Lanthanum ruthenium indide, La21Ru9+xIn5-x (x = 1.2)

Tursina, A.I.; Cherviakov, S.G.; Noël, H.; Chernyshev, V.V.; Seropegin, Y.D.

doi:10.1107/S1600536810014509

inorganic compounds

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Volume 66| Part 5| May 2010| Page i40

https://doi.org/10.1107/S1600536810014509

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Lanthanum ruthenium indide, La₂₁Ru_9+xIn_5-x (x = 1.2)

Anna I. Tursina,^a Sergei G. Cherviakov,^a Henri Noël,^b Vladimir V. Chernyshev ^a ^* and Yuri D. Seropegin ^a

^aDepartment of Chemistry, Moscow State University, Leninskie Gory 1/3, 119 992 Moscow, Russian Federation, and ^bLaboratoire de Chimie du Solide et Matériaux, UMR6226 CNRS-Université de Rennes 1, Avenue du Général Leclerc, 30542 Rennes, France
^*Correspondence e-mail: vladimir@struct.chem.msu.ru

(Received 26 March 2010; accepted 20 April 2010; online 24 April 2010)

La₂₁Ru_9+xIn_5-x (Pearson symbol tI140) is isotypic to the filled Y₃Rh₂-type structure, from which it can be derived through an ordered substitution at two sites. One of the square-prismatic sites (site symmetry ..m) is occupied by a mixture of Ru and In atoms and one of the square-antiprismatic sites (4/m..) is fully occupied by In atoms.

Related literature

For related structures, see: Zaremba et al. (2007 ); Moreau et al. (1976 ). For standardization of crystal structures, see: Gelato & Parthé (1987 ).

Experimental

Crystal data

La₂₁Ru_10.16In_3.84
M_r = 4384.89
Tetragonal, I 4/m c m
a = 12.1298 (3) Å
c = 25.9820 (7) Å
V = 3822.79 (17) Å³
Z = 4
Mo Kα radiation
μ = 28.98 mm⁻¹
T = 293 K
0.06 × 0.05 × 0.05 mm

Data collection

Nonius KappaCCD diffractometer
Absorption correction: for a sphere (WinGX; Farrugia, 1999 ) T_min = 0.243, T_max = 0.261
22423 measured reflections
1202 independent reflections
927 reflections with I > 2σ(I)
R_int = 0.087

Refinement

R[F² > 2σ(F²)] = 0.036
wR(F²) = 0.062
S = 1.12
1202 reflections
53 parameters
Δρ_max = 2.00 e Å⁻³
Δρ_min = −2.74 e Å⁻³

Data collection: COLLECT (Nonius, 1998 ); cell refinement: DENZO (Otwinowski & Minor, 1997 ); data reduction: DENZO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 1999 ); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks I, global. DOI: https://doi.org/10.1107/S1600536810014509/mg2098sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536810014509/mg2098Isup2.hkl

checkCIF report

Comment top

New rare-earth metal-rich indium compounds RE₃T_2-_xIn_x (RE = Gd, Tb, Dy, Ho, Er, Tm; T = Rh, Pd, Ir) have been recently synthesized (Zaremba et al., 2007). They can be regarded as extensions of the parent binaries RE₃T₂ with either the Y₃Rh₂- (T = Rh, Ir) or U₃Si₂-type (T = Pd) structures into the ternary RE–T–In systems. In contrast, La₂₁Ru₉₊_xIn_5-_x, presented here, is strictly a ternary compound with no corresponding La-Ru binary of the same stoichiometry.

In the Y₃Rh₂–type structure, six crystallographically independent transition metal sites are available with trigonal prismatic, square prismatic, and square antiprismatic coordination environments (Moreau et al., 1976). The structure of La₂₁Ru₉₊_xIn_5-_x is derived through an ordered substitution at two sites, with the square prismatic site (16l) occupied by a mixture of Ru and In atoms and one of the square antiprismatic sites (4c) occupied fully by In atoms (Fig. 1). This suggests the existence of a solid solution, as confirmed by EDX measurements which revealed a homogeneity range of ca. 3 at.% in La₂₁Ru₉₊_xIn_5-_x.

Related literature top

For related structures, see: Zaremba et al. (2007); Moreau et al. (1976). For standardization of crystal structures, see: Gelato & Parthé (1987).

Experimental top

The title compound was prepared by arc-melting of the constituent elements (La, 99.8%; Ru, 99.9%, In, 99.999%) under a high purity argon atmosphere on a water-cooled cooper hearth. The arc-melted button, with nominal composition La_59.26Ru_29.63In_11.11, was turned over and remelted to ensure its homogeneity. The weight loss was less than 1%. The sample was annealed in an evacuated quartz ampoule at 870 K for 600 h and quenched in cold water. The single crystal was selected from the crushed sample.

EDX analysis of the majority phase in a number of samples revealed that the composition of the new compound ranges from La_58.8Ru_26.2In_15.0 to La_61.1Ru_28.3In_10.7 with an uncertainty of about 1 at.% for each element. Thus the homogeneity range of the title compound is approximately 3 at.% at 870 K.

Structure description top

For related structures, see: Zaremba et al. (2007); Moreau et al. (1976). For standardization of crystal structures, see: Gelato & Parthé (1987).

Computing details top

Data collection: COLLECT (Nonius, 1998); cell refinement: DENZO (Otwinowski & Minor, 1997); data reduction: DENZO (Otwinowski & Minor, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 1999); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top

Fig. 1. Structure of the title compound emphasizing the coordination polyhedra, with atom labelling shown and displacement ellipsoids drawn at the 50% probability level.

lanthanum ruthenium indium (21/10.2/3.8) top

Crystal data top

La₂₁Ru_10.16In_3.84	D_x = 7.619 Mg m⁻³
M_r = 4384.89	Mo Kα radiation, λ = 0.71073 Å
Tetragonal, I4/mcm	Cell parameters from 12585 reflections
Hall symbol: -I 4 2c	θ = 2.9–27.5°
a = 12.1298 (3) Å	µ = 28.98 mm⁻¹
c = 25.9820 (7) Å	T = 293 K
V = 3822.79 (17) Å³	Prism, metallic-dark-grey
Z = 4	0.06 × 0.05 × 0.05 mm
F(000) = 7329

Data collection top

Nonius KappaCCD diffractometer	1202 independent reflections
Radiation source: fine-focus sealed tube	927 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.087
φ and ω scans	θ_max = 27.5°, θ_min = 3.7°
Absorption correction: for a sphere (WinGX; Farrugia, 1999)	h = −15→15
T_min = 0.243, T_max = 0.261	k = −15→15
22423 measured reflections	l = −33→32

Refinement top

Refinement on F²	0 restraints
Least-squares matrix: full	Primary atom site location: structure-invariant direct methods
R[F² > 2σ(F²)] = 0.036	Secondary atom site location: difference Fourier map
wR(F²) = 0.062	w = 1/[σ²(F_o²) + (0.0131P)² + 224.3566P] where P = (F_o² + 2F_c²)/3
S = 1.12	(Δ/σ)_max < 0.001
1202 reflections	Δρ_max = 2.00 e Å⁻³
53 parameters	Δρ_min = −2.74 e Å⁻³

Crystal data top

La₂₁Ru_10.16In_3.84	Z = 4
M_r = 4384.89	Mo Kα radiation
Tetragonal, I4/mcm	µ = 28.98 mm⁻¹
a = 12.1298 (3) Å	T = 293 K
c = 25.9820 (7) Å	0.06 × 0.05 × 0.05 mm
V = 3822.79 (17) Å³

Data collection top

Nonius KappaCCD diffractometer	1202 independent reflections
Absorption correction: for a sphere (WinGX; Farrugia, 1999)	927 reflections with I > 2σ(I)
T_min = 0.243, T_max = 0.261	R_int = 0.087
22423 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.036	0 restraints
wR(F²) = 0.062	w = 1/[σ²(F_o²) + (0.0131P)² + 224.3566P] where P = (F_o² + 2F_c²)/3
S = 1.12	Δρ_max = 2.00 e Å⁻³
1202 reflections	Δρ_min = −2.74 e Å⁻³
53 parameters

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
La1	0.07818 (5)	0.20842 (5)	0.07297 (2)	0.01886 (15)
La2	0.20391 (6)	0.07950 (6)	0.19170 (2)	0.02653 (17)
La3	0.85106 (8)	0.35106 (8)	0.0000	0.0208 (3)
La4	0.0000	0.5000	0.10584 (5)	0.0255 (3)
La5	0.0000	0.5000	0.2500	0.0615 (8)
Ru1	0.81308 (11)	0.31308 (11)	0.10986 (6)	0.0429 (4)
Ru2	0.65628 (8)	0.15628 (8)	0.18661 (5)	0.0287 (4)	0.29 (4)
Ru3	0.59671 (12)	0.09671 (12)	0.0000	0.0247 (4)
Ru4	0.0000	0.0000	0.12798 (6)	0.0207 (4)
Ru5	0.0000	0.0000	0.2500	0.0213 (5)
In1	0.65628 (8)	0.15628 (8)	0.18661 (5)	0.0287 (4)	0.71 (4)
In2	0.0000	0.0000	0.0000	0.0200 (5)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
La1	0.0226 (3)	0.0185 (3)	0.0154 (3)	−0.0006 (3)	0.0001 (2)	0.0002 (2)
La2	0.0305 (4)	0.0311 (4)	0.0180 (3)	−0.0036 (3)	0.0003 (3)	−0.0001 (3)
La3	0.0218 (4)	0.0218 (4)	0.0188 (6)	0.0021 (6)	0.000	0.000
La4	0.0260 (4)	0.0260 (4)	0.0247 (7)	0.0035 (6)	0.000	0.000
La5	0.0793 (13)	0.0793 (13)	0.0258 (12)	0.000	0.000	0.000
Ru1	0.0471 (6)	0.0471 (6)	0.0345 (8)	0.0213 (8)	−0.0168 (6)	−0.0168 (6)
Ru2	0.0244 (5)	0.0244 (5)	0.0372 (8)	0.0073 (5)	−0.0070 (4)	−0.0070 (4)
Ru3	0.0270 (6)	0.0270 (6)	0.0202 (9)	0.0055 (8)	0.000	0.000
Ru4	0.0195 (5)	0.0195 (5)	0.0232 (9)	0.000	0.000	0.000
Ru5	0.0199 (8)	0.0199 (8)	0.0241 (12)	0.000	0.000	0.000
In1	0.0244 (5)	0.0244 (5)	0.0372 (8)	0.0073 (5)	−0.0070 (4)	−0.0070 (4)
In2	0.0206 (7)	0.0206 (7)	0.0190 (10)	0.000	0.000	0.000

