.2478 (11)	C8—C5	1.507 (2)
Cd1—O3	2.4263 (11)	C8—H8A	0.9600
Cd1—O4	2.3794 (11)	C8—H8B	0.9600
Cd1—O7	2.2947 (11)	C8—H8C	0.9600
Cd1—N1	2.3295 (12)	C9—C10	1.491 (2)
Cd1—N3	2.3671 (13)	C10—C11	1.395 (2)
O1—C1	1.2730 (18)	C10—C15	1.396 (2)
O2—C1	1.2535 (18)	C11—H11	0.9300
O3—C9	1.2730 (18)	C12—C11	1.390 (2)
O4—C9	1.2622 (18)	C12—C13	1.393 (2)
O5—C22	1.2325 (19)	C12—H12	0.9300
O6—C28	1.2422 (18)	C13—C16	1.506 (2)
O7—H71	0.79 (3)	C14—C13	1.393 (2)
O7—H72	0.80 (2)	C14—C15	1.385 (2)
O8—H81	0.79 (3)	C14—H14	0.9300
O8—H82	0.81 (3)	C15—H15	0.9300
N1—C17	1.3406 (19)	C16—H16A	0.9600
N1—C21	1.3435 (19)	C16—H16B	0.9600
N2—C22	1.333 (2)	C16—H16C	0.9600
N2—H21	0.85 (2)	C17—H17	0.9300
N2—H22	0.87 (2)	C18—C17	1.387 (2)
N3—C23	1.3425 (19)	C18—C19	1.394 (2)
N3—C27	1.3433 (19)	C18—H18	0.9300
N4—C28	1.325 (2)	C20—C19	1.387 (2)
N4—H41	0.87 (2)	C20—H20	0.9300
N4—H42	0.86 (2)	C21—C20	1.385 (2)
C1—C2	1.500 (2)	C21—H21A	0.9300
C2—C3	1.390 (2)	C22—C19	1.506 (2)
C2—C7	1.392 (2)	C23—C24	1.387 (2)
C3—C4	1.391 (2)	C23—H23	0.9300
C3—H3	0.9300	C24—H24	0.9300
C4—C5	1.391 (2)	C25—C24	1.391 (2)
C4—H4	0.9300	C26—C25	1.391 (2)
C6—C5	1.393 (2)	C26—C27	1.390 (2)
C6—C7	1.388 (2)	C26—H26	0.9300
C6—H6	0.9300	C27—H27	0.9300
C7—H7	0.9300	C28—C25	1.5077 (19)

