(Perchlorato-κO)tris­(triphenyl­phosphine-κP)silver(I)

Cui, L.-N.; Hu, K.-Y.; Jin, Q.-H.; Zhang, C.-L.

doi:10.1107/S1600536810025171

metal-organic compounds

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 66| Part 8| August 2010| Page m871

https://doi.org/10.1107/S1600536810025171

Open

access

(Perchlorato-κO)tris(triphenylphosphine-κP)silver(I)

Li-Na Cui,^a Ke-Yi Hu,^a Qiong-Hua Jin ^a ^* and Cun-Lin Zhang ^b

^aDepartment of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China, and ^bBeijing Key Laboratory for Terahertz Spectroscopy and Imaging, Key Laboratory of Terahertz Optoelectronics, Ministry of Education, Capital Normal University, Beijing 100048, People's Republic of China
^*Correspondence e-mail: jinqh204@163.com

(Received 13 June 2010; accepted 27 June 2010; online 3 July 2010)

In the title complex, [Ag(C₁₈H₁₅P)₃(ClO₄)], the silver coordination environment is dominated by the distorted P₃AgO tetrahedron in which Ag—O = 2.608 (12) Å and the Ag—P bond lengths are 2.5663 (17), 2.5076(16) and 2.5450 (17) Å. The perchlorate O-atoms are disordered over two positions in a 0.584 (14):0.416 (14) ratio.

Related literature

For similar compounds, see: Awaleh et al. (2005 ); Effendy et al. (2007a ,b ,c ); Jin et al. (2010 ); Di Nicola et al. (2007 ); Pettinari et al. (2007 ).

Experimental

Crystal data

[Ag(C₁₈H₁₅P)₃(ClO₄)]
M_r = 994.13
Monoclinic, P 2₁ /n
a = 18.066 (2) Å
b = 13.7779 (16) Å
c = 19.064 (2) Å
β = 94.132 (2)°
V = 4733.0 (9) Å³
Z = 4
Mo Kα radiation
μ = 0.63 mm⁻¹
T = 298 K
0.19 × 0.18 × 0.17 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 2008 ) T_min = 0.890, T_max = 0.901
23792 measured reflections
8339 independent reflections
4010 reflections with I > 2σ(I)
R_int = 0.069

Refinement

R[F² > 2σ(F²)] = 0.057
wR(F²) = 0.128
S = 1.03
8339 reflections
605 parameters
H-atom parameters constrained
Δρ_max = 0.85 e Å⁻³
Δρ_min = −1.07 e Å⁻³

Table 1
Selected bond angles (°)

P2—Ag1—P3	118.38 (6)
P2—Ag1—P1	114.66 (5)
P3—Ag1—P1	119.17 (6)
P2—Ag1—O1	92.9 (4)
P3—Ag1—O1	87.0 (4)
P1—Ag1—O1	118.0 (4)

Data collection: SMART (Bruker, 2007 ); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks global, I. DOI: https://doi.org/10.1107/S1600536810025171/su2189sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536810025171/su2189Isup2.hkl

checkCIF report

Comment top

Reports concerning with the structural and kinetic features of silver(I)-phosphine complexes are growing in number as the participation of these compounds in biological processes are discovered. A recent report (Effendy et al., 2007a) described a series of complexes of silver perchlorate and nitrate, tertiary phosphine ligand and oligodentate N-base adducts of the form AgX:dpex:L(2:1:2). In these complexes, the perchlorate acts either as a counteranion or as a ligand coordinating to silver(I) by one oxygen atom in a monodentate mode or by two oxygen atoms in a bidentate-chelating mode. We have studied the catalytic function of some nitrogen heterocyclic ligands (Jin et al., 2010), and herein we report on the new title complex, which was synthesized under catalysis of 2-aminopyrimidine.

The molecular structure of the title complex is depicted in Fig. 1. The silver atom is four coordinated by three phosphorus atoms from PPh₃ groups and one oxygen atom from the ClO₄ anion. The Ag—P distances are 2.5641 (14), 2.5047 (13) Å and 2.5415 (13) Å. The Ag—O distance [2.668 (14) Å] is slightly longer than that in adducts of AgClO₄:dppe:bpy [2.539 (2) Å] (Effendy et al., 2007a). The angles P—Ag—P are in the range of 114.70 (4) - 119.17 (5)°, while angles P—Ag—O are in the range of 87.1 (4) - 118.1 (4) °, which comfirms the distorted tetrahedral environment around the silver atom.

The crystal structure data show little differences between the title complex and other AgX:PPh₃:L, where X is a simple inorganic or organic anion, for example, nitrate (Di Nicola et al., 2007), nitrite (Pettinari et al., 2007), acetate (Effendy et al., 2007b), perchlorate (Effendy et al., 2007c) or trifluoroacetate (Awaleh et al., 2005).

Related literature top

For similar compounds, see: Awaleh et al. (2005); Effendy et al. (2007a,b,c); Jin et al. (2010); Di Nicola et al. (2007); Pettinari et al. (2007).

Experimental top

A mixture of AgClO₄, PPh₃ and 2-aminopyrimidine, in the molar ratio 1:1:2, in CH₂Cl₂ and MeOH (10 ml, V/V=1/1) was stirred for 2 h at ambient temperature, then filtered. Subsequent slow evaporation of the filtrate resulted in the formation of colorless crystals of the title complex. Crystals suitable for single-crystal X-ray diffraction were selected directly from the sample as prepared. Analysis found: C 65.40%, H 5.07%; calculated: C 65.19%, H 4.35%.

Structure description top

For similar compounds, see: Awaleh et al. (2005); Effendy et al. (2007a,b,c); Jin et al. (2010); Di Nicola et al. (2007); Pettinari et al. (2007).

Computing details top

Data collection: SMART (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

Fig. 1. A view of a basic unit of the title complex. Displacement ellipsoids are drawn at the 50% probability level and H-atoms have been omitted for clarity.