Geometric parameters (Å, º) top

La1—Ru1ⁱ	3.0174 (15)	La4—La2ⁱ	4.3365 (10)
La1—Ru3ⁱⁱ	3.0385 (12)	La5—In1^xxix	3.1464 (14)
La1—Ru4	3.0550 (10)	La5—Ru2^xxix	3.1464 (14)
La1—In2	3.2992 (6)	La5—In1^xii	3.1464 (14)
La1—In1ⁱ	3.5084 (13)	La5—Ru2^xii	3.1464 (14)
La1—Ru2ⁱ	3.5084 (13)	La5—In1ⁱ	3.1464 (14)
La1—Ru1ⁱⁱⁱ	3.5875 (11)	La5—In1^xxv	3.1464 (14)
La1—La2^iv	3.6299 (9)	La5—Ru2ⁱ	3.1464 (14)
La1—La1^v	3.6607 (13)	La5—Ru2^xxv	3.1464 (14)
La1—La4	3.7600 (7)	La5—La4^xxx	3.7457 (13)
La1—La3ⁱⁱⁱ	3.7653 (7)	La5—La2ⁱ	4.0154 (7)
La1—La2	3.7798 (9)	La5—La2^iv	4.0154 (7)
La1—La1^vi	3.7919 (11)	La5—La2^xxxi	4.0154 (7)
La1—La1^iv	3.8185 (9)	La5—La2^xii	4.0154 (7)
La1—La1^vii	3.8185 (9)	La5—La2^xxviii	4.0154 (7)
La1—La3ⁱⁱ	3.8822 (12)	La5—La2^xxv	4.0154 (7)
La2—Ru1ⁱ	2.8235 (14)	La5—La2^xxix	4.0154 (7)
La2—Ru5	3.0565 (7)	La5—La2^x	4.0154 (7)
La2—Ru4	3.1286 (11)	Ru1—La2^xxiii	2.8235 (14)
La2—In1ⁱ	3.2592 (13)	Ru1—La2^xxii	2.8235 (14)
La2—Ru2ⁱ	3.2592 (13)	Ru1—La1^xxii	3.0174 (15)
La2—In1^viii	3.3276 (8)	Ru1—La1^xxiii	3.0174 (15)
La2—Ru2^viii	3.3276 (8)	Ru1—La4^xvi	3.2082 (19)
La2—La2^ix	3.5915 (13)	Ru1—La1^xvi	3.5875 (11)
La2—La1^vii	3.6299 (9)	Ru1—La1^xx	3.5875 (11)
La2—La2^x	3.7060 (13)	Ru2—La5^xii	3.1464 (14)
La2—In1^xi	3.7068 (12)	Ru2—La2^xxii	3.2592 (13)
La2—Ru2^xi	3.7068 (12)	Ru2—La2^xxiii	3.2592 (13)
La2—La2^v	3.7154 (14)	Ru2—La2^v	3.3276 (8)
La2—La2^vii	3.7544 (10)	Ru2—La2^viii	3.3276 (8)
La2—La2^iv	3.7544 (10)	Ru2—La4^xiii	3.4047 (15)
La2—La5^xii	4.0154 (7)	Ru2—La1^xxii	3.5084 (13)
La2—La4^xiii	4.3365 (10)	Ru2—La1^xxiii	3.5084 (13)
La3—Ru1^vi	2.9278 (17)	Ru2—La2^xxxii	3.7068 (12)
La3—Ru1	2.9278 (17)	Ru2—La2^xi	3.7068 (12)
La3—Ru3^xiv	3.0463 (16)	Ru3—La1^xiv	3.0385 (12)
La3—Ru3^xv	3.0463 (16)	Ru3—La1^xxii	3.0385 (12)
La3—La4^xvi	3.7536 (13)	Ru3—La1^xxiii	3.0385 (12)
La3—La4^xvii	3.7536 (13)	Ru3—La1^xxi	3.0385 (12)
La3—La1^xvi	3.7653 (7)	Ru3—La3ⁱⁱ	3.0463 (16)
La3—La1^xviii	3.7653 (7)	Ru3—La3^xxxiii	3.0463 (16)
La3—La1^xix	3.7653 (7)	Ru3—La4^xiv	3.2115 (15)
La3—La1^xx	3.7653 (7)	Ru3—La4^xiii	3.2115 (15)
La3—La1^xiv	3.8822 (12)	Ru4—La1^xxxiv	3.0550 (10)
La3—La1^xxi	3.8822 (12)	Ru4—La1^iv	3.0550 (10)
La3—La1^xxii	3.8822 (12)	Ru4—La1^vii	3.0550 (10)
La3—La1^xxiii	3.8822 (12)	Ru4—La2^iv	3.1286 (11)
La4—Ru1^xxiv	3.2082 (19)	Ru4—La2^xxxiv	3.1286 (11)
La4—Ru1ⁱⁱⁱ	3.2082 (19)	Ru4—La2^vii	3.1286 (11)
La4—Ru3^xxv	3.2115 (15)	Ru5—La2^x	3.0565 (7)
La4—Ru3ⁱⁱ	3.2115 (15)	Ru5—La2^xxxiv	3.0565 (7)
La4—In1ⁱ	3.4047 (15)	Ru5—La2^vii	3.0565 (7)
La4—In1^xxv	3.4047 (15)	Ru5—La2^ix	3.0565 (7)
La4—Ru2ⁱ	3.4047 (15)	Ru5—La2^xxxv	3.0565 (7)
La4—Ru2^xxv	3.4047 (15)	Ru5—La2^xxxvi	3.0565 (7)
La4—La5	3.7457 (13)	Ru5—La2^iv	3.0565 (7)
La4—La3ⁱⁱⁱ	3.7536 (13)	In2—La1^xxxvii	3.2992 (6)
La4—La3^xvii	3.7536 (13)	In2—La1^iv	3.2992 (6)
La4—La1^v	3.7600 (7)	In2—La1^xxxiv	3.2992 (6)
La4—La1^xxvi	3.7600 (7)	In2—La1^vii	3.2992 (6)
La4—La1^xxvii	3.7600 (7)	In2—La1^xxxviii	3.2992 (6)
La4—La2^xxviii	4.3365 (10)	In2—La1^vi	3.2992 (6)
La4—La2^xxv	4.3365 (10)	In2—La1^xxxix	3.2992 (6)
La4—La2^iv	4.3365 (10)