O1—Cd1—O3	137.23 (4)	O4—C9—O3	121.19 (13)
O1—Cd1—O4	83.65 (4)	O4—C9—C10	119.45 (13)
O1—Cd1—O7	133.14 (4)	C11—C10—C15	118.94 (14)
O1—Cd1—N1	99.39 (4)	C11—C10—C9	120.24 (13)
O1—Cd1—N3	87.65 (4)	C15—C10—C9	120.82 (13)
O4—Cd1—O3	54.71 (4)	C10—C11—H11	119.8
O7—Cd1—O3	88.51 (4)	C12—C11—C10	120.44 (14)
O7—Cd1—O4	143.07 (4)	C12—C11—H11	119.8
O7—Cd1—N1	84.40 (4)	C11—C12—C13	120.59 (15)
O7—Cd1—N3	82.88 (4)	C11—C12—H12	119.7
N1—Cd1—O3	93.12 (4)	C13—C12—H12	119.7
N1—Cd1—O4	93.53 (4)	C12—C13—C14	118.64 (14)
N1—Cd1—N3	167.06 (4)	C12—C13—C16	121.48 (15)
N3—Cd1—O3	88.91 (4)	C14—C13—C16	119.87 (15)
N3—Cd1—O4	98.06 (4)	C13—C14—H14	119.5
C1—O1—Cd1	105.84 (9)	C15—C14—C13	121.06 (14)
C9—O3—Cd1	90.83 (8)	C15—C14—H14	119.5
C9—O4—Cd1	93.27 (9)	C10—C15—H15	119.9
Cd1—O7—H71	123.1 (17)	C14—C15—C10	120.21 (14)
Cd1—O7—H72	127.0 (17)	C14—C15—H15	119.9
H72—O7—H71	110 (2)	C13—C16—H16A	109.5
H81—O8—H82	103 (3)	C13—C16—H16B	109.5
C17—N1—Cd1	121.04 (10)	C13—C16—H16C	109.5
C17—N1—C21	118.25 (13)	H16A—C16—H16B	109.5
C21—N1—Cd1	120.31 (10)	H16A—C16—H16C	109.5
C22—N2—H21	120.3 (15)	H16B—C16—H16C	109.5
C22—N2—H22	119.5 (15)	N1—C17—C18	122.87 (14)
H22—N2—H21	119 (2)	N1—C17—H17	118.6
C23—N3—Cd1	118.71 (10)	C18—C17—H17	118.6
C23—N3—C27	117.68 (13)	C17—C18—C19	118.55 (14)
C27—N3—Cd1	123.03 (10)	C17—C18—H18	120.7
C28—N4—H41	124.1 (14)	C19—C18—H18	120.7
C28—N4—H42	118.4 (14)	C18—C19—C22	122.10 (14)
H42—N4—H41	117.4 (19)	C20—C19—C18	118.62 (13)
O1—C1—C2	117.01 (13)	C20—C19—C22	119.28 (13)
O2—C1—O1	121.75 (13)	C19—C20—H20	120.4
O2—C1—C2	121.20 (13)	C21—C20—C19	119.15 (14)
C3—C2—C1	119.49 (14)	C21—C20—H20	120.4
C3—C2—C7	119.02 (14)	N1—C21—C20	122.46 (14)
C7—C2—C1	121.47 (13)	N1—C21—H21A	118.8
C2—C3—C4	120.48 (15)	C20—C21—H21A	118.8
C2—C3—H3	119.8	O5—C22—N2	124.40 (14)
C4—C3—H3	119.8	O5—C22—C19	120.11 (14)
C3—C4—H4	119.6	N2—C22—C19	115.49 (13)
C5—C4—C3	120.82 (15)	N3—C23—C24	122.90 (14)
C5—C4—H4	119.6	N3—C23—H23	118.5
C4—C5—C6	118.36 (14)	C24—C23—H23	118.5
C4—C5—C8	120.82 (16)	C23—C24—C25	119.07 (14)
C6—C5—C8	120.82 (16)	C23—C24—H24	120.5
C5—C6—H6	119.5	C25—C24—H24	120.5
C7—C6—C5	121.08 (15)	C24—C25—C26	118.47 (13)
C7—C6—H6	119.5	C24—C25—C28	118.30 (13)
C2—C7—H7	119.9	C26—C25—C28	123.23 (13)
C6—C7—C2	120.24 (15)	C25—C26—H26	120.7
C6—C7—H7	119.9	C27—C26—C25	118.64 (14)
C5—C8—H8A	109.5	C27—C26—H26	120.7
C5—C8—H8B	109.5	N3—C27—C26	123.20 (14)
C5—C8—H8C	109.5	N3—C27—H27	118.4
H8A—C8—H8B	109.5	C26—C27—H27	118.4
H8A—C8—H8C	109.5	O6—C28—N4	123.03 (14)
H8B—C8—H8C	109.5	O6—C28—C25	119.00 (13)
O3—C9—C10	119.35 (13)	N4—C28—C25	117.97 (13)