(Perchlorato-κO)tris(triphenylphosphine-κP)silver(I) top

Crystal data top

[Ag(C₁₈H₁₅P)₃(ClO₄)]	F(000) = 2040
M_r = 994.13	D_x = 1.395 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 2750 reflections
a = 18.066 (2) Å	θ = 2.7–19.5°
b = 13.7779 (16) Å	µ = 0.63 mm⁻¹
c = 19.064 (2) Å	T = 298 K
β = 94.132 (2)°	Block, colourless
V = 4733.0 (9) Å³	0.19 × 0.18 × 0.17 mm
Z = 4

Data collection top

Bruker SMART CCD area-detector diffractometer	8339 independent reflections
Radiation source: fine-focus sealed tube	4010 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.069
phi and ω scans	θ_max = 25.0°, θ_min = 1.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 2008)	h = −21→19
T_min = 0.890, T_max = 0.901	k = −13→16
23792 measured reflections	l = −22→22

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.057	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.128	H-atom parameters constrained
S = 1.03	w = 1/[σ²(F_o²) + (0.0375P)²] where P = (F_o² + 2F_c²)/3
8339 reflections	(Δ/σ)_max = 0.001
605 parameters	Δρ_max = 0.85 e Å⁻³
0 restraints	Δρ_min = −1.07 e Å⁻³

Crystal data top

[Ag(C₁₈H₁₅P)₃(ClO₄)]	V = 4733.0 (9) Å³
M_r = 994.13	Z = 4
Monoclinic, P2₁/n	Mo Kα radiation
a = 18.066 (2) Å	µ = 0.63 mm⁻¹
b = 13.7779 (16) Å	T = 298 K
c = 19.064 (2) Å	0.19 × 0.18 × 0.17 mm
β = 94.132 (2)°

