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organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 66| Part 5| May 2010| Page o1084
https://doi.org/10.1107/S1600536810012912

2-Hydr­­oxy-N′-(2-hydr­­oxy-3-meth­­oxy-5-nitro­benzyl­­idene)-3-methyl­benzo­hydrazide

You-Yue Han,a* Yong-Hong Lia and Qiu-Rong Zhaoa

aDepartment of Chemistry and Life Science, Chuzhou University, Chuzhou, Anhui 239000, People's Republic of China
*Correspondence e-mail: hanyouyue@126.com

(Received 6 April 2010; accepted 7 April 2010; online 14 April 2010)

In the title compound, C16H15N3O6, the dihedral angle between the two benzene rings is 0.9 (2)°. The mol­ecule adopts an E configuration with respect to the C=N bond. There are intra­molecular O—H⋯N and O—H⋯O hydrogen bonds in the mol­ecule. In the crystal structure, mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds to form chains running along the c axis.

Related literature

For the biological properties of hydrazone compounds, see: Patil et al. (2010[Patil, S. A., Naik, V. H., Kulkarni, A. D., Kamble, U., Bagihalli, G. B. & Badami, P. S. (2010). J. Coord. Chem. 63, 688-699.]); Cukurovali et al. (2006[Cukurovali, A., Yilmaz, I., Gur, S. & Kazaz, C. (2006). Eur. J. Med. Chem. 41, 201-207.]). For the crystal structures of hydrazone compounds, see: Mohd Lair et al. (2009[Mohd Lair, N., Mohd Ali, H. & Ng, S. W. (2009). Acta Cryst. E65, o190.]); Lin & Sang (2009[Lin, X.-S. & Sang, Y.-L. (2009). Acta Cryst. E65, o1650.]); Suleiman Gwaram et al. (2010[Suleiman Gwaram, N., Khaledi, H., Mohd Ali, H., Robinson, W. T. & Abdulla, M. A. (2010). Acta Cryst. E66, o721.]). For the hydrazone compounds we reported recently, see: Han & Zhao (2010a[Han, Y.-Y. & Zhao, Q.-R. (2010a). Acta Cryst. E66, o1025.],b[Han, Y.-Y. & Zhao, Q.-R. (2010b). Acta Cryst. E66, o1026.]). For bond-length data, see: Allen et al. (1987[Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1-19.]). For similar compounds, see: Li & Ban (2009[Li, C.-M. & Ban, H.-Y. (2009). Acta Cryst. E65, o876.]); Lo & Ng (2009[Lo, K. M. & Ng, S. W. (2009). Acta Cryst. E65, o969.]); Ning & Xu (2009[Ning, J.-H. & Xu, X.-W. (2009). Acta Cryst. E65, o905-o906.]); Zhu et al. (2009[Zhu, C.-G., Wei, Y.-J. & Zhu, Q.-Y. (2009). Acta Cryst. E65, o85.]).

[Scheme 1]

Experimental

Crystal data

  • C16H15N3O6

  • Mr = 345.31

  • Monoclinic, P 21 /n

  • a = 7.482 (1) Å

  • b = 17.158 (1) Å

  • c = 12.250 (1) Å

  • β = 91.565 (1)°

  • V = 1572.0 (3) Å3

  • Z = 4

  • Mo Kα radiation

  • μ = 0.11 mm−1

  • T = 298 K

  • 0.10 × 0.07 × 0.05 mm
Data collection

  • Bruker SMART CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.989, Tmax = 0.994

  • 14545 measured reflections

  • 2612 independent reflections

  • 2165 reflections with I > 2σ(I)

  • Rint = 0.023
Refinement

  • R[F2 > 2σ(F2)] = 0.037

  • wR(F2) = 0.108

  • S = 1.07

  • 2612 reflections

  • 233 parameters

  • 1 restraint

  • H atoms treated by a mixture of independent and constrained refinement

  • Δρmax = 0.14 e Å−3

  • Δρmin = −0.27 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A D⋯A D—H⋯A
N3—H3⋯O6i 0.90 (1) 2.22 (1) 3.0190 (17) 147 (2)
O4—H4⋯O3 0.82 1.79 2.5192 (15) 148
O1—H1⋯N2 0.82 1.90 2.6166 (17) 145
Symmetry code: (i) [x-{\script{1\over 2}}, -y+{\script{3\over 2}}, z-{\script{1\over 2}}].