O3—Cd1—O1—C1	178.82 (8)	O1—C1—C2—C3	−9.6 (2)
O4—Cd1—O1—C1	−168.65 (9)	O1—C1—C2—C7	168.54 (14)
O7—Cd1—O1—C1	15.00 (11)	O2—C1—C2—C3	172.66 (14)
N1—Cd1—O1—C1	−76.11 (9)	O2—C1—C2—C7	−9.2 (2)
N3—Cd1—O1—C1	92.97 (9)	C1—C2—C3—C4	177.80 (14)
O1—Cd1—O3—C9	15.18 (11)	C7—C2—C3—C4	−0.4 (2)
O4—Cd1—O3—C9	−0.14 (8)	C1—C2—C7—C6	−177.67 (14)
O7—Cd1—O3—C9	−176.56 (9)	C3—C2—C7—C6	0.5 (2)
N1—Cd1—O3—C9	−92.25 (9)	C2—C3—C4—C5	0.0 (3)
N3—Cd1—O3—C9	100.53 (9)	C3—C4—C5—C6	0.3 (3)
O1—Cd1—O4—C9	−169.47 (9)	C3—C4—C5—C8	−179.23 (16)
O3—Cd1—O4—C9	0.14 (8)	C5—C6—C7—C2	−0.2 (2)
O7—Cd1—O4—C9	6.09 (12)	C7—C6—C5—C4	−0.2 (2)
N1—Cd1—O4—C9	91.47 (9)	C7—C6—C5—C8	179.32 (15)
N3—Cd1—O4—C9	−82.76 (9)	O3—C9—C10—C11	159.36 (14)
O1—Cd1—N1—C17	−98.58 (11)	O3—C9—C10—C15	−20.3 (2)
O1—Cd1—N1—C21	88.82 (11)	O4—C9—C10—C11	−21.4 (2)
O3—Cd1—N1—C17	40.37 (11)	O4—C9—C10—C15	158.92 (14)
O3—Cd1—N1—C21	−132.23 (11)	C9—C10—C11—C12	−176.66 (14)
O4—Cd1—N1—C17	−14.44 (11)	C15—C10—C11—C12	3.0 (2)
O4—Cd1—N1—C21	172.96 (11)	C9—C10—C15—C14	177.96 (14)
O7—Cd1—N1—C17	128.57 (12)	C11—C10—C15—C14	−1.7 (2)
O7—Cd1—N1—C21	−44.04 (11)	C13—C12—C11—C10	−1.2 (2)
N3—Cd1—N1—C17	139.16 (18)	C11—C12—C13—C14	−1.9 (2)
N3—Cd1—N1—C21	−33.4 (3)	C11—C12—C13—C16	176.95 (15)
O1—Cd1—N3—C23	−178.51 (11)	C15—C14—C13—C12	3.3 (2)
O1—Cd1—N3—C27	−7.44 (12)	C15—C14—C13—C16	−175.65 (15)
O3—Cd1—N3—C23	44.13 (11)	C13—C14—C15—C10	−1.5 (2)
O3—Cd1—N3—C27	−144.80 (12)	C19—C18—C17—N1	−0.4 (2)
O4—Cd1—N3—C23	98.24 (11)	C17—C18—C19—C20	−2.6 (2)
O4—Cd1—N3—C27	−90.69 (12)	C17—C18—C19—C22	177.02 (14)
O7—Cd1—N3—C23	−44.50 (11)	C21—C20—C19—C18	3.1 (2)
O7—Cd1—N3—C27	126.57 (12)	C21—C20—C19—C22	−176.49 (13)
N1—Cd1—N3—C23	−55.1 (2)	N1—C21—C20—C19	−0.8 (2)
N1—Cd1—N3—C27	115.9 (2)	O5—C22—C19—C18	145.44 (16)
Cd1—N1—C17—C18	−170.02 (12)	O5—C22—C19—C20	−35.0 (2)
C21—N1—C17—C18	2.7 (2)	N2—C22—C19—C18	−34.9 (2)
Cd1—N1—C21—C20	170.65 (11)	N2—C22—C19—C20	144.70 (15)
C17—N1—C21—C20	−2.2 (2)	N3—C23—C24—C25	0.6 (2)
Cd1—N3—C23—C24	169.79 (12)	C26—C25—C24—C23	1.5 (2)
C27—N3—C23—C24	−1.8 (2)	C28—C25—C24—C23	−177.50 (14)
Cd1—N3—C27—C26	−170.25 (12)	C27—C26—C25—C24	−2.2 (2)
C23—N3—C27—C26	0.9 (2)	C27—C26—C25—C28	176.66 (14)
Cd1—O1—C1—O2	7.16 (16)	C25—C26—C27—N3	1.1 (2)
Cd1—O1—C1—C2	−170.52 (10)	O6—C28—C25—C24	3.6 (2)
Cd1—O3—C9—O4	0.24 (14)	O6—C28—C25—C26	−175.30 (14)
Cd1—O3—C9—C10	179.43 (11)	N4—C28—C25—C24	−176.55 (14)
Cd1—O4—C9—O3	−0.25 (14)	N4—C28—C25—C26	4.5 (2)
Cd1—O4—C9—C10	−179.43 (11)

Hydrogen-bond geometry (Å, º) top

Cg3 and Cg4 are the centroids of the N1/C17-C21 and N3/C23-C27 rings, respectively.