Data collection top

Bruker SMART CCD area-detector diffractometer	8339 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 2008)	4010 reflections with I > 2σ(I)
T_min = 0.890, T_max = 0.901	R_int = 0.069
23792 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.057	0 restraints
wR(F²) = 0.128	H-atom parameters constrained
S = 1.03	Δρ_max = 0.85 e Å⁻³
8339 reflections	Δρ_min = −1.07 e Å⁻³
605 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ag1	0.24335 (3)	0.81327 (3)	0.01311 (2)	0.05196 (17)
P1	0.34225 (9)	0.68176 (12)	0.00117 (8)	0.0493 (4)
P2	0.17377 (9)	0.80044 (11)	0.12190 (8)	0.0477 (4)
P3	0.26351 (10)	0.98099 (11)	−0.03809 (8)	0.0519 (5)
Cl1	0.09855 (15)	0.72401 (17)	−0.11116 (12)	0.0802 (6)
O1	0.1224 (7)	0.8041 (13)	−0.0700 (9)	0.089 (5)	0.584 (14)
O2	0.0255 (6)	0.7017 (6)	−0.0998 (4)	0.080 (4)	0.584 (14)
O3	0.1416 (7)	0.6407 (8)	−0.0977 (5)	0.080 (4)	0.584 (14)
O4	0.1075 (10)	0.7556 (15)	−0.1821 (10)	0.105 (6)	0.584 (14)
O1'	0.1765 (8)	0.7147 (13)	−0.0977 (7)	0.097 (6)	0.416 (14)
O2'	0.0779 (9)	0.6317 (10)	−0.0900 (7)	0.080 (6)	0.416 (14)
O3'	0.0800 (10)	0.8015 (17)	−0.0690 (12)	0.080 (6)	0.416 (14)
O4'	0.0664 (14)	0.728 (2)	−0.1794 (14)	0.105 (9)	0.416 (14)
C1	0.3718 (4)	0.6630 (5)	−0.0865 (3)	0.0579 (18)
C2	0.3609 (4)	0.7343 (5)	−0.1358 (4)	0.084 (2)
H2	0.3376	0.7916	−0.1241	0.101*
C3	0.3840 (5)	0.7227 (6)	−0.2031 (4)	0.102 (3)
H3	0.3756	0.7721	−0.2360	0.123*
C4	0.4186 (5)	0.6403 (6)	−0.2217 (4)	0.088 (2)
H4	0.4355	0.6342	−0.2664	0.106*
C5	0.4285 (4)	0.5664 (6)	−0.1743 (4)	0.095 (3)
H5	0.4508	0.5088	−0.1870	0.114*
C6	0.4050 (4)	0.5775 (5)	−0.1071 (4)	0.082 (2)
H6	0.4116	0.5267	−0.0751	0.099*
C7	0.3143 (4)	0.5609 (5)	0.0251 (4)	0.0632 (19)
C8	0.2590 (5)	0.5177 (6)	−0.0159 (4)	0.096 (3)
H8	0.2371	0.5520	−0.0540	0.115*
C9	0.2338 (5)	0.4246 (7)	−0.0034 (5)	0.117 (3)
H9	0.1987	0.3953	−0.0346	0.141*
C10	0.2612 (6)	0.3772 (7)	0.0549 (5)	0.111 (3)
H10	0.2400	0.3187	0.0675	0.133*
C11	0.3199 (7)	0.4149 (7)	0.0955 (5)	0.127 (4)
H11	0.3425	0.3790	0.1324	0.153*
C12	0.3457 (5)	0.5080 (6)	0.0809 (4)	0.100 (3)
H12	0.3846	0.5345	0.1092	0.120*
C13	0.4285 (4)	0.6985 (5)	0.0558 (3)	0.0600 (18)
C14	0.4977 (4)	0.6821 (5)	0.0321 (4)	0.083 (2)
H14	0.5015	0.6629	−0.0142	0.100*
C15	0.5622 (4)	0.6935 (6)	0.0762 (5)	0.098 (3)
H15	0.6085	0.6830	0.0594	0.117*
C16	0.5561 (5)	0.7207 (5)	0.1453 (4)	0.079 (2)
H16	0.5985	0.7264	0.1757	0.095*
C17	0.4898 (5)	0.7387 (5)	0.1686 (4)	0.081 (2)
H17	0.4861	0.7583	0.2149	0.097*
C18	0.4253 (4)	0.7284 (5)	0.1235 (4)	0.072 (2)
H18	0.3794	0.7422	0.1403	0.086*
C19	0.2416 (3)	0.7986 (5)	0.1960 (3)	0.0549 (17)
C20	0.2915 (4)	0.8770 (5)	0.2022 (3)	0.069 (2)
H20	0.2876	0.9272	0.1695	0.083*
C21	0.3461 (4)	0.8798 (6)	0.2567 (4)	0.087 (2)
H21	0.3778	0.9329	0.2618	0.105*
C22	0.3534 (4)	0.8046 (7)	0.3030 (4)	0.086 (2)
H22	0.3909	0.8065	0.3390	0.104*
C23	0.3075 (5)	0.7275 (6)	0.2978 (4)	0.087 (2)
H23	0.3137	0.6770	0.3301	0.105*
C24	0.2503 (4)	0.7230 (5)	0.2438 (4)	0.071 (2)
H24	0.2186	0.6698	0.2402	0.085*
C25	0.1121 (3)	0.8980 (4)	0.1440 (3)	0.0477 (16)
C26	0.0521 (4)	0.9169 (4)	0.0966 (3)	0.0610 (18)
H26	0.0459	0.8811	0.0552	0.073*
C27	0.0013 (4)	0.9883 (5)	0.1101 (4)	0.070 (2)
H27	−0.0393	0.9993	0.0783	0.084*
C28	0.0105 (4)	1.0430 (5)	0.1701 (4)	0.069 (2)
H28	−0.0237	1.0910	0.1791	0.083*
C29	0.0696 (4)	1.0266 (5)	0.2160 (4)	0.069 (2)
H29	0.0767	1.0650	0.2561	0.082*
C30	0.1202 (4)	0.9529 (5)	0.2045 (3)	0.0609 (18)
H30	0.1594	0.9408	0.2376	0.073*
C31	0.1149 (3)	0.6960 (4)	0.1318 (3)	0.0524 (16)
C32	0.0666 (4)	0.6891 (5)	0.1848 (4)	0.0699 (19)
H32	0.0660	0.7379	0.2185	0.084*
C33	0.0191 (4)	0.6104 (6)	0.1885 (4)	0.082 (2)
H33	−0.0127	0.6062	0.2246	0.098*
C34	0.0192 (4)	0.5392 (6)	0.1388 (5)	0.082 (2)
H34	−0.0135	0.4872	0.1405	0.099*
C35	0.0671 (5)	0.5438 (5)	0.0865 (4)	0.088 (2)
H35	0.0678	0.4944	0.0534	0.105*
C36	0.1148 (4)	0.6225 (5)	0.0831 (4)	0.070 (2)
H36	0.1471	0.6254	0.0474	0.083*
C37	0.1963 (4)	1.0789 (4)	−0.0370 (3)	0.0534 (17)
C38	0.1552 (4)	1.0904 (5)	0.0203 (4)	0.0644 (19)
H38	0.1614	1.0470	0.0576	0.077*
C39	0.1041 (4)	1.1663 (5)	0.0236 (4)	0.070 (2)
H39	0.0768	1.1730	0.0628	0.084*
C40	0.0943 (4)	1.2308 (5)	−0.0310 (4)	0.067 (2)
H40	0.0610	1.2820	−0.0286	0.080*
C41	0.1332 (4)	1.2192 (5)	−0.0882 (4)	0.074 (2)
H41	0.1254	1.2619	−0.1257	0.089*
C42	0.1845 (4)	1.1457 (5)	−0.0922 (3)	0.0660 (19)
H42	0.2114	1.1403	−0.1318	0.079*
C43	0.3407 (4)	1.0289 (5)	0.0146 (3)	0.0617 (19)
C44	0.3482 (5)	1.1219 (6)	0.0385 (4)	0.103 (3)
H44	0.3118	1.1669	0.0242	0.123*
C45	0.4078 (6)	1.1526 (7)	0.0834 (5)	0.121 (3)
H45	0.4110	1.2169	0.0982	0.145*
C46	0.4611 (5)	1.0881 (8)	0.1054 (4)	0.109 (3)
H46	0.5006	1.1077	0.1361	0.131*
C47	0.4567 (5)	0.9952 (8)	0.0826 (5)	0.127 (4)
H47	0.4937	0.9508	0.0964	0.152*
C48	0.3963 (5)	0.9671 (6)	0.0385 (4)	0.101 (3)
H48	0.3933	0.9026	0.0242	0.121*
C49	0.2882 (4)	0.9838 (4)	−0.1286 (3)	0.0586 (18)
C50	0.2438 (4)	0.9347 (5)	−0.1780 (4)	0.073 (2)