Ru1ⁱ—La1—Ru3ⁱⁱ	101.28 (4)	Ru2^xxv—La4—La1^v	143.53 (3)
Ru1ⁱ—La1—Ru4	94.19 (3)	La5—La4—La1^v	103.13 (2)
Ru3ⁱⁱ—La1—Ru4	163.46 (3)	La3ⁱⁱⁱ—La4—La1^v	99.50 (3)
Ru1ⁱ—La1—In2	112.81 (4)	La3^xvii—La4—La1^v	60.151 (15)
Ru3ⁱⁱ—La1—In2	104.998 (19)	La1—La4—La1^v	58.26 (2)
Ru4—La1—In2	62.97 (3)	Ru1^xxiv—La4—La1^xxvi	119.600 (14)
Ru1ⁱ—La1—In1ⁱ	61.19 (4)	Ru1ⁱⁱⁱ—La4—La1^xxvi	61.370 (13)
Ru3ⁱⁱ—La1—In1ⁱ	98.12 (2)	Ru3^xxv—La4—La1^xxvi	50.94 (3)
Ru4—La1—In1ⁱ	94.43 (3)	Ru3ⁱⁱ—La4—La1^xxvi	103.96 (4)
In2—La1—In1ⁱ	156.88 (2)	In1ⁱ—La4—La1^xxvi	143.53 (3)
Ru1ⁱ—La1—Ru2ⁱ	61.19 (4)	In1^xxv—La4—La1^xxvi	58.39 (2)
Ru3ⁱⁱ—La1—Ru2ⁱ	98.12 (2)	Ru2ⁱ—La4—La1^xxvi	143.53 (3)
Ru4—La1—Ru2ⁱ	94.43 (3)	Ru2^xxv—La4—La1^xxvi	58.39 (2)
In2—La1—Ru2ⁱ	156.88 (2)	La5—La4—La1^xxvi	103.13 (2)
In1ⁱ—La1—Ru2ⁱ	0.00 (2)	La3ⁱⁱⁱ—La4—La1^xxvi	60.151 (15)
Ru1ⁱ—La1—Ru1ⁱⁱⁱ	142.38 (5)	La3^xvii—La4—La1^xxvi	99.50 (3)
Ru3ⁱⁱ—La1—Ru1ⁱⁱⁱ	87.58 (5)	La1—La4—La1^xxvi	115.02 (2)
Ru4—La1—Ru1ⁱⁱⁱ	83.66 (3)	La1^v—La4—La1^xxvi	153.75 (4)
In2—La1—Ru1ⁱⁱⁱ	99.62 (3)	Ru1^xxiv—La4—La1^xxvii	61.370 (13)
In1ⁱ—La1—Ru1ⁱⁱⁱ	81.47 (3)	Ru1ⁱⁱⁱ—La4—La1^xxvii	119.600 (14)
Ru2ⁱ—La1—Ru1ⁱⁱⁱ	81.47 (3)	Ru3^xxv—La4—La1^xxvii	50.94 (3)
Ru1ⁱ—La1—La2^iv	103.08 (4)	Ru3ⁱⁱ—La4—La1^xxvii	103.96 (4)
Ru3ⁱⁱ—La1—La2^iv	125.52 (4)	In1ⁱ—La4—La1^xxvii	143.53 (3)
Ru4—La1—La2^iv	55.00 (3)	In1^xxv—La4—La1^xxvii	58.39 (2)
In2—La1—La2^iv	108.99 (2)	Ru2ⁱ—La4—La1^xxvii	143.53 (3)
In1ⁱ—La1—La2^iv	55.539 (19)	Ru2^xxv—La4—La1^xxvii	58.39 (2)
Ru2ⁱ—La1—La2^iv	55.539 (19)	La5—La4—La1^xxvii	103.13 (2)
Ru1ⁱⁱⁱ—La1—La2^iv	46.06 (3)	La3ⁱⁱⁱ—La4—La1^xxvii	99.50 (3)
Ru1ⁱ—La1—La1^v	52.66 (2)	La3^xvii—La4—La1^xxvii	60.151 (15)
Ru3ⁱⁱ—La1—La1^v	52.959 (19)	La1—La4—La1^xxvii	153.75 (4)
Ru4—La1—La1^v	143.57 (2)	La1^v—La4—La1^xxvii	115.02 (2)
In2—La1—La1^v	138.165 (11)	La1^xxvi—La4—La1^xxvii	58.26 (2)
In1ⁱ—La1—La1^v	58.553 (15)	Ru1^xxiv—La4—La2^xxviii	40.60 (3)
Ru2ⁱ—La1—La1^v	58.553 (15)	Ru1ⁱⁱⁱ—La4—La2^xxviii	136.53 (4)
Ru1ⁱⁱⁱ—La1—La1^v	112.56 (3)	Ru3^xxv—La4—La2^xxviii	102.66 (2)
La2^iv—La1—La1^v	112.533 (15)	Ru3ⁱⁱ—La4—La2^xxviii	131.435 (17)
Ru1ⁱ—La1—La4	104.32 (3)	In1ⁱ—La4—La2^xxviii	91.16 (3)
Ru3ⁱⁱ—La1—La4	55.15 (3)	In1^xxv—La4—La2^xxviii	49.124 (14)
Ru4—La1—La4	126.43 (3)	Ru2ⁱ—La4—La2^xxviii	91.16 (3)
In2—La1—La4	141.15 (2)	Ru2^xxv—La4—La2^xxviii	49.124 (14)
In1ⁱ—La1—La4	55.73 (3)	La5—La4—La2^xxviii	59.041 (17)
Ru2ⁱ—La1—La4	55.73 (3)	La3ⁱⁱⁱ—La4—La2^xxviii	151.947 (19)
Ru1ⁱⁱⁱ—La1—La4	51.71 (3)	La3^xvii—La4—La2^xxviii	82.601 (16)
La2^iv—La1—La4	71.84 (2)	La1—La4—La2^xxviii	147.12 (2)
La1^v—La1—La4	60.869 (10)	La1^v—La4—La2^xxviii	96.692 (16)
Ru1ⁱ—La1—La3ⁱⁱⁱ	152.94 (3)	La1^xxvi—La4—La2^xxviii	96.726 (16)
Ru3ⁱⁱ—La1—La3ⁱⁱⁱ	51.86 (3)	La1^xxvii—La4—La2^xxviii	52.689 (13)
Ru4—La1—La3ⁱⁱⁱ	112.87 (3)	Ru1^xxiv—La4—La2^xxv	40.60 (3)
In2—La1—La3ⁱⁱⁱ	81.52 (2)	Ru1ⁱⁱⁱ—La4—La2^xxv	136.53 (4)
In1ⁱ—La1—La3ⁱⁱⁱ	113.98 (3)	Ru3^xxv—La4—La2^xxv	131.435 (17)
Ru2ⁱ—La1—La3ⁱⁱⁱ	113.98 (3)	Ru3ⁱⁱ—La4—La2^xxv	102.66 (2)
Ru1ⁱⁱⁱ—La1—La3ⁱⁱⁱ	46.85 (3)	In1ⁱ—La4—La2^xxv	49.124 (14)
La2^iv—La1—La3ⁱⁱⁱ	92.826 (19)	In1^xxv—La4—La2^xxv	91.16 (3)
La1^v—La1—La3ⁱⁱⁱ	101.09 (2)	Ru2ⁱ—La4—La2^xxv	49.124 (14)
La4—La1—La3ⁱⁱⁱ	59.84 (2)	Ru2^xxv—La4—La2^xxv	91.16 (3)
Ru1ⁱ—La1—La2	47.47 (3)	La5—La4—La2^xxv	59.041 (17)
Ru3ⁱⁱ—La1—La2	143.25 (3)	La3ⁱⁱⁱ—La4—La2^xxv	151.947 (19)
Ru4—La1—La2	53.21 (3)	La3^xvii—La4—La2^xxv	82.601 (16)
In2—La1—La2	105.542 (19)	La1—La4—La2^xxv	96.726 (16)
In1ⁱ—La1—La2	52.97 (2)	La1^v—La4—La2^xxv	52.689 (13)
Ru2ⁱ—La1—La2	52.97 (2)	La1^xxvi—La4—La2^xxv	147.12 (2)
Ru1ⁱⁱⁱ—La1—La2	106.86 (3)	La1^xxvii—La4—La2^xxv	96.692 (16)
La2^iv—La1—La2	60.85 (2)	La2^xxviii—La4—La2^xxv	50.73 (2)
La1^v—La1—La2	90.414 (15)	Ru1^xxiv—La4—La2^iv	136.53 (4)
La4—La1—La2	107.79 (3)	Ru1ⁱⁱⁱ—La4—La2^iv	40.60 (3)
La3ⁱⁱⁱ—La1—La2	153.67 (2)	Ru3^xxv—La4—La2^iv	131.435 (17)
Ru1ⁱ—La1—La1^vi	108.52 (3)	Ru3ⁱⁱ—La4—La2^iv	102.66 (2)
Ru3ⁱⁱ—La1—La1^vi	51.393 (19)	In1ⁱ—La4—La2^iv	49.124 (14)
Ru4—La1—La1^vi	117.89 (3)	In1^xxv—La4—La2^iv	91.16 (3)
In2—La1—La1^vi	54.924 (10)	Ru2ⁱ—La4—La2^iv	49.124 (14)
In1ⁱ—La1—La1^vi	147.308 (15)	Ru2^xxv—La4—La2^iv	91.16 (3)
Ru2ⁱ—La1—La1^vi	147.308 (15)	La5—La4—La2^iv	59.041 (17)
Ru1ⁱⁱⁱ—La1—La1^vi	105.49 (3)	La3ⁱⁱⁱ—La4—La2^iv	82.601 (16)
La2^iv—La1—La1^vi	148.189 (14)	La3^xvii—La4—La2^iv	151.947 (19)
La1^v—La1—La1^vi	90.0	La1—La4—La2^iv	52.689 (13)
La4—La1—La1^vi	103.13 (2)	La1^v—La4—La2^iv	96.726 (16)
La3ⁱⁱⁱ—La1—La1^vi	59.766 (9)	La1^xxvi—La4—La2^iv	96.692 (16)
La2—La1—La1^vi	144.697 (13)	La1^xxvii—La4—La2^iv	147.12 (2)
Ru1ⁱ—La1—La1^iv	145.48 (3)	La2^xxviii—La4—La2^iv	118.08 (3)
Ru3ⁱⁱ—La1—La1^iv	112.90 (3)	La2^xxv—La4—La2^iv	95.95 (3)
Ru4—La1—La1^iv	51.321 (13)	Ru1^xxiv—La4—La2ⁱ	136.53 (4)
In2—La1—La1^iv	54.641 (5)	Ru1ⁱⁱⁱ—La4—La2ⁱ	40.60 (3)
In1ⁱ—La1—La1^iv	116.06 (2)	Ru3^xxv—La4—La2ⁱ	102.66 (2)
Ru2ⁱ—La1—La1^iv	116.06 (2)	Ru3ⁱⁱ—La4—La2ⁱ	131.435 (17)
Ru1ⁱⁱⁱ—La1—La1^iv	47.96 (3)	In1ⁱ—La4—La2ⁱ	91.16 (3)
La2^iv—La1—La1^iv	60.927 (16)	In1^xxv—La4—La2ⁱ	49.124 (14)
La1^v—La1—La1^iv	159.439 (14)	Ru2ⁱ—La4—La2ⁱ	91.16 (3)
La4—La1—La1^iv	99.18 (2)	Ru2^xxv—La4—La2ⁱ	49.124 (14)
La3ⁱⁱⁱ—La1—La1^iv	61.58 (3)	La5—La4—La2ⁱ	59.041 (17)
La2—La1—La1^iv	101.314 (14)	La3ⁱⁱⁱ—La4—La2ⁱ	82.601 (16)
La1^vi—La1—La1^iv	90.0	La3^xvii—La4—La2ⁱ	151.947 (19)
