[μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ2P:P′]nona­carbonyl-1κ3C,2κ3C,3κ3C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate

Shawkataly, O. bin; Khan, I.A.; Hafiz Malik, H.A.; Yeap, C.S.; Fun, H.-K.

doi:10.1107/S160053681100081X

metal-organic compounds

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ISSN: 2056-9890

Volume 67| Part 2| February 2011| Pages m195-m196

doi:10.1107/S160053681100081X

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[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ²P:P′]nonacarbonyl-1κ³C,2κ³C,3κ³C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate

Omar bin Shawkataly,^a ^*‡ Imthyaz Ahmed Khan,^a § H. A. Hafiz Malik,^a Chin Sing Yeap ^b ¶ and Hoong-Kun Fun ^b ‡‡

^aChemical Sciences Programme, School of Distance Education, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia, and ^bX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
^*Correspondence e-mail: omarsa@usm.my

(Received 22 December 2010; accepted 6 January 2011; online 15 January 2011)

In the title compound, [Ru₃(C₂₉H₃₀P₂)(C₁₉H₁₇PS)(CO)₉]·0.25CH₂Cl₂, the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru₃ triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenylphosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, molecules are linked into [001] chains via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions also occur.

Related literature

For general background to triangulo-triruthenium derivatives, see: Bruce et al. (1985 , 1988a ,b ). For related structures, see: Shawkataly et al. (1998 , 2004 , 2010 ). For the synthesis of diphenyl((phenylthio)methyl)phosphine, see: Sanger (1983 ) and for that of bis(di-o-tolylphosphanyl)methane, see: Filby et al. (2006 ). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ).

Experimental

Crystal data

[Ru₃(C₂₉H₃₀P₂)(C₁₉H₁₇PS)(CO)₉]·0.25CH₂Cl₂
M_r = 1325.36
Monoclinic, P 2₁ /c
a = 11.022 (2) Å
b = 28.576 (6) Å
c = 18.454 (4) Å
β = 106.069 (3)°
V = 5585 (2) Å³
Z = 4
Mo Kα radiation
μ = 1.00 mm⁻¹
T = 100 K
0.15 × 0.09 × 0.08 mm

Data collection

Bruker APEXII DUO CCD diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2009 ) T_min = 0.862, T_max = 0.928
39779 measured reflections
12798 independent reflections
8500 reflections with I > 2σ(I)
R_int = 0.066

Refinement

R[F² > 2σ(F²)] = 0.040
wR(F²) = 0.092
S = 1.02
12798 reflections
699 parameters
180 restraints
H-atom parameters constrained
Δρ_max = 0.55 e Å⁻³
Δρ_min = −0.66 e Å⁻³

Table 1
Selected bond lengths (Å)

Ru1—P1	2.3594 (11)
Ru2—P2	2.3476 (11)
Ru3—P3	2.3289 (12)

Table 2
Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the C7–C12 and C14–C19 benzene rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C9—H9A⋯O1ⁱ	0.93	2.53	3.330 (5)	144
C29—H29B⋯Cg1ⁱⁱ	0.96	2.97	3.554 (5)	121
C40—H40A⋯Cg1ⁱⁱⁱ	0.93	2.92	3.670 (6)	139
C58—H58A⋯Cg2^iv	0.97	2.67	3.585 (19)	158
Symmetry codes: (i) $[x, -y+{\script{1\over 2}}, z+{\script{1\over 2}}]$ ; (ii) x+1, y, z; (iii) $[-x, y-{\script{1\over 2}}, -z+{\script{1\over 2}}]$ ; (iv) $[x, -y-{\script{1\over 2}}, z-{\script{1\over 2}}]$ .

Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009 ).

Supporting information

Crystal structure: contains datablocks global, I. DOI: 10.1107/S160053681100081X/hb5785sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S160053681100081X/hb5785Isup2.hkl

checkCIF report

Comment top

A large number of substituted derivatives, Ru₃(CO)_12-nL_n (L = group 15 ligand) have been reported (Bruce et al., 1985, 1988a,b). As part of our study on the substitution of transition metal-carbonyl clusters with mixed-ligand complexes, we have published several structures of triangulo-triruthenium-carbonyl clusters containing mixed P/As and P/Sb ligands (Shawkataly et al., 1998, 2004, 2010). Herein we report the synthesis and structure of the title compound.

The asymmetric unit of title triangulo-triruthenium compound consists of one triangulo-triruthenium complex molecule and one-quarter molecule of dichloromethane solvent. The dichloromethane solvent lies across a crystallographic inversion center leading to the disorder of this solvent molecule over two positions. The bis(di-o-tolylphosphanyl)methane ligand bridges the Ru1–Ru2 bond and the monodentate phosphine ligand bonds to the Ru3 atom. Both phosphine ligands are equatorial with respect to the Ru₃ triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands (Fig 1). The dihedral angles between the two benzene rings (C1–C6/C7–C12 and C14–C19/C20–C25) are 68.4 (2) and 71.5 (2)° for the two diphenylphosphanyl groups respectively.

In the crystal, the molecules are linked into one-dimensional chains along c axis via intermolecular C9—H9A···O1 hydrogen bonds (Fig. 2, Table 1). Weak intermolecular C—H···π (Table 1) interactions stabilize the crystal structure.

Related literature top

For general background to triangulo-triruthenium derivatives, see: Bruce et al. (1985, 1988a,b). For related structures, see: Shawkataly et al. (1998, 2004, 2010). For the synthesis of diphenyl((phenylthio)methyl)phosphine, see: Sanger (1983) and for that of bis(di-o-tolylphosphanyl)methane, see: Filby et al. (2006). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986).

Experimental top

All manipulations were performed under a dry oxygen-free nitrogen atmosphere using standard Schlenk techniques. All solvents were dried over sodium and distilled from sodium benzophenone ketyl under dry oxygen free nitrogen. Diphenyl((phenylthio)methyl)phosphine (Sanger, 1983) and bis(di-o-tolylphosphanyl)methane (Filby et al., 2006) were prepared by the reported procedures. Ru₃(CO)₁₀(µ-(2-CH₃C₆H₄)₂PCH₂P(2-CH₃C₆H₄)₂) was prepared by reacting Ru₃(CO)₁₂ with bis(di-o-tolylphosphanyl)methane in presence of sodium benzophenone ketyl radical in THF. The title compound was obtained by refluxing equimolar quantities of Ru₃(CO)₁₀(µ-(2-(CH₃C₆H₄)₂PCH₂P(2-CH₃C₆H₄)₂) and P(CH₂SC₆H₅)(C₆H₅)₂ in hexane under nitrogen atmosphere. Orange blocks of the title compound were grown by slow solvent / solvent diffusion of CH₃OH into CH₂Cl₂.

Computing details top

Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009).

Figures top

	Fig. 1. The molecular structure of the title compound with 50% probability ellipsoids for non-H atoms. Minor disorder component is shown with open bonds. Atoms with suffix X are generated by the symmetry operation (-x, -y, 1 - z).
	Fig. 2. The packing of the title compound, viewed down the a axis, showing the molecules linked into chains along c axis. Hydrogen atoms not involved in the hydrogen-bonding (dashed lines), minor disorder component and solvent molecules have been omitted for clarity.