H50	0.2044	0.8975	−0.1641	0.088*
C51	0.2574 (5)	0.9402 (6)	−0.2484 (4)	0.089 (2)
H51	0.2264	0.9072	−0.2814	0.106*
C52	0.3145 (5)	0.9924 (6)	−0.2702 (4)	0.091 (3)
H52	0.3232	0.9946	−0.3177	0.109*
C53	0.3594 (4)	1.0416 (5)	−0.2222 (4)	0.083 (2)
H53	0.3988	1.0780	−0.2368	0.099*
C54	0.3465 (4)	1.0378 (5)	−0.1515 (4)	0.071 (2)
H54	0.3774	1.0718	−0.1190	0.086*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.0555 (3)	0.0565 (3)	0.0441 (3)	−0.0045 (3)	0.0050 (2)	−0.0010 (3)
P1	0.0562 (11)	0.0492 (10)	0.0425 (9)	−0.0009 (9)	0.0046 (8)	−0.0011 (8)
P2	0.0503 (11)	0.0525 (11)	0.0405 (9)	−0.0021 (8)	0.0053 (8)	−0.0001 (8)
P3	0.0540 (12)	0.0500 (11)	0.0511 (10)	−0.0032 (8)	−0.0011 (9)	0.0055 (8)
Cl1	0.0718 (19)	0.0748 (17)	0.0907 (17)	0.0112 (14)	−0.0162 (14)	−0.0081 (13)
O1	0.066 (10)	0.110 (9)	0.087 (7)	−0.031 (11)	−0.029 (9)	−0.029 (6)
O2	0.072 (8)	0.075 (7)	0.091 (7)	0.011 (5)	−0.016 (5)	−0.008 (5)
O3	0.072 (9)	0.075 (8)	0.091 (7)	0.011 (7)	−0.016 (6)	−0.008 (5)
O4	0.126 (16)	0.123 (13)	0.058 (8)	0.007 (10)	−0.042 (11)	−0.014 (7)
O1'	0.072 (11)	0.097 (14)	0.116 (11)	0.001 (9)	−0.028 (8)	−0.033 (9)
O2'	0.072 (13)	0.075 (11)	0.091 (10)	0.011 (9)	−0.016 (9)	−0.008 (7)
O3'	0.072 (13)	0.075 (12)	0.091 (10)	0.011 (12)	−0.016 (12)	−0.008 (8)
O4'	0.13 (2)	0.123 (18)	0.058 (11)	0.007 (14)	−0.042 (15)	−0.014 (10)
C1	0.072 (5)	0.058 (5)	0.045 (4)	0.008 (4)	0.011 (3)	−0.002 (3)
C2	0.114 (7)	0.081 (6)	0.060 (5)	0.024 (5)	0.021 (5)	−0.005 (4)
C3	0.151 (9)	0.099 (7)	0.060 (5)	0.025 (6)	0.026 (5)	0.016 (5)
C4	0.120 (7)	0.093 (6)	0.056 (5)	0.020 (5)	0.036 (5)	0.001 (5)
C5	0.122 (8)	0.100 (7)	0.066 (5)	0.036 (5)	0.033 (5)	−0.007 (5)
C6	0.105 (7)	0.082 (6)	0.062 (5)	0.025 (5)	0.020 (5)	0.003 (4)
C7	0.084 (6)	0.053 (5)	0.053 (4)	0.006 (4)	0.010 (4)	−0.004 (4)
C8	0.099 (7)	0.072 (6)	0.113 (7)	−0.011 (5)	−0.020 (6)	0.009 (5)
C9	0.130 (9)	0.082 (8)	0.139 (9)	−0.028 (6)	0.002 (7)	−0.006 (6)
C10	0.148 (10)	0.078 (7)	0.111 (8)	−0.039 (7)	0.037 (7)	0.001 (6)
C11	0.195 (12)	0.096 (8)	0.090 (7)	−0.023 (7)	0.006 (7)	0.009 (6)
C12	0.150 (9)	0.072 (6)	0.075 (6)	−0.030 (6)	−0.009 (6)	0.003 (5)
C13	0.057 (5)	0.067 (5)	0.055 (4)	0.010 (4)	0.002 (4)	0.001 (4)
C14	0.075 (6)	0.111 (6)	0.062 (5)	0.012 (5)	−0.004 (4)	−0.016 (5)
C15	0.059 (6)	0.133 (7)	0.100 (7)	0.012 (5)	0.000 (5)	−0.006 (6)
C16	0.066 (6)	0.095 (6)	0.074 (6)	0.002 (4)	−0.019 (5)	0.003 (4)
C17	0.072 (6)	0.101 (6)	0.068 (5)	0.002 (5)	−0.009 (5)	−0.006 (4)
C18	0.068 (6)	0.083 (5)	0.064 (5)	0.005 (4)	0.000 (4)	−0.014 (4)
C19	0.055 (5)	0.066 (5)	0.044 (4)	0.003 (4)	0.008 (3)	−0.001 (3)
C20	0.065 (5)	0.082 (5)	0.058 (5)	−0.006 (4)	−0.004 (4)	−0.001 (4)
C21	0.077 (6)	0.109 (7)	0.074 (6)	−0.010 (5)	−0.011 (5)	−0.016 (5)
C22	0.074 (6)	0.120 (8)	0.062 (5)	0.014 (6)	−0.013 (4)	−0.005 (5)
C23	0.093 (7)	0.102 (7)	0.066 (5)	0.013 (5)	−0.004 (5)	0.005 (5)
C24	0.068 (5)	0.083 (6)	0.062 (5)	0.010 (4)	0.000 (4)	0.001 (4)
C25	0.052 (5)	0.045 (4)	0.046 (4)	−0.004 (3)	0.007 (3)	0.002 (3)
C26	0.065 (5)	0.058 (5)	0.059 (4)	0.001 (4)	0.000 (4)	−0.006 (3)
C27	0.064 (5)	0.069 (5)	0.077 (5)	0.001 (4)	0.002 (4)	0.003 (4)
C28	0.073 (6)	0.059 (5)	0.078 (5)	0.007 (4)	0.022 (4)	0.000 (4)
C29	0.084 (6)	0.063 (5)	0.060 (5)	0.004 (4)	0.013 (4)	−0.008 (4)
C30	0.068 (5)	0.062 (5)	0.053 (4)	0.005 (4)	0.007 (4)	0.002 (4)
C31	0.054 (4)	0.052 (4)	0.051 (4)	0.003 (3)	0.003 (3)	0.004 (3)
C32	0.078 (5)	0.062 (5)	0.071 (5)	−0.008 (4)	0.015 (4)	−0.002 (4)
C33	0.076 (6)	0.075 (6)	0.097 (6)	−0.013 (5)	0.025 (5)	0.018 (5)
C34	0.079 (7)	0.065 (6)	0.101 (7)	−0.017 (4)	−0.004 (5)	0.012 (5)
C35	0.096 (7)	0.066 (6)	0.100 (7)	−0.011 (5)	0.001 (6)	−0.010 (5)
C36	0.073 (6)	0.063 (5)	0.074 (5)	−0.007 (4)	0.013 (4)	−0.002 (4)
C37	0.059 (5)	0.048 (4)	0.052 (4)	−0.007 (3)	−0.003 (4)	0.001 (3)
C38	0.067 (5)	0.060 (5)	0.066 (5)	−0.002 (4)	0.001 (4)	0.002 (4)
C39	0.072 (6)	0.065 (5)	0.071 (5)	−0.001 (4)	0.005 (4)	−0.006 (4)
C40	0.067 (5)	0.059 (5)	0.072 (5)	0.009 (4)	−0.003 (4)	−0.007 (4)
C41	0.087 (6)	0.064 (5)	0.071 (5)	0.012 (4)	−0.004 (5)	0.010 (4)
C42	0.073 (5)	0.065 (5)	0.060 (5)	0.007 (4)	0.005 (4)	0.004 (4)
C43	0.062 (5)	0.061 (5)	0.061 (4)	−0.004 (4)	−0.007 (4)	0.014 (4)
C44	0.085 (7)	0.095 (7)	0.123 (8)	−0.004 (5)	−0.024 (6)	−0.014 (6)
C45	0.108 (9)	0.109 (8)	0.140 (9)	−0.016 (6)	−0.028 (7)	−0.040 (7)
C46	0.096 (8)	0.128 (9)	0.098 (7)	−0.027 (7)	−0.037 (6)	0.006 (6)
C47	0.098 (8)	0.125 (9)	0.149 (9)	−0.010 (7)	−0.050 (7)	0.025 (7)
C48	0.086 (7)	0.088 (7)	0.122 (7)	−0.012 (5)	−0.031 (6)	0.002 (5)
C49	0.066 (5)	0.054 (4)	0.055 (4)	0.001 (4)	−0.002 (4)	0.006 (3)
C50	0.080 (6)	0.079 (5)	0.062 (5)	−0.014 (4)	0.007 (4)	0.001 (4)
C51	0.097 (7)	0.104 (6)	0.063 (5)	−0.010 (5)	−0.011 (5)	−0.003 (5)
C52	0.104 (8)	0.103 (7)	0.067 (6)	−0.001 (5)	0.011 (6)	0.006 (5)
C53	0.083 (6)	0.092 (6)	0.076 (6)	−0.009 (5)	0.025 (5)	0.017 (5)
C54	0.073 (6)	0.076 (5)	0.066 (5)	−0.007 (4)	0.005 (4)	0.005 (4)