Ru1ⁱ—La1—La1^vii	62.01 (3)	La1—La4—La2ⁱ	96.692 (16)
Ru3ⁱⁱ—La1—La1^vii	132.66 (4)	La1^v—La4—La2ⁱ	147.12 (2)
Ru4—La1—La1^vii	51.321 (13)	La1^xxvi—La4—La2ⁱ	52.689 (13)
In2—La1—La1^vii	54.641 (5)	La1^xxvii—La4—La2ⁱ	96.726 (16)
In1ⁱ—La1—La1^vii	108.31 (3)	La2^xxviii—La4—La2ⁱ	95.95 (3)
Ru2ⁱ—La1—La1^vii	108.31 (3)	La2^xxv—La4—La2ⁱ	118.08 (3)
Ru1ⁱⁱⁱ—La1—La1^vii	133.87 (3)	La2^iv—La4—La2ⁱ	50.73 (2)
La2^iv—La1—La1^vii	101.787 (14)	In1^xxix—La5—Ru2^xxix	0.00 (5)
La1^v—La1—La1^vii	110.561 (14)	In1^xxix—La5—In1^xii	116.87 (4)
La4—La1—La1^vii	163.89 (2)	Ru2^xxix—La5—In1^xii	116.87 (4)
La3ⁱⁱⁱ—La1—La1^vii	136.140 (19)	In1^xxix—La5—Ru2^xii	116.87 (4)
La2—La1—La1^vii	57.072 (15)	Ru2^xxix—La5—Ru2^xii	116.87 (4)
La1^vi—La1—La1^vii	90.0	In1^xii—La5—Ru2^xii	0.00 (5)
La1^iv—La1—La1^vii	90.0	In1^xxix—La5—In1ⁱ	105.90 (2)
Ru1ⁱ—La1—La3ⁱⁱ	48.24 (4)	Ru2^xxix—La5—In1ⁱ	105.90 (2)
Ru3ⁱⁱ—La1—La3ⁱⁱ	77.10 (4)	In1^xii—La5—In1ⁱ	105.90 (2)
Ru4—La1—La3ⁱⁱ	109.84 (2)	Ru2^xii—La5—In1ⁱ	105.90 (2)
In2—La1—La3ⁱⁱ	79.748 (13)	In1^xxix—La5—In1^xxv	105.90 (2)
In1ⁱ—La1—La3ⁱⁱ	105.53 (2)	Ru2^xxix—La5—In1^xxv	105.90 (2)
Ru2ⁱ—La1—La3ⁱⁱ	105.53 (2)	In1^xii—La5—In1^xxv	105.90 (2)
Ru1ⁱⁱⁱ—La1—La3ⁱⁱ	163.83 (3)	Ru2^xii—La5—In1^xxv	105.90 (2)
La2^iv—La1—La3ⁱⁱ	149.48 (2)	In1ⁱ—La5—In1^xxv	116.87 (4)
La1^v—La1—La3ⁱⁱ	61.869 (12)	In1^xxix—La5—Ru2ⁱ	105.90 (2)
La4—La1—La3ⁱⁱ	120.05 (2)	Ru2^xxix—La5—Ru2ⁱ	105.90 (2)
La3ⁱⁱⁱ—La1—La3ⁱⁱ	117.600 (15)	In1^xii—La5—Ru2ⁱ	105.90 (2)
La2—La1—La3ⁱⁱ	88.72 (2)	Ru2^xii—La5—Ru2ⁱ	105.90 (2)
La1^vi—La1—La3ⁱⁱ	60.766 (12)	In1ⁱ—La5—Ru2ⁱ	0.00 (5)
La1^iv—La1—La3ⁱⁱ	134.374 (13)	In1^xxv—La5—Ru2ⁱ	116.87 (4)
La1^vii—La1—La3ⁱⁱ	58.54 (2)	In1^xxix—La5—Ru2^xxv	105.90 (2)
Ru1ⁱ—La2—Ru5	153.94 (4)	Ru2^xxix—La5—Ru2^xxv	105.90 (2)
Ru1ⁱ—La2—Ru4	96.58 (4)	In1^xii—La5—Ru2^xxv	105.90 (2)
Ru5—La2—Ru4	61.66 (3)	Ru2^xii—La5—Ru2^xxv	105.90 (2)
Ru1ⁱ—La2—In1ⁱ	66.35 (5)	In1ⁱ—La5—Ru2^xxv	116.87 (4)
Ru5—La2—In1ⁱ	100.77 (3)	In1^xxv—La5—Ru2^xxv	0.00 (5)
Ru4—La2—In1ⁱ	98.14 (2)	Ru2ⁱ—La5—Ru2^xxv	116.87 (4)
Ru1ⁱ—La2—Ru2ⁱ	66.35 (5)	In1^xxix—La5—La4^xxx	58.44 (2)
Ru5—La2—Ru2ⁱ	100.77 (3)	Ru2^xxix—La5—La4^xxx	58.44 (2)
Ru4—La2—Ru2ⁱ	98.14 (2)	In1^xii—La5—La4^xxx	58.44 (2)
In1ⁱ—La2—Ru2ⁱ	0.00 (5)	Ru2^xii—La5—La4^xxx	58.44 (2)
Ru1ⁱ—La2—In1^viii	97.34 (5)	In1ⁱ—La5—La4^xxx	121.56 (2)
Ru5—La2—In1^viii	99.26 (3)	In1^xxv—La5—La4^xxx	121.56 (2)
Ru4—La2—In1^viii	96.72 (3)	Ru2ⁱ—La5—La4^xxx	121.56 (2)
In1ⁱ—La2—In1^viii	159.05 (3)	Ru2^xxv—La5—La4^xxx	121.56 (2)
Ru2ⁱ—La2—In1^viii	159.05 (3)	In1^xxix—La5—La4	121.56 (2)
Ru1ⁱ—La2—Ru2^viii	97.34 (5)	Ru2^xxix—La5—La4	121.56 (2)
Ru5—La2—Ru2^viii	99.26 (3)	In1^xii—La5—La4	121.56 (2)
Ru4—La2—Ru2^viii	96.72 (3)	Ru2^xii—La5—La4	121.56 (2)
In1ⁱ—La2—Ru2^viii	159.05 (3)	In1ⁱ—La5—La4	58.44 (2)
Ru2ⁱ—La2—Ru2^viii	159.05 (3)	In1^xxv—La5—La4	58.44 (2)
In1^viii—La2—Ru2^viii	0.00 (5)	Ru2ⁱ—La5—La4	58.44 (2)
Ru1ⁱ—La2—La2^ix	152.02 (3)	Ru2^xxv—La5—La4	58.44 (2)
Ru5—La2—La2^ix	54.020 (13)	La4^xxx—La5—La4	180.0
Ru4—La2—La2^ix	106.31 (3)	In1^xxix—La5—La2ⁱ	151.770 (11)
In1ⁱ—La2—La2^ix	124.21 (4)	Ru2^xxix—La5—La2ⁱ	151.770 (11)
Ru2ⁱ—La2—La2^ix	124.21 (4)	In1^xii—La5—La2ⁱ	60.91 (2)
In1^viii—La2—La2^ix	64.66 (3)	Ru2^xii—La5—La2ⁱ	60.91 (2)
Ru2^viii—La2—La2^ix	64.66 (3)	In1ⁱ—La5—La2ⁱ	101.346 (16)
Ru1ⁱ—La2—La1^vii	66.18 (3)	In1^xxv—La5—La2ⁱ	53.724 (10)
Ru5—La2—La1^vii	105.49 (2)	Ru2ⁱ—La5—La2ⁱ	101.346 (16)
Ru4—La2—La1^vii	53.12 (3)	Ru2^xxv—La5—La2ⁱ	53.724 (10)
In1ⁱ—La2—La1^vii	119.10 (3)	La4^xxx—La5—La2ⁱ	112.164 (9)
Ru2ⁱ—La2—La1^vii	119.10 (3)	La4—La5—La2ⁱ	67.836 (9)
In1^viii—La2—La1^vii	60.38 (3)	In1^xxix—La5—La2^iv	151.770 (11)
Ru2^viii—La2—La1^vii	60.38 (3)	Ru2^xxix—La5—La2^iv	151.770 (11)
La2^ix—La2—La1^vii	115.72 (3)	In1^xii—La5—La2^iv	60.91 (2)
Ru1ⁱ—La2—La2^x	128.22 (4)	Ru2^xii—La5—La2^iv	60.91 (2)
Ru5—La2—La2^x	52.682 (13)	In1ⁱ—La5—La2^iv	53.724 (10)
Ru4—La2—La2^x	103.66 (3)	In1^xxv—La5—La2^iv	101.346 (16)
In1ⁱ—La2—La2^x	63.93 (3)	Ru2ⁱ—La5—La2^iv	53.724 (10)
Ru2ⁱ—La2—La2^x	63.93 (3)	Ru2^xxv—La5—La2^iv	101.346 (16)
In1^viii—La2—La2^x	126.15 (4)	La4^xxx—La5—La2^iv	112.164 (9)
Ru2^viii—La2—La2^x	126.15 (4)	La4—La5—La2^iv	67.836 (9)
La2^ix—La2—La2^x	61.90 (2)	La2ⁱ—La5—La2^iv	55.12 (2)
La1^vii—La2—La2^x	156.27 (2)	In1^xxix—La5—La2^xxxi	53.724 (10)
Ru1ⁱ—La2—In1^xi	108.17 (3)	Ru2^xxix—La5—La2^xxxi	53.724 (10)
Ru5—La2—In1^xi	91.53 (2)	In1^xii—La5—La2^xxxi	101.346 (16)
Ru4—La2—In1^xi	152.93 (4)	Ru2^xii—La5—La2^xxxi	101.346 (16)
In1ⁱ—La2—In1^xi	82.45 (3)	In1ⁱ—La5—La2^xxxi	151.770 (11)
Ru2ⁱ—La2—In1^xi	82.45 (3)	In1^xxv—La5—La2^xxxi	60.91 (2)
In1^viii—La2—In1^xi	90.96 (4)	Ru2ⁱ—La5—La2^xxxi	151.770 (11)
Ru2^viii—La2—In1^xi	90.96 (4)	Ru2^xxv—La5—La2^xxxi	60.91 (2)
La2^ix—La2—In1^xi	54.223 (18)	La4^xxx—La5—La2^xxxi	67.836 (9)
La1^vii—La2—In1^xi	148.25 (3)	La4—La5—La2^xxxi	112.164 (9)
La2^x—La2—In1^xi	52.17 (2)	La2ⁱ—La5—La2^xxxi	98.183 (7)
Ru1ⁱ—La2—Ru2^xi	108.17 (3)	La2^iv—La5—La2^xxxi	152.21 (2)
Ru5—La2—Ru2^xi	91.53 (2)	In1^xxix—La5—La2^xii	53.724 (10)
Ru4—La2—Ru2^xi	152.93 (4)	Ru2^xxix—La5—La2^xii	53.724 (10)
In1ⁱ—La2—Ru2^xi	82.45 (3)	In1^xii—La5—La2^xii	101.346 (16)
Ru2ⁱ—La2—Ru2^xi	82.45 (3)	Ru2^xii—La5—La2^xii	101.346 (16)
In1^viii—La2—Ru2^xi	90.96 (4)	In1ⁱ—La5—La2^xii	60.91 (2)
Ru2^viii—La2—Ru2^xi	90.96 (4)	In1^xxv—La5—La2^xii	151.770 (11)