Data collection: SMART (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks global, I. DOI: https://doi.org/10.1107/S1600536810012912/hg2671sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536810012912/hg2671Isup2.hkl

checkCIF report


Comment top

Hydrazone compounds have been widely investigated for their biological properties (Patil et al., 2010; Cukurovali et al., 2006). Furthermore, the crystal structures of the hydrazone compounds have also attracted much attention in recent years (Mohd Lair et al., 2009; Lin & Sang, 2009; Suleiman Gwaram et al., 2010). As a continuous work on the structural characterization of such compounds (Han & Zhao, 2010a,b), the title new hydrazone compound is reported.

In the title compound, Fig. 1, the dihedral angle between the two benzene rings is 0.9 (2)°. The molecule adopts an E configuration with respect to the C═N bond. There are intramolecular O—H···N and O—H···O hydrogen bonds in the molecule (Table 1). All the bond lengths are within normal ranges (Allen et al., 1987), and are comparable with those in the similar compounds (Li & Ban, 2009; Lo & Ng, 2009; Ning & Xu, 2009; Zhu et al., 2009).

In the crystal structure, molecules are linked through intermolecular N—H···O hydrogen bonds (Table 1) to form chains running along the c axis (Fig. 2).

Related literature top

For the biological properties of hydrazone compounds, see: Patil et al. (2010); Cukurovali et al. (2006). For the crystal structures of hydrazone compounds, see: Mohd Lair et al. (2009); Lin & Sang (2009); Suleiman Gwaram et al. (2010). For the hydrazone compounds we reported recently, see: Han & Zhao (2010a,b). For bond-length data, see: Allen et al. (1987). For similar compounds, see: Li & Ban (2009); Lo & Ng (2009); Ning & Xu (2009); Zhu et al. (2009).

Experimental top

A mixture of 3-methoxy-5-nitrosalicylaldehyde (0.197 g, 1 mmol) and 2-hydroxy-3-methylbenzohydrazide (0.166 g, 1 mmol) in 50 ml methanol was stirred at room temperature for 1 h. The mixture was filtered to remove impurities, and then left at room temperature. After a few days, single crystals of the title compound, suitable for X-ray diffraction, were formed.

Refinement top

Amino H atom was located from a difference Fourier map and refined isotropically, with N—H distance restrained to 0.90 (1) Å. Other H atoms were positioned geometrically and refined using the riding-model approximation, with C—H = 0.93 or 0.96 Å, O—H = 0.82 Å, and Uiso(H) = 1.2Ueq(C) or Uiso(H) = 1.5Ueq(methyl C and O).

Structure description top

Hydrazone compounds have been widely investigated for their biological properties (Patil et al., 2010; Cukurovali et al., 2006). Furthermore, the crystal structures of the hydrazone compounds have also attracted much attention in recent years (Mohd Lair et al., 2009; Lin & Sang, 2009; Suleiman Gwaram et al., 2010). As a continuous work on the structural characterization of such compounds (Han & Zhao, 2010a,b), the title new hydrazone compound is reported.

In the title compound, Fig. 1, the dihedral angle between the two benzene rings is 0.9 (2)°. The molecule adopts an E configuration with respect to the C═N bond. There are intramolecular O—H···N and O—H···O hydrogen bonds in the molecule (Table 1). All the bond lengths are within normal ranges (Allen et al., 1987), and are comparable with those in the similar compounds (Li & Ban, 2009; Lo & Ng, 2009; Ning & Xu, 2009; Zhu et al., 2009).

In the crystal structure, molecules are linked through intermolecular N—H···O hydrogen bonds (Table 1) to form chains running along the c axis (Fig. 2).