Geometric parameters (Å, º) top

Ag1—P2	2.5076 (16)	C22—C23	1.347 (9)
Ag1—P3	2.5450 (17)	C22—H22	0.9300
Ag1—P1	2.5663 (17)	C23—C24	1.407 (9)
Ag1—O1	2.608 (12)	C23—H23	0.9300
P1—C7	1.809 (7)	C24—H24	0.9300
P1—C1	1.809 (6)	C25—C30	1.378 (7)
P1—C13	1.826 (6)	C25—C26	1.386 (7)
P2—C19	1.803 (6)	C26—C27	1.382 (8)
P2—C31	1.808 (6)	C26—H26	0.9300
P2—C25	1.815 (6)	C27—C28	1.369 (8)
P3—C43	1.785 (7)	C27—H27	0.9300
P3—C49	1.814 (7)	C28—C29	1.351 (8)
P3—C37	1.815 (6)	C28—H28	0.9300
Cl1—O2	1.386 (10)	C29—C30	1.393 (8)
Cl1—O4'	1.39 (2)	C29—H29	0.9300
Cl1—O3'	1.39 (2)	C30—H30	0.9300
Cl1—O2'	1.393 (14)	C31—C36	1.373 (8)
Cl1—O3	1.400 (10)	C31—C32	1.386 (8)
Cl1—O1	1.403 (16)	C32—C33	1.388 (9)
Cl1—O1'	1.419 (14)	C32—H32	0.9300
Cl1—O4	1.44 (2)	C33—C34	1.363 (9)
C1—C2	1.364 (8)	C33—H33	0.9300
C1—C6	1.391 (8)	C34—C35	1.368 (10)
C2—C3	1.388 (9)	C34—H34	0.9300
C2—H2	0.9300	C35—C36	1.389 (9)
C3—C4	1.354 (9)	C35—H35	0.9300
C3—H3	0.9300	C36—H36	0.9300
C4—C5	1.365 (9)	C37—C38	1.374 (8)
C4—H4	0.9300	C37—C42	1.403 (8)
C5—C6	1.386 (9)	C38—C39	1.399 (8)
C5—H5	0.9300	C38—H38	0.9300
C6—H6	0.9300	C39—C40	1.369 (8)
C7—C8	1.361 (9)	C39—H39	0.9300
C7—C12	1.377 (9)	C40—C41	1.349 (9)
C8—C9	1.386 (10)	C40—H40	0.9300
C8—H8	0.9300	C41—C42	1.378 (8)
C9—C10	1.351 (11)	C41—H41	0.9300
C9—H9	0.9300	C42—H42	0.9300
C10—C11	1.370 (11)	C43—C44	1.363 (9)
C10—H10	0.9300	C43—C48	1.370 (9)
C11—C12	1.399 (10)	C44—C45	1.392 (10)
C11—H11	0.9300	C44—H44	0.9300
C12—H12	0.9300	C45—C46	1.354 (11)
C13—C18	1.359 (8)	C45—H45	0.9300
C13—C14	1.378 (9)	C46—C47	1.353 (11)
C14—C15	1.395 (9)	C46—H46	0.9300
C14—H14	0.9300	C47—C48	1.384 (10)
C15—C16	1.382 (9)	C47—H47	0.9300
C15—H15	0.9300	C48—H48	0.9300
C16—C17	1.330 (9)	C49—C50	1.370 (8)
C16—H16	0.9300	C49—C54	1.386 (8)
C17—C18	1.405 (8)	C50—C51	1.385 (9)
C17—H17	0.9300	C50—H50	0.9300
C18—H18	0.9300	C51—C52	1.348 (10)
C19—C24	1.385 (8)	C51—H51	0.9300
C19—C20	1.406 (8)	C52—C53	1.360 (9)
C20—C21	1.382 (8)	C52—H52	0.9300
C20—H20	0.9300	C53—C54	1.384 (8)
C21—C22	1.360 (9)	C53—H53	0.9300
C21—H21	0.9300	C54—H54	0.9300