[µ-Bis(di-o-tolylphosphanyl)methane- 1:2κ²P:P']nonacarbonyl- 1κ³C,2κ³C,3κ³C- [diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo- triruthenium(0) dichloromethane 0.25-solvate top

Crystal data top

[Ru₃(C₂₉H₃₀P₂)(C₁₉H₁₇PS)(CO)₉]·0.25CH₂Cl₂	F(000) = 2658
M_r = 1325.36	D_x = 1.576 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 5023 reflections
a = 11.022 (2) Å	θ = 2.4–27.9°
b = 28.576 (6) Å	µ = 1.00 mm⁻¹
c = 18.454 (4) Å	T = 100 K
β = 106.069 (3)°	Block, orange
V = 5585 (2) Å³	0.15 × 0.09 × 0.08 mm
Z = 4

Data collection top

Bruker APEXII DUO CCD diffractometer	12798 independent reflections
Radiation source: fine-focus sealed tube	8500 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.066
ϕ and ω scans	θ_max = 27.5°, θ_min = 2.4°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −12→14
T_min = 0.862, T_max = 0.928	k = −35→37
39779 measured reflections	l = −23→23

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.092	H-atom parameters constrained
S = 1.02	w = 1/[σ²(F_o²) + (0.0285P)² + 2.1069P] where P = (F_o² + 2F_c²)/3
12798 reflections	(Δ/σ)_max = 0.001
699 parameters	Δρ_max = 0.55 e Å⁻³
180 restraints	Δρ_min = −0.66 e Å⁻³

Crystal data top

[Ru₃(C₂₉H₃₀P₂)(C₁₉H₁₇PS)(CO)₉]·0.25CH₂Cl₂	V = 5585 (2) Å³
M_r = 1325.36	Z = 4
Monoclinic, P2₁/c	Mo Kα radiation
a = 11.022 (2) Å	µ = 1.00 mm⁻¹
b = 28.576 (6) Å	T = 100 K
c = 18.454 (4) Å	0.15 × 0.09 × 0.08 mm
β = 106.069 (3)°

Data collection top

Bruker APEXII DUO CCD diffractometer	12798 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 2009)	8500 reflections with I > 2σ(I)
T_min = 0.862, T_max = 0.928	R_int = 0.066
39779 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.040	180 restraints
wR(F²) = 0.092	H-atom parameters constrained
S = 1.02	Δρ_max = 0.55 e Å⁻³
12798 reflections	Δρ_min = −0.66 e Å⁻³
699 parameters

Special details top

Experimental. The crystal was placed in the cold stream of an Oxford Cryosystems Cobra open-flow nitrogen cryostat (Cosier & Glazer, 1986) operating at 100.0 (1) K.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ru1	−0.14245 (3)	0.203379 (11)	0.156805 (15)	0.01570 (8)
Ru2	0.09910 (3)	0.204897 (11)	0.129353 (15)	0.01651 (8)
Ru3	−0.01551 (3)	0.117561 (11)	0.141835 (17)	0.01934 (8)
S1	−0.34596 (12)	0.01710 (4)	0.22273 (7)	0.0368 (3)
P1	−0.16719 (9)	0.28466 (4)	0.13530 (5)	0.0168 (2)
P2	0.12747 (9)	0.28484 (3)	0.15843 (5)	0.0169 (2)
P3	−0.16771 (10)	0.06123 (4)	0.14285 (6)	0.0209 (2)
O1	−0.3047 (3)	0.18309 (10)	−0.00412 (14)	0.0258 (6)
O2	−0.3753 (3)	0.17910 (10)	0.20596 (15)	0.0274 (7)
O3	0.0073 (2)	0.20921 (10)	0.32350 (14)	0.0266 (7)
O4	0.2607 (3)	0.17983 (10)	0.28865 (14)	0.0288 (7)
O5	0.3265 (3)	0.17506 (11)	0.07823 (16)	0.0358 (8)
O6	−0.0517 (2)	0.22118 (10)	−0.03527 (14)	0.0251 (6)
O7	−0.1001 (3)	0.11920 (10)	−0.03116 (15)	0.0311 (7)
O8	0.2027 (3)	0.05687 (14)	0.1291 (2)	0.0571 (10)
O9	0.0685 (3)	0.10898 (10)	0.31393 (16)	0.0409 (8)
C1	−0.2515 (3)	0.29940 (13)	0.03786 (19)	0.0174 (8)
C2	−0.1848 (4)	0.31381 (14)	−0.0127 (2)	0.0243 (9)
H2A	−0.0973	0.3161	0.0038	0.029*
C3	−0.2464 (4)	0.32457 (16)	−0.0863 (2)	0.0330 (11)
H3A	−0.2002	0.3338	−0.1191	0.040*
C4	−0.3756 (4)	0.32185 (16)	−0.1116 (2)	0.0349 (11)
H4A	−0.4174	0.3302	−0.1609	0.042*
C5	−0.4422 (4)	0.30662 (14)	−0.0634 (2)	0.0282 (10)
H5A	−0.5296	0.3044	−0.0811	0.034*
C6	−0.3832 (3)	0.29441 (14)	0.0110 (2)	0.0203 (8)
C7	−0.2427 (3)	0.31845 (14)	0.1965 (2)	0.0194 (8)
C8	−0.2342 (3)	0.29804 (14)	0.2660 (2)	0.0213 (9)
H8A	−0.1986	0.2684	0.2761	0.026*
C9	−0.2771 (4)	0.32042 (15)	0.3208 (2)	0.0251 (9)
H9A	−0.2676	0.3065	0.3676	0.030*
C10	−0.3339 (4)	0.36350 (16)	0.3049 (2)	0.0323 (11)
H10A	−0.3658	0.3785	0.3405	0.039*
C11	−0.3436 (4)	0.38439 (15)	0.2366 (2)	0.0293 (10)
H11A	−0.3829	0.4134	0.2267	0.035*
C12	−0.2963 (4)	0.36350 (14)	0.1813 (2)	0.0244 (9)
C13	−0.0186 (3)	0.31861 (13)	0.1525 (2)	0.0230 (9)
H13A	−0.0288	0.3414	0.1123	0.028*
H13B	−0.0068	0.3358	0.1993	0.028*
C14	0.1976 (4)	0.32245 (14)	0.0999 (2)	0.0233 (9)
C15	0.1957 (3)	0.30541 (15)	0.0289 (2)	0.0229 (9)
H15A	0.1674	0.2750	0.0161	0.028*
C16	0.2342 (4)	0.33195 (16)	−0.0233 (2)	0.0319 (11)
H16A	0.2295	0.3201	−0.0709	0.038*
C17	0.2792 (5)	0.37592 (18)	−0.0034 (3)	0.0474 (14)