La2^ix—La2—Ru2^xi	54.223 (18)	Ru2ⁱ—La5—La2^xii	60.91 (2)
La1^vii—La2—Ru2^xi	148.25 (3)	Ru2^xxv—La5—La2^xii	151.770 (11)
La2^x—La2—Ru2^xi	52.17 (2)	La4^xxx—La5—La2^xii	67.836 (9)
In1^xi—La2—Ru2^xi	0.00 (2)	La4—La5—La2^xii	112.164 (9)
Ru1ⁱ—La2—La2^v	48.86 (3)	La2ⁱ—La5—La2^xii	152.21 (2)
Ru5—La2—La2^v	142.682 (13)	La2^iv—La5—La2^xii	98.183 (7)
Ru4—La2—La2^v	140.98 (2)	La2^xxxi—La5—La2^xii	106.69 (2)
In1ⁱ—La2—La2^v	55.251 (18)	In1^xxix—La5—La2^xxviii	60.91 (2)
Ru2ⁱ—La2—La2^v	55.251 (18)	Ru2^xxix—La5—La2^xxviii	60.91 (2)
In1^viii—La2—La2^v	104.32 (2)	In1^xii—La5—La2^xxviii	151.770 (11)
Ru2^viii—La2—La2^v	104.32 (2)	Ru2^xii—La5—La2^xxviii	151.770 (11)
La2^ix—La2—La2^v	112.316 (14)	In1ⁱ—La5—La2^xxviii	101.346 (16)
La1^vii—La2—La2^v	111.218 (15)	In1^xxv—La5—La2^xxviii	53.724 (10)
La2^x—La2—La2^v	90.0	Ru2ⁱ—La5—La2^xxviii	101.346 (16)
In1^xi—La2—La2^v	59.923 (14)	Ru2^xxv—La5—La2^xxviii	53.724 (10)
Ru2^xi—La2—La2^v	59.923 (14)	La4^xxx—La5—La2^xxviii	112.164 (9)
Ru1ⁱ—La2—La2^vii	127.67 (3)	La4—La5—La2^xxviii	67.836 (9)
Ru5—La2—La2^vii	52.110 (5)	La2ⁱ—La5—La2^xxviii	106.69 (2)
Ru4—La2—La2^vii	53.130 (14)	La2^iv—La5—La2^xxviii	135.671 (18)
In1ⁱ—La2—La2^vii	146.01 (3)	La2^xxxi—La5—La2^xxviii	53.130 (19)
Ru2ⁱ—La2—La2^vii	146.01 (3)	La2^xii—La5—La2^xxviii	98.183 (7)
In1^viii—La2—La2^vii	54.40 (3)	In1^xxix—La5—La2^xxv	60.91 (2)
Ru2^viii—La2—La2^vii	54.40 (3)	Ru2^xxix—La5—La2^xxv	60.91 (2)
La2^ix—La2—La2^vii	60.55 (2)	In1^xii—La5—La2^xxv	151.770 (11)
La1^vii—La2—La2^vii	61.549 (16)	Ru2^xii—La5—La2^xxv	151.770 (11)
La2^x—La2—La2^vii	102.075 (5)	In1ⁱ—La5—La2^xxv	53.724 (10)
In1^xi—La2—La2^vii	114.454 (19)	In1^xxv—La5—La2^xxv	101.346 (16)
Ru2^xi—La2—La2^vii	114.454 (19)	Ru2ⁱ—La5—La2^xxv	53.724 (10)
La2^v—La2—La2^vii	158.701 (16)	Ru2^xxv—La5—La2^xxv	101.346 (16)
Ru1ⁱ—La2—La2^iv	104.12 (4)	La4^xxx—La5—La2^xxv	112.164 (9)
Ru5—La2—La2^iv	52.110 (5)	La4—La5—La2^xxv	67.836 (9)
Ru4—La2—La2^iv	53.130 (14)	La2ⁱ—La5—La2^xxv	135.671 (18)
In1ⁱ—La2—La2^iv	56.11 (3)	La2^iv—La5—La2^xxv	106.69 (2)
Ru2ⁱ—La2—La2^iv	56.11 (3)	La2^xxxi—La5—La2^xxv	98.183 (7)
In1^viii—La2—La2^iv	144.30 (3)	La2^xii—La5—La2^xxv	53.130 (19)
Ru2^viii—La2—La2^iv	144.30 (3)	La2^xxviii—La5—La2^xxv	55.12 (2)
La2^ix—La2—La2^iv	102.465 (5)	In1^xxix—La5—La2^xxix	101.346 (16)
La1^vii—La2—La2^iv	103.037 (14)	Ru2^xxix—La5—La2^xxix	101.346 (16)
La2^x—La2—La2^iv	57.55 (2)	In1^xii—La5—La2^xxix	53.724 (10)
In1^xi—La2—La2^iv	108.54 (3)	Ru2^xii—La5—La2^xxix	53.724 (10)
Ru2^xi—La2—La2^iv	108.54 (3)	In1ⁱ—La5—La2^xxix	151.770 (11)
La2^v—La2—La2^iv	111.299 (16)	In1^xxv—La5—La2^xxix	60.91 (2)
La2^vii—La2—La2^iv	90.0	Ru2ⁱ—La5—La2^xxix	151.770 (11)
Ru1ⁱ—La2—La1	51.96 (3)	Ru2^xxv—La5—La2^xxix	60.91 (2)
Ru5—La2—La1	102.03 (2)	La4^xxx—La5—La2^xxix	67.836 (9)
Ru4—La2—La1	51.44 (2)	La4—La5—La2^xxix	112.164 (9)
In1ⁱ—La2—La1	59.24 (3)	La2ⁱ—La5—La2^xxix	53.130 (19)
Ru2ⁱ—La2—La1	59.24 (3)	La2^iv—La5—La2^xxix	98.183 (7)
In1^viii—La2—La1	121.93 (3)	La2^xxxi—La5—La2^xxix	55.12 (2)
Ru2^viii—La2—La1	121.93 (3)	La2^xii—La5—La2^xxix	135.671 (18)
La2^ix—La2—La1	155.591 (17)	La2^xxviii—La5—La2^xxix	98.183 (7)
La1^vii—La2—La1	62.001 (19)	La2^xxv—La5—La2^xxix	152.21 (2)
La2^x—La2—La1	109.54 (3)	In1^xxix—La5—La2^x	101.346 (16)
In1^xi—La2—La1	140.96 (3)	Ru2^xxix—La5—La2^x	101.346 (16)
Ru2^xi—La2—La1	140.96 (3)	In1^xii—La5—La2^x	53.724 (10)
La2^v—La2—La1	89.586 (15)	Ru2^xii—La5—La2^x	53.724 (10)
La2^vii—La2—La1	102.512 (13)	In1ⁱ—La5—La2^x	60.91 (2)
La2^iv—La2—La1	57.604 (16)	In1^xxv—La5—La2^x	151.770 (11)
Ru1ⁱ—La2—La5^xii	88.59 (4)	Ru2ⁱ—La5—La2^x	60.91 (2)
Ru5—La2—La5^xii	117.455 (19)	Ru2^xxv—La5—La2^x	151.770 (11)
Ru4—La2—La5^xii	146.38 (2)	La4^xxx—La5—La2^x	67.836 (9)
In1ⁱ—La2—La5^xii	114.20 (2)	La4—La5—La2^x	112.164 (9)
Ru2ⁱ—La2—La5^xii	114.20 (2)	La2ⁱ—La5—La2^x	98.183 (7)
In1^viii—La2—La5^xii	49.67 (2)	La2^iv—La5—La2^x	53.130 (19)
Ru2^viii—La2—La5^xii	49.67 (2)	La2^xxxi—La5—La2^x	135.671 (18)
La2^ix—La2—La5^xii	63.435 (9)	La2^xii—La5—La2^x	55.12 (2)
La1^vii—La2—La5^xii	100.404 (19)	La2^xxviii—La5—La2^x	152.21 (2)
La2^x—La2—La5^xii	98.84 (2)	La2^xxv—La5—La2^x	98.183 (7)
In1^xi—La2—La5^xii	47.88 (2)	La2^xxix—La5—La2^x	106.69 (2)
Ru2^xi—La2—La5^xii	47.88 (2)	La2^xxiii—Ru1—La2^xxii	82.28 (5)
La2^v—La2—La5^xii	62.442 (10)	La2^xxiii—Ru1—La3	137.34 (3)
La2^vii—La2—La5^xii	98.03 (2)	La2^xxii—Ru1—La3	137.34 (3)
La2^iv—La2—La5^xii	156.280 (13)	La2^xxiii—Ru1—La1^xxii	129.38 (7)
La1—La2—La5^xii	140.19 (2)	La2^xxii—Ru1—La1^xxii	80.57 (3)
Ru1ⁱ—La2—La4^xiii	47.69 (4)	La3—Ru1—La1^xxii	81.52 (4)
Ru5—La2—La4^xiii	148.76 (2)	La2^xxiii—Ru1—La1^xxiii	80.57 (3)
Ru4—La2—La4^xiii	108.30 (3)	La2^xxii—Ru1—La1^xxiii	129.38 (7)
In1ⁱ—La2—La4^xiii	110.16 (3)	La3—Ru1—La1^xxiii	81.52 (4)
Ru2ⁱ—La2—La4^xiii	110.16 (3)	La1^xxii—Ru1—La1^xxiii	74.69 (5)
In1^viii—La2—La4^xiii	50.68 (2)	La2^xxiii—Ru1—La4^xvi	91.71 (5)
Ru2^viii—La2—La4^xiii	50.68 (2)	La2^xxii—Ru1—La4^xvi	91.71 (5)
La2^ix—La2—La4^xiii	108.33 (2)	La3—Ru1—La4^xvi	75.27 (6)
La1^vii—La2—La4^xiii	55.473 (19)	La1^xxii—Ru1—La4^xvi	135.90 (4)
La2^x—La2—La4^xiii	148.03 (2)	La1^xxiii—Ru1—La4^xvi	135.90 (4)
In1^xi—La2—La4^xiii	96.65 (3)	La2^xxiii—Ru1—La1^xvi	67.76 (2)
Ru2^xi—La2—La4^xiii	96.65 (3)	La2^xxii—Ru1—La1^xvi	141.71 (5)
La2^v—La2—La4^xiii	64.635 (10)	La3—Ru1—La1^xvi	69.77 (3)
La2^vii—La2—La4^xiii	97.43 (2)	La1^xxii—Ru1—La1^xvi	136.97 (5)
La2^iv—La2—La4^xiii	147.966 (18)	La1^xxiii—Ru1—La1^xvi	70.03 (2)
La1—La2—La4^xiii	90.36 (2)	La4^xvi—Ru1—La1^xvi	66.92 (3)
La5^xii—La2—La4^xiii	53.123 (17)	La2^xxiii—Ru1—La1^xx	141.71 (5)
Ru1^vi—La3—Ru1	154.28 (9)	La2^xxii—Ru1—La1^xx	67.76 (2)
Ru1^vi—La3—Ru3^xiv	100.76 (4)	La3—Ru1—La1^xx	69.77 (3)
Ru1—La3—Ru3^xiv	100.76 (4)	La1^xxii—Ru1—La1^xx	70.03 (2)
Ru1^vi—La3—Ru3^xv	100.76 (4)	La1^xxiii—Ru1—La1^xx	136.97 (5)
Ru1—La3—Ru3^xv	100.76 (4)	La4^xvi—Ru1—La1^xx	66.92 (3)
Ru3^xiv—La3—Ru3^xv	65.99 (7)	La1^xvi—Ru1—La1^xx	124.26 (6)
Ru1^vi—La3—La4^xvi	149.96 (5)	La5^xii—Ru2—La2^xxii	132.69 (3)
Ru1—La3—La4^xvi	55.75 (4)	La5^xii—Ru2—La2^xxiii	132.69 (3)
Ru3^xiv—La3—La4^xvi	55.19 (2)	La2^xxii—Ru2—La2^xxiii	69.50 (4)
Ru3^xv—La3—La4^xvi	55.19 (2)	La5^xii—Ru2—La2^v	76.61 (3)
Ru1^vi—La3—La4^xvii	55.75 (4)	La2^xxii—Ru2—La2^v	69.49 (3)
Ru1—La3—La4^xvii	149.96 (5)	La2^xxiii—Ru2—La2^v	138.87 (3)
Ru3^xiv—La3—La4^xvii	55.19 (2)	La5^xii—Ru2—La2^viii	76.61 (3)
Ru3^xv—La3—La4^xvii	55.19 (2)	La2^xxii—Ru2—La2^viii	138.87 (3)
La4^xvi—La3—La4^xvii	94.21 (4)	La2^xxiii—Ru2—La2^viii	69.49 (3)
Ru1^vi—La3—La1^xvi	122.257 (9)	La2^v—Ru2—La2^viii	150.98 (5)
Ru1—La3—La1^xvi	63.380 (15)	La5^xii—Ru2—La4^xiii	69.62 (3)
Ru3^xiv—La3—La1^xvi	51.68 (3)	La2^xxii—Ru2—La4^xiii	132.16 (3)
Ru3^xv—La3—La1^xvi	107.30 (4)	La2^xxiii—Ru2—La4^xiii	132.16 (3)
La4^xvi—La3—La1^xvi	60.009 (14)	La2^v—Ru2—La4^xiii	80.19 (2)
La4^xvii—La3—La1^xvi	103.76 (3)	La2^viii—Ru2—La4^xiii	80.19 (2)
Ru1^vi—La3—La1^xviii	63.380 (15)	La5^xii—Ru2—La1^xxii	124.03 (3)
Ru1—La3—La1^xviii	122.257 (9)	La2^xxii—Ru2—La1^xxii	67.79 (3)
Ru3^xiv—La3—La1^xviii	107.30 (4)	La2^xxiii—Ru2—La1^xxii	102.52 (4)
Ru3^xv—La3—La1^xviii	51.68 (3)	La2^v—Ru2—La1^xxii	64.082 (19)
La4^xvi—La3—La1^xviii	103.76 (3)	La2^viii—Ru2—La1^xxii	124.96 (4)
La4^xvii—La3—La1^xviii	60.009 (14)	La4^xiii—Ru2—La1^xxii	65.88 (3)
La1^xvi—La3—La1^xviii	157.81 (4)	La5^xii—Ru2—La1^xxiii	124.03 (3)
Ru1^vi—La3—La1^xix	63.380 (15)	La2^xxii—Ru2—La1^xxiii	102.52 (4)
Ru1—La3—La1^xix	122.257 (9)	La2^xxiii—Ru2—La1^xxiii	67.79 (3)
Ru3^xiv—La3—La1^xix	51.68 (3)	La2^v—Ru2—La1^xxiii	124.96 (4)
Ru3^xv—La3—La1^xix	107.30 (4)	La2^viii—Ru2—La1^xxiii	64.082 (19)
La4^xvi—La3—La1^xix	103.76 (3)	La4^xiii—Ru2—La1^xxiii	65.88 (3)
La4^xvii—La3—La1^xix	60.009 (14)	La1^xxii—Ru2—La1^xxiii	62.89 (3)
La1^xvi—La3—La1^xix	60.467 (19)	La5^xii—Ru2—La2^xxxii	71.20 (3)
La1^xviii—La3—La1^xix	114.76 (2)	La2^xxii—Ru2—La2^xxxii	63.90 (3)
Ru1^vi—La3—La1^xx	122.257 (9)	La2^xxiii—Ru2—La2^xxxii	97.55 (3)
Ru1—La3—La1^xx	63.380 (15)	La2^v—Ru2—La2^xxxii	61.12 (2)
Ru3^xiv—La3—La1^xx	107.30 (4)	La2^viii—Ru2—La2^xxxii	119.17 (4)
Ru3^xv—La3—La1^xx	51.68 (3)	La4^xiii—Ru2—La2^xxxii	129.84 (4)
La4^xvi—La3—La1^xx	60.009 (14)	La1^xxii—Ru2—La2^xxxii	115.849 (17)
La4^xvii—La3—La1^xx	103.76 (3)	La1^xxiii—Ru2—La2^xxxii	163.52 (4)
La1^xvi—La3—La1^xx	114.76 (2)	La5^xii—Ru2—La2^xi	71.20 (3)
La1^xviii—La3—La1^xx	60.467 (19)	La2^xxii—Ru2—La2^xi	97.55 (3)
La1^xix—La3—La1^xx	157.81 (4)	La2^xxiii—Ru2—La2^xi	63.90 (3)
Ru1^vi—La3—La1^xiv	50.24 (3)	La2^v—Ru2—La2^xi	119.17 (4)
Ru1—La3—La1^xiv	108.22 (4)	La2^viii—Ru2—La2^xi	61.12 (2)
Ru3^xiv—La3—La1^xiv	150.765 (12)	La4^xiii—Ru2—La2^xi	129.84 (4)
Ru3^xv—La3—La1^xiv	111.05 (3)	La1^xxii—Ru2—La2^xi	163.52 (4)
La4^xvi—La3—La1^xiv	149.047 (11)	La1^xxiii—Ru2—La2^xi	115.849 (17)
La4^xvii—La3—La1^xiv	98.166 (15)	La2^xxxii—Ru2—La2^xi	60.15 (3)
La1^xvi—La3—La1^xiv	141.66 (3)	La1^xiv—Ru3—La1^xxii	77.21 (4)
La1^xviii—La3—La1^xiv	59.886 (19)	La1^xiv—Ru3—La1^xxiii	120.29 (7)
La1^xix—La3—La1^xiv	107.008 (19)	La1^xxii—Ru3—La1^xxiii	74.08 (4)
La1^xx—La3—La1^xiv	89.43 (2)	La1^xiv—Ru3—La1^xxi	74.08 (4)
Ru1^vi—La3—La1^xxi	50.24 (3)	La1^xxii—Ru3—La1^xxi	120.29 (7)
Ru1—La3—La1^xxi	108.22 (4)	La1^xxiii—Ru3—La1^xxi	77.21 (4)
Ru3^xiv—La3—La1^xxi	111.04 (3)	La1^xiv—Ru3—La3ⁱⁱ	76.459 (16)
Ru3^xv—La3—La1^xxi	150.765 (12)	La1^xxii—Ru3—La3ⁱⁱ	76.459 (16)
La4^xvi—La3—La1^xxi	149.047 (11)	La1^xxiii—Ru3—La3ⁱⁱ	140.924 (12)
La4^xvii—La3—La1^xxi	98.166 (15)	La1^xxi—Ru3—La3ⁱⁱ	140.924 (12)
La1^xvi—La3—La1^xxi	89.43 (2)	La1^xiv—Ru3—La3^xxxiii	140.924 (12)
La1^xviii—La3—La1^xxi	107.008 (19)	La1^xxii—Ru3—La3^xxxiii	140.924 (12)
La1^xix—La3—La1^xxi	59.886 (19)	La1^xxiii—Ru3—La3^xxxiii	76.459 (16)
La1^xx—La3—La1^xxi	141.66 (3)	La1^xxi—Ru3—La3^xxxiii	76.459 (16)
La1^xiv—La3—La1^xxi	56.26 (2)	La3ⁱⁱ—Ru3—La3^xxxiii	114.01 (7)
Ru1^vi—La3—La1^xxii	108.22 (4)	La1^xiv—Ru3—La4^xiv	73.911 (15)
Ru1—La3—La1^xxii	50.24 (3)	La1^xxii—Ru3—La4^xiv	142.318 (12)
Ru3^xiv—La3—La1^xxii	150.765 (12)	La1^xxiii—Ru3—La4^xiv	142.317 (12)
Ru3^xv—La3—La1^xxii	111.05 (3)	La1^xxi—Ru3—La4^xiv	73.911 (15)
La4^xvi—La3—La1^xxii	98.166 (15)	La3ⁱⁱ—Ru3—La4^xiv	73.66 (3)
La4^xvii—La3—La1^xxii	149.047 (11)	La3^xxxiii—Ru3—La4^xiv	73.66 (3)
La1^xvi—La3—La1^xxii	107.008 (19)	La1^xiv—Ru3—La4^xiii	142.317 (12)
La1^xviii—La3—La1^xxii	89.43 (2)	La1^xxii—Ru3—La4^xiii	73.911 (15)
La1^xix—La3—La1^xxii	141.66 (3)	La1^xxiii—Ru3—La4^xiii	73.911 (15)
La1^xx—La3—La1^xxii	59.886 (19)	La1^xxi—Ru3—La4^xiii	142.318 (12)
La1^xiv—La3—La1^xxii	58.47 (2)	La3ⁱⁱ—Ru3—La4^xiii	73.66 (3)
La1^xxi—La3—La1^xxii	85.50 (3)	La3^xxxiii—Ru3—La4^xiii	73.66 (3)
Ru1^vi—La3—La1^xxiii	108.22 (4)	La4^xiv—Ru3—La4^xiii	117.80 (7)
Ru1—La3—La1^xxiii	50.24 (3)	La1^xxxiv—Ru4—La1^iv	77.36 (3)
Ru3^xiv—La3—La1^xxiii	111.04 (3)	La1^xxxiv—Ru4—La1	124.21 (6)
Ru3^xv—La3—La1^xxiii	150.765 (12)	La1^iv—Ru4—La1	77.36 (3)
La4^xvi—La3—La1^xxiii	98.166 (15)	La1^xxxiv—Ru4—La1^vii	77.36 (3)
La4^xvii—La3—La1^xxiii	149.047 (11)	La1^iv—Ru4—La1^vii	124.21 (6)
La1^xvi—La3—La1^xxiii	59.886 (19)	La1—Ru4—La1^vii	77.36 (3)
La1^xviii—La3—La1^xxiii	141.66 (3)	La1^xxxiv—Ru4—La2	138.418 (17)
La1^xix—La3—La1^xxiii	89.43 (2)	La1^iv—Ru4—La2	143.716 (18)
La1^xx—La3—La1^xxiii	107.008 (19)	La1—Ru4—La2	75.350 (16)
La1^xiv—La3—La1^xxiii	85.50 (3)	La1^vii—Ru4—La2	71.881 (16)
La1^xxi—La3—La1^xxiii	58.47 (2)	La1^xxxiv—Ru4—La2^iv	143.716 (18)
La1^xxii—La3—La1^xxiii	56.26 (2)	La1^iv—Ru4—La2^iv	75.350 (16)
Ru1^xxiv—La4—Ru1ⁱⁱⁱ	176.27 (8)	La1—Ru4—La2^iv	71.881 (16)
Ru1^xxiv—La4—Ru3^xxv	91.60 (3)	La1^vii—Ru4—La2^iv	138.418 (17)
Ru1ⁱⁱⁱ—La4—Ru3^xxv	91.60 (3)	La2—Ru4—La2^iv	73.74 (3)
Ru1^xxiv—La4—Ru3ⁱⁱ	91.60 (3)	La1^xxxiv—Ru4—La2^xxxiv	75.350 (16)
Ru1ⁱⁱⁱ—La4—Ru3ⁱⁱ	91.60 (3)	La1^iv—Ru4—La2^xxxiv	71.881 (16)
Ru3^xxv—La4—Ru3ⁱⁱ	62.20 (7)	La1—Ru4—La2^xxxiv	138.418 (17)
Ru1^xxiv—La4—In1ⁱ	88.85 (2)	La1^vii—Ru4—La2^xxxiv	143.716 (18)
Ru1ⁱⁱⁱ—La4—In1ⁱ	88.85 (2)	La2—Ru4—La2^xxxiv	116.11 (6)
Ru3^xxv—La4—In1ⁱ	159.16 (5)	La2^iv—Ru4—La2^xxxiv	73.74 (3)
Ru3ⁱⁱ—La4—In1ⁱ	96.95 (4)	La1^xxxiv—Ru4—La2^vii	71.881 (16)
Ru1^xxiv—La4—In1^xxv	88.85 (2)	La1^iv—Ru4—La2^vii	138.418 (17)
Ru1ⁱⁱⁱ—La4—In1^xxv	88.85 (2)	La1—Ru4—La2^vii	143.716 (18)
Ru3^xxv—La4—In1^xxv	96.95 (4)	La1^vii—Ru4—La2^vii	75.350 (16)
Ru3ⁱⁱ—La4—In1^xxv	159.16 (5)	La2—Ru4—La2^vii	73.74 (3)
In1ⁱ—La4—In1^xxv	103.89 (6)	La2^iv—Ru4—La2^vii	116.11 (6)
Ru1^xxiv—La4—Ru2ⁱ	88.85 (2)	La2^xxxiv—Ru4—La2^vii	73.74 (3)
Ru1ⁱⁱⁱ—La4—Ru2ⁱ	88.85 (2)	La2^x—Ru5—La2^xxxiv	139.13 (3)
Ru3^xxv—La4—Ru2ⁱ	159.16 (5)	La2^x—Ru5—La2^vii	143.22 (3)
Ru3ⁱⁱ—La4—Ru2ⁱ	96.95 (4)	La2^xxxiv—Ru5—La2^vii	75.781 (11)
In1ⁱ—La4—Ru2ⁱ	0.00 (4)	La2^x—Ru5—La2^ix	75.781 (11)
In1^xxv—La4—Ru2ⁱ	103.89 (6)	La2^xxxiv—Ru5—La2^ix	143.22 (3)
Ru1^xxiv—La4—Ru2^xxv	88.85 (2)	La2^vii—Ru5—La2^ix	74.64 (3)
Ru1ⁱⁱⁱ—La4—Ru2^xxv	88.85 (2)	La2^x—Ru5—La2^xxxv	120.58 (2)
Ru3^xxv—La4—Ru2^xxv	96.95 (4)	La2^xxxiv—Ru5—La2^xxxv	74.64 (3)
Ru3ⁱⁱ—La4—Ru2^xxv	159.16 (5)	La2^vii—Ru5—La2^xxxv	71.96 (3)
In1ⁱ—La4—Ru2^xxv	103.89 (6)	La2^ix—Ru5—La2^xxxv	75.781 (11)
In1^xxv—La4—Ru2^xxv	0.00 (4)	La2^x—Ru5—La2	74.64 (3)
Ru2ⁱ—La4—Ru2^xxv	103.89 (6)	La2^xxxiv—Ru5—La2	120.58 (2)
Ru1^xxiv—La4—La5	88.13 (4)	La2^vii—Ru5—La2	75.781 (11)
Ru1ⁱⁱⁱ—La4—La5	88.13 (4)	La2^ix—Ru5—La2	71.96 (3)
Ru3^xxv—La4—La5	148.90 (3)	La2^xxxv—Ru5—La2	139.13 (3)
Ru3ⁱⁱ—La4—La5	148.90 (3)	La2^x—Ru5—La2^xxxvi	75.781 (11)
In1ⁱ—La4—La5	51.94 (3)	La2^xxxiv—Ru5—La2^xxxvi	71.96 (3)
In1^xxv—La4—La5	51.94 (3)	La2^vii—Ru5—La2^xxxvi	139.13 (3)
Ru2ⁱ—La4—La5	51.94 (3)	La2^ix—Ru5—La2^xxxvi	120.58 (2)
Ru2^xxv—La4—La5	51.94 (3)	La2^xxxv—Ru5—La2^xxxvi	75.781 (11)
Ru1^xxiv—La4—La3ⁱⁱⁱ	134.76 (5)	La2—Ru5—La2^xxxvi	143.22 (3)
Ru1ⁱⁱⁱ—La4—La3ⁱⁱⁱ	48.97 (3)	La2^x—Ru5—La2^iv	71.96 (3)
Ru3^xxv—La4—La3ⁱⁱⁱ	51.15 (3)	La2^xxxiv—Ru5—La2^iv	75.781 (11)
Ru3ⁱⁱ—La4—La3ⁱⁱⁱ	51.15 (3)	La2^vii—Ru5—La2^iv	120.58 (2)
In1ⁱ—La4—La3ⁱⁱⁱ	116.846 (17)	La2^ix—Ru5—La2^iv	139.13 (3)
In1^xxv—La4—La3ⁱⁱⁱ	116.845 (17)	La2^xxxv—Ru5—La2^iv	143.22 (3)
Ru2ⁱ—La4—La3ⁱⁱⁱ	116.846 (17)	La2—Ru5—La2^iv	75.781 (11)
Ru2^xxv—La4—La3ⁱⁱⁱ	116.845 (17)	La2^xxxvi—Ru5—La2^iv	74.64 (3)
La5—La4—La3ⁱⁱⁱ	137.10 (2)	La1—In2—La1^xxxvii	180.00 (3)
Ru1^xxiv—La4—La3^xvii	48.97 (3)	La1—In2—La1^iv	70.717 (10)
Ru1ⁱⁱⁱ—La4—La3^xvii	134.76 (5)	La1^xxxvii—In2—La1^iv	109.283 (10)
Ru3^xxv—La4—La3^xvii	51.15 (3)	La1—In2—La1^xxxiv	109.85 (2)
Ru3ⁱⁱ—La4—La3^xvii	51.15 (3)	La1^xxxvii—In2—La1^xxxiv	70.15 (2)
In1ⁱ—La4—La3^xvii	116.845 (17)	La1^iv—In2—La1^xxxiv	70.717 (10)
In1^xxv—La4—La3^xvii	116.845 (17)	La1—In2—La1^vii	70.717 (10)
Ru2ⁱ—La4—La3^xvii	116.845 (17)	La1^xxxvii—In2—La1^vii	109.283 (10)
Ru2^xxv—La4—La3^xvii	116.845 (17)	La1^iv—In2—La1^vii	109.85 (2)
La5—La4—La3^xvii	137.10 (2)	La1^xxxiv—In2—La1^vii	70.717 (10)
La3ⁱⁱⁱ—La4—La3^xvii	85.79 (4)	La1—In2—La1^xxxviii	109.283 (10)
Ru1^xxiv—La4—La1	119.600 (14)	La1^xxxvii—In2—La1^xxxviii	70.717 (10)
Ru1ⁱⁱⁱ—La4—La1	61.370 (13)	La1^iv—In2—La1^xxxviii	70.15 (2)
Ru3^xxv—La4—La1	103.96 (4)	La1^xxxiv—In2—La1^xxxviii	109.283 (10)
Ru3ⁱⁱ—La4—La1	50.94 (3)	La1^vii—In2—La1^xxxviii	180.00 (3)
In1ⁱ—La4—La1	58.39 (2)	La1—In2—La1^vi	70.15 (2)
In1^xxv—La4—La1	143.53 (3)	La1^xxxvii—In2—La1^vi	109.85 (2)
Ru2ⁱ—La4—La1	58.39 (2)	La1^iv—In2—La1^vi	109.283 (10)
Ru2^xxv—La4—La1	143.53 (3)	La1^xxxiv—In2—La1^vi	180.00 (2)
La5—La4—La1	103.13 (2)	La1^vii—In2—La1^vi	109.283 (10)
La3ⁱⁱⁱ—La4—La1	60.151 (15)	La1^xxxviii—In2—La1^vi	70.717 (10)
La3^xvii—La4—La1	99.50 (3)	La1—In2—La1^xxxix	109.283 (10)
Ru1^xxiv—La4—La1^v	61.370 (13)	La1^xxxvii—In2—La1^xxxix	70.717 (10)
Ru1ⁱⁱⁱ—La4—La1^v	119.600 (14)	La1^iv—In2—La1^xxxix	180.00 (2)
Ru3^xxv—La4—La1^v	103.96 (4)	La1^xxxiv—In2—La1^xxxix	109.283 (10)
Ru3ⁱⁱ—La4—La1^v	50.94 (3)	La1^vii—In2—La1^xxxix	70.15 (2)
In1ⁱ—La4—La1^v	58.39 (2)	La1^xxxviii—In2—La1^xxxix	109.85 (2)
In1^xxv—La4—La1^v	143.53 (3)	La1^vi—In2—La1^xxxix	70.717 (10)
Ru2ⁱ—La4—La1^v	58.39 (2)