P2—Ag1—P3	118.38 (6)	C24—C19—P2	124.3 (5)
P2—Ag1—P1	114.66 (5)	C20—C19—P2	116.7 (5)
P3—Ag1—P1	119.17 (6)	C21—C20—C19	120.2 (7)
P2—Ag1—O1	92.9 (4)	C21—C20—H20	119.9
P3—Ag1—O1	87.0 (4)	C19—C20—H20	119.9
P1—Ag1—O1	118.0 (4)	C22—C21—C20	119.8 (7)
C7—P1—C1	102.0 (3)	C22—C21—H21	120.1
C7—P1—C13	102.4 (3)	C20—C21—H21	120.1
C1—P1—C13	104.4 (3)	C23—C22—C21	121.5 (8)
C7—P1—Ag1	114.7 (2)	C23—C22—H22	119.2
C1—P1—Ag1	115.9 (2)	C21—C22—H22	119.2
C13—P1—Ag1	115.6 (2)	C22—C23—C24	120.2 (8)
C19—P2—C31	106.2 (3)	C22—C23—H23	119.9
C19—P2—C25	102.8 (3)	C24—C23—H23	119.9
C31—P2—C25	101.0 (3)	C19—C24—C23	119.4 (7)
C19—P2—Ag1	107.2 (2)	C19—C24—H24	120.3
C31—P2—Ag1	118.4 (2)	C23—C24—H24	120.3
C25—P2—Ag1	119.49 (19)	C30—C25—C26	118.2 (6)
C43—P3—C49	107.0 (3)	C30—C25—P2	124.9 (5)
C43—P3—C37	102.4 (3)	C26—C25—P2	116.9 (5)
C49—P3—C37	101.8 (3)	C27—C26—C25	120.7 (6)
C43—P3—Ag1	104.3 (2)	C27—C26—H26	119.6
C49—P3—Ag1	115.9 (2)	C25—C26—H26	119.6
C37—P3—Ag1	123.8 (2)	C28—C27—C26	120.4 (7)
O2—Cl1—O4'	79.4 (12)	C28—C27—H27	119.8
O2—Cl1—O3'	79.0 (9)	C26—C27—H27	119.8
O4'—Cl1—O3'	113.9 (16)	C29—C28—C27	119.5 (7)
O2—Cl1—O2'	58.4 (7)	C29—C28—H28	120.3
O4'—Cl1—O2'	102.1 (12)	C27—C28—H28	120.3
O3'—Cl1—O2'	116.9 (11)	C28—C29—C30	121.0 (6)
O2—Cl1—O3	108.2 (7)	C28—C29—H29	119.5
O4'—Cl1—O3	113.4 (14)	C30—C29—H29	119.5
O3'—Cl1—O3	132.6 (9)	C25—C30—C29	120.1 (6)
O2'—Cl1—O3	49.8 (6)	C25—C30—H30	119.9
O2—Cl1—O1	110.2 (7)	C29—C30—H30	119.9
O4'—Cl1—O1	125.5 (14)	C36—C31—C32	118.1 (6)
O3'—Cl1—O1	31.9 (7)	C36—C31—P2	119.3 (5)
O2'—Cl1—O1	129.3 (9)	C32—C31—P2	122.5 (5)
O3—Cl1—O1	113.5 (8)	C31—C32—C33	121.0 (7)
O2—Cl1—O1'	153.5 (8)	C31—C32—H32	119.5
O4'—Cl1—O1'	121.1 (14)	C33—C32—H32	119.5
O3'—Cl1—O1'	104.0 (8)	C34—C33—C32	119.7 (8)
O2'—Cl1—O1'	98.5 (9)	C34—C33—H33	120.1
O3—Cl1—O1'	50.4 (7)	C32—C33—H33	120.1
O1—Cl1—O1'	73.1 (7)	C33—C34—C35	120.4 (7)
O2—Cl1—O4	112.7 (7)	C33—C34—H34	119.8
O4'—Cl1—O4	34.4 (10)	C35—C34—H34	119.8
O3'—Cl1—O4	111.0 (13)	C34—C35—C36	119.8 (7)
O2'—Cl1—O4	126.7 (9)	C34—C35—H35	120.1
O3—Cl1—O4	108.7 (11)	C36—C35—H35	120.1
O1—Cl1—O4	103.7 (11)	C31—C36—C35	121.0 (7)
O1'—Cl1—O4	91.1 (10)	C31—C36—H36	119.5
Cl1—O1—Ag1	126.0 (10)	C35—C36—H36	119.5
C2—C1—C6	117.3 (6)	C38—C37—C42	117.2 (6)
C2—C1—P1	119.7 (5)	C38—C37—P3	119.7 (5)
C6—C1—P1	123.0 (5)	C42—C37—P3	123.0 (5)
C1—C2—C3	121.1 (7)	C37—C38—C39	121.2 (6)
C1—C2—H2	119.5	C37—C38—H38	119.4
C3—C2—H2	119.5	C39—C38—H38	119.4
C4—C3—C2	120.9 (7)	C40—C39—C38	120.1 (7)
C4—C3—H3	119.6	C40—C39—H39	120.0
C2—C3—H3	119.6	C38—C39—H39	120.0
C3—C4—C5	119.5 (7)	C41—C40—C39	119.4 (7)
C3—C4—H4	120.2	C41—C40—H40	120.3
C5—C4—H4	120.2	C39—C40—H40	120.3
C4—C5—C6	119.7 (7)	C40—C41—C42	121.6 (7)
C4—C5—H5	120.2	C40—C41—H41	119.2
C6—C5—H5	120.2	C42—C41—H41	119.2
C5—C6—C1	121.4 (7)	C41—C42—C37	120.5 (7)
C1—C6—H6	119.3	C41—C42—H42	119.8
C8—C7—C12	117.1 (7)	C37—C42—H42	119.8
C8—C7—P1	117.7 (6)	C44—C43—C48	114.9 (7)
C12—C7—P1	125.1 (6)	C44—C43—P3	126.2 (6)
C7—C8—C9	122.8 (8)	C48—C43—P3	118.8 (6)
C7—C8—H8	118.6	C43—C44—C45	123.0 (8)
C9—C8—H8	118.6	C43—C44—H44	118.5
C10—C9—C8	119.0 (9)	C45—C44—H44	118.5
C10—C9—H9	120.5	C46—C45—C44	119.5 (9)
C8—C9—H9	120.5	C46—C45—H45	120.2
C9—C10—C11	120.2 (9)	C44—C45—H45	120.2
C9—C10—H10	119.9	C47—C46—C45	119.8 (9)
C11—C10—H10	119.9	C47—C46—H46	120.1
C10—C11—C12	119.3 (9)	C45—C46—H46	120.1
C10—C11—H11	120.3	C46—C47—C48	119.1 (9)
C12—C11—H11	120.3	C46—C47—H47	120.5
C7—C12—C11	121.0 (8)	C48—C47—H47	120.5
C7—C12—H12	119.5	C43—C48—C47	123.7 (8)
C11—C12—H12	119.5	C43—C48—H48	118.1
C18—C13—C14	117.6 (6)	C47—C48—H48	118.1
C18—C13—P1	119.1 (6)	C50—C49—C54	118.0 (6)
C14—C13—P1	123.4 (5)	C50—C49—P3	118.1 (6)
C13—C14—C15	121.4 (7)	C54—C49—P3	123.8 (5)
C13—C14—H14	119.3	C49—C50—C51	120.2 (7)
C15—C14—H14	119.3	C49—C50—H50	119.9
C16—C15—C14	119.0 (8)	C51—C50—H50	119.9
C16—C15—H15	120.5	C52—C51—C50	121.4 (8)
C14—C15—H15	120.5	C52—C51—H51	119.3
C17—C16—C15	120.3 (7)	C50—C51—H51	119.3
C17—C16—H16	119.9	C51—C52—C53	119.4 (8)
C15—C16—H16	119.9	C51—C52—H52	120.3
C16—C17—C18	120.3 (7)	C53—C52—H52	120.3
C16—C17—H17	119.9	C52—C53—C54	120.2 (7)
C18—C17—H17	119.9	C52—C53—H53	119.9
C13—C18—C17	121.4 (7)	C54—C53—H53	119.9
C13—C18—H18	119.3	C53—C54—C49	120.8 (7)
C17—C18—H18	119.3	C53—C54—H54	119.6
C24—C19—C20	118.8 (6)	C49—C54—H54	119.6