H17A	0.3068	0.3941	−0.0375	0.057*
C18	0.2841 (5)	0.39359 (18)	0.0663 (3)	0.0490 (14)
H18A	0.3168	0.4234	0.0786	0.059*
C19	0.2417 (4)	0.36852 (15)	0.1195 (2)	0.0319 (10)
C20	0.2198 (3)	0.29290 (13)	0.25651 (19)	0.0175 (8)
C21	0.1587 (4)	0.29948 (13)	0.3124 (2)	0.0203 (8)
H21A	0.0710	0.3009	0.2989	0.024*
C22	0.2255 (4)	0.30390 (13)	0.3873 (2)	0.0242 (9)
H22A	0.1831	0.3081	0.4239	0.029*
C23	0.3561 (4)	0.30198 (14)	0.4075 (2)	0.0260 (10)
H23A	0.4022	0.3064	0.4574	0.031*
C24	0.4167 (4)	0.29364 (14)	0.3536 (2)	0.0233 (9)
H24A	0.5044	0.2917	0.3680	0.028*
C25	0.3519 (3)	0.28793 (13)	0.2774 (2)	0.0198 (8)
C26	−0.4634 (4)	0.27819 (15)	0.0604 (2)	0.0263 (10)
H26A	−0.5421	0.2662	0.0294	0.039*
H26B	−0.4794	0.3040	0.0897	0.039*
H26C	−0.4198	0.2540	0.0936	0.039*
C27	−0.3046 (4)	0.39113 (15)	0.1106 (2)	0.0313 (10)
H27A	−0.3243	0.4231	0.1184	0.047*
H27B	−0.3697	0.3782	0.0697	0.047*
H27C	−0.2252	0.3897	0.0988	0.047*
C28	0.2465 (5)	0.39181 (16)	0.1941 (3)	0.0437 (13)
H28A	0.2626	0.4247	0.1909	0.065*
H28B	0.3128	0.3780	0.2334	0.065*
H28C	0.1672	0.3875	0.2053	0.065*
C29	0.4268 (4)	0.27706 (16)	0.2230 (2)	0.0300 (10)
H29A	0.5022	0.2605	0.2488	0.045*
H29B	0.4491	0.3057	0.2027	0.045*
H29C	0.3772	0.2580	0.1828	0.045*
C30	−0.2357 (4)	0.06438 (14)	0.2232 (2)	0.0249 (9)
H30A	−0.1680	0.0632	0.2698	0.030*
H30B	−0.2789	0.0941	0.2218	0.030*
C31A	−0.3953 (4)	0.03194 (16)	0.3037 (2)	0.030 (5)	0.53 (4)
C32A	−0.5173 (9)	0.0494 (7)	0.2898 (3)	0.052 (4)	0.53 (4)
H32A	−0.5660	0.0542	0.2405	0.063*	0.53 (4)
C33A	−0.5664 (6)	0.0597 (9)	0.3497 (5)	0.065 (4)	0.53 (4)
H33A	−0.6480	0.0714	0.3405	0.078*	0.53 (4)
C34A	−0.4935 (6)	0.0526 (5)	0.4234 (4)	0.063 (4)	0.53 (4)
H34A	−0.5264	0.0595	0.4635	0.076*	0.53 (4)
C35A	−0.3715 (10)	0.03513 (18)	0.43726 (15)	0.046 (4)	0.53 (4)
H35A	−0.3228	0.0303	0.4866	0.056*	0.53 (4)
C36A	−0.3224 (7)	0.0248 (3)	0.3774 (3)	0.035 (3)	0.53 (4)
H36A	−0.2408	0.0131	0.3866	0.042*	0.53 (4)
C31B	−0.4008 (4)	0.02967 (18)	0.30122 (19)	0.033 (6)	0.47 (4)
C32B	−0.5287 (3)	0.0312 (7)	0.2968 (4)	0.058 (4)	0.47 (4)
H32B	−0.5885	0.0287	0.2502	0.069*	0.47 (4)
C33B	−0.5671 (6)	0.0365 (9)	0.3620 (6)	0.065 (4)	0.47 (4)
H33B	−0.6527	0.0375	0.3590	0.078*	0.47 (4)
C34B	−0.4777 (10)	0.0402 (5)	0.4316 (4)	0.058 (4)	0.47 (4)
H34B	−0.5035	0.0437	0.4752	0.070*	0.47 (4)
C35B	−0.3498 (9)	0.0387 (3)	0.43603 (19)	0.060 (5)	0.47 (4)
H35B	−0.2900	0.0412	0.4826	0.072*	0.47 (4)
C36B	−0.3114 (4)	0.0334 (4)	0.3708 (4)	0.053 (4)	0.47 (4)
H36B	−0.2258	0.0324	0.3738	0.063*	0.47 (4)
C37	−0.1059 (4)	0.00157 (14)	0.1538 (2)	0.0248 (9)
C38	0.0052 (5)	−0.00675 (16)	0.2102 (3)	0.0411 (12)
H38A	0.0448	0.0180	0.2403	0.049*
C39	0.0580 (5)	−0.05091 (16)	0.2224 (3)	0.0457 (13)
H39A	0.1307	−0.0559	0.2616	0.055*
C40	0.0030 (5)	−0.08741 (16)	0.1765 (3)	0.0384 (12)
H40A	0.0404	−0.1169	0.1827	0.046*
C41	−0.1074 (5)	−0.07998 (16)	0.1217 (3)	0.0382 (11)
H41A	−0.1461	−0.1049	0.0917	0.046*
C42	−0.1626 (4)	−0.03638 (14)	0.1100 (2)	0.0311 (10)
H42A	−0.2382	−0.0323	0.0726	0.037*
C43	−0.3036 (4)	0.06080 (13)	0.0597 (2)	0.0221 (9)
C44	−0.2919 (4)	0.04285 (14)	−0.0075 (2)	0.0280 (10)
H44A	−0.2155	0.0300	−0.0097	0.034*
C45	−0.3939 (4)	0.04392 (15)	−0.0721 (2)	0.0336 (11)
H45A	−0.3865	0.0304	−0.1165	0.040*
C46	−0.5057 (4)	0.06497 (15)	−0.0703 (2)	0.0347 (11)
H46A	−0.5732	0.0663	−0.1137	0.042*
C47	−0.5163 (4)	0.08400 (15)	−0.0035 (3)	0.0346 (11)
H47A	−0.5913	0.0984	−0.0021	0.041*
C48	−0.4170 (4)	0.08181 (14)	0.0613 (2)	0.0276 (10)
H48A	−0.4258	0.0944	0.1061	0.033*
C49	−0.2362 (3)	0.18993 (13)	0.0545 (2)	0.0190 (8)
C50	−0.2871 (4)	0.18831 (13)	0.1871 (2)	0.0205 (9)
C51	−0.0414 (3)	0.20681 (14)	0.2606 (2)	0.0198 (8)
C52	0.1944 (3)	0.18872 (13)	0.2310 (2)	0.0200 (8)
C53	0.2411 (4)	0.18684 (15)	0.0974 (2)	0.0250 (9)
C54	−0.0023 (3)	0.21497 (13)	0.0274 (2)	0.0199 (8)
C55	−0.0706 (4)	0.12134 (14)	0.0332 (2)	0.0238 (9)
C56	0.1201 (4)	0.07923 (17)	0.1345 (3)	0.0364 (11)
C57	0.0378 (4)	0.11576 (14)	0.2504 (2)	0.0287 (10)
Cl1	0.0339 (6)	0.0158 (2)	0.4242 (3)	0.0608 (15)*	0.25
Cl2	−0.0173 (6)	0.0494 (2)	0.5618 (3)	0.0599 (15)*	0.25
C58	−0.0061 (18)	0.0667 (6)	0.4726 (10)	0.036 (4)*	0.25
H58A	0.0585	0.0905	0.4781	0.043*	0.25
H58B	−0.0859	0.0798	0.4434	0.043*	0.25

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ru1	0.01344 (15)	0.02026 (17)	0.01309 (14)	0.00001 (13)	0.00318 (11)	0.00101 (12)
Ru2	0.01358 (16)	0.02206 (18)	0.01362 (14)	−0.00093 (13)	0.00329 (11)	−0.00147 (12)
Ru3	0.01813 (16)	0.01951 (17)	0.01903 (15)	0.00044 (14)	0.00291 (11)	−0.00097 (13)
S1	0.0514 (8)	0.0312 (7)	0.0345 (6)	−0.0142 (6)	0.0228 (5)	−0.0077 (5)
P1	0.0152 (5)	0.0225 (6)	0.0118 (4)	0.0006 (4)	0.0023 (4)	−0.0001 (4)
P2	0.0138 (5)	0.0219 (6)	0.0145 (4)	−0.0024 (4)	0.0033 (4)	−0.0008 (4)
P3	0.0235 (5)	0.0171 (5)	0.0210 (5)	0.0005 (4)	0.0042 (4)	0.0006 (4)
O1	0.0249 (15)	0.0328 (17)	0.0192 (14)	−0.0014 (13)	0.0049 (12)	−0.0026 (12)
O2	0.0223 (16)	0.0363 (18)	0.0274 (15)	−0.0035 (13)	0.0132 (12)	0.0007 (13)
O3	0.0235 (15)	0.0366 (18)	0.0164 (13)	0.0010 (13)	−0.0001 (11)	0.0018 (12)
O4	0.0269 (16)	0.0392 (18)	0.0165 (14)	−0.0008 (14)	−0.0004 (12)	0.0041 (12)
O5	0.0248 (17)	0.057 (2)	0.0290 (17)	0.0106 (16)	0.0135 (13)	0.0004 (15)
O6	0.0221 (15)	0.0332 (17)	0.0177 (14)	−0.0031 (13)	0.0018 (11)	0.0004 (12)
O7	0.0423 (18)	0.0302 (17)	0.0206 (15)	−0.0017 (14)	0.0085 (13)	−0.0015 (12)
O8	0.035 (2)	0.069 (3)	0.068 (3)	0.0206 (19)	0.0147 (18)	−0.007 (2)
O9	0.059 (2)	0.0323 (19)	0.0230 (16)	−0.0101 (16)	−0.0034 (14)	0.0057 (13)
C1	0.0186 (19)	0.021 (2)	0.0121 (16)	0.0061 (16)	0.0033 (14)	0.0006 (15)
C2	0.019 (2)	0.029 (2)	0.025 (2)	0.0048 (18)	0.0072 (16)	0.0049 (17)
C3	0.040 (3)	0.043 (3)	0.020 (2)	0.012 (2)	0.0157 (19)	0.0071 (19)
C4	0.035 (3)	0.050 (3)	0.017 (2)	0.009 (2)	0.0019 (18)	0.0042 (19)
C5	0.024 (2)	0.035 (3)	0.022 (2)	0.0042 (19)	−0.0001 (16)	−0.0031 (18)
C6	0.020 (2)	0.025 (2)	0.0153 (17)	0.0034 (17)	0.0031 (14)	−0.0018 (16)
C7	0.0123 (19)	0.028 (2)	0.0167 (18)	−0.0023 (16)	0.0019 (14)	−0.0076 (16)
C8	0.0134 (19)	0.029 (2)	0.0196 (18)	0.0023 (17)	0.0011 (14)	−0.0019 (17)
C9	0.019 (2)	0.040 (3)	0.0171 (19)	−0.0014 (19)	0.0052 (15)	−0.0060 (17)
C10	0.027 (2)	0.039 (3)	0.034 (2)	−0.003 (2)	0.0134 (19)	−0.018 (2)
C11	0.030 (2)	0.024 (2)	0.033 (2)	0.0019 (19)	0.0078 (18)	−0.0102 (18)
C12	0.021 (2)	0.028 (2)	0.023 (2)	−0.0015 (18)	0.0033 (16)	−0.0019 (17)
C13	0.020 (2)	0.020 (2)	0.027 (2)	0.0002 (18)	0.0036 (16)	0.0004 (17)
C14	0.020 (2)	0.029 (2)	0.0199 (19)	−0.0032 (18)	0.0032 (16)	0.0020 (16)
C15	0.0145 (19)	0.033 (2)	0.0196 (19)	−0.0008 (17)	0.0018 (15)	0.0032 (17)
C16	0.029 (2)	0.048 (3)	0.018 (2)	−0.003 (2)	0.0052 (17)	0.0052 (19)
C17	0.060 (3)	0.047 (3)	0.036 (3)	−0.016 (3)	0.014 (2)	0.015 (2)
C18	0.072 (4)	0.038 (3)	0.040 (3)	−0.023 (3)	0.020 (3)	−0.002 (2)
C19	0.038 (3)	0.034 (3)	0.026 (2)	−0.009 (2)	0.0133 (19)	0.0052 (19)
C20	0.0179 (19)	0.019 (2)	0.0150 (17)	−0.0022 (16)	0.0030 (14)	−0.0026 (15)
C21	0.021 (2)	0.016 (2)	0.026 (2)	−0.0014 (17)	0.0104 (16)	0.0000 (16)
C22	0.031 (2)	0.026 (2)	0.0181 (19)	0.0000 (18)	0.0112 (16)	−0.0006 (16)
C23	0.033 (2)	0.026 (2)	0.0156 (18)	0.0006 (19)	0.0007 (16)	−0.0021 (16)
C24	0.0154 (19)	0.032 (2)	0.0199 (19)	0.0010 (18)	0.0002 (15)	0.0020 (17)
C25	0.0150 (19)	0.025 (2)	0.0201 (19)	−0.0008 (17)	0.0055 (15)	−0.0021 (16)
C26	0.017 (2)	0.034 (2)	0.023 (2)	0.0016 (18)	−0.0028 (16)	0.0007 (17)
C27	0.039 (3)	0.027 (2)	0.026 (2)	0.008 (2)	0.0068 (18)	0.0005 (18)
C28	0.065 (4)	0.030 (3)	0.038 (3)	−0.020 (2)	0.017 (2)	−0.005 (2)
C29	0.016 (2)	0.047 (3)	0.026 (2)	−0.0009 (19)	0.0045 (17)	−0.0130 (19)
C30	0.028 (2)	0.023 (2)	0.024 (2)	−0.0024 (18)	0.0072 (17)	−0.0001 (16)
C31A	0.036 (9)	0.029 (9)	0.033 (9)	−0.003 (8)	0.025 (8)	0.006 (8)
C32A	0.040 (7)	0.073 (9)	0.040 (6)	0.007 (6)	0.006 (5)	0.008 (5)
C33A	0.045 (7)	0.102 (11)	0.052 (7)	0.019 (7)	0.020 (5)	0.009 (7)
C34A	0.073 (9)	0.082 (9)	0.040 (7)	0.030 (7)	0.025 (6)	−0.004 (6)
C35A	0.056 (7)	0.059 (9)	0.025 (7)	0.010 (7)	0.013 (5)	−0.014 (6)
C36A	0.042 (7)	0.035 (6)	0.030 (6)	−0.002 (5)	0.013 (5)	0.000 (5)
C31B	0.039 (11)	0.029 (10)	0.026 (10)	0.002 (9)	0.003 (9)	−0.009 (9)
C32B	0.051 (8)	0.079 (9)	0.051 (7)	−0.009 (7)	0.028 (6)	−0.005 (7)
C33B	0.056 (8)	0.082 (12)	0.072 (9)	0.006 (7)	0.042 (7)	−0.001 (8)
C34B	0.075 (10)	0.064 (8)	0.047 (8)	0.005 (8)	0.038 (7)	−0.001 (6)
C35B	0.068 (9)	0.070 (11)	0.045 (10)	0.000 (9)	0.020 (8)	0.007 (9)
C36B	0.056 (9)	0.073 (9)	0.030 (8)	0.014 (8)	0.013 (7)	0.003 (7)
C37	0.028 (2)	0.023 (2)	0.025 (2)	0.0029 (18)	0.0099 (17)	0.0044 (17)
C38	0.047 (3)	0.027 (3)	0.040 (3)	0.008 (2)	−0.004 (2)	0.000 (2)
C39	0.050 (3)	0.032 (3)	0.048 (3)	0.014 (2)	0.003 (2)	0.010 (2)
C40	0.048 (3)	0.021 (3)	0.053 (3)	0.011 (2)	0.027 (2)	0.010 (2)
C41	0.046 (3)	0.023 (3)	0.050 (3)	0.000 (2)	0.020 (2)	−0.005 (2)
C42	0.030 (2)	0.018 (2)	0.042 (3)	−0.0025 (19)	0.0059 (19)	−0.0002 (18)
C43	0.025 (2)	0.017 (2)	0.022 (2)	−0.0077 (17)	0.0035 (16)	0.0021 (16)
C44	0.029 (2)	0.028 (2)	0.028 (2)	−0.0056 (19)	0.0115 (18)	−0.0013 (18)
C45	0.043 (3)	0.030 (3)	0.026 (2)	−0.014 (2)	0.0062 (19)	−0.0026 (18)
C46	0.033 (3)	0.033 (3)	0.029 (2)	−0.010 (2)	−0.0049 (19)	0.0021 (19)
C47	0.026 (2)	0.031 (3)	0.042 (3)	−0.001 (2)	0.0004 (19)	0.002 (2)
C48	0.031 (2)	0.020 (2)	0.032 (2)	−0.0008 (19)	0.0085 (18)	−0.0002 (17)
C49	0.018 (2)	0.023 (2)	0.0189 (19)	0.0011 (16)	0.0100 (15)	0.0002 (15)
C50	0.023 (2)	0.021 (2)	0.0158 (18)	0.0036 (17)	0.0031 (15)	0.0013 (15)
C51	0.0129 (18)	0.024 (2)	0.023 (2)	0.0010 (17)	0.0071 (15)	0.0012 (16)
C52	0.016 (2)	0.022 (2)	0.025 (2)	0.0003 (16)	0.0101 (16)	0.0003 (16)
C53	0.026 (2)	0.030 (2)	0.0169 (19)	−0.0007 (19)	0.0018 (16)	0.0006 (16)
C54	0.0134 (19)	0.022 (2)	0.025 (2)	−0.0037 (16)	0.0068 (15)	−0.0039 (16)
C55	0.023 (2)	0.018 (2)	0.031 (2)	0.0005 (17)	0.0091 (17)	−0.0009 (17)
C56	0.024 (2)	0.042 (3)	0.042 (3)	0.004 (2)	0.007 (2)	−0.001 (2)
C57	0.032 (2)	0.018 (2)	0.034 (2)	−0.0035 (19)	0.0054 (19)	−0.0019 (18)

Geometric parameters (Å, º) top

Ru1—C50	1.880 (4)	C21—C22	1.381 (5)
Ru1—C49	1.924 (4)	C21—H21A	0.9300
Ru1—C51	1.933 (4)	C22—C23	1.384 (5)
Ru1—P1	2.3594 (11)	C22—H22A	0.9300
Ru1—Ru2	2.8449 (7)	C23—C24	1.364 (6)
Ru1—Ru3	2.8744 (6)	C23—H23A	0.9300
Ru2—C53	1.891 (5)	C24—C25	1.399 (5)
Ru2—C54	1.925 (4)	C24—H24A	0.9300
Ru2—C52	1.936 (4)	C25—C29	1.498 (5)
Ru2—P2	2.3476 (11)	C26—H26A	0.9600
Ru2—Ru3	2.8352 (6)	C26—H26B	0.9600
Ru3—C56	1.888 (5)	C26—H26C	0.9600
Ru3—C57	1.926 (4)	C27—H27A	0.9600
Ru3—C55	1.931 (4)	C27—H27B	0.9600
Ru3—P3	2.3289 (12)	C27—H27C	0.9600
S1—C31B	1.754 (3)	C28—H28A	0.9600
S1—C31A	1.777 (3)	C28—H28B	0.9600
S1—C30	1.816 (4)	C28—H28C	0.9600
P1—C1	1.830 (3)	C29—H29A	0.9600
P1—C7	1.849 (4)	C29—H29B	0.9600
P1—C13	1.854 (4)	C29—H29C	0.9600
P2—C20	1.829 (3)	C30—H30A	0.9700
P2—C14	1.839 (4)	C30—H30B	0.9700
P2—C13	1.854 (4)	C31A—C32A	1.3900
P3—C43	1.824 (4)	C31A—C36A	1.3900
P3—C37	1.826 (4)	C32A—C33A	1.3900
P3—C30	1.840 (4)	C32A—H32A	0.9300
O1—C49	1.151 (4)	C33A—C34A	1.3900
O2—C50	1.149 (5)	C33A—H33A	0.9300
O3—C51	1.139 (4)	C34A—C35A	1.3900
O4—C52	1.139 (4)	C34A—H34A	0.9300
O5—C53	1.144 (5)	C35A—C36A	1.3900
O6—C54	1.148 (4)	C35A—H35A	0.9300
O7—C55	1.142 (5)	C36A—H36A	0.9300
O8—C56	1.140 (5)	C31B—C32B	1.3900
O9—C57	1.143 (5)	C31B—C36B	1.3900
C1—C2	1.401 (5)	C32B—C33B	1.3900
C1—C6	1.405 (5)	C32B—H32B	0.9300
C2—C3	1.374 (5)	C33B—C34B	1.3900
C2—H2A	0.9300	C33B—H33B	0.9300
C3—C4	1.373 (6)	C34B—C35B	1.3900
C3—H3A	0.9300	C34B—H34B	0.9300
C4—C5	1.372 (6)	C35B—C36B	1.3900
C4—H4A	0.9300	C35B—H35B	0.9300
C5—C6	1.392 (5)	C36B—H36B	0.9300
C5—H5A	0.9300	C37—C38	1.390 (6)
C6—C26	1.508 (5)	C37—C42	1.393 (5)
C7—C8	1.389 (5)	C38—C39	1.382 (6)
C7—C12	1.412 (5)	C38—H38A	0.9300
C8—C9	1.385 (5)	C39—C40	1.374 (6)
C8—H8A	0.9300	C39—H39A	0.9300
C9—C10	1.376 (6)	C40—C41	1.366 (6)
C9—H9A	0.9300	C40—H40A	0.9300
C10—C11	1.372 (6)	C41—C42	1.377 (6)
C10—H10A	0.9300	C41—H41A	0.9300
C11—C12	1.402 (6)	C42—H42A	0.9300
C11—H11A	0.9300	C43—C44	1.380 (5)
C12—C27	1.505 (5)	C43—C48	1.395 (6)
C13—H13A	0.9700	C44—C45	1.394 (6)
C13—H13B	0.9700	C44—H44A	0.9300
C14—C15	1.392 (5)	C45—C46	1.380 (6)
C14—C19	1.415 (6)	C45—H45A	0.9300
C15—C16	1.381 (5)	C46—C47	1.383 (6)
C15—H15A	0.9300	C46—H46A	0.9300
C16—C17	1.363 (6)	C47—C48	1.381 (5)
C16—H16A	0.9300	C47—H47A	0.9300
C17—C18	1.368 (7)	C48—H48A	0.9300
C17—H17A	0.9300	Cl1—C58	1.824 (19)
C18—C19	1.397 (6)	Cl1—Cl2ⁱ	1.896 (8)
C18—H18A	0.9300	Cl2—C58	1.755 (19)
C19—C28	1.517 (6)	Cl2—Cl1ⁱ	1.896 (8)
C20—C21	1.392 (5)	C58—H58A	0.9700
C20—C25	1.406 (5)	C58—H58B	0.9700

C50—Ru1—C49	88.68 (16)	C21—C22—C23	119.5 (4)
C50—Ru1—C51	91.17 (15)	C21—C22—H22A	120.2
C49—Ru1—C51	171.19 (16)	C23—C22—H22A	120.2
C50—Ru1—P1	101.97 (12)	C24—C23—C22	119.6 (3)
C49—Ru1—P1	91.48 (12)	C24—C23—H23A	120.2
C51—Ru1—P1	97.16 (12)	C22—C23—H23A	120.2
C50—Ru1—Ru2	165.71 (11)	C23—C24—C25	122.4 (4)
C49—Ru1—Ru2	95.92 (11)	C23—C24—H24A	118.8
C51—Ru1—Ru2	82.22 (11)	C25—C24—H24A	118.8
P1—Ru1—Ru2	91.45 (3)	C24—C25—C20	117.7 (3)
C50—Ru1—Ru3	107.98 (12)	C24—C25—C29	118.3 (3)
C49—Ru1—Ru3	83.03 (11)	C20—C25—C29	123.9 (3)
C51—Ru1—Ru3	88.64 (11)	C6—C26—H26A	109.5
P1—Ru1—Ru3	149.37 (3)	C6—C26—H26B	109.5
Ru2—Ru1—Ru3	59.434 (13)	H26A—C26—H26B	109.5
C53—Ru2—C54	92.46 (16)	C6—C26—H26C	109.5
C53—Ru2—C52	87.91 (16)	H26A—C26—H26C	109.5
C54—Ru2—C52	174.47 (16)	H26B—C26—H26C	109.5
C53—Ru2—P2	105.51 (13)	C12—C27—H27A	109.5
C54—Ru2—P2	94.73 (11)	C12—C27—H27B	109.5
C52—Ru2—P2	90.49 (12)	H27A—C27—H27B	109.5
C53—Ru2—Ru3	102.18 (13)	C12—C27—H27C	109.5
C54—Ru2—Ru3	93.42 (11)	H27A—C27—H27C	109.5
C52—Ru2—Ru3	81.11 (11)	H27B—C27—H27C	109.5
P2—Ru2—Ru3	150.71 (3)	C19—C28—H28A	109.5
C53—Ru2—Ru1	161.38 (12)	C19—C28—H28B	109.5
C54—Ru2—Ru1	81.79 (11)	H28A—C28—H28B	109.5
C52—Ru2—Ru1	96.15 (11)	C19—C28—H28C	109.5
P2—Ru2—Ru1	92.65 (3)	H28A—C28—H28C	109.5
Ru3—Ru2—Ru1	60.801 (13)	H28B—C28—H28C	109.5
C56—Ru3—C57	92.27 (19)	C25—C29—H29A	109.5
C56—Ru3—C55	89.19 (18)	C25—C29—H29B	109.5
C57—Ru3—C55	178.22 (17)	H29A—C29—H29B	109.5
C56—Ru3—P3	100.71 (15)	C25—C29—H29C	109.5
C57—Ru3—P3	89.20 (13)	H29A—C29—H29C	109.5
C55—Ru3—P3	91.53 (12)	H29B—C29—H29C	109.5
C56—Ru3—Ru2	97.21 (15)	S1—C30—P3	112.4 (2)
C57—Ru3—Ru2	95.37 (12)	S1—C30—H30A	109.1
C55—Ru3—Ru2	83.43 (12)	P3—C30—H30A	109.1
P3—Ru3—Ru2	161.31 (3)	S1—C30—H30B	109.1
C56—Ru3—Ru1	156.64 (14)	P3—C30—H30B	109.1
C57—Ru3—Ru1	86.51 (13)	H30A—C30—H30B	107.9
C55—Ru3—Ru1	91.75 (12)	C32A—C31A—C36A	120.0
P3—Ru3—Ru1	102.60 (3)	C32A—C31A—S1	115.9 (3)
Ru2—Ru3—Ru1	59.765 (17)	C36A—C31A—S1	124.0 (4)
C31B—S1—C30	103.1 (2)	C31A—C32A—C33A	120.0
C31A—S1—C30	100.3 (2)	C31A—C32A—H32A	120.0
C1—P1—C7	106.70 (17)	C33A—C32A—H32A	120.0
C1—P1—C13	103.41 (18)	C34A—C33A—C32A	120.0
C7—P1—C13	98.52 (17)	C34A—C33A—H33A	120.0
C1—P1—Ru1	113.30 (12)	C32A—C33A—H33A	120.0
C7—P1—Ru1	117.52 (13)	C35A—C34A—C33A	120.0
C13—P1—Ru1	115.52 (13)	C35A—C34A—H34A	120.0
C20—P2—C14	107.36 (17)	C33A—C34A—H34A	120.0
C20—P2—C13	103.26 (17)	C34A—C35A—C36A	120.0
C14—P2—C13	99.22 (18)	C34A—C35A—H35A	120.0
C20—P2—Ru2	110.56 (12)	C36A—C35A—H35A	120.0
C14—P2—Ru2	119.04 (14)	C35A—C36A—C31A	120.0
C13—P2—Ru2	115.75 (13)	C35A—C36A—H36A	120.0
C43—P3—C37	106.34 (18)	C31A—C36A—H36A	120.0
C43—P3—C30	104.83 (19)	C32B—C31B—C36B	120.0
C37—P3—C30	100.34 (18)	C32B—C31B—S1	122.2 (3)
C43—P3—Ru3	115.05 (13)	C36B—C31B—S1	117.4 (3)
C37—P3—Ru3	113.48 (14)	C31B—C32B—C33B	120.0
C30—P3—Ru3	115.32 (13)	C31B—C32B—H32B	120.0
C2—C1—C6	118.5 (3)	C33B—C32B—H32B	120.0
C2—C1—P1	120.3 (3)	C34B—C33B—C32B	120.0
C6—C1—P1	121.1 (3)	C34B—C33B—H33B	120.0
C3—C2—C1	121.1 (4)	C32B—C33B—H33B	120.0
C3—C2—H2A	119.4	C33B—C34B—C35B	120.0
C1—C2—H2A	119.4	C33B—C34B—H34B	120.0
C4—C3—C2	120.5 (4)	C35B—C34B—H34B	120.0
C4—C3—H3A	119.8	C34B—C35B—C36B	120.0
C2—C3—H3A	119.8	C34B—C35B—H35B	120.0
C5—C4—C3	119.2 (4)	C36B—C35B—H35B	120.0
C5—C4—H4A	120.4	C35B—C36B—C31B	120.0
C3—C4—H4A	120.4	C35B—C36B—H36B	120.0
C4—C5—C6	122.1 (4)	C31B—C36B—H36B	120.0
C4—C5—H5A	118.9	C38—C37—C42	117.5 (4)
C6—C5—H5A	118.9	C38—C37—P3	117.8 (3)
C5—C6—C1	118.5 (4)	C42—C37—P3	124.7 (3)
C5—C6—C26	118.8 (3)	C39—C38—C37	121.5 (4)
C1—C6—C26	122.6 (3)	C39—C38—H38A	119.2
C8—C7—C12	118.9 (4)	C37—C38—H38A	119.2
C8—C7—P1	114.7 (3)	C40—C39—C38	119.9 (4)
C12—C7—P1	126.1 (3)	C40—C39—H39A	120.1
C9—C8—C7	122.1 (4)	C38—C39—H39A	120.1
C9—C8—H8A	119.0	C41—C40—C39	119.3 (4)
C7—C8—H8A	119.0	C41—C40—H40A	120.4
C10—C9—C8	119.1 (4)	C39—C40—H40A	120.4
C10—C9—H9A	120.5	C40—C41—C42	121.4 (4)
C8—C9—H9A	120.5	C40—C41—H41A	119.3
C11—C10—C9	120.0 (4)	C42—C41—H41A	119.3
C11—C10—H10A	120.0	C41—C42—C37	120.3 (4)
C9—C10—H10A	120.0	C41—C42—H42A	119.8
C10—C11—C12	122.3 (4)	C37—C42—H42A	119.8
C10—C11—H11A	118.9	C44—C43—C48	119.1 (4)
C12—C11—H11A	118.9	C44—C43—P3	119.9 (3)
C11—C12—C7	117.6 (4)	C48—C43—P3	120.8 (3)
C11—C12—C27	117.5 (4)	C43—C44—C45	120.4 (4)
C7—C12—C27	124.9 (4)	C43—C44—H44A	119.8
P2—C13—P1	116.7 (2)	C45—C44—H44A	119.8
P2—C13—H13A	108.1	C46—C45—C44	120.3 (4)
P1—C13—H13A	108.1	C46—C45—H45A	119.9
P2—C13—H13B	108.1	C44—C45—H45A	119.9
P1—C13—H13B	108.1	C45—C46—C47	119.3 (4)
H13A—C13—H13B	107.3	C45—C46—H46A	120.4
C15—C14—C19	118.8 (4)	C47—C46—H46A	120.4
C15—C14—P2	116.7 (3)	C48—C47—C46	120.8 (4)
C19—C14—P2	124.3 (3)	C48—C47—H47A	119.6
C16—C15—C14	122.4 (4)	C46—C47—H47A	119.6
C16—C15—H15A	118.8	C47—C48—C43	120.1 (4)
C14—C15—H15A	118.8	C47—C48—H48A	120.0
C17—C16—C15	118.5 (4)	C43—C48—H48A	120.0
C17—C16—H16A	120.7	O1—C49—Ru1	172.0 (3)
C15—C16—H16A	120.7	O2—C50—Ru1	179.7 (4)
C16—C17—C18	120.6 (5)	O3—C51—Ru1	173.3 (3)
C16—C17—H17A	119.7	O4—C52—Ru2	173.4 (3)
C18—C17—H17A	119.7	O5—C53—Ru2	178.7 (4)
C17—C18—C19	122.5 (5)	O6—C54—Ru2	173.2 (3)
C17—C18—H18A	118.7	O7—C55—Ru3	173.5 (3)
C19—C18—H18A	118.7	O8—C56—Ru3	178.4 (5)
C18—C19—C14	117.0 (4)	O9—C57—Ru3	171.8 (4)
C18—C19—C28	118.6 (4)	C58—Cl1—Cl2ⁱ	132.1 (7)
C14—C19—C28	124.3 (4)	C58—Cl2—Cl1ⁱ	116.0 (7)
C21—C20—C25	119.2 (3)	Cl2—C58—Cl1	108.9 (10)
C21—C20—P2	119.9 (3)	Cl2—C58—H58A	109.9
C25—C20—P2	120.6 (3)	Cl1—C58—H58A	109.9
C22—C21—C20	121.3 (4)	Cl2—C58—H58B	109.9
C22—C21—H21A	119.3	Cl1—C58—H58B	109.9
C20—C21—H21A	119.3	H58A—C58—H58B	108.3

C50—Ru1—Ru2—C53	55.6 (6)	P1—C1—C2—C3	179.4 (3)
C49—Ru1—Ru2—C53	−52.7 (4)	C1—C2—C3—C4	0.6 (7)
C51—Ru1—Ru2—C53	118.6 (4)	C2—C3—C4—C5	−2.3 (7)
P1—Ru1—Ru2—C53	−144.3 (4)	C3—C4—C5—C6	0.9 (7)
Ru3—Ru1—Ru2—C53	25.6 (4)	C4—C5—C6—C1	2.1 (6)
C50—Ru1—Ru2—C54	128.6 (5)	C4—C5—C6—C26	179.8 (4)
C49—Ru1—Ru2—C54	20.31 (16)	C2—C1—C6—C5	−3.7 (6)
C51—Ru1—Ru2—C54	−168.36 (16)	P1—C1—C6—C5	179.4 (3)
P1—Ru1—Ru2—C54	−71.33 (12)	C2—C1—C6—C26	178.7 (4)
Ru3—Ru1—Ru2—C54	98.61 (11)	P1—C1—C6—C26	1.8 (5)
C50—Ru1—Ru2—C52	−46.3 (5)	C1—P1—C7—C8	152.3 (3)
C49—Ru1—Ru2—C52	−154.51 (16)	C13—P1—C7—C8	−100.9 (3)
C51—Ru1—Ru2—C52	16.81 (16)	Ru1—P1—C7—C8	23.8 (3)
P1—Ru1—Ru2—C52	113.84 (12)	C1—P1—C7—C12	−33.5 (4)
Ru3—Ru1—Ru2—C52	−76.22 (11)	C13—P1—C7—C12	73.4 (3)
C50—Ru1—Ru2—P2	−137.0 (5)	Ru1—P1—C7—C12	−162.0 (3)
C49—Ru1—Ru2—P2	114.71 (12)	C12—C7—C8—C9	0.2 (6)
C51—Ru1—Ru2—P2	−73.96 (12)	P1—C7—C8—C9	174.9 (3)
P1—Ru1—Ru2—P2	23.07 (3)	C7—C8—C9—C10	2.3 (6)
Ru3—Ru1—Ru2—P2	−166.99 (3)	C8—C9—C10—C11	−2.2 (6)
C50—Ru1—Ru2—Ru3	30.0 (5)	C9—C10—C11—C12	−0.5 (6)
C49—Ru1—Ru2—Ru3	−78.30 (11)	C10—C11—C12—C7	3.0 (6)
C51—Ru1—Ru2—Ru3	93.03 (12)	C10—C11—C12—C27	−176.0 (4)
P1—Ru1—Ru2—Ru3	−169.94 (3)	C8—C7—C12—C11	−2.8 (5)
C53—Ru2—Ru3—C56	12.34 (18)	P1—C7—C12—C11	−176.8 (3)
C54—Ru2—Ru3—C56	105.60 (18)	C8—C7—C12—C27	176.1 (4)
C52—Ru2—Ru3—C56	−73.55 (18)	P1—C7—C12—C27	2.1 (6)
P2—Ru2—Ru3—C56	−148.41 (15)	C20—P2—C13—P1	−114.1 (2)
Ru1—Ru2—Ru3—C56	−175.77 (14)	C14—P2—C13—P1	135.5 (2)
C53—Ru2—Ru3—C57	105.32 (17)	Ru2—P2—C13—P1	6.8 (3)
C54—Ru2—Ru3—C57	−161.42 (17)	C1—P1—C13—P2	−108.1 (2)
C52—Ru2—Ru3—C57	19.42 (17)	C7—P1—C13—P2	142.3 (2)
P2—Ru2—Ru3—C57	−55.43 (14)	Ru1—P1—C13—P2	16.2 (3)
Ru1—Ru2—Ru3—C57	−82.79 (13)	C20—P2—C14—C15	145.2 (3)
C53—Ru2—Ru3—C55	−76.00 (16)	C13—P2—C14—C15	−107.7 (3)
C54—Ru2—Ru3—C55	17.26 (16)	Ru2—P2—C14—C15	18.8 (4)
C52—Ru2—Ru3—C55	−161.90 (17)	C20—P2—C14—C19	−40.9 (4)
P2—Ru2—Ru3—C55	123.25 (13)	C13—P2—C14—C19	66.3 (4)
Ru1—Ru2—Ru3—C55	95.89 (12)	Ru2—P2—C14—C19	−167.3 (3)
C53—Ru2—Ru3—P3	−151.13 (14)	C19—C14—C15—C16	−0.6 (6)
C54—Ru2—Ru3—P3	−57.87 (15)	P2—C14—C15—C16	173.7 (3)
C52—Ru2—Ru3—P3	122.97 (15)	C14—C15—C16—C17	2.0 (6)
P2—Ru2—Ru3—P3	48.11 (11)	C15—C16—C17—C18	−1.1 (7)
Ru1—Ru2—Ru3—P3	20.76 (9)	C16—C17—C18—C19	−1.3 (9)
C53—Ru2—Ru3—Ru1	−171.89 (11)	C17—C18—C19—C14	2.7 (8)
C54—Ru2—Ru3—Ru1	−78.63 (12)	C17—C18—C19—C28	−177.7 (5)
C52—Ru2—Ru3—Ru1	102.22 (12)	C15—C14—C19—C18	−1.7 (6)
P2—Ru2—Ru3—Ru1	27.36 (5)	P2—C14—C19—C18	−175.5 (4)
C50—Ru1—Ru3—C56	−161.9 (4)	C15—C14—C19—C28	178.7 (4)
C49—Ru1—Ru3—C56	111.7 (4)	P2—C14—C19—C28	4.9 (6)
C51—Ru1—Ru3—C56	−71.1 (4)	C14—P2—C20—C21	134.1 (3)
P1—Ru1—Ru3—C56	30.7 (4)	C13—P2—C20—C21	29.9 (4)
Ru2—Ru1—Ru3—C56	10.6 (4)	Ru2—P2—C20—C21	−94.6 (3)
C50—Ru1—Ru3—C57	−74.27 (17)	C14—P2—C20—C25	−52.2 (4)
C49—Ru1—Ru3—C57	−160.60 (17)	C13—P2—C20—C25	−156.5 (3)
C51—Ru1—Ru3—C57	16.52 (17)	Ru2—P2—C20—C25	79.1 (3)
P1—Ru1—Ru3—C57	118.32 (14)	C25—C20—C21—C22	3.8 (6)
Ru2—Ru1—Ru3—C57	98.28 (13)	P2—C20—C21—C22	177.5 (3)
C50—Ru1—Ru3—C55	106.08 (16)	C20—C21—C22—C23	0.3 (6)
C49—Ru1—Ru3—C55	19.75 (17)	C21—C22—C23—C24	−3.0 (6)
C51—Ru1—Ru3—C55	−163.12 (16)	C22—C23—C24—C25	1.6 (6)
P1—Ru1—Ru3—C55	−61.32 (13)	C23—C24—C25—C20	2.5 (6)
Ru2—Ru1—Ru3—C55	−81.36 (12)	C23—C24—C25—C29	−177.7 (4)
C50—Ru1—Ru3—P3	14.13 (11)	C21—C20—C25—C24	−5.0 (6)
C49—Ru1—Ru3—P3	−72.20 (12)	P2—C20—C25—C24	−178.7 (3)
C51—Ru1—Ru3—P3	104.92 (12)	C21—C20—C25—C29	175.1 (4)
P1—Ru1—Ru3—P3	−153.28 (5)	P2—C20—C25—C29	1.4 (6)
Ru2—Ru1—Ru3—P3	−173.32 (3)	C31B—S1—C30—P3	−177.5 (2)
C50—Ru1—Ru3—Ru2	−172.55 (11)	C31A—S1—C30—P3	−178.2 (2)
C49—Ru1—Ru3—Ru2	101.12 (11)	C43—P3—C30—S1	56.0 (3)
C51—Ru1—Ru3—Ru2	−81.76 (11)	C37—P3—C30—S1	−54.1 (2)
P1—Ru1—Ru3—Ru2	20.04 (5)	Ru3—P3—C30—S1	−176.38 (14)
C50—Ru1—P1—C1	−91.35 (17)	C31B—S1—C31A—C32A	−60.50 (19)
C49—Ru1—P1—C1	−2.38 (18)	C30—S1—C31A—C32A	107.6 (9)
C51—Ru1—P1—C1	175.92 (17)	C31B—S1—C31A—C36A	116.08 (16)
Ru2—Ru1—P1—C1	93.58 (14)	C30—S1—C31A—C36A	−75.8 (8)
Ru3—Ru1—P1—C1	76.41 (15)	C36A—C31A—C32A—C33A	0.0
C50—Ru1—P1—C7	33.91 (17)	S1—C31A—C32A—C33A	176.7 (3)
C49—Ru1—P1—C7	122.88 (17)	C31A—C32A—C33A—C34A	0.0
C51—Ru1—P1—C7	−58.83 (17)	C32A—C33A—C34A—C35A	0.0
Ru2—Ru1—P1—C7	−141.16 (13)	C33A—C34A—C35A—C36A	0.0
Ru3—Ru1—P1—C7	−158.33 (12)	C34A—C35A—C36A—C31A	0.0
C50—Ru1—P1—C13	149.62 (18)	C32A—C31A—C36A—C35A	0.0
C49—Ru1—P1—C13	−121.42 (18)	S1—C31A—C36A—C35A	−176.5 (3)
C51—Ru1—P1—C13	56.88 (18)	C31A—S1—C31B—C32B	141.4 (3)
Ru2—Ru1—P1—C13	−25.46 (15)	C30—S1—C31B—C32B	129.4 (9)
Ru3—Ru1—P1—C13	−42.63 (16)	C31A—S1—C31B—C36B	−45.18 (11)
C53—Ru2—P2—C20	−87.92 (18)	C30—S1—C31B—C36B	−57.2 (8)
C54—Ru2—P2—C20	178.21 (17)	C36B—C31B—C32B—C33B	0.0
C52—Ru2—P2—C20	0.05 (17)	S1—C31B—C32B—C33B	173.3 (4)
Ru3—Ru2—P2—C20	72.55 (15)	C31B—C32B—C33B—C34B	0.0
Ru1—Ru2—P2—C20	96.23 (13)	C32B—C33B—C34B—C35B	0.0
C53—Ru2—P2—C14	37.03 (18)	C33B—C34B—C35B—C36B	0.0
C54—Ru2—P2—C14	−56.84 (18)	C34B—C35B—C36B—C31B	0.0
C52—Ru2—P2—C14	125.00 (18)	C32B—C31B—C36B—C35B	0.0
Ru3—Ru2—P2—C14	−162.50 (13)	S1—C31B—C36B—C35B	−173.6 (3)
Ru1—Ru2—P2—C14	−138.82 (14)	C43—P3—C37—C38	174.9 (4)
C53—Ru2—P2—C13	155.15 (18)	C30—P3—C37—C38	−76.2 (4)
C54—Ru2—P2—C13	61.28 (19)	Ru3—P3—C37—C38	47.4 (4)
C52—Ru2—P2—C13	−116.88 (18)	C43—P3—C37—C42	−5.6 (4)
Ru3—Ru2—P2—C13	−44.38 (16)	C30—P3—C37—C42	103.3 (4)
Ru1—Ru2—P2—C13	−20.70 (15)	Ru3—P3—C37—C42	−133.1 (4)
C56—Ru3—P3—C43	−112.4 (2)	C42—C37—C38—C39	0.2 (7)
C57—Ru3—P3—C43	155.4 (2)	P3—C37—C38—C39	179.7 (4)
C55—Ru3—P3—C43	−22.93 (19)	C37—C38—C39—C40	2.3 (8)
Ru2—Ru3—P3—C43	50.91 (19)	C38—C39—C40—C41	−3.4 (8)
Ru1—Ru3—P3—C43	69.20 (16)	C39—C40—C41—C42	2.0 (8)
C56—Ru3—P3—C37	10.4 (2)	C40—C41—C42—C37	0.6 (7)
C57—Ru3—P3—C37	−81.77 (19)	C38—C37—C42—C41	−1.7 (7)
C55—Ru3—P3—C37	99.85 (18)	P3—C37—C42—C41	178.8 (4)
Ru2—Ru3—P3—C37	173.70 (14)	C37—P3—C43—C44	−51.9 (4)
Ru1—Ru3—P3—C37	−168.01 (14)	C30—P3—C43—C44	−157.6 (3)
C56—Ru3—P3—C30	125.4 (2)	Ru3—P3—C43—C44	74.6 (3)
C57—Ru3—P3—C30	33.20 (19)	C37—P3—C43—C48	133.2 (3)
C55—Ru3—P3—C30	−145.18 (19)	C30—P3—C43—C48	27.5 (4)
Ru2—Ru3—P3—C30	−71.34 (18)	Ru3—P3—C43—C48	−100.2 (3)
Ru1—Ru3—P3—C30	−53.05 (15)	C48—C43—C44—C45	−2.7 (6)
C7—P1—C1—C2	128.6 (3)	P3—C43—C44—C45	−177.7 (3)
C13—P1—C1—C2	25.3 (4)	C43—C44—C45—C46	3.1 (6)
Ru1—P1—C1—C2	−100.5 (3)	C44—C45—C46—C47	−1.5 (6)
C7—P1—C1—C6	−54.5 (4)	C45—C46—C47—C48	−0.5 (7)
C13—P1—C1—C6	−157.8 (3)	C46—C47—C48—C43	0.9 (6)
Ru1—P1—C1—C6	76.4 (3)	C44—C43—C48—C47	0.7 (6)
C6—C1—C2—C3	2.4 (6)	P3—C43—C48—C47	175.6 (3)