For the biological properties of hydrazone compounds, see: Patil et al. (2010); Cukurovali et al. (2006). For the crystal structures of hydrazone compounds, see: Mohd Lair et al. (2009); Lin & Sang (2009); Suleiman Gwaram et al. (2010). For the hydrazone compounds we reported recently, see: Han & Zhao (2010a,b). For bond-length data, see: Allen et al. (1987). For similar compounds, see: Li & Ban (2009); Lo & Ng (2009); Ning & Xu (2009); Zhu et al. (2009).

Computing details top

Data collection: SMART (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title compound with atom labels and the 30% probability displacement ellipsoids for non-H atoms. Intramolecular hydrogen bonds are shown as dashed lines.
[Figure 2] Fig. 2. The molecular packing of the title compound. Hydrogen bonds are shown as dashed lines.
2-Hydroxy-N'-(2-hydroxy-3-methoxy-5-nitrobenzylidene)- 3-methylbenzohydrazide top
Crystal data top
C16H15N3O6F(000) = 720
Mr = 345.31Dx = 1.459 Mg m−3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 6384 reflections
a = 7.482 (1) Åθ = 2.4–28.1°
b = 17.158 (1) ŵ = 0.11 mm−1
c = 12.250 (1) ÅT = 298 K
β = 91.565 (1)°Block, colourless
V = 1572.0 (3) Å30.10 × 0.07 × 0.05 mm
Z = 4
Data collection top
Bruker SMART CCD area-detector
diffractometer		2612 independent reflections
Radiation source: fine-focus sealed tube2165 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.023
ω scansθmax = 25.0°, θmin = 2.0°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		h = −8→8
Tmin = 0.989, Tmax = 0.994k = −20→19
14545 measured reflectionsl = −13→13
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.037Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.108H atoms treated by a mixture of independent and constrained refinement
S = 1.07 w = 1/[σ2(Fo2) + (0.0597P)2 + 0.2485P]
where P = (Fo2 + 2Fc2)/3
2612 reflections(Δ/σ)max = 0.001
233 parametersΔρmax = 0.14 e Å−3
1 restraintΔρmin = −0.27 e Å−3
Crystal data top
C16H15N3O6V = 1572.0 (3) Å3
Mr = 345.31Z = 4
Monoclinic, P21/nMo Kα radiation
a = 7.482 (1) ŵ = 0.11 mm−1
b = 17.158 (1) ÅT = 298 K
c = 12.250 (1) Å0.10 × 0.07 × 0.05 mm
β = 91.565 (1)°
Data collection top
Bruker SMART CCD area-detector
diffractometer		2612 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		2165 reflections with I > 2σ(I)
Tmin = 0.989, Tmax = 0.994Rint = 0.023
14545 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0371 restraint
wR(F2) = 0.108H atoms treated by a mixture of independent and constrained refinement
S = 1.07Δρmax = 0.14 e Å−3
2612 reflectionsΔρmin = −0.27 e Å−3
233 parameters
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
O10.91330 (15)0.99426 (5)0.21838 (9)0.0529 (3)
H10.86391.00750.16070.079*
O21.05158 (16)0.93423 (6)0.39521 (9)0.0569 (3)
O30.67111 (17)1.11702 (6)0.00680 (9)0.0596 (3)
O40.55183 (17)1.23435 (6)−0.09508 (10)0.0633 (3)
H40.59861.2096−0.04470.095*
O51.0371 (2)0.63937 (6)0.14205 (11)0.0805 (4)
O61.13335 (17)0.65067 (6)0.30689 (10)0.0654 (4)
N11.06881 (16)0.67848 (7)0.22311 (11)0.0481 (3)
N20.78019 (15)0.97366 (7)0.02075 (10)0.0428 (3)
N30.70013 (16)1.00078 (6)−0.07337 (10)0.0434 (3)
C10.91165 (17)0.87130 (8)0.12358 (11)0.0391 (3)
C20.94794 (18)0.91768 (8)0.21567 (12)0.0397 (3)
C31.02423 (19)0.88404 (8)0.31098 (12)0.0422 (3)
C41.06361 (18)0.80575 (8)0.31361 (12)0.0425 (4)
H4A1.11300.78300.37640.051*
C51.02806 (18)0.76137 (8)0.22055 (12)0.0406 (3)
C60.95409 (18)0.79211 (8)0.12723 (12)0.0423 (3)
H60.93210.76060.06650.051*
C71.1154 (3)0.90321 (10)0.49667 (14)0.0671 (5)
H7A1.03190.86540.52240.101*
H7B1.12810.94450.54910.101*
H7C1.22930.87880.48700.101*
C80.8290 (2)0.90257 (8)0.02500 (12)0.0444 (4)
H80.81130.8706−0.03570.053*
C90.64676 (18)1.07636 (8)−0.07544 (12)0.0398 (3)
C100.56400 (18)1.10707 (8)−0.17680 (12)0.0393 (3)
C110.52198 (18)1.18678 (8)−0.18113 (12)0.0433 (4)
C120.44698 (19)1.22062 (9)−0.27568 (13)0.0486 (4)
C130.4115 (2)1.17278 (10)−0.36333 (14)0.0566 (4)
H130.36041.1941−0.42660.068*
C140.4493 (2)1.09387 (10)−0.36069 (14)0.0587 (4)
H140.42301.0629−0.42140.070*
C150.5255 (2)1.06140 (9)−0.26864 (13)0.0493 (4)
H150.55191.0084−0.26730.059*
C160.4079 (2)1.30676 (10)−0.27722 (16)0.0659 (5)
H16A0.35631.3210−0.34700.099*
H16B0.51691.3352−0.26460.099*
H16C0.32551.3190−0.22100.099*
H30.686 (3)0.9691 (10)−0.1318 (12)0.080*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
O10.0724 (7)0.0306 (5)0.0552 (7)0.0048 (4)−0.0085 (5)−0.0008 (4)
O20.0815 (8)0.0413 (6)0.0468 (7)0.0050 (5)−0.0152 (5)−0.0065 (5)
O30.0876 (8)0.0438 (6)0.0464 (7)0.0091 (5)−0.0182 (6)−0.0042 (5)
O40.0868 (8)0.0393 (6)0.0628 (8)0.0129 (5)−0.0201 (6)−0.0052 (5)
O50.1370 (12)0.0401 (6)0.0630 (9)0.0209 (7)−0.0251 (8)−0.0099 (6)
O60.0919 (9)0.0429 (6)0.0603 (8)0.0125 (6)−0.0219 (6)0.0094 (5)
N10.0588 (8)0.0361 (6)0.0490 (9)0.0068 (5)−0.0062 (6)0.0023 (6)
N20.0485 (7)0.0384 (6)0.0413 (8)0.0007 (5)−0.0027 (5)0.0079 (5)
N30.0558 (7)0.0357 (6)0.0382 (8)0.0026 (5)−0.0060 (6)0.0050 (5)
C10.0416 (7)0.0353 (7)0.0401 (9)−0.0001 (5)−0.0008 (6)0.0039 (6)
C20.0417 (7)0.0320 (7)0.0455 (9)0.0005 (5)0.0009 (6)0.0020 (6)
C30.0455 (8)0.0390 (7)0.0417 (9)−0.0014 (6)−0.0026 (6)−0.0032 (6)
C40.0452 (8)0.0398 (7)0.0419 (9)0.0021 (6)−0.0059 (6)0.0043 (6)
C50.0443 (7)0.0320 (7)0.0453 (9)0.0034 (6)−0.0022 (6)0.0025 (6)
C60.0510 (8)0.0359 (7)0.0397 (9)0.0019 (6)−0.0029 (6)−0.0019 (6)
C70.0994 (14)0.0544 (10)0.0465 (11)0.0060 (9)−0.0192 (9)−0.0069 (8)
C80.0537 (9)0.0385 (7)0.0406 (9)0.0015 (6)−0.0034 (7)0.0017 (6)
C90.0436 (8)0.0359 (7)0.0396 (9)−0.0017 (6)−0.0019 (6)0.0019 (6)
C100.0418 (7)0.0381 (7)0.0381 (9)−0.0014 (6)0.0000 (6)0.0051 (6)
C110.0434 (7)0.0409 (7)0.0454 (9)0.0004 (6)−0.0010 (6)0.0033 (7)
C120.0448 (8)0.0495 (8)0.0514 (10)0.0019 (6)0.0005 (7)0.0149 (7)
C130.0556 (9)0.0691 (11)0.0449 (10)0.0022 (8)−0.0037 (7)0.0193 (8)
C140.0693 (11)0.0656 (11)0.0407 (10)−0.0021 (8)−0.0083 (8)−0.0010 (8)
C150.0588 (9)0.0442 (8)0.0447 (10)0.0004 (7)−0.0039 (7)0.0010 (7)
C160.0663 (11)0.0524 (10)0.0786 (13)0.0071 (8)−0.0083 (9)0.0239 (9)
Geometric parameters (Å, º) top
O1—C21.3399 (16)C5—C61.363 (2)
O1—H10.8200C6—H60.9300
O2—C31.3553 (17)C7—H7A0.9600
O2—C71.423 (2)C7—H7B0.9600
O3—C91.2348 (17)C7—H7C0.9600
O4—C111.3469 (18)C8—H80.9300
O4—H40.8200C9—C101.470 (2)
O5—N11.2165 (16)C10—C151.395 (2)
O6—N11.2195 (16)C10—C111.4040 (19)
N1—C51.4547 (18)C11—C121.399 (2)
N2—C81.2739 (18)C12—C131.372 (2)
N2—N31.3664 (17)C12—C161.507 (2)
N3—C91.3569 (18)C13—C141.383 (2)
N3—H30.903 (9)C13—H130.9300
C1—C61.3958 (18)C14—C151.368 (2)
C1—C21.401 (2)C14—H140.9300
C1—C81.445 (2)C15—H150.9300
C2—C31.409 (2)C16—H16A0.9600
C3—C41.3754 (19)C16—H16B0.9600
C4—C51.391 (2)C16—H16C0.9600
C4—H4A0.9300
C2—O1—H1109.5H7A—C7—H7C109.5
C3—O2—C7117.87 (12)H7B—C7—H7C109.5
C11—O4—H4109.5N2—C8—C1120.36 (14)
O5—N1—O6122.35 (12)N2—C8—H8119.8
O5—N1—C5119.05 (12)C1—C8—H8119.8
O6—N1—C5118.60 (13)O3—C9—N3119.19 (13)
C8—N2—N3118.63 (13)O3—C9—C10122.42 (12)
C9—N3—N2117.60 (12)N3—C9—C10118.38 (13)
C9—N3—H3122.2 (13)C15—C10—C11118.41 (13)
N2—N3—H3120.2 (13)C15—C10—C9123.57 (12)
C6—C1—C2119.23 (13)C11—C10—C9118.02 (13)
C6—C1—C8118.69 (13)O4—C11—C12116.78 (13)
C2—C1—C8122.08 (12)O4—C11—C10121.90 (13)
O1—C2—C1122.93 (13)C12—C11—C10121.31 (14)
O1—C2—C3117.09 (13)C13—C12—C11117.67 (14)
C1—C2—C3119.98 (12)C13—C12—C16122.95 (15)
O2—C3—C4125.10 (14)C11—C12—C16119.39 (15)
O2—C3—C2114.82 (12)C12—C13—C14122.16 (15)
C4—C3—C2120.07 (13)C12—C13—H13118.9
C3—C4—C5118.66 (13)C14—C13—H13118.9
C3—C4—H4A120.7C15—C14—C13119.88 (16)
C5—C4—H4A120.7C15—C14—H14120.1
C6—C5—C4122.69 (12)C13—C14—H14120.1
C6—C5—N1118.46 (13)C14—C15—C10120.55 (14)
C4—C5—N1118.84 (13)C14—C15—H15119.7
C5—C6—C1119.37 (13)C10—C15—H15119.7
C5—C6—H6120.3C12—C16—H16A109.5
C1—C6—H6120.3C12—C16—H16B109.5
O2—C7—H7A109.5H16A—C16—H16B109.5
O2—C7—H7B109.5C12—C16—H16C109.5
H7A—C7—H7B109.5H16A—C16—H16C109.5
O2—C7—H7C109.5H16B—C16—H16C109.5
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N3—H3···O6i0.90 (1)2.22 (1)3.0190 (17)147 (2)
O4—H4···O30.821.792.5192 (15)148
O1—H1···N20.821.902.6166 (17)145
Symmetry code: (i) x−1/2, −y+3/2, z−1/2.

Experimental details

Crystal data
Chemical formulaC16H15N3O6
Mr345.31
Crystal system, space groupMonoclinic, P21/n
Temperature (K)298
a, b, c (Å)7.482 (1), 17.158 (1), 12.250 (1)
β (°) 91.565 (1)
V (Å3)1572.0 (3)
Z4
Radiation typeMo Kα
µ (mm−1)0.11
Crystal size (mm)0.10 × 0.07 × 0.05
Data collection
DiffractometerBruker SMART CCD area-detector
Absorption correctionMulti-scan
(SADABS; Bruker, 2001)
Tmin, Tmax0.989, 0.994
No. of measured, independent and
observed [I > 2σ(I)] reflections		14545, 2612, 2165
Rint0.023
(sin θ/λ)max (Å−1)0.595
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.037, 0.108, 1.07
No. of reflections2612
No. of parameters233
No. of restraints1
H-atom treatmentH atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å−3)0.14, −0.27

Computer programs: SMART (Bruker, 2007), SAINT (Bruker, 2007), SHELXTL (Sheldrick, 2008).

Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N3—H3···O6i0.903 (9)2.219 (13)3.0190 (17)147.3 (17)
O4—H4···O30.821.792.5192 (15)147.7
O1—H1···N20.821.902.6166 (17)145.3
Symmetry code: (i) x−1/2, −y+3/2, z−1/2.
 

Acknowledgements

This work was supported by the Applied Chemistry Key Subject of Anhui Province (grant No. 200802187C).

References

First citationAllen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1–19.  CSD CrossRef Web of Science Google Scholar
 First citationBruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
 First citationBruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
 First citationCukurovali, A., Yilmaz, I., Gur, S. & Kazaz, C. (2006). Eur. J. Med. Chem. 41, 201–207.  Web of Science CrossRef PubMed CAS Google Scholar
 First citationHan, Y.-Y. & Zhao, Q.-R. (2010a). Acta Cryst. E66, o1025.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationHan, Y.-Y. & Zhao, Q.-R. (2010b). Acta Cryst. E66, o1026.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationLi, C.-M. & Ban, H.-Y. (2009). Acta Cryst. E65, o876.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationLin, X.-S. & Sang, Y.-L. (2009). Acta Cryst. E65, o1650.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationLo, K. M. & Ng, S. W. (2009). Acta Cryst. E65, o969.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationMohd Lair, N., Mohd Ali, H. & Ng, S. W. (2009). Acta Cryst. E65, o190.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationNing, J.-H. & Xu, X.-W. (2009). Acta Cryst. E65, o905–o906.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationPatil, S. A., Naik, V. H., Kulkarni, A. D., Kamble, U., Bagihalli, G. B. & Badami, P. S. (2010). J. Coord. Chem. 63, 688–699.  Web of Science CrossRef CAS Google Scholar
 First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
 First citationSuleiman Gwaram, N., Khaledi, H., Mohd Ali, H., Robinson, W. T. & Abdulla, M. A. (2010). Acta Cryst. E66, o721.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationZhu, C.-G., Wei, Y.-J. & Zhu, Q.-Y. (2009). Acta Cryst. E65, o85.  Web of Science CSD CrossRef IUCr Journals Google Scholar

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ISSN: 2056-9890
Volume 66| Part 5| May 2010| Page o1084
https://doi.org/10.1107/S1600536810012912
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