P2—Ag1—P1—C7	41.9 (3)	C31—P2—C19—C20	−176.2 (5)
P3—Ag1—P1—C7	−169.3 (2)	C25—P2—C19—C20	−70.6 (5)
O1—Ag1—P1—C7	−66.1 (5)	Ag1—P2—C19—C20	56.2 (5)
P2—Ag1—P1—C1	160.5 (2)	C24—C19—C20—C21	−2.5 (10)
P3—Ag1—P1—C1	−50.7 (2)	P2—C19—C20—C21	−178.6 (5)
O1—Ag1—P1—C1	52.5 (5)	C19—C20—C21—C22	2.5 (11)
P2—Ag1—P1—C13	−77.0 (2)	C20—C21—C22—C23	−1.2 (13)
P3—Ag1—P1—C13	71.8 (2)	C21—C22—C23—C24	0.0 (13)
O1—Ag1—P1—C13	175.1 (5)	C20—C19—C24—C23	1.3 (10)
P3—Ag1—P2—C19	−94.4 (2)	P2—C19—C24—C23	177.0 (5)
P1—Ag1—P2—C19	54.6 (2)	C22—C23—C24—C19	0.0 (11)
O1—Ag1—P2—C19	177.4 (5)	C19—P2—C25—C30	−0.2 (6)
P3—Ag1—P2—C31	145.6 (2)	C31—P2—C25—C30	109.5 (6)
P1—Ag1—P2—C31	−65.4 (2)	Ag1—P2—C25—C30	−118.7 (5)
O1—Ag1—P2—C31	57.4 (4)	C19—P2—C25—C26	−179.1 (5)
P3—Ag1—P2—C25	21.9 (2)	C31—P2—C25—C26	−69.4 (5)
P1—Ag1—P2—C25	170.9 (2)	Ag1—P2—C25—C26	62.4 (5)
O1—Ag1—P2—C25	−66.3 (5)	C30—C25—C26—C27	−0.6 (10)
P2—Ag1—P3—C43	80.6 (3)	P2—C25—C26—C27	178.4 (5)
P1—Ag1—P3—C43	−67.0 (3)	C25—C26—C27—C28	1.3 (11)
O1—Ag1—P3—C43	172.3 (5)	C26—C27—C28—C29	0.0 (11)
P2—Ag1—P3—C49	−162.1 (2)	C27—C28—C29—C30	−2.0 (11)
P1—Ag1—P3—C49	50.3 (3)	C26—C25—C30—C29	−1.4 (9)
O1—Ag1—P3—C49	−70.4 (5)	P2—C25—C30—C29	179.8 (5)
P2—Ag1—P3—C37	−35.3 (2)	C28—C29—C30—C25	2.7 (11)
P1—Ag1—P3—C37	177.0 (2)	C19—P2—C31—C36	−114.7 (5)
O1—Ag1—P3—C37	56.4 (5)	C25—P2—C31—C36	138.3 (5)
O2—Cl1—O1—Ag1	129.0 (9)	Ag1—P2—C31—C36	5.8 (6)
O4'—Cl1—O1—Ag1	−139.7 (17)	C19—P2—C31—C32	68.7 (6)
O3'—Cl1—O1—Ag1	142 (3)	C25—P2—C31—C32	−38.3 (6)
O2'—Cl1—O1—Ag1	64.0 (16)	Ag1—P2—C31—C32	−170.8 (4)
O3—Cl1—O1—Ag1	7.6 (14)	C36—C31—C32—C33	−0.4 (10)
O1'—Cl1—O1—Ag1	−23.2 (10)	P2—C31—C32—C33	176.2 (5)
O4—Cl1—O1—Ag1	−110.2 (12)	C31—C32—C33—C34	−0.7 (11)
P2—Ag1—O1—Cl1	−106.1 (11)	C32—C33—C34—C35	1.6 (12)
P3—Ag1—O1—Cl1	135.6 (12)	C33—C34—C35—C36	−1.4 (12)
P1—Ag1—O1—Cl1	13.9 (13)	C32—C31—C36—C35	0.6 (10)
C7—P1—C1—C2	146.1 (6)	P2—C31—C36—C35	−176.2 (5)
C13—P1—C1—C2	−107.6 (6)	C34—C35—C36—C31	0.3 (11)
Ag1—P1—C1—C2	20.7 (7)	C43—P3—C37—C38	−79.7 (6)
C7—P1—C1—C6	−33.1 (7)	C49—P3—C37—C38	169.7 (5)
C13—P1—C1—C6	73.2 (7)	Ag1—P3—C37—C38	37.1 (6)
Ag1—P1—C1—C6	−158.5 (5)	C43—P3—C37—C42	99.3 (5)
C6—C1—C2—C3	−1.8 (11)	C49—P3—C37—C42	−11.3 (6)
P1—C1—C2—C3	179.0 (6)	Ag1—P3—C37—C42	−143.8 (4)
C1—C2—C3—C4	−0.5 (13)	C42—C37—C38—C39	−0.6 (9)
C2—C3—C4—C5	2.4 (14)	P3—C37—C38—C39	178.5 (5)
C3—C4—C5—C6	−1.9 (13)	C37—C38—C39—C40	0.1 (10)
C4—C5—C6—C1	−0.4 (12)	C38—C39—C40—C41	1.1 (10)
C2—C1—C6—C5	2.3 (11)	C39—C40—C41—C42	−1.9 (11)
P1—C1—C6—C5	−178.6 (6)	C40—C41—C42—C37	1.5 (11)
C1—P1—C7—C8	−59.7 (7)	C38—C37—C42—C41	−0.2 (9)
C13—P1—C7—C8	−167.6 (6)	P3—C37—C42—C41	−179.3 (5)
Ag1—P1—C7—C8	66.4 (6)	C49—P3—C43—C44	97.5 (7)
C1—P1—C7—C12	118.7 (7)	C37—P3—C43—C44	−9.2 (8)
C13—P1—C7—C12	10.9 (7)	Ag1—P3—C43—C44	−139.3 (6)
Ag1—P1—C7—C12	−115.1 (6)	C49—P3—C43—C48	−87.6 (6)
C12—C7—C8—C9	0.3 (13)	C37—P3—C43—C48	165.8 (6)
P1—C7—C8—C9	178.8 (7)	Ag1—P3—C43—C48	35.7 (7)
C7—C8—C9—C10	5.1 (15)	C48—C43—C44—C45	0.4 (12)
C8—C9—C10—C11	−8.9 (16)	P3—C43—C44—C45	175.5 (7)
C9—C10—C11—C12	7.4 (16)	C43—C44—C45—C46	−0.6 (15)
C8—C7—C12—C11	−1.8 (12)	C44—C45—C46—C47	1.3 (16)
P1—C7—C12—C11	179.7 (7)	C45—C46—C47—C48	−1.8 (16)
C10—C11—C12—C7	−1.9 (14)	C44—C43—C48—C47	−0.9 (13)
C7—P1—C13—C18	−83.5 (6)	P3—C43—C48—C47	−176.5 (7)
C1—P1—C13—C18	170.5 (5)	C46—C47—C48—C43	1.7 (15)
Ag1—P1—C13—C18	42.0 (6)	C43—P3—C49—C50	168.3 (5)
C7—P1—C13—C14	96.3 (6)	C37—P3—C49—C50	−84.6 (6)
C1—P1—C13—C14	−9.7 (7)	Ag1—P3—C49—C50	52.5 (6)
Ag1—P1—C13—C14	−138.2 (6)	C43—P3—C49—C54	−15.9 (7)
C18—C13—C14—C15	1.4 (11)	C37—P3—C49—C54	91.1 (6)
P1—C13—C14—C15	−178.4 (6)	Ag1—P3—C49—C54	−131.8 (5)
C13—C14—C15—C16	0.9 (12)	C54—C49—C50—C51	−0.5 (10)
C14—C15—C16—C17	−2.2 (12)	P3—C49—C50—C51	175.5 (6)
C15—C16—C17—C18	1.4 (12)	C49—C50—C51—C52	0.9 (12)
C14—C13—C18—C17	−2.3 (10)	C50—C51—C52—C53	−0.8 (13)
P1—C13—C18—C17	177.5 (5)	C51—C52—C53—C54	0.3 (13)
C16—C17—C18—C13	1.0 (11)	C52—C53—C54—C49	0.1 (11)
C31—P2—C19—C24	7.9 (6)	C50—C49—C54—C53	0.0 (10)
C25—P2—C19—C24	113.5 (6)	P3—C49—C54—C53	−175.8 (5)
Ag1—P2—C19—C24	−119.6 (5)