Symmetry code: (i) −x, −y, −z+1.

Hydrogen-bond geometry (Å, º) top

Cg1 and Cg2 are the centroids of the C7–C12 and C14–C19 benzene rings, respectively.

D—H···A	D—H	H···A	D···A	D—H···A
C9—H9A···O1ⁱⁱ	0.93	2.53	3.330 (5)	144
C29—H29B···Cg1ⁱⁱⁱ	0.96	2.97	3.554 (5)	121
C40—H40A···Cg1^iv	0.93	2.92	3.670 (6)	139
C58—H58A···Cg2^v	0.97	2.67	3.585 (19)	158

Symmetry codes: (ii) x, −y+1/2, z+1/2; (iii) x+1, y, z; (iv) −x, y−1/2, −z+1/2; (v) x, −y−1/2, z−1/2.

Experimental details

Crystal data
Chemical formula	[Ru₃(C₂₉H₃₀P₂)(C₁₉H₁₇PS)(CO)₉]·0.25CH₂Cl₂
M_r	1325.36
Crystal system, space group	Monoclinic, P2₁/c
Temperature (K)	100
a, b, c (Å)	11.022 (2), 28.576 (6), 18.454 (4)
β (°)	106.069 (3)
V (Å³)	5585 (2)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	1.00
Crystal size (mm)	0.15 × 0.09 × 0.08

Data collection
Diffractometer	Bruker APEXII DUO CCD diffractometer
Absorption correction	Multi-scan (SADABS; Bruker, 2009)
T_min, T_max	0.862, 0.928
No. of measured, independent and observed [I > 2σ(I)] reflections	39779, 12798, 8500
R_int	0.066
(sin θ/λ)_max (Å⁻¹)	0.650

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.040, 0.092, 1.02
No. of reflections	12798
No. of parameters	699
No. of restraints	180
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.55, −0.66

Computer programs: APEX2 (Bruker, 2009), SAINT (Bruker, 2009), SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009).

Selected bond lengths (Å) top

Ru1—P1	2.3594 (11)	Ru3—P3	2.3289 (12)
Ru2—P2	2.3476 (11)

Hydrogen-bond geometry (Å, º) top

Cg1 and Cg2 are the centroids of the C7–C12 and C14–C19 benzene rings, respectively.

D—H···A	D—H	H···A	D···A	D—H···A
C9—H9A···O1ⁱ	0.93	2.53	3.330 (5)	144
C29—H29B···Cg1ⁱⁱ	0.96	2.97	3.554 (5)	121
C40—H40A···Cg1ⁱⁱⁱ	0.93	2.92	3.670 (6)	139
C58—H58A···Cg2^iv	0.97	2.67	3.585 (19)	158

Symmetry codes: (i) x, −y+1/2, z+1/2; (ii) x+1, y, z; (iii) −x, y−1/2, −z+1/2; (iv) x, −y−1/2, z−1/2.

Footnotes

‡Thomson Reuters ResearcherID: B-6034-2009. On secondment to: Multimedia University, Melaka Campus, Jalan Ayer Keroh Lama, 74750 Melaka, Malaysia.

§Thomson Reuters ResearcherID: E-2833-2010. Current address: Department of Chemistry, Gokhale Centenary College, Ankola 581 314, NK, Karnataka, India.

¶Thomson Reuters ResearcherID: A-5523-2009.

‡‡Thomson Reuters ResearcherID: A-3561-2009. Additional correspondence author, e-mail: hkfun@usm.my.

Acknowledgements

The authors thank the Malaysian Government and Universiti Sains Malaysia (USM) for the Research Grant 1001/PJJAUH/811115. IAK is grateful to USM for a Visiting Researcher position. HKF and CSY thank USM for the Research University Grant No. 1001/PFIZIK/811160.

References

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Volume 67| Part 2| February 2011| Pages m195-m196

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