Symmetry codes: (i) x−1/2, −y+1/2, z; (ii) x−1/2, −y+1/2, −z; (iii) x−1, y, z; (iv) −y, x, z; (v) −y+1/2, −x+1/2, z; (vi) x, y, −z; (vii) y, −x, z; (viii) −x+1, −y, z; (ix) x, −y, −z+1/2; (x) y, x, −z+1/2; (xi) −x+1, y, −z+1/2; (xii) −x+1/2, −y+1/2, −z+1/2; (xiii) −x+1/2, y−1/2, z; (xiv) x+1/2, −y+1/2, −z; (xv) −x+3/2, y+1/2, z; (xvi) x+1, y, z; (xvii) −x+1, −y+1, −z; (xviii) y+1/2, x+1/2, −z; (xix) x+1, y, −z; (xx) y+1/2, x+1/2, z; (xxi) −y+1, x, −z; (xxii) x+1/2, −y+1/2, z; (xxiii) −y+1, x, z; (xxiv) −x+1, −y+1, z; (xxv) −x+1/2, y+1/2, z; (xxvi) y−1/2, x+1/2, z; (xxvii) −x, −y+1, z; (xxviii) y, −x+1, z; (xxix) x−1/2, y+1/2, −z+1/2; (xxx) x, −y+1, −z+1/2; (xxxi) −y, −x+1, −z+1/2; (xxxii) y+1/2, −x+1/2, −z+1/2; (xxxiii) −x+3/2, y−1/2, z; (xxxiv) −x, −y, z; (xxxv) −y, −x, −z+1/2; (xxxvi) −x, y, −z+1/2; (xxxvii) −x, −y, −z; (xxxviii) −y, x, −z; (xxxix) y, −x, −z.

Experimental details

Crystal data
Chemical formula	La₂₁Ru_10.16In_3.84
M_r	4384.89
Crystal system, space group	Tetragonal, I4/mcm
Temperature (K)	293
a, c (Å)	12.1298 (3), 25.9820 (7)
V (Å³)	3822.79 (17)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	28.98
Crystal size (mm)	0.06 × 0.05 × 0.05

Data collection
Diffractometer	Nonius KappaCCD diffractometer
Absorption correction	For a sphere (WinGX; Farrugia, 1999)
T_min, T_max	0.243, 0.261
No. of measured, independent and observed [I > 2σ(I)] reflections	22423, 1202, 927
R_int	0.087
(sin θ/λ)_max (Å⁻¹)	0.649

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.036, 0.062, 1.12
No. of reflections	1202
No. of parameters	53
	w = 1/[σ²(F_o²) + (0.0131P)² + 224.3566P] where P = (F_o² + 2F_c²)/3
Δρ_max, Δρ_min (e Å⁻³)	2.00, −2.74

Computer programs: COLLECT (Nonius, 1998), DENZO (Otwinowski & Minor, 1997), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), DIAMOND (Brandenburg, 1999).

Acknowledgements

This work was supported by the RFBR project 080300702a.

References

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