D—H···A	D—H	H···A	D···A	D—H···A
N2—H21···O5ⁱ	0.85 (2)	2.05 (2)	2.8990 (19)	177 (2)
N2—H22···O6ⁱⁱ	0.87 (3)	2.10 (3)	2.948 (2)	163 (2)
N4—H41···O8ⁱⁱⁱ	0.87 (2)	1.99 (2)	2.822 (2)	160 (2)
N4—H42···O6^iv	0.86 (2)	2.05 (2)	2.8979 (18)	171 (2)
O7—H71···O2^v	0.79 (3)	1.93 (3)	2.7186 (19)	175 (2)
O7—H72···O3ⁱⁱ	0.80 (3)	1.97 (3)	2.7690 (18)	174 (3)
O8—H81···O4	0.79 (3)	2.21 (3)	2.8767 (18)	143 (3)
O8—H82···O1	0.80 (3)	1.93 (3)	2.7269 (18)	169 (3)
C6—H6···Cg4^vi	0.93	2.82	3.720 (2)	163
C14—H14···Cg3^vii	0.93	2.78	3.6840 (19)	164

Symmetry codes: (i) −x+1, −y+1, −z−1; (ii) −x, −y, −z; (iii) −x, −y, −z+1; (iv) −x, −y−1, −z+1; (v) −x+1, −y, −z; (vi) x+1, y, z; (vii) x−1, y, z.

Experimental details

Crystal data
Chemical formula	[Cd(C₈H₇O₂)₂(C₆H₆N₂O)₂(H₂O)]·H₂O
M_r	662.97
Crystal system, space group	Triclinic, P1
Temperature (K)	102
a, b, c (Å)	9.5032 (2), 12.3543 (3), 13.6134 (3)
α, β, γ (°)	78.278 (3), 69.776 (2), 71.746 (3)
V (Å³)	1416.18 (6)
Z	2
Radiation type	Mo Kα
µ (mm⁻¹)	0.83
Crystal size (mm)	0.40 × 0.20 × 0.15

Data collection
Diffractometer	Bruker Kappa APEXII CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Bruker, 2005)
T_min, T_max	0.819, 0.881
No. of measured, independent and observed [I > 2σ(I)] reflections	25922, 7154, 6962
R_int	0.021
(sin θ/λ)_max (Å⁻¹)	0.673

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.020, 0.053, 1.14
No. of reflections	7154
No. of parameters	404
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
Δρ_max, Δρ_min (e Å⁻³)	0.56, −0.38

Computer programs: APEX2 (Bruker, 2007), SAINT (Bruker, 2007), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), ORTEP-3 for Windows (Farrugia, 1997), WinGX (Farrugia, 1999) and PLATON (Spek, 2009).

Selected bond lengths (Å) top

Cd1—O1	2.2478 (11)	Cd1—O7	2.2947 (11)
Cd1—O3	2.4263 (11)	Cd1—N1	2.3295 (12)
Cd1—O4	2.3794 (11)	Cd1—N3	2.3671 (13)

Hydrogen-bond geometry (Å, º) top

Cg3 and Cg4 are the centroids of the N1/C17-C21 and N3/C23-C27 rings, respectively.

D—H···A	D—H	H···A	D···A	D—H···A
N2—H21···O5ⁱ	0.85 (2)	2.05 (2)	2.8990 (19)	177 (2)
N2—H22···O6ⁱⁱ	0.87 (3)	2.10 (3)	2.948 (2)	163 (2)
N4—H41···O8ⁱⁱⁱ	0.87 (2)	1.99 (2)	2.822 (2)	160 (2)
N4—H42···O6^iv	0.86 (2)	2.05 (2)	2.8979 (18)	171 (2)
O7—H71···O2^v	0.79 (3)	1.93 (3)	2.7186 (19)	175 (2)
O7—H72···O3ⁱⁱ	0.80 (3)	1.97 (3)	2.7690 (18)	174 (3)
O8—H81···O4	0.79 (3)	2.21 (3)	2.8767 (18)	143 (3)
O8—H82···O1	0.80 (3)	1.93 (3)	2.7269 (18)	169 (3)
C6—H6···Cg4^vi	0.93	2.82	3.7196 (20)	163
C14—H14···Cg3^vii	0.93	2.78	3.6840 (19)	164

Symmetry codes: (i) −x+1, −y+1, −z−1; (ii) −x, −y, −z; (iii) −x, −y, −z+1; (iv) −x, −y−1, −z+1; (v) −x+1, −y, −z; (vi) x+1, y, z; (vii) x−1, y, z.

Acknowledgements

The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskişehir, Turkey, for the use of X-ray diffractometer. This work was supported financially by Kafkas University Research Fund (grant No. 2009-FEF-03).

References

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Volume 66| Part 4| April 2010| Pages m392-m393

doi:10.1107/S1600536810008366

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