Experimental details

Crystal data
Chemical formula	[Ag(C₁₈H₁₅P)₃(ClO₄)]
M_r	994.13
Crystal system, space group	Monoclinic, P2₁/n
Temperature (K)	298
a, b, c (Å)	18.066 (2), 13.7779 (16), 19.064 (2)
β (°)	94.132 (2)
V (Å³)	4733.0 (9)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	0.63
Crystal size (mm)	0.19 × 0.18 × 0.17

Data collection
Diffractometer	Bruker SMART CCD area-detector
Absorption correction	Multi-scan (SADABS; Sheldrick, 2008)
T_min, T_max	0.890, 0.901
No. of measured, independent and observed [I > 2σ(I)] reflections	23792, 8339, 4010
R_int	0.069
(sin θ/λ)_max (Å⁻¹)	0.595

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.057, 0.128, 1.03
No. of reflections	8339
No. of parameters	605
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.85, −1.07

Computer programs: SMART (Bruker, 2007), SAINT (Bruker, 2007), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

Selected geometric parameters (Å, º) top

Ag1—P2	2.5076 (16)	Ag1—P1	2.5663 (17)
Ag1—P3	2.5450 (17)	Ag1—O1	2.608 (12)

P2—Ag1—P3	118.38 (6)	P2—Ag1—O1	92.9 (4)
P2—Ag1—P1	114.66 (5)	P3—Ag1—O1	87.0 (4)
P3—Ag1—P1	119.17 (6)	P1—Ag1—O1	118.0 (4)

Acknowledgements

This work was supported by the National Keystone Basic Research Program (973 Program) under grants Nos. 2007CB310408 & 2006CB302901, and the Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the jurisdiction of Beijing Municipality, and by the State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences.

References

Awaleh, M. O., Badia, A. & Brisse, F. (2005). Inorg. Chem. 44, 7833–7845. Web of Science CSD CrossRef PubMed CAS Google Scholar
Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Di Nicola, C., Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007). Inorg. Chim. Acta, 360, 1433–1450. Web of Science CSD CrossRef CAS Google Scholar
Effendy, Marchetti, F., Pettinari, C., Pettinari, R., Skelton, B.W &, White, A. H. (2007a). Inorg. Chim. Acta, 360, 1388–1413. Google Scholar
Effendy, Marchetti, F., Pettinari, C., Pettinari, R., Skelton, B. W. & White, A. H. (2007c). Inorg. Chim. Acta, 360, 1451–1465. Web of Science CSD CrossRef CAS Google Scholar
Effendy, Marchetti, F., Pettinari, C., Skelton, B. W. & White, A. H. (2007b). Inorg. Chim. Acta, 360, 1424–1432. Web of Science CSD CrossRef CAS Google Scholar
Jin, Q. H., Hu, K. Y., Song, L. L., Zhang C. L., Zuo, X. & Lu, X. M. (2010). Polyhedron, 29, 441–445. Google Scholar
Pettinari, C., Ngoune, J., Skelton, B. W. & White, A. H. (2007). Inorg. Chem. Commun. 10, 329–331. Web of Science CSD CrossRef CAS Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar