metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
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ISSN: 2056-9890
Volume 67| Part 2| February 2011| Pages m177-m178

[μ-Bis(di­phenyl­phosphan­yl)ethane-1:2κ2P:P′]nona­carbonyl-1κ3C,2κ3C,3κ3C-(tri­phenyl­stibine-3κSb)-triangulo-triruthenium(0)

aChemical Sciences Programme, School of Distance Education, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia, and bX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia
*Correspondence e-mail: omarsa@usm.my

(Received 21 December 2010; accepted 25 December 2010; online 15 January 2011)

The asymmetric unit of the title triangulo-triruthenium compound, [Ru3(C26H24P2)(C18H15Sb)(CO)9], consists of two crystallographically independent mol­ecules, A and B. The bis­(diphenyl­phosphan­yl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in mol­ecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in mol­ecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenyl­phosphanyl groups in mol­ecule A and 84.0 (3) and 72.6 (4)° in mol­ecule B. In the crystal, mol­ecules are linked into tetra­mers via inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure.

Related literature

For general background to triangulo-triruthenium derivatives, see: Bruce et al. (1985[Bruce, M. I., Shawkataly, O. bin. & Williams, M. L. (1985). J. Organomet. Chem. 287, 127-131.], 1988a[Bruce, M. I., Liddell, M. J., Hughes, C. A., Patrick, J. M., Skelton, B. W. & White, A. H. (1988a). J. Organomet. Chem. 347, 181-205.],b[Bruce, M. I., Liddell, M. J., Shawkataly, O. bin., Hughes, C. A., Skelton, B. W. & White, A. H. (1988b). J. Organomet. Chem. 347, 207-235.]). For related structures, see: Shawkataly et al. (1998[Shawkataly, O. bin., Ramalingam, K., Lee, S. T., Parameswary, M., Fun, H.-K. & Sivakumar, K. (1998). Polyhedron, 17, 1211-1216.], 2004[Shawkataly, O. bin, Ramalingam, K., Fun, H.-K., Abdul Rahman, A., & Razak, I. A. (2004). J. Cluster Sci. 15, 387-394.], 2010[Shawkataly, O. bin, Khan, I. A., Yeap, C. S. & Fun, H.-K. (2010). Acta Cryst. E66, m94-m95.], 2011[Shawkataly, O. bin, Khan, I. A., Sirat, S. S., Yeap, C. S. & Fun, H.-K. (2011). Acta Cryst. E67, m175-m176.]). For the synthesis of Ru3(CO)10(μ-Ph2PCH2CH2PPh2), see: Bruce et al. (1983[Bruce, M. I., Matisons, J. G. & Nicholson, B. K. (1983). J. Organomet. Chem. 247, 321-343.]). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986[Cosier, J. & Glazer, A. M. (1986). J. Appl. Cryst. 19, 105-107.]).

[Scheme 1]

Experimental

Crystal data
  • [Ru3(C26H24P2)(C18H15Sb)(CO)9]

  • Mr = 1306.74

  • Triclinic, [P \overline 1]

  • a = 15.1589 (8) Å

  • b = 18.6156 (10) Å

  • c = 20.0398 (11) Å

  • α = 113.233 (1)°

  • β = 97.986 (1)°

  • γ = 97.339 (1)°

  • V = 5041.5 (5) Å3

  • Z = 4

  • Mo Kα radiation

  • μ = 1.53 mm−1

  • T = 100 K

  • 0.51 × 0.15 × 0.08 mm

Data collection
  • Bruker APEXII DUO CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.506, Tmax = 0.885

  • 82542 measured reflections

  • 28970 independent reflections

  • 21778 reflections with I > 2σ(I)

  • Rint = 0.033

Refinement
  • R[F2 > 2σ(F2)] = 0.045

  • wR(F2) = 0.121

  • S = 1.11

  • 28970 reflections

  • 1225 parameters

  • H-atom parameters constrained

  • Δρmax = 3.47 e Å−3

  • Δρmin = −2.34 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

Cg1, Cg2 and Cg3 are the centroids of the C21B–C26B, C39B–C44B and C15A–C20A benzene rings, respectively.

D—H⋯A D—H H⋯A DA D—H⋯A
C18A—H18A⋯O7Bi 0.93 2.55 3.337 (7) 142
C34A—H34A⋯O2A 0.93 2.56 3.375 (7) 147
C34B—H34B⋯O8Bi 0.93 2.57 3.414 (7) 151
C5B—H5BACg1ii 0.93 3.00 3.723 (9) 136
C25B—H25BCg2iii 0.93 2.95 3.856 (8) 166
C43A—H43ACg3iii 0.93 2.91 3.624 (6) 135
Symmetry codes: (i) -x+1, -y+1, -z+1; (ii) -x, -y, -z+1; (iii) x-1, y, z.

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2009[Bruker (2009). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]).

Supporting information


Comment top

A large number of substituted derivatives, Ru3(CO)12-nLn (L = group 15 ligand) have been reported (Bruce et al., 1985, 1988a,b). As part of our study on the substitution of transition metal-carbonyl clusters with mixed-ligand complexes, we have published several structures of triangulo-triruthenium-carbonyl clusters containing mixed P/As and P/Sb ligands (Shawkataly et al., 1998, 2004, 2010, 2011). Herein we report the synthesis and structure of the title compound.

The asymmetric unit of title compound consists of two crystallographically independent molecules, A and B (Fig. 1). The bis(diphenylphosphanyl)ethane ligand bridges the Ru1–Ru2 bond and the monodentate stibine ligand bonds to the Ru3 atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles (C27–C32/C33–C38, C27–C32/C39–C44 and C33–C38/C39–C44) of 38.7 (3), 71.5 (3) and 70.0 (3) (19)° with each other respectively for molecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° for molecule B. Similarly, the dihedral angles between the two benzene rings (C1–C6/C7–C12 and C15–C20/C21–C26) are 80.7 (3) and 87.6 (3)° in molecule A and 84.0 (3) and 72.6 (4)° in molecule B for the two diphenylphosphanyl groups respectively.

In the crystal packing, the molecules are linked together via intermolecular C18—H18A···O7B, C34A—H34A···O2A and C34B—H34B···O8B hydrogen bonds into tetramers (Fig. 2, Table 1). Weak intermolecular C—H···π interactions (Table 1) further stabilize the crystal structure.

Related literature top

For general background to triangulo-triruthenium derivatives, see: Bruce et al. (1985, 1988a,b). For related structures, see: Shawkataly et al. (1998, 2004, 2010, 2011). For the synthesis of Ru3(CO)10(µ-Ph2PCH2CH2PPh2), see: Bruce et al. (1983). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986).

Experimental top

All manipulations were performed under a dry, oxygen-free nitrogen atmosphere using standard Schlenk techniques. All solvents were dried over sodium and distilled from sodium benzophenone ketyl under dry oxygen free nitrogen. Triphenylstibine (Fluka) is used as received and Ru3(CO)10(µ-Ph2PCH2CH2PPh2) (Bruce et al.,1983) was prepared by a reported procedure. The title compound was obtained by refluxing equimolar quantities of Ru3(CO)10(µ-Ph2PCH2CH2PPh2) and triphenylstibine in hexane under a nitrogen atmosphere. Crystals suitable for X-ray diffraction were grown by slow solvent / solvent diffusion of CH3OH into CH2Cl3.

Refinement top

All hydrogen atoms were positioned geometrically and refined using a riding model with C—H = 0.93 or 0.97 Å and Uiso(H) = 1.2Ueq(C). The maximum and minimum residual electron density peaks of 2.13 and -1.16 e Å-3 were located 0.85 Å and 1.41 Å, respectively from the Ru3 atom.

Computing details top

Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title compound with 50% probability ellipsoids for non-H atoms.
[Figure 2] Fig. 2. The crystal packing of the title compound, showing the molecules linked into a tetramer. Hydrogen atoms that are not involved in the hydrogen-bonding (dashed lines) have been omitted for clarity.
[µ-Bis(diphenylphosphanyl)ethane-1:2κ2P:P']nonacarbonyl- 1κ3C,2κ3C,3κ3C- (triphenylstibine-3κSb)-triangulo-triruthenium(0) top
Crystal data top
[Ru3(C26H24P2)(C18H15Sb)(CO)9]Z = 4
Mr = 1306.74F(000) = 2568
Triclinic, P1Dx = 1.722 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 15.1589 (8) ÅCell parameters from 9952 reflections
b = 18.6156 (10) Åθ = 2.6–32.6°
c = 20.0398 (11) ŵ = 1.53 mm1
α = 113.233 (1)°T = 100 K
β = 97.986 (1)°Plate, brown
γ = 97.339 (1)°0.51 × 0.15 × 0.08 mm
V = 5041.5 (5) Å3
Data collection top
Bruker APEXII DUO CCD area-detector
diffractometer
28970 independent reflections
Radiation source: fine-focus sealed tube21778 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.033
ϕ and ω scansθmax = 30.0°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Bruker, 2009)
h = 2121
Tmin = 0.506, Tmax = 0.885k = 2626
82542 measured reflectionsl = 2828
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.045Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.121H-atom parameters constrained
S = 1.11 w = 1/[σ2(Fo2) + (0.0352P)2 + 25.152P]
where P = (Fo2 + 2Fc2)/3
28970 reflections(Δ/σ)max = 0.001
1225 parametersΔρmax = 3.47 e Å3
0 restraintsΔρmin = 2.34 e Å3
Crystal data top
[Ru3(C26H24P2)(C18H15Sb)(CO)9]γ = 97.339 (1)°
Mr = 1306.74V = 5041.5 (5) Å3
Triclinic, P1Z = 4
a = 15.1589 (8) ÅMo Kα radiation
b = 18.6156 (10) ŵ = 1.53 mm1
c = 20.0398 (11) ÅT = 100 K
α = 113.233 (1)°0.51 × 0.15 × 0.08 mm
β = 97.986 (1)°
Data collection top
Bruker APEXII DUO CCD area-detector
diffractometer
28970 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2009)
21778 reflections with I > 2σ(I)
Tmin = 0.506, Tmax = 0.885Rint = 0.033
82542 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0450 restraints
wR(F2) = 0.121H-atom parameters constrained
S = 1.11 w = 1/[σ2(Fo2) + (0.0352P)2 + 25.152P]
where P = (Fo2 + 2Fc2)/3
28970 reflectionsΔρmax = 3.47 e Å3
1225 parametersΔρmin = 2.34 e Å3
Special details top

Experimental. The crystal was placed in the cold stream of an Oxford Cryosystems Cobra open-flow nitrogen cryostat (Cosier & Glazer, 1986) operating at 100.0 (1) K.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sb1A0.061486 (19)0.701152 (17)0.978302 (16)0.02093 (6)
Ru1A0.21003 (2)0.819388 (19)1.014099 (18)0.01705 (7)
Ru2A0.27903 (2)0.67570 (2)0.955200 (18)0.01778 (7)
Ru3A0.09780 (2)0.66624 (2)0.973168 (18)0.01816 (7)
P1A0.32886 (8)0.91401 (6)1.01639 (6)0.0191 (2)
P2A0.43433 (7)0.72287 (7)0.97737 (6)0.0196 (2)
O1A0.1010 (2)0.8075 (2)0.8671 (2)0.0351 (8)
O2A0.0940 (2)0.9232 (2)1.1051 (2)0.0333 (8)
O3A0.3215 (3)0.8307 (2)1.15895 (19)0.0348 (8)
O4A0.3109 (3)0.6504 (3)1.0984 (2)0.0448 (10)
O5A0.2593 (3)0.4989 (2)0.8596 (3)0.0493 (11)
O6A0.2524 (2)0.7124 (2)0.81825 (19)0.0318 (8)
O7A0.0570 (3)0.6188 (2)0.8050 (2)0.0382 (9)
O8A0.0677 (3)0.4919 (2)0.9450 (2)0.0409 (9)
O9A0.1349 (3)0.7158 (2)1.1413 (2)0.0375 (8)
C1A0.3020 (3)0.9671 (3)0.9585 (2)0.0224 (8)
C2A0.2874 (4)0.9255 (3)0.8817 (3)0.0299 (10)
H2AA0.29230.87220.86100.036*
C3A0.2655 (4)0.9632 (4)0.8352 (3)0.0402 (13)
H3AA0.25580.93500.78400.048*
C4A0.2585 (4)1.0422 (4)0.8656 (3)0.0421 (13)
H4AA0.24491.06750.83480.051*
C5A0.2714 (4)1.0842 (3)0.9420 (3)0.0377 (12)
H5AA0.26551.13720.96240.045*
C6A0.2934 (3)1.0465 (3)0.9879 (3)0.0314 (10)
H6AA0.30241.07481.03910.038*
C7A0.3792 (3)0.9948 (3)1.1076 (2)0.0229 (8)
C8A0.3235 (4)1.0310 (3)1.1547 (3)0.0338 (11)
H8AA0.26101.01191.13990.041*
C9A0.3581 (4)1.0945 (3)1.2230 (3)0.0397 (13)
H9AA0.31891.11811.25290.048*
C10A0.4501 (4)1.1227 (3)1.2466 (3)0.0388 (12)
H10A0.47351.16571.29230.047*
C11A0.5076 (4)1.0868 (3)1.2017 (3)0.0376 (12)
H11A0.57011.10501.21800.045*
C12A0.4734 (3)1.0240 (3)1.1330 (3)0.0299 (10)
H12A0.51311.00091.10330.036*
C13A0.4276 (3)0.8756 (3)0.9828 (2)0.0227 (8)
H13A0.40870.83900.93080.027*
H13B0.47290.91970.98690.027*
C14A0.4710 (3)0.8320 (3)1.0261 (2)0.0237 (9)
H14A0.45480.85001.07450.028*
H14B0.53670.84591.03390.028*
C15A0.4848 (3)0.6985 (3)0.8949 (2)0.0229 (8)
C16A0.4413 (3)0.6350 (3)0.8281 (3)0.0305 (10)
H16A0.38630.60440.82550.037*
C17A0.4782 (4)0.6165 (4)0.7650 (3)0.0387 (13)
H17A0.44890.57290.72120.046*
C18A0.5570 (4)0.6619 (4)0.7672 (3)0.0425 (14)
H18A0.58080.65010.72460.051*
C19A0.6022 (4)0.7259 (4)0.8329 (4)0.0453 (15)
H19A0.65620.75690.83440.054*
C20A0.5664 (4)0.7436 (3)0.8968 (3)0.0377 (12)
H20A0.59750.78580.94110.045*
C21A0.5025 (3)0.6893 (3)1.0373 (3)0.0254 (9)
C22A0.5174 (5)0.7281 (4)1.1142 (3)0.057 (2)
H22A0.49830.77601.13610.069*
C23A0.5599 (6)0.6968 (5)1.1585 (4)0.065 (2)
H23A0.56730.72321.20980.078*
C24A0.5911 (4)0.6284 (4)1.1292 (4)0.0468 (15)
H24A0.62100.60821.15970.056*
C25A0.5776 (5)0.5894 (4)1.0532 (4)0.0549 (18)
H25A0.59800.54201.03200.066*
C26A0.5344 (5)0.6194 (4)1.0083 (3)0.0478 (16)
H26A0.52640.59210.95700.057*
C27A0.0963 (3)0.7794 (3)0.9286 (3)0.0244 (9)
C28A0.1235 (4)0.7446 (3)0.8524 (3)0.0325 (10)
H28A0.13230.68940.82720.039*
C29A0.1381 (4)0.7898 (4)0.8122 (3)0.0385 (12)
H29A0.15610.76500.76070.046*
C30A0.1256 (4)0.8714 (4)0.8493 (3)0.0399 (13)
H30A0.13540.90220.82310.048*
C31A0.0984 (5)0.9073 (4)0.9262 (4)0.0467 (15)
H31A0.08960.96240.95130.056*
C32A0.0842 (4)0.8617 (3)0.9658 (3)0.0348 (11)
H32A0.06650.88631.01730.042*
C33A0.1068 (3)0.7415 (3)1.0806 (3)0.0264 (9)
C34A0.0888 (4)0.8221 (3)1.1319 (3)0.0374 (12)
H34A0.05800.86111.12080.045*
C35A0.1168 (4)0.8437 (3)1.1990 (3)0.0396 (12)
H35A0.10570.89711.23230.048*
C36A0.1614 (4)0.7854 (4)1.2163 (3)0.0440 (14)
H36A0.18330.79971.25990.053*
C37A0.1725 (5)0.7078 (4)1.1692 (3)0.0508 (17)
H37A0.19780.66841.18260.061*
C38A0.1467 (5)0.6859 (3)1.1008 (3)0.0467 (15)
H38A0.15710.63221.06850.056*
C39A0.1726 (3)0.6039 (3)0.9140 (3)0.0265 (9)
C40A0.1574 (3)0.5277 (3)0.8797 (3)0.0324 (11)
H40A0.09820.51890.88280.039*
C41A0.2300 (4)0.4641 (3)0.8404 (3)0.0388 (12)
H41A0.21970.41260.81780.047*
C42A0.3179 (4)0.4777 (3)0.8351 (3)0.0349 (11)
H42A0.36680.43510.80940.042*
C43A0.3330 (3)0.5543 (3)0.8678 (3)0.0368 (12)
H43A0.39190.56340.86290.044*
C44A0.2608 (3)0.6175 (3)0.9078 (3)0.0349 (11)
H44A0.27120.66900.93050.042*
C45A0.2793 (3)0.8205 (3)1.1024 (3)0.0259 (9)
C46A0.1361 (3)0.8842 (3)1.0680 (2)0.0226 (8)
C47A0.1414 (3)0.8080 (3)0.9201 (3)0.0248 (9)
C48A0.2959 (3)0.6618 (3)1.0469 (3)0.0290 (10)
C49A0.2688 (3)0.5651 (3)0.8966 (3)0.0300 (10)
C50A0.2583 (3)0.7017 (3)0.8714 (2)0.0224 (8)
C51A0.0762 (3)0.6387 (3)0.8677 (2)0.0249 (9)
C52A0.0763 (3)0.5579 (3)0.9553 (3)0.0267 (9)
C53A0.1248 (3)0.6998 (3)1.0792 (3)0.0248 (9)
Sb1B0.591162 (19)0.322816 (17)0.539002 (15)0.01948 (6)
Ru1B0.32201 (2)0.19935 (2)0.497165 (19)0.02039 (7)
Ru2B0.24537 (2)0.33890 (2)0.55496 (2)0.02058 (7)
Ru3B0.42965 (2)0.35418 (2)0.542128 (18)0.01812 (7)
P1B0.21368 (9)0.10411 (7)0.50293 (7)0.0261 (2)
P2B0.09114 (8)0.28330 (7)0.52371 (7)0.0242 (2)
O1B0.2092 (2)0.1901 (2)0.3535 (2)0.0332 (8)
O2B0.4344 (3)0.0905 (2)0.4061 (2)0.0417 (9)
O3B0.4351 (3)0.2219 (2)0.6473 (2)0.0361 (8)
O4B0.2727 (3)0.2988 (2)0.6902 (2)0.0365 (8)
O5B0.2437 (3)0.5110 (3)0.6536 (3)0.0613 (14)
O6B0.2258 (3)0.3753 (3)0.4175 (3)0.0490 (11)
O7B0.3918 (2)0.2976 (2)0.37254 (19)0.0339 (8)
O8B0.4642 (3)0.5285 (2)0.5714 (2)0.0411 (9)
O9B0.4645 (3)0.4055 (2)0.7112 (2)0.0364 (8)
C1B0.1669 (3)0.0142 (3)0.4166 (3)0.0310 (10)
C2B0.1947 (3)0.0015 (3)0.3512 (3)0.0315 (10)
H2BA0.23790.04080.34970.038*
C3B0.1604 (4)0.0680 (3)0.2873 (3)0.0397 (12)
H3BA0.18090.07520.24390.048*
C4B0.0965 (4)0.1258 (4)0.2885 (3)0.0475 (15)
H4BA0.07190.17190.24540.057*
C5B0.0682 (4)0.1159 (4)0.3538 (4)0.0485 (15)
H5BA0.02530.15580.35480.058*
C6B0.1035 (4)0.0470 (3)0.4175 (3)0.0403 (13)
H6BA0.08510.04110.46140.048*
C7B0.2515 (4)0.0621 (3)0.5682 (3)0.0304 (10)
C8B0.3394 (4)0.0449 (3)0.5725 (3)0.0384 (12)
H8BA0.37640.05560.54280.046*
C9B0.3718 (5)0.0124 (4)0.6201 (3)0.0467 (15)
H9BA0.43020.00180.62260.056*
C10B0.3171 (6)0.0041 (4)0.6639 (4)0.0557 (18)
H10B0.33890.02560.69620.067*
C11B0.2304 (5)0.0109 (5)0.6599 (4)0.0569 (18)
H11B0.19330.00190.68850.068*
C12B0.1974 (5)0.0454 (4)0.6130 (3)0.0447 (14)
H12B0.13950.05700.61190.054*
C13B0.1080 (4)0.1364 (3)0.5292 (3)0.0325 (11)
H13C0.06550.09070.52550.039*
H13D0.12220.17530.58050.039*
C14B0.0626 (3)0.1730 (3)0.4805 (3)0.0318 (10)
H14C0.00280.15560.47070.038*
H14D0.08160.15340.43320.038*
C15B0.0242 (3)0.3097 (3)0.4569 (3)0.0284 (10)
C16B0.0167 (4)0.3756 (3)0.4824 (3)0.0365 (11)
H16B0.01330.40300.53310.044*
C17B0.0626 (4)0.4012 (4)0.4335 (3)0.0442 (14)
H17B0.08950.44540.45150.053*
C18B0.0681 (4)0.3604 (4)0.3581 (3)0.0451 (15)
H18B0.09930.37680.32500.054*
C19B0.0273 (4)0.2955 (4)0.3321 (3)0.0454 (15)
H19B0.03010.26870.28140.054*
C20B0.0180 (4)0.2699 (4)0.3809 (3)0.0406 (13)
H20B0.04450.22550.36250.049*
C21B0.0274 (3)0.3058 (3)0.5985 (3)0.0269 (9)
C22B0.0680 (4)0.3562 (4)0.6709 (3)0.0430 (14)
H22B0.12900.38060.68270.052*
C23B0.0178 (5)0.3708 (5)0.7267 (4)0.059 (2)
H23B0.04570.40510.77550.071*
C24B0.0712 (5)0.3355 (5)0.7106 (4)0.0568 (19)
H24B0.10370.34460.74830.068*
C25B0.1140 (5)0.2854 (5)0.6371 (4)0.0548 (18)
H25B0.17530.26200.62560.066*
C26B0.0646 (4)0.2708 (4)0.5815 (3)0.0400 (13)
H26B0.09300.23750.53260.048*
C27B0.6993 (3)0.4228 (3)0.6026 (2)0.0227 (8)
C28B0.7858 (4)0.4236 (3)0.5888 (4)0.0427 (14)
H28B0.79720.38090.54940.051*
C29B0.8555 (4)0.4873 (3)0.6331 (4)0.0478 (16)
H29B0.91380.48670.62360.057*
C30B0.8404 (3)0.5514 (3)0.6907 (3)0.0318 (10)
H30B0.88790.59400.72030.038*
C31B0.7536 (4)0.5520 (3)0.7043 (3)0.0375 (12)
H31B0.74240.59540.74320.045*
C32B0.6835 (4)0.4885 (3)0.6605 (3)0.0349 (11)
H32B0.62510.48960.66970.042*
C33B0.6441 (3)0.2765 (3)0.4407 (2)0.0217 (8)
C34B0.6234 (3)0.3025 (3)0.3861 (3)0.0263 (9)
H34B0.58000.33420.38940.032*
C35B0.6664 (4)0.2822 (3)0.3259 (3)0.0313 (10)
H35B0.65120.29950.28890.038*
C36B0.7323 (3)0.2358 (3)0.3216 (3)0.0289 (10)
H36B0.76210.22280.28210.035*
C37B0.7536 (3)0.2093 (3)0.3758 (3)0.0327 (11)
H37B0.79720.17780.37240.039*
C38B0.7100 (3)0.2292 (3)0.4359 (3)0.0320 (11)
H38B0.72470.21120.47240.038*
C39B0.6245 (3)0.2472 (3)0.5910 (2)0.0224 (8)
C40B0.6090 (4)0.1649 (3)0.5533 (3)0.0318 (10)
H40B0.58970.14100.50190.038*
C41B0.6220 (5)0.1176 (3)0.5918 (3)0.0429 (14)
H41B0.61210.06240.56610.052*
C42B0.6495 (4)0.1528 (4)0.6680 (3)0.0420 (13)
H42B0.65680.12110.69370.050*
C43B0.6664 (4)0.2347 (3)0.7063 (3)0.0345 (11)
H43B0.68590.25820.75770.041*
C44B0.6541 (3)0.2822 (3)0.6682 (3)0.0272 (9)
H44B0.66560.33750.69410.033*
C45B0.2505 (3)0.1991 (3)0.4099 (3)0.0248 (9)
C46B0.3946 (3)0.1328 (3)0.4428 (2)0.0265 (9)
C47B0.3945 (3)0.2181 (3)0.5931 (3)0.0265 (9)
C48B0.2661 (3)0.3111 (3)0.6383 (3)0.0269 (9)
C49B0.2434 (4)0.4467 (3)0.6153 (3)0.0353 (11)
C50B0.2353 (3)0.3600 (3)0.4666 (3)0.0323 (11)
C51B0.4029 (3)0.3167 (3)0.4355 (3)0.0246 (9)
C52B0.4522 (3)0.4623 (3)0.5594 (3)0.0262 (9)
C53B0.4480 (3)0.3832 (3)0.6477 (3)0.0251 (9)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sb1A0.01861 (13)0.02543 (14)0.02117 (13)0.00765 (11)0.00624 (10)0.01061 (11)
Ru1A0.01765 (15)0.01983 (15)0.01511 (14)0.00562 (12)0.00476 (12)0.00779 (12)
Ru2A0.01684 (15)0.02065 (15)0.01764 (15)0.00657 (12)0.00564 (12)0.00836 (12)
Ru3A0.01704 (15)0.02083 (15)0.01852 (15)0.00543 (12)0.00573 (12)0.00904 (12)
P1A0.0210 (5)0.0193 (5)0.0165 (5)0.0035 (4)0.0053 (4)0.0067 (4)
P2A0.0170 (5)0.0247 (5)0.0172 (5)0.0063 (4)0.0044 (4)0.0080 (4)
O1A0.0322 (19)0.047 (2)0.0255 (17)0.0062 (16)0.0008 (14)0.0161 (16)
O2A0.0356 (19)0.0302 (17)0.0361 (19)0.0141 (15)0.0184 (16)0.0101 (15)
O3A0.041 (2)0.043 (2)0.0249 (17)0.0106 (17)0.0008 (15)0.0198 (16)
O4A0.055 (3)0.063 (3)0.039 (2)0.028 (2)0.0200 (19)0.037 (2)
O5A0.052 (3)0.0236 (18)0.061 (3)0.0103 (18)0.016 (2)0.0041 (18)
O6A0.0326 (19)0.046 (2)0.0236 (16)0.0126 (16)0.0102 (14)0.0181 (15)
O7A0.0311 (19)0.054 (2)0.0235 (17)0.0002 (17)0.0037 (15)0.0135 (17)
O8A0.045 (2)0.0284 (18)0.056 (3)0.0123 (17)0.0181 (19)0.0205 (18)
O9A0.041 (2)0.051 (2)0.0263 (18)0.0113 (18)0.0122 (16)0.0196 (17)
C1A0.020 (2)0.026 (2)0.024 (2)0.0015 (16)0.0035 (16)0.0140 (17)
C2A0.037 (3)0.032 (2)0.023 (2)0.008 (2)0.0072 (19)0.0124 (19)
C3A0.049 (3)0.052 (3)0.024 (2)0.016 (3)0.007 (2)0.020 (2)
C4A0.044 (3)0.054 (3)0.044 (3)0.017 (3)0.008 (3)0.035 (3)
C5A0.039 (3)0.034 (3)0.044 (3)0.008 (2)0.002 (2)0.022 (2)
C6A0.033 (3)0.033 (2)0.028 (2)0.005 (2)0.001 (2)0.014 (2)
C7A0.023 (2)0.023 (2)0.0193 (19)0.0009 (16)0.0017 (16)0.0076 (16)
C8A0.029 (2)0.033 (3)0.027 (2)0.001 (2)0.007 (2)0.001 (2)
C9A0.038 (3)0.037 (3)0.030 (3)0.004 (2)0.009 (2)0.001 (2)
C10A0.042 (3)0.031 (3)0.026 (2)0.003 (2)0.001 (2)0.000 (2)
C11A0.031 (3)0.033 (3)0.034 (3)0.004 (2)0.001 (2)0.006 (2)
C12A0.026 (2)0.028 (2)0.029 (2)0.0025 (19)0.0050 (19)0.0064 (19)
C13A0.023 (2)0.023 (2)0.021 (2)0.0033 (16)0.0059 (16)0.0076 (16)
C14A0.021 (2)0.028 (2)0.0194 (19)0.0053 (17)0.0022 (16)0.0078 (17)
C15A0.022 (2)0.028 (2)0.024 (2)0.0109 (17)0.0079 (17)0.0135 (18)
C16A0.027 (2)0.041 (3)0.023 (2)0.012 (2)0.0096 (18)0.010 (2)
C17A0.042 (3)0.057 (3)0.025 (2)0.030 (3)0.015 (2)0.017 (2)
C18A0.061 (4)0.053 (3)0.042 (3)0.036 (3)0.036 (3)0.033 (3)
C19A0.046 (3)0.043 (3)0.063 (4)0.014 (3)0.037 (3)0.029 (3)
C20A0.040 (3)0.031 (3)0.045 (3)0.007 (2)0.022 (2)0.014 (2)
C21A0.019 (2)0.036 (2)0.025 (2)0.0095 (18)0.0063 (17)0.0139 (19)
C22A0.084 (5)0.064 (4)0.023 (3)0.047 (4)0.002 (3)0.010 (3)
C23A0.087 (6)0.084 (5)0.026 (3)0.047 (5)0.001 (3)0.021 (3)
C24A0.048 (4)0.063 (4)0.045 (3)0.024 (3)0.007 (3)0.036 (3)
C25A0.079 (5)0.056 (4)0.041 (3)0.039 (4)0.009 (3)0.026 (3)
C26A0.071 (4)0.050 (3)0.031 (3)0.036 (3)0.010 (3)0.018 (3)
C27A0.019 (2)0.033 (2)0.025 (2)0.0105 (18)0.0057 (17)0.0157 (19)
C28A0.038 (3)0.032 (2)0.027 (2)0.006 (2)0.006 (2)0.013 (2)
C29A0.043 (3)0.050 (3)0.028 (3)0.012 (3)0.008 (2)0.021 (2)
C30A0.045 (3)0.048 (3)0.041 (3)0.021 (3)0.008 (2)0.030 (3)
C31A0.064 (4)0.034 (3)0.045 (3)0.020 (3)0.006 (3)0.018 (3)
C32A0.044 (3)0.036 (3)0.029 (2)0.018 (2)0.005 (2)0.015 (2)
C33A0.028 (2)0.034 (2)0.025 (2)0.0155 (19)0.0118 (18)0.0158 (19)
C34A0.041 (3)0.032 (3)0.036 (3)0.004 (2)0.012 (2)0.011 (2)
C35A0.043 (3)0.038 (3)0.032 (3)0.007 (2)0.010 (2)0.009 (2)
C36A0.051 (4)0.052 (3)0.033 (3)0.010 (3)0.021 (3)0.017 (3)
C37A0.083 (5)0.038 (3)0.043 (3)0.008 (3)0.033 (3)0.024 (3)
C38A0.078 (5)0.031 (3)0.039 (3)0.014 (3)0.027 (3)0.016 (2)
C39A0.026 (2)0.035 (2)0.026 (2)0.0124 (19)0.0092 (18)0.0179 (19)
C40A0.022 (2)0.034 (3)0.039 (3)0.0036 (19)0.003 (2)0.014 (2)
C41A0.031 (3)0.030 (3)0.044 (3)0.004 (2)0.007 (2)0.006 (2)
C42A0.027 (2)0.040 (3)0.032 (3)0.002 (2)0.001 (2)0.015 (2)
C43A0.019 (2)0.050 (3)0.042 (3)0.005 (2)0.004 (2)0.021 (3)
C44A0.023 (2)0.041 (3)0.040 (3)0.011 (2)0.004 (2)0.015 (2)
C45A0.030 (2)0.028 (2)0.026 (2)0.0105 (19)0.0085 (18)0.0158 (19)
C46A0.022 (2)0.026 (2)0.024 (2)0.0044 (17)0.0086 (17)0.0143 (17)
C47A0.022 (2)0.029 (2)0.023 (2)0.0057 (17)0.0050 (17)0.0096 (18)
C48A0.033 (3)0.033 (2)0.030 (2)0.015 (2)0.014 (2)0.018 (2)
C49A0.025 (2)0.029 (2)0.036 (3)0.0091 (19)0.009 (2)0.013 (2)
C50A0.018 (2)0.026 (2)0.022 (2)0.0044 (16)0.0044 (16)0.0094 (17)
C51A0.022 (2)0.027 (2)0.022 (2)0.0015 (17)0.0039 (17)0.0084 (17)
C52A0.024 (2)0.029 (2)0.028 (2)0.0078 (18)0.0090 (18)0.0116 (19)
C53A0.023 (2)0.028 (2)0.024 (2)0.0048 (17)0.0056 (17)0.0113 (18)
Sb1B0.01926 (13)0.02293 (13)0.01749 (12)0.00678 (10)0.00551 (10)0.00843 (10)
Ru1B0.02591 (17)0.02054 (15)0.01923 (15)0.00768 (13)0.00992 (13)0.01034 (13)
Ru2B0.02011 (16)0.02150 (16)0.02397 (17)0.00693 (13)0.01028 (13)0.01081 (13)
Ru3B0.01884 (16)0.02118 (15)0.01860 (15)0.00665 (12)0.00762 (12)0.01070 (12)
P1B0.0347 (6)0.0212 (5)0.0257 (6)0.0054 (5)0.0161 (5)0.0101 (5)
P2B0.0210 (5)0.0293 (6)0.0229 (5)0.0038 (4)0.0088 (4)0.0106 (5)
O1B0.0322 (19)0.045 (2)0.0300 (18)0.0109 (16)0.0067 (15)0.0222 (16)
O2B0.038 (2)0.051 (2)0.033 (2)0.0233 (18)0.0120 (17)0.0094 (18)
O3B0.047 (2)0.0373 (19)0.0271 (18)0.0160 (17)0.0082 (16)0.0141 (16)
O4B0.039 (2)0.050 (2)0.0294 (18)0.0110 (17)0.0159 (16)0.0224 (17)
O5B0.064 (3)0.030 (2)0.077 (4)0.016 (2)0.020 (3)0.005 (2)
O6B0.037 (2)0.079 (3)0.062 (3)0.024 (2)0.018 (2)0.056 (3)
O7B0.0318 (19)0.047 (2)0.0248 (17)0.0002 (16)0.0077 (14)0.0189 (16)
O8B0.068 (3)0.0246 (17)0.040 (2)0.0158 (18)0.027 (2)0.0158 (16)
O9B0.039 (2)0.046 (2)0.0244 (17)0.0063 (17)0.0077 (15)0.0146 (16)
C1B0.030 (2)0.027 (2)0.032 (3)0.0026 (19)0.012 (2)0.008 (2)
C2B0.030 (2)0.035 (3)0.030 (2)0.007 (2)0.008 (2)0.013 (2)
C3B0.041 (3)0.041 (3)0.030 (3)0.011 (2)0.011 (2)0.006 (2)
C4B0.037 (3)0.039 (3)0.042 (3)0.001 (2)0.003 (2)0.005 (3)
C5B0.044 (3)0.036 (3)0.048 (4)0.002 (3)0.006 (3)0.004 (3)
C6B0.043 (3)0.033 (3)0.038 (3)0.001 (2)0.014 (2)0.009 (2)
C7B0.044 (3)0.024 (2)0.026 (2)0.007 (2)0.013 (2)0.0115 (19)
C8B0.047 (3)0.034 (3)0.038 (3)0.014 (2)0.013 (2)0.016 (2)
C9B0.067 (4)0.041 (3)0.039 (3)0.028 (3)0.010 (3)0.019 (3)
C10B0.086 (5)0.054 (4)0.050 (4)0.033 (4)0.026 (4)0.035 (3)
C11B0.069 (5)0.081 (5)0.047 (4)0.023 (4)0.026 (3)0.047 (4)
C12B0.054 (4)0.049 (3)0.043 (3)0.018 (3)0.026 (3)0.024 (3)
C13B0.038 (3)0.025 (2)0.037 (3)0.004 (2)0.022 (2)0.012 (2)
C14B0.026 (2)0.031 (2)0.031 (2)0.0012 (19)0.0082 (19)0.006 (2)
C15B0.022 (2)0.038 (3)0.024 (2)0.0003 (19)0.0054 (17)0.013 (2)
C16B0.038 (3)0.037 (3)0.031 (3)0.001 (2)0.000 (2)0.015 (2)
C17B0.050 (4)0.038 (3)0.046 (3)0.004 (3)0.001 (3)0.024 (3)
C18B0.033 (3)0.063 (4)0.040 (3)0.013 (3)0.006 (2)0.033 (3)
C19B0.029 (3)0.076 (4)0.028 (3)0.001 (3)0.002 (2)0.022 (3)
C20B0.027 (3)0.065 (4)0.028 (3)0.011 (3)0.008 (2)0.018 (3)
C21B0.025 (2)0.039 (3)0.028 (2)0.0136 (19)0.0134 (18)0.021 (2)
C22B0.030 (3)0.066 (4)0.031 (3)0.016 (3)0.013 (2)0.014 (3)
C23B0.056 (4)0.096 (6)0.032 (3)0.040 (4)0.022 (3)0.022 (3)
C24B0.056 (4)0.089 (5)0.060 (4)0.044 (4)0.045 (4)0.047 (4)
C25B0.040 (3)0.073 (5)0.069 (5)0.021 (3)0.036 (3)0.037 (4)
C26B0.031 (3)0.052 (3)0.044 (3)0.013 (2)0.017 (2)0.022 (3)
C27B0.0159 (19)0.030 (2)0.023 (2)0.0048 (16)0.0004 (16)0.0130 (18)
C28B0.027 (3)0.033 (3)0.054 (4)0.008 (2)0.010 (2)0.003 (2)
C29B0.023 (3)0.037 (3)0.067 (4)0.007 (2)0.012 (3)0.005 (3)
C30B0.024 (2)0.034 (3)0.031 (2)0.0051 (19)0.0015 (19)0.012 (2)
C31B0.036 (3)0.037 (3)0.027 (2)0.002 (2)0.008 (2)0.002 (2)
C32B0.032 (3)0.036 (3)0.029 (2)0.002 (2)0.012 (2)0.005 (2)
C33B0.021 (2)0.025 (2)0.0202 (19)0.0062 (16)0.0057 (16)0.0090 (16)
C34B0.027 (2)0.025 (2)0.028 (2)0.0061 (18)0.0092 (18)0.0113 (18)
C35B0.034 (3)0.039 (3)0.024 (2)0.007 (2)0.012 (2)0.016 (2)
C36B0.028 (2)0.033 (2)0.021 (2)0.0016 (19)0.0107 (18)0.0058 (18)
C37B0.028 (2)0.040 (3)0.031 (2)0.016 (2)0.011 (2)0.012 (2)
C38B0.031 (3)0.046 (3)0.027 (2)0.019 (2)0.012 (2)0.018 (2)
C39B0.019 (2)0.030 (2)0.021 (2)0.0092 (17)0.0039 (16)0.0125 (17)
C40B0.038 (3)0.034 (2)0.023 (2)0.013 (2)0.006 (2)0.0096 (19)
C41B0.070 (4)0.027 (2)0.037 (3)0.022 (3)0.016 (3)0.014 (2)
C42B0.054 (4)0.050 (3)0.042 (3)0.026 (3)0.013 (3)0.034 (3)
C43B0.036 (3)0.045 (3)0.027 (2)0.009 (2)0.004 (2)0.020 (2)
C44B0.025 (2)0.030 (2)0.023 (2)0.0042 (18)0.0038 (17)0.0078 (18)
C45B0.021 (2)0.027 (2)0.033 (2)0.0066 (17)0.0129 (18)0.0172 (19)
C46B0.032 (2)0.031 (2)0.020 (2)0.0111 (19)0.0082 (18)0.0121 (18)
C47B0.033 (2)0.027 (2)0.023 (2)0.0099 (19)0.0088 (18)0.0110 (18)
C48B0.027 (2)0.028 (2)0.025 (2)0.0034 (18)0.0106 (18)0.0097 (18)
C49B0.027 (2)0.031 (3)0.046 (3)0.011 (2)0.011 (2)0.012 (2)
C50B0.024 (2)0.042 (3)0.046 (3)0.014 (2)0.015 (2)0.029 (2)
C51B0.021 (2)0.034 (2)0.026 (2)0.0069 (18)0.0094 (17)0.0168 (19)
C52B0.036 (3)0.028 (2)0.022 (2)0.0137 (19)0.0150 (19)0.0130 (18)
C53B0.025 (2)0.026 (2)0.027 (2)0.0069 (18)0.0097 (18)0.0125 (18)
Geometric parameters (Å, º) top
Sb1A—C33A2.133 (4)Sb1B—C39B2.125 (4)
Sb1A—C39A2.133 (5)Sb1B—C27B2.132 (4)
Sb1A—C27A2.142 (5)Sb1B—C33B2.132 (4)
Sb1A—Ru3A2.5846 (4)Sb1B—Ru3B2.5919 (4)
Ru1A—C46A1.879 (4)Ru1B—C46B1.884 (4)
Ru1A—C45A1.919 (5)Ru1B—C45B1.923 (5)
Ru1A—C47A1.939 (5)Ru1B—C47B1.953 (5)
Ru1A—P1A2.3350 (12)Ru1B—P1B2.3073 (12)
Ru1A—Ru2A2.8651 (5)Ru1B—Ru3B2.8500 (5)
Ru1A—Ru3A2.8676 (5)Ru1B—Ru2B2.8655 (5)
Ru2A—C49A1.898 (5)Ru2B—C49B1.898 (5)
Ru2A—C50A1.919 (5)Ru2B—C48B1.932 (5)
Ru2A—C48A1.942 (5)Ru2B—C50B1.950 (5)
Ru2A—P2A2.3202 (12)Ru2B—P2B2.3224 (12)
Ru2A—Ru3A2.8124 (5)Ru2B—Ru3B2.8292 (5)
Ru3A—C52A1.880 (5)Ru3B—C52B1.879 (5)
Ru3A—C53A1.929 (5)Ru3B—C51B1.930 (5)
Ru3A—C51A1.936 (5)Ru3B—C53B1.935 (5)
P1A—C7A1.826 (4)P1B—C7B1.834 (5)
P1A—C1A1.835 (5)P1B—C1B1.836 (5)
P1A—C13A1.838 (4)P1B—C13B1.853 (5)
P2A—C21A1.820 (5)P2B—C15B1.826 (5)
P2A—C15A1.836 (4)P2B—C21B1.834 (4)
P2A—C14A1.839 (5)P2B—C14B1.850 (5)
O1A—C47A1.146 (6)O1B—C45B1.151 (6)
O2A—C46A1.145 (5)O2B—C46B1.146 (6)
O3A—C45A1.152 (6)O3B—C47B1.143 (6)
O4A—C48A1.131 (6)O4B—C48B1.145 (6)
O5A—C49A1.137 (6)O5B—C49B1.137 (6)
O6A—C50A1.153 (5)O6B—C50B1.125 (6)
O7A—C51A1.142 (6)O7B—C51B1.149 (5)
O8A—C52A1.148 (6)O8B—C52B1.143 (6)
O9A—C53A1.142 (6)O9B—C53B1.149 (6)
C1A—C6A1.389 (7)C1B—C2B1.374 (7)
C1A—C2A1.393 (6)C1B—C6B1.401 (7)
C2A—C3A1.399 (7)C2B—C3B1.385 (7)
C2A—H2AA0.9300C2B—H2BA0.9300
C3A—C4A1.376 (8)C3B—C4B1.363 (9)
C3A—H3AA0.9300C3B—H3BA0.9300
C4A—C5A1.388 (8)C4B—C5B1.386 (9)
C4A—H4AA0.9300C4B—H4BA0.9300
C5A—C6A1.391 (7)C5B—C6B1.380 (8)
C5A—H5AA0.9300C5B—H5BA0.9300
C6A—H6AA0.9300C6B—H6BA0.9300
C7A—C8A1.386 (6)C7B—C12B1.390 (7)
C7A—C12A1.406 (6)C7B—C8B1.409 (8)
C8A—C9A1.383 (7)C8B—C9B1.386 (8)
C8A—H8AA0.9300C8B—H8BA0.9300
C9A—C10A1.370 (8)C9B—C10B1.379 (9)
C9A—H9AA0.9300C9B—H9BA0.9300
C10A—C11A1.381 (8)C10B—C11B1.377 (10)
C10A—H10A0.9300C10B—H10B0.9300
C11A—C12A1.381 (7)C11B—C12B1.405 (9)
C11A—H11A0.9300C11B—H11B0.9300
C12A—H12A0.9300C12B—H12B0.9300
C13A—C14A1.542 (6)C13B—C14B1.532 (8)
C13A—H13A0.9700C13B—H13C0.9700
C13A—H13B0.9700C13B—H13D0.9700
C14A—H14A0.9700C14B—H14C0.9700
C14A—H14B0.9700C14B—H14D0.9700
C15A—C20A1.390 (7)C15B—C20B1.390 (7)
C15A—C16A1.390 (7)C15B—C16B1.391 (8)
C16A—C17A1.390 (6)C16B—C17B1.390 (8)
C16A—H16A0.9300C16B—H16B0.9300
C17A—C18A1.357 (9)C17B—C18B1.383 (9)
C17A—H17A0.9300C17B—H17B0.9300
C18A—C19A1.387 (9)C18B—C19B1.378 (10)
C18A—H18A0.9300C18B—H18B0.9300
C19A—C20A1.396 (7)C19B—C20B1.385 (8)
C19A—H19A0.9300C19B—H19B0.9300
C20A—H20A0.9300C20B—H20B0.9300
C21A—C26A1.381 (7)C21B—C22B1.376 (7)
C21A—C22A1.390 (7)C21B—C26B1.395 (7)
C22A—C23A1.373 (8)C22B—C23B1.398 (8)
C22A—H22A0.9300C22B—H22B0.9300
C23A—C24A1.355 (9)C23B—C24B1.357 (10)
C23A—H23A0.9300C23B—H23B0.9300
C24A—C25A1.376 (9)C24B—C25B1.398 (11)
C24A—H24A0.9300C24B—H24B0.9300
C25A—C26A1.370 (8)C25B—C26B1.386 (8)
C25A—H25A0.9300C25B—H25B0.9300
C26A—H26A0.9300C26B—H26B0.9300
C27A—C28A1.376 (7)C27B—C28B1.376 (7)
C27A—C32A1.388 (7)C27B—C32B1.389 (6)
C28A—C29A1.393 (7)C28B—C29B1.379 (8)
C28A—H28A0.9300C28B—H28B0.9300
C29A—C30A1.376 (8)C29B—C30B1.364 (8)
C29A—H29A0.9300C29B—H29B0.9300
C30A—C31A1.389 (8)C30B—C31B1.382 (7)
C30A—H30A0.9300C30B—H30B0.9300
C31A—C32A1.389 (8)C31B—C32B1.377 (7)
C31A—H31A0.9300C31B—H31B0.9300
C32A—H32A0.9300C32B—H32B0.9300
C33A—C38A1.357 (7)C33B—C34B1.374 (6)
C33A—C34A1.408 (7)C33B—C38B1.403 (6)
C34A—C35A1.387 (7)C34B—C35B1.395 (6)
C34A—H34A0.9300C34B—H34B0.9300
C35A—C36A1.390 (8)C35B—C36B1.391 (7)
C35A—H35A0.9300C35B—H35B0.9300
C36A—C37A1.350 (8)C36B—C37B1.377 (7)
C36A—H36A0.9300C36B—H36B0.9300
C37A—C38A1.396 (8)C37B—C38B1.398 (6)
C37A—H37A0.9300C37B—H37B0.9300
C38A—H38A0.9300C38B—H38B0.9300
C39A—C40A1.376 (7)C39B—C40B1.385 (7)
C39A—C44A1.390 (6)C39B—C44B1.398 (6)
C40A—C41A1.387 (7)C40B—C41B1.396 (7)
C40A—H40A0.9300C40B—H40B0.9300
C41A—C42A1.384 (7)C41B—C42B1.378 (8)
C41A—H41A0.9300C41B—H41B0.9300
C42A—C43A1.379 (8)C42B—C43B1.379 (8)
C42A—H42A0.9300C42B—H42B0.9300
C43A—C44A1.381 (8)C43B—C44B1.392 (7)
C43A—H43A0.9300C43B—H43B0.9300
C44A—H44A0.9300C44B—H44B0.9300
C33A—Sb1A—C39A98.08 (19)C39B—Sb1B—C27B98.51 (17)
C33A—Sb1A—C27A105.68 (17)C39B—Sb1B—C33B102.13 (16)
C39A—Sb1A—C27A97.20 (18)C27B—Sb1B—C33B97.89 (17)
C33A—Sb1A—Ru3A120.39 (13)C39B—Sb1B—Ru3B115.01 (12)
C39A—Sb1A—Ru3A115.03 (12)C27B—Sb1B—Ru3B114.69 (12)
C27A—Sb1A—Ru3A116.63 (12)C33B—Sb1B—Ru3B124.42 (12)
C46A—Ru1A—C45A92.10 (19)C46B—Ru1B—C45B93.28 (19)
C46A—Ru1A—C47A92.31 (19)C46B—Ru1B—C47B93.58 (19)
C45A—Ru1A—C47A174.59 (19)C45B—Ru1B—C47B170.68 (19)
C46A—Ru1A—P1A101.91 (14)C46B—Ru1B—P1B99.49 (15)
C45A—Ru1A—P1A88.87 (15)C45B—Ru1B—P1B93.42 (14)
C47A—Ru1A—P1A93.28 (14)C47B—Ru1B—P1B91.67 (15)
C46A—Ru1A—Ru2A154.44 (13)C46B—Ru1B—Ru3B102.02 (15)
C45A—Ru1A—Ru2A78.44 (14)C45B—Ru1B—Ru3B94.56 (14)
C47A—Ru1A—Ru2A96.26 (13)C47B—Ru1B—Ru3B77.83 (14)
P1A—Ru1A—Ru2A101.59 (3)P1B—Ru1B—Ru3B156.56 (3)
C46A—Ru1A—Ru3A98.87 (14)C46B—Ru1B—Ru2B157.28 (15)
C45A—Ru1A—Ru3A93.91 (15)C45B—Ru1B—Ru2B76.72 (13)
C47A—Ru1A—Ru3A82.31 (14)C47B—Ru1B—Ru2B94.62 (13)
P1A—Ru1A—Ru3A158.92 (3)P1B—Ru1B—Ru2B101.41 (3)
Ru2A—Ru1A—Ru3A58.759 (12)Ru3B—Ru1B—Ru2B59.339 (12)
C49A—Ru2A—C50A94.3 (2)C49B—Ru2B—C48B93.7 (2)
C49A—Ru2A—C48A92.3 (2)C49B—Ru2B—C50B91.1 (2)
C50A—Ru2A—C48A172.99 (19)C48B—Ru2B—C50B173.32 (19)
C49A—Ru2A—P2A101.77 (15)C49B—Ru2B—P2B100.33 (16)
C50A—Ru2A—P2A91.35 (13)C48B—Ru2B—P2B92.98 (14)
C48A—Ru2A—P2A89.58 (15)C50B—Ru2B—P2B90.74 (15)
C49A—Ru2A—Ru3A96.33 (15)C49B—Ru2B—Ru3B100.09 (16)
C50A—Ru2A—Ru3A95.05 (13)C48B—Ru2B—Ru3B94.22 (14)
C48A—Ru2A—Ru3A81.88 (15)C50B—Ru2B—Ru3B80.34 (14)
P2A—Ru2A—Ru3A160.28 (3)P2B—Ru2B—Ru3B157.84 (3)
C49A—Ru2A—Ru1A154.29 (15)C49B—Ru2B—Ru1B156.86 (16)
C50A—Ru2A—Ru1A77.77 (13)C48B—Ru2B—Ru1B77.34 (14)
C48A—Ru2A—Ru1A95.24 (14)C50B—Ru2B—Ru1B96.49 (15)
P2A—Ru2A—Ru1A102.82 (3)P2B—Ru2B—Ru1B101.39 (3)
Ru3A—Ru2A—Ru1A60.664 (11)Ru3B—Ru2B—Ru1B60.057 (12)
C52A—Ru3A—C53A92.0 (2)C52B—Ru3B—C51B93.8 (2)
C52A—Ru3A—C51A91.2 (2)C52B—Ru3B—C53B90.71 (19)
C53A—Ru3A—C51A176.3 (2)C51B—Ru3B—C53B174.62 (19)
C52A—Ru3A—Sb1A103.07 (14)C52B—Ru3B—Sb1B101.26 (15)
C53A—Ru3A—Sb1A90.78 (13)C51B—Ru3B—Sb1B90.55 (13)
C51A—Ru3A—Sb1A90.36 (14)C53B—Ru3B—Sb1B91.52 (13)
C52A—Ru3A—Ru2A95.94 (14)C52B—Ru3B—Ru2B98.10 (14)
C53A—Ru3A—Ru2A96.45 (13)C51B—Ru3B—Ru2B94.91 (13)
C51A—Ru3A—Ru2A81.31 (13)C53B—Ru3B—Ru2B81.48 (14)
Sb1A—Ru3A—Ru2A159.415 (17)Sb1B—Ru3B—Ru2B159.491 (17)
C52A—Ru3A—Ru1A154.47 (14)C52B—Ru3B—Ru1B156.09 (15)
C53A—Ru3A—Ru1A81.75 (14)C51B—Ru3B—Ru1B78.56 (14)
C51A—Ru3A—Ru1A94.55 (14)C53B—Ru3B—Ru1B96.16 (14)
Sb1A—Ru3A—Ru1A101.740 (14)Sb1B—Ru3B—Ru1B101.418 (15)
Ru2A—Ru3A—Ru1A60.576 (12)Ru2B—Ru3B—Ru1B60.604 (12)
C7A—P1A—C1A103.1 (2)C7B—P1B—C1B102.2 (2)
C7A—P1A—C13A103.4 (2)C7B—P1B—C13B103.6 (2)
C1A—P1A—C13A100.7 (2)C1B—P1B—C13B100.9 (2)
C7A—P1A—Ru1A115.41 (15)C7B—P1B—Ru1B115.21 (18)
C1A—P1A—Ru1A116.31 (15)C1B—P1B—Ru1B116.72 (16)
C13A—P1A—Ru1A115.84 (15)C13B—P1B—Ru1B116.02 (16)
C21A—P2A—C15A105.1 (2)C15B—P2B—C21B102.8 (2)
C21A—P2A—C14A102.0 (2)C15B—P2B—C14B103.2 (2)
C15A—P2A—C14A102.9 (2)C21B—P2B—C14B100.9 (2)
C21A—P2A—Ru2A114.15 (16)C15B—P2B—Ru2B114.64 (16)
C15A—P2A—Ru2A115.98 (16)C21B—P2B—Ru2B118.02 (17)
C14A—P2A—Ru2A115.03 (15)C14B—P2B—Ru2B115.19 (17)
C6A—C1A—C2A118.7 (4)C2B—C1B—C6B117.6 (5)
C6A—C1A—P1A122.8 (4)C2B—C1B—P1B123.1 (4)
C2A—C1A—P1A118.5 (4)C6B—C1B—P1B119.2 (4)
C1A—C2A—C3A120.6 (5)C1B—C2B—C3B122.0 (5)
C1A—C2A—H2AA119.7C1B—C2B—H2BA119.0
C3A—C2A—H2AA119.7C3B—C2B—H2BA119.0
C4A—C3A—C2A119.8 (5)C4B—C3B—C2B119.6 (5)
C4A—C3A—H3AA120.1C4B—C3B—H3BA120.2
C2A—C3A—H3AA120.1C2B—C3B—H3BA120.2
C3A—C4A—C5A120.4 (5)C3B—C4B—C5B120.0 (5)
C3A—C4A—H4AA119.8C3B—C4B—H4BA120.0
C5A—C4A—H4AA119.8C5B—C4B—H4BA120.0
C4A—C5A—C6A119.6 (5)C6B—C5B—C4B120.1 (6)
C4A—C5A—H5AA120.2C6B—C5B—H5BA120.0
C6A—C5A—H5AA120.2C4B—C5B—H5BA120.0
C1A—C6A—C5A121.0 (5)C5B—C6B—C1B120.6 (5)
C1A—C6A—H6AA119.5C5B—C6B—H6BA119.7
C5A—C6A—H6AA119.5C1B—C6B—H6BA119.7
C8A—C7A—C12A117.1 (4)C12B—C7B—C8B118.3 (5)
C8A—C7A—P1A119.9 (4)C12B—C7B—P1B123.4 (5)
C12A—C7A—P1A123.0 (3)C8B—C7B—P1B118.3 (4)
C9A—C8A—C7A122.0 (5)C9B—C8B—C7B121.2 (5)
C9A—C8A—H8AA119.0C9B—C8B—H8BA119.4
C7A—C8A—H8AA119.0C7B—C8B—H8BA119.4
C10A—C9A—C8A120.1 (5)C10B—C9B—C8B119.7 (6)
C10A—C9A—H9AA119.9C10B—C9B—H9BA120.1
C8A—C9A—H9AA119.9C8B—C9B—H9BA120.1
C9A—C10A—C11A119.3 (5)C11B—C10B—C9B120.3 (6)
C9A—C10A—H10A120.3C11B—C10B—H10B119.9
C11A—C10A—H10A120.3C9B—C10B—H10B119.9
C12A—C11A—C10A120.8 (5)C10B—C11B—C12B120.6 (6)
C12A—C11A—H11A119.6C10B—C11B—H11B119.7
C10A—C11A—H11A119.6C12B—C11B—H11B119.7
C11A—C12A—C7A120.6 (5)C7B—C12B—C11B119.9 (6)
C11A—C12A—H12A119.7C7B—C12B—H12B120.0
C7A—C12A—H12A119.7C11B—C12B—H12B120.0
C14A—C13A—P1A113.1 (3)C14B—C13B—P1B113.1 (3)
C14A—C13A—H13A109.0C14B—C13B—H13C109.0
P1A—C13A—H13A109.0P1B—C13B—H13C109.0
C14A—C13A—H13B109.0C14B—C13B—H13D109.0
P1A—C13A—H13B109.0P1B—C13B—H13D109.0
H13A—C13A—H13B107.8H13C—C13B—H13D107.8
C13A—C14A—P2A112.5 (3)C13B—C14B—P2B112.8 (4)
C13A—C14A—H14A109.1C13B—C14B—H14C109.0
P2A—C14A—H14A109.1P2B—C14B—H14C109.0
C13A—C14A—H14B109.1C13B—C14B—H14D109.0
P2A—C14A—H14B109.1P2B—C14B—H14D109.0
H14A—C14A—H14B107.8H14C—C14B—H14D107.8
C20A—C15A—C16A118.0 (4)C20B—C15B—C16B118.1 (5)
C20A—C15A—P2A121.3 (4)C20B—C15B—P2B122.2 (4)
C16A—C15A—P2A120.7 (4)C16B—C15B—P2B119.5 (4)
C17A—C16A—C15A121.3 (5)C17B—C16B—C15B121.4 (5)
C17A—C16A—H16A119.4C17B—C16B—H16B119.3
C15A—C16A—H16A119.4C15B—C16B—H16B119.3
C18A—C17A—C16A120.2 (6)C18B—C17B—C16B119.5 (6)
C18A—C17A—H17A119.9C18B—C17B—H17B120.3
C16A—C17A—H17A119.9C16B—C17B—H17B120.3
C17A—C18A—C19A120.1 (5)C19B—C18B—C17B119.9 (6)
C17A—C18A—H18A120.0C19B—C18B—H18B120.1
C19A—C18A—H18A120.0C17B—C18B—H18B120.1
C18A—C19A—C20A119.9 (5)C18B—C19B—C20B120.4 (6)
C18A—C19A—H19A120.0C18B—C19B—H19B119.8
C20A—C19A—H19A120.0C20B—C19B—H19B119.8
C15A—C20A—C19A120.5 (5)C19B—C20B—C15B120.8 (6)
C15A—C20A—H20A119.7C19B—C20B—H20B119.6
C19A—C20A—H20A119.7C15B—C20B—H20B119.6
C26A—C21A—C22A116.7 (5)C22B—C21B—C26B119.1 (5)
C26A—C21A—P2A121.2 (4)C22B—C21B—P2B121.8 (4)
C22A—C21A—P2A121.9 (4)C26B—C21B—P2B119.1 (4)
C23A—C22A—C21A121.1 (6)C21B—C22B—C23B120.3 (6)
C23A—C22A—H22A119.4C21B—C22B—H22B119.9
C21A—C22A—H22A119.4C23B—C22B—H22B119.9
C24A—C23A—C22A121.5 (6)C24B—C23B—C22B120.7 (6)
C24A—C23A—H23A119.3C24B—C23B—H23B119.6
C22A—C23A—H23A119.3C22B—C23B—H23B119.6
C23A—C24A—C25A118.2 (6)C23B—C24B—C25B119.8 (5)
C23A—C24A—H24A120.9C23B—C24B—H24B120.1
C25A—C24A—H24A120.9C25B—C24B—H24B120.1
C26A—C25A—C24A120.9 (6)C26B—C25B—C24B119.7 (6)
C26A—C25A—H25A119.5C26B—C25B—H25B120.1
C24A—C25A—H25A119.5C24B—C25B—H25B120.1
C25A—C26A—C21A121.5 (6)C25B—C26B—C21B120.4 (6)
C25A—C26A—H26A119.2C25B—C26B—H26B119.8
C21A—C26A—H26A119.2C21B—C26B—H26B119.8
C28A—C27A—C32A118.7 (5)C28B—C27B—C32B118.5 (5)
C28A—C27A—Sb1A115.7 (4)C28B—C27B—Sb1B121.6 (4)
C32A—C27A—Sb1A125.2 (4)C32B—C27B—Sb1B119.9 (3)
C27A—C28A—C29A121.8 (5)C27B—C28B—C29B120.4 (5)
C27A—C28A—H28A119.1C27B—C28B—H28B119.8
C29A—C28A—H28A119.1C29B—C28B—H28B119.8
C30A—C29A—C28A119.3 (5)C30B—C29B—C28B121.1 (5)
C30A—C29A—H29A120.3C30B—C29B—H29B119.5
C28A—C29A—H29A120.3C28B—C29B—H29B119.5
C29A—C30A—C31A119.5 (5)C29B—C30B—C31B119.1 (5)
C29A—C30A—H30A120.3C29B—C30B—H30B120.5
C31A—C30A—H30A120.3C31B—C30B—H30B120.5
C32A—C31A—C30A120.8 (5)C32B—C31B—C30B120.2 (5)
C32A—C31A—H31A119.6C32B—C31B—H31B119.9
C30A—C31A—H31A119.6C30B—C31B—H31B119.9
C27A—C32A—C31A119.9 (5)C31B—C32B—C27B120.6 (5)
C27A—C32A—H32A120.0C31B—C32B—H32B119.7
C31A—C32A—H32A120.0C27B—C32B—H32B119.7
C38A—C33A—C34A118.1 (5)C34B—C33B—C38B119.4 (4)
C38A—C33A—Sb1A118.1 (4)C34B—C33B—Sb1B119.4 (3)
C34A—C33A—Sb1A123.4 (4)C38B—C33B—Sb1B120.5 (3)
C35A—C34A—C33A120.3 (5)C33B—C34B—C35B121.0 (4)
C35A—C34A—H34A119.8C33B—C34B—H34B119.5
C33A—C34A—H34A119.8C35B—C34B—H34B119.5
C34A—C35A—C36A119.9 (5)C36B—C35B—C34B119.4 (5)
C34A—C35A—H35A120.0C36B—C35B—H35B120.3
C36A—C35A—H35A120.0C34B—C35B—H35B120.3
C37A—C36A—C35A119.4 (5)C37B—C36B—C35B120.1 (4)
C37A—C36A—H36A120.3C37B—C36B—H36B120.0
C35A—C36A—H36A120.3C35B—C36B—H36B120.0
C36A—C37A—C38A120.8 (5)C36B—C37B—C38B120.5 (5)
C36A—C37A—H37A119.6C36B—C37B—H37B119.8
C38A—C37A—H37A119.6C38B—C37B—H37B119.8
C33A—C38A—C37A121.2 (5)C37B—C38B—C33B119.5 (5)
C33A—C38A—H38A119.4C37B—C38B—H38B120.2
C37A—C38A—H38A119.4C33B—C38B—H38B120.2
C40A—C39A—C44A120.0 (5)C40B—C39B—C44B119.0 (4)
C40A—C39A—Sb1A120.3 (3)C40B—C39B—Sb1B123.0 (3)
C44A—C39A—Sb1A119.7 (4)C44B—C39B—Sb1B117.6 (3)
C39A—C40A—C41A120.2 (5)C39B—C40B—C41B120.5 (5)
C39A—C40A—H40A119.9C39B—C40B—H40B119.7
C41A—C40A—H40A119.9C41B—C40B—H40B119.7
C42A—C41A—C40A119.8 (5)C42B—C41B—C40B119.9 (5)
C42A—C41A—H41A120.1C42B—C41B—H41B120.1
C40A—C41A—H41A120.1C40B—C41B—H41B120.1
C43A—C42A—C41A120.1 (5)C41B—C42B—C43B120.4 (5)
C43A—C42A—H42A120.0C41B—C42B—H42B119.8
C41A—C42A—H42A120.0C43B—C42B—H42B119.8
C42A—C43A—C44A120.2 (5)C42B—C43B—C44B120.0 (5)
C42A—C43A—H43A119.9C42B—C43B—H43B120.0
C44A—C43A—H43A119.9C44B—C43B—H43B120.0
C43A—C44A—C39A119.8 (5)C43B—C44B—C39B120.2 (5)
C43A—C44A—H44A120.1C43B—C44B—H44B119.9
C39A—C44A—H44A120.1C39B—C44B—H44B119.9
O3A—C45A—Ru1A172.0 (4)O1B—C45B—Ru1B172.1 (4)
O2A—C46A—Ru1A175.3 (4)O2B—C46B—Ru1B175.8 (4)
O1A—C47A—Ru1A174.6 (4)O3B—C47B—Ru1B173.8 (4)
O4A—C48A—Ru2A174.6 (4)O4B—C48B—Ru2B173.6 (4)
O5A—C49A—Ru2A177.1 (5)O5B—C49B—Ru2B177.5 (6)
O6A—C50A—Ru2A172.8 (4)O6B—C50B—Ru2B175.6 (5)
O7A—C51A—Ru3A174.5 (4)O7B—C51B—Ru3B175.8 (4)
O8A—C52A—Ru3A176.7 (4)O8B—C52B—Ru3B178.0 (4)
O9A—C53A—Ru3A174.8 (4)O9B—C53B—Ru3B174.4 (4)
C46A—Ru1A—Ru2A—C49A60.7 (5)C46B—Ru1B—Ru2B—C49B71.4 (6)
C45A—Ru1A—Ru2A—C49A130.7 (4)C45B—Ru1B—Ru2B—C49B137.1 (5)
C47A—Ru1A—Ru2A—C49A48.2 (4)C47B—Ru1B—Ru2B—C49B39.4 (5)
P1A—Ru1A—Ru2A—C49A142.9 (4)P1B—Ru1B—Ru2B—C49B132.0 (5)
Ru3A—Ru1A—Ru2A—C49A28.9 (4)Ru3B—Ru1B—Ru2B—C49B33.5 (5)
C46A—Ru1A—Ru2A—C50A134.8 (4)C46B—Ru1B—Ru2B—C48B140.4 (4)
C45A—Ru1A—Ru2A—C50A155.1 (2)C45B—Ru1B—Ru2B—C48B153.9 (2)
C47A—Ru1A—Ru2A—C50A25.95 (19)C47B—Ru1B—Ru2B—C48B29.6 (2)
P1A—Ru1A—Ru2A—C50A68.71 (14)P1B—Ru1B—Ru2B—C48B63.06 (15)
Ru3A—Ru1A—Ru2A—C50A103.01 (13)Ru3B—Ru1B—Ru2B—C48B102.50 (15)
C46A—Ru1A—Ru2A—C48A45.8 (4)C46B—Ru1B—Ru2B—C50B37.0 (4)
C45A—Ru1A—Ru2A—C48A24.2 (2)C45B—Ru1B—Ru2B—C50B28.7 (2)
C47A—Ru1A—Ru2A—C48A154.7 (2)C47B—Ru1B—Ru2B—C50B147.8 (2)
P1A—Ru1A—Ru2A—C48A110.64 (16)P1B—Ru1B—Ru2B—C50B119.54 (16)
Ru3A—Ru1A—Ru2A—C48A77.63 (16)Ru3B—Ru1B—Ru2B—C50B74.90 (16)
C46A—Ru1A—Ru2A—P2A136.6 (3)C46B—Ru1B—Ru2B—P2B129.1 (4)
C45A—Ru1A—Ru2A—P2A66.54 (15)C45B—Ru1B—Ru2B—P2B63.38 (13)
C47A—Ru1A—Ru2A—P2A114.54 (14)C47B—Ru1B—Ru2B—P2B120.11 (15)
P1A—Ru1A—Ru2A—P2A19.88 (4)P1B—Ru1B—Ru2B—P2B27.47 (5)
Ru3A—Ru1A—Ru2A—P2A168.40 (3)Ru3B—Ru1B—Ru2B—P2B166.97 (3)
C46A—Ru1A—Ru2A—Ru3A31.8 (3)C46B—Ru1B—Ru2B—Ru3B37.9 (4)
C45A—Ru1A—Ru2A—Ru3A101.86 (15)C45B—Ru1B—Ru2B—Ru3B103.59 (13)
C47A—Ru1A—Ru2A—Ru3A77.06 (14)C47B—Ru1B—Ru2B—Ru3B72.91 (14)
P1A—Ru1A—Ru2A—Ru3A171.72 (3)P1B—Ru1B—Ru2B—Ru3B165.56 (4)
C33A—Sb1A—Ru3A—C52A88.6 (2)C39B—Sb1B—Ru3B—C52B140.72 (19)
C39A—Sb1A—Ru3A—C52A28.4 (2)C27B—Sb1B—Ru3B—C52B27.51 (19)
C27A—Sb1A—Ru3A—C52A141.3 (2)C33B—Sb1B—Ru3B—C52B92.4 (2)
C33A—Sb1A—Ru3A—C53A3.6 (2)C39B—Sb1B—Ru3B—C51B125.34 (19)
C39A—Sb1A—Ru3A—C53A120.60 (19)C27B—Sb1B—Ru3B—C51B121.45 (19)
C27A—Sb1A—Ru3A—C53A126.5 (2)C33B—Sb1B—Ru3B—C51B1.6 (2)
C33A—Sb1A—Ru3A—C51A179.9 (2)C39B—Sb1B—Ru3B—C53B49.70 (19)
C39A—Sb1A—Ru3A—C51A62.94 (19)C27B—Sb1B—Ru3B—C53B63.52 (19)
C27A—Sb1A—Ru3A—C51A50.0 (2)C33B—Sb1B—Ru3B—C53B176.6 (2)
C33A—Sb1A—Ru3A—Ru2A114.47 (16)C39B—Sb1B—Ru3B—Ru2B19.69 (14)
C39A—Sb1A—Ru3A—Ru2A128.56 (14)C27B—Sb1B—Ru3B—Ru2B132.91 (14)
C27A—Sb1A—Ru3A—Ru2A15.66 (15)C33B—Sb1B—Ru3B—Ru2B107.22 (15)
C33A—Sb1A—Ru3A—Ru1A85.37 (16)C39B—Sb1B—Ru3B—Ru1B46.90 (13)
C39A—Sb1A—Ru3A—Ru1A157.66 (14)C27B—Sb1B—Ru3B—Ru1B160.11 (13)
C27A—Sb1A—Ru3A—Ru1A44.77 (14)C33B—Sb1B—Ru3B—Ru1B80.02 (15)
C49A—Ru2A—Ru3A—C52A22.8 (2)C49B—Ru2B—Ru3B—C52B24.3 (2)
C50A—Ru2A—Ru3A—C52A117.7 (2)C48B—Ru2B—Ru3B—C52B118.8 (2)
C48A—Ru2A—Ru3A—C52A68.7 (2)C50B—Ru2B—Ru3B—C52B65.1 (2)
P2A—Ru2A—Ru3A—C52A133.87 (18)P2B—Ru2B—Ru3B—C52B132.58 (17)
Ru1A—Ru2A—Ru3A—C52A169.41 (15)Ru1B—Ru2B—Ru3B—C52B168.44 (14)
C49A—Ru2A—Ru3A—C53A115.4 (2)C49B—Ru2B—Ru3B—C51B118.8 (2)
C50A—Ru2A—Ru3A—C53A149.66 (19)C48B—Ru2B—Ru3B—C51B146.7 (2)
C48A—Ru2A—Ru3A—C53A24.0 (2)C50B—Ru2B—Ru3B—C51B29.4 (2)
P2A—Ru2A—Ru3A—C53A41.19 (17)P2B—Ru2B—Ru3B—C51B38.07 (17)
Ru1A—Ru2A—Ru3A—C53A76.73 (14)Ru1B—Ru2B—Ru3B—C51B73.93 (14)
C49A—Ru2A—Ru3A—C51A67.6 (2)C49B—Ru2B—Ru3B—C53B65.2 (2)
C50A—Ru2A—Ru3A—C51A27.35 (19)C48B—Ru2B—Ru3B—C53B29.3 (2)
C48A—Ru2A—Ru3A—C51A159.0 (2)C50B—Ru2B—Ru3B—C53B154.6 (2)
P2A—Ru2A—Ru3A—C51A135.82 (17)P2B—Ru2B—Ru3B—C53B137.92 (16)
Ru1A—Ru2A—Ru3A—C51A100.27 (14)Ru1B—Ru2B—Ru3B—C53B102.06 (14)
C49A—Ru2A—Ru3A—Sb1A134.69 (17)C49B—Ru2B—Ru3B—Sb1B136.30 (19)
C50A—Ru2A—Ru3A—Sb1A39.78 (14)C48B—Ru2B—Ru3B—Sb1B41.82 (15)
C48A—Ru2A—Ru3A—Sb1A133.86 (16)C50B—Ru2B—Ru3B—Sb1B134.28 (17)
P2A—Ru2A—Ru3A—Sb1A68.69 (11)P2B—Ru2B—Ru3B—Sb1B66.82 (11)
Ru1A—Ru2A—Ru3A—Sb1A33.14 (5)Ru1B—Ru2B—Ru3B—Sb1B30.96 (5)
C49A—Ru2A—Ru3A—Ru1A167.83 (16)C49B—Ru2B—Ru3B—Ru1B167.26 (19)
C50A—Ru2A—Ru3A—Ru1A72.93 (13)C48B—Ru2B—Ru3B—Ru1B72.77 (14)
C48A—Ru2A—Ru3A—Ru1A100.72 (15)C50B—Ru2B—Ru3B—Ru1B103.32 (16)
P2A—Ru2A—Ru3A—Ru1A35.55 (9)P2B—Ru2B—Ru3B—Ru1B35.86 (9)
C46A—Ru1A—Ru3A—C52A141.6 (4)C46B—Ru1B—Ru3B—C52B136.6 (4)
C45A—Ru1A—Ru3A—C52A48.9 (4)C45B—Ru1B—Ru3B—C52B42.3 (3)
C47A—Ru1A—Ru3A—C52A127.2 (4)C47B—Ru1B—Ru3B—C52B132.2 (4)
P1A—Ru1A—Ru3A—C52A48.2 (3)P1B—Ru1B—Ru3B—C52B67.2 (3)
Ru2A—Ru1A—Ru3A—C52A25.1 (3)Ru2B—Ru1B—Ru3B—C52B29.3 (3)
C46A—Ru1A—Ru3A—C53A64.46 (19)C46B—Ru1B—Ru3B—C51B63.6 (2)
C45A—Ru1A—Ru3A—C53A28.29 (19)C45B—Ru1B—Ru3B—C51B30.74 (18)
C47A—Ru1A—Ru3A—C53A155.60 (19)C47B—Ru1B—Ru3B—C51B154.71 (19)
P1A—Ru1A—Ru3A—C53A125.32 (16)P1B—Ru1B—Ru3B—C51B140.27 (16)
Ru2A—Ru1A—Ru3A—C53A102.24 (14)Ru2B—Ru1B—Ru3B—C51B102.37 (13)
C46A—Ru1A—Ru3A—C51A115.9 (2)C46B—Ru1B—Ru3B—C53B117.4 (2)
C45A—Ru1A—Ru3A—C51A151.31 (19)C45B—Ru1B—Ru3B—C53B148.22 (18)
C47A—Ru1A—Ru3A—C51A24.80 (19)C47B—Ru1B—Ru3B—C53B26.33 (19)
P1A—Ru1A—Ru3A—C51A54.28 (17)P1B—Ru1B—Ru3B—C53B38.69 (17)
Ru2A—Ru1A—Ru3A—C51A77.36 (14)Ru2B—Ru1B—Ru3B—C53B76.60 (13)
C46A—Ru1A—Ru3A—Sb1A24.62 (14)C46B—Ru1B—Ru3B—Sb1B24.63 (14)
C45A—Ru1A—Ru3A—Sb1A117.37 (13)C45B—Ru1B—Ru3B—Sb1B118.97 (13)
C47A—Ru1A—Ru3A—Sb1A66.52 (13)C47B—Ru1B—Ru3B—Sb1B66.48 (14)
P1A—Ru1A—Ru3A—Sb1A145.60 (9)P1B—Ru1B—Ru3B—Sb1B131.50 (9)
Ru2A—Ru1A—Ru3A—Sb1A168.678 (17)Ru2B—Ru1B—Ru3B—Sb1B169.406 (17)
C46A—Ru1A—Ru3A—Ru2A166.70 (14)C46B—Ru1B—Ru3B—Ru2B165.96 (14)
C45A—Ru1A—Ru3A—Ru2A73.95 (13)C45B—Ru1B—Ru3B—Ru2B71.62 (13)
C47A—Ru1A—Ru3A—Ru2A102.15 (13)C47B—Ru1B—Ru3B—Ru2B102.93 (14)
P1A—Ru1A—Ru3A—Ru2A23.07 (9)P1B—Ru1B—Ru3B—Ru2B37.91 (9)
C46A—Ru1A—P1A—C7A48.9 (2)C46B—Ru1B—P1B—C7B74.8 (2)
C45A—Ru1A—P1A—C7A43.0 (2)C45B—Ru1B—P1B—C7B168.7 (2)
C47A—Ru1A—P1A—C7A141.9 (2)C47B—Ru1B—P1B—C7B19.1 (2)
Ru2A—Ru1A—P1A—C7A121.00 (17)Ru3B—Ru1B—P1B—C7B81.6 (2)
Ru3A—Ru1A—P1A—C7A141.00 (17)Ru2B—Ru1B—P1B—C7B114.18 (17)
C46A—Ru1A—P1A—C1A72.1 (2)C46B—Ru1B—P1B—C1B45.1 (2)
C45A—Ru1A—P1A—C1A164.1 (2)C45B—Ru1B—P1B—C1B48.8 (2)
C47A—Ru1A—P1A—C1A20.9 (2)C47B—Ru1B—P1B—C1B139.0 (2)
Ru2A—Ru1A—P1A—C1A117.99 (16)Ru3B—Ru1B—P1B—C1B158.53 (19)
Ru3A—Ru1A—P1A—C1A97.98 (18)Ru2B—Ru1B—P1B—C1B125.9 (2)
C46A—Ru1A—P1A—C13A169.8 (2)C46B—Ru1B—P1B—C13B163.9 (2)
C45A—Ru1A—P1A—C13A77.9 (2)C45B—Ru1B—P1B—C13B70.0 (2)
C47A—Ru1A—P1A—C13A97.1 (2)C47B—Ru1B—P1B—C13B102.2 (2)
Ru2A—Ru1A—P1A—C13A0.03 (17)Ru3B—Ru1B—P1B—C13B39.8 (2)
Ru3A—Ru1A—P1A—C13A20.0 (2)Ru2B—Ru1B—P1B—C13B7.1 (2)
C49A—Ru2A—P2A—C21A68.3 (2)C49B—Ru2B—P2B—C15B72.9 (3)
C50A—Ru2A—P2A—C21A163.0 (2)C48B—Ru2B—P2B—C15B167.2 (2)
C48A—Ru2A—P2A—C21A24.0 (2)C50B—Ru2B—P2B—C15B18.4 (2)
Ru3A—Ru2A—P2A—C21A87.96 (19)Ru3B—Ru2B—P2B—C15B84.0 (2)
Ru1A—Ru2A—P2A—C21A119.28 (17)Ru1B—Ru2B—P2B—C15B115.14 (18)
C49A—Ru2A—P2A—C15A54.1 (2)C49B—Ru2B—P2B—C21B48.4 (3)
C50A—Ru2A—P2A—C15A40.5 (2)C48B—Ru2B—P2B—C21B45.8 (2)
C48A—Ru2A—P2A—C15A146.4 (2)C50B—Ru2B—P2B—C21B139.7 (2)
Ru3A—Ru2A—P2A—C15A149.62 (16)Ru3B—Ru2B—P2B—C21B154.70 (17)
Ru1A—Ru2A—P2A—C15A118.30 (16)Ru1B—Ru2B—P2B—C21B123.51 (18)
C49A—Ru2A—P2A—C14A174.2 (2)C49B—Ru2B—P2B—C14B167.6 (3)
C50A—Ru2A—P2A—C14A79.6 (2)C48B—Ru2B—P2B—C14B73.3 (2)
C48A—Ru2A—P2A—C14A93.5 (2)C50B—Ru2B—P2B—C14B101.1 (2)
Ru3A—Ru2A—P2A—C14A29.5 (2)Ru3B—Ru2B—P2B—C14B35.6 (2)
Ru1A—Ru2A—P2A—C14A1.80 (16)Ru1B—Ru2B—P2B—C14B4.38 (19)
C7A—P1A—C1A—C6A20.2 (4)C7B—P1B—C1B—C2B125.4 (5)
C13A—P1A—C1A—C6A126.8 (4)C13B—P1B—C1B—C2B127.9 (5)
Ru1A—P1A—C1A—C6A107.2 (4)Ru1B—P1B—C1B—C2B1.3 (5)
C7A—P1A—C1A—C2A161.4 (4)C7B—P1B—C1B—C6B50.9 (5)
C13A—P1A—C1A—C2A54.8 (4)C13B—P1B—C1B—C6B55.8 (5)
Ru1A—P1A—C1A—C2A71.2 (4)Ru1B—P1B—C1B—C6B177.5 (4)
C6A—C1A—C2A—C3A0.7 (7)C6B—C1B—C2B—C3B1.6 (8)
P1A—C1A—C2A—C3A179.1 (4)P1B—C1B—C2B—C3B177.9 (4)
C1A—C2A—C3A—C4A0.1 (9)C1B—C2B—C3B—C4B0.6 (9)
C2A—C3A—C4A—C5A1.1 (9)C2B—C3B—C4B—C5B2.0 (10)
C3A—C4A—C5A—C6A1.2 (9)C3B—C4B—C5B—C6B1.1 (10)
C2A—C1A—C6A—C5A0.5 (7)C4B—C5B—C6B—C1B1.2 (10)
P1A—C1A—C6A—C5A178.9 (4)C2B—C1B—C6B—C5B2.5 (9)
C4A—C5A—C6A—C1A0.4 (8)P1B—C1B—C6B—C5B178.9 (5)
C1A—P1A—C7A—C8A84.7 (4)C1B—P1B—C7B—C12B92.3 (5)
C13A—P1A—C7A—C8A170.8 (4)C13B—P1B—C7B—C12B12.2 (5)
Ru1A—P1A—C7A—C8A43.3 (5)Ru1B—P1B—C7B—C12B140.1 (4)
C1A—P1A—C7A—C12A94.4 (4)C1B—P1B—C7B—C8B86.8 (4)
C13A—P1A—C7A—C12A10.2 (5)C13B—P1B—C7B—C8B168.6 (4)
Ru1A—P1A—C7A—C12A137.7 (4)Ru1B—P1B—C7B—C8B40.8 (4)
C12A—C7A—C8A—C9A1.8 (8)C12B—C7B—C8B—C9B0.2 (8)
P1A—C7A—C8A—C9A177.3 (5)P1B—C7B—C8B—C9B179.4 (4)
C7A—C8A—C9A—C10A1.2 (9)C7B—C8B—C9B—C10B0.5 (9)
C8A—C9A—C10A—C11A0.5 (9)C8B—C9B—C10B—C11B0.5 (11)
C9A—C10A—C11A—C12A1.4 (9)C9B—C10B—C11B—C12B1.9 (11)
C10A—C11A—C12A—C7A0.8 (9)C8B—C7B—C12B—C11B1.2 (9)
C8A—C7A—C12A—C11A0.8 (8)P1B—C7B—C12B—C11B178.0 (5)
P1A—C7A—C12A—C11A178.2 (4)C10B—C11B—C12B—C7B2.2 (11)
C7A—P1A—C13A—C14A69.4 (3)C7B—P1B—C13B—C14B179.1 (4)
C1A—P1A—C13A—C14A175.8 (3)C1B—P1B—C13B—C14B73.6 (4)
Ru1A—P1A—C13A—C14A57.8 (3)Ru1B—P1B—C13B—C14B53.5 (4)
P1A—C13A—C14A—P2A98.9 (3)P1B—C13B—C14B—P2B97.8 (4)
C21A—P2A—C14A—C13A175.7 (3)C15B—P2B—C14B—C13B177.1 (3)
C15A—P2A—C14A—C13A66.9 (3)C21B—P2B—C14B—C13B71.0 (4)
Ru2A—P2A—C14A—C13A60.2 (3)Ru2B—P2B—C14B—C13B57.2 (4)
C21A—P2A—C15A—C20A75.2 (5)C21B—P2B—C15B—C20B148.0 (4)
C14A—P2A—C15A—C20A31.2 (5)C14B—P2B—C15B—C20B43.4 (5)
Ru2A—P2A—C15A—C20A157.7 (4)Ru2B—P2B—C15B—C20B82.6 (5)
C21A—P2A—C15A—C16A106.1 (4)C21B—P2B—C15B—C16B37.0 (5)
C14A—P2A—C15A—C16A147.5 (4)C14B—P2B—C15B—C16B141.6 (4)
Ru2A—P2A—C15A—C16A21.0 (4)Ru2B—P2B—C15B—C16B92.3 (4)
C20A—C15A—C16A—C17A0.5 (7)C20B—C15B—C16B—C17B0.0 (8)
P2A—C15A—C16A—C17A179.3 (4)P2B—C15B—C16B—C17B175.2 (4)
C15A—C16A—C17A—C18A1.8 (8)C15B—C16B—C17B—C18B0.2 (9)
C16A—C17A—C18A—C19A1.6 (8)C16B—C17B—C18B—C19B0.7 (9)
C17A—C18A—C19A—C20A0.1 (9)C17B—C18B—C19B—C20B1.1 (9)
C16A—C15A—C20A—C19A1.0 (8)C18B—C19B—C20B—C15B0.9 (9)
P2A—C15A—C20A—C19A177.7 (4)C16B—C15B—C20B—C19B0.3 (8)
C18A—C19A—C20A—C15A1.2 (9)P2B—C15B—C20B—C19B174.7 (4)
C15A—P2A—C21A—C26A38.5 (5)C15B—P2B—C21B—C22B125.0 (5)
C14A—P2A—C21A—C26A145.6 (5)C14B—P2B—C21B—C22B128.6 (5)
Ru2A—P2A—C21A—C26A89.7 (5)Ru2B—P2B—C21B—C22B2.2 (5)
C15A—P2A—C21A—C22A147.9 (5)C15B—P2B—C21B—C26B55.0 (5)
C14A—P2A—C21A—C22A40.8 (6)C14B—P2B—C21B—C26B51.3 (5)
Ru2A—P2A—C21A—C22A83.9 (6)Ru2B—P2B—C21B—C26B177.7 (4)
C26A—C21A—C22A—C23A1.6 (11)C26B—C21B—C22B—C23B1.2 (9)
P2A—C21A—C22A—C23A172.3 (7)P2B—C21B—C22B—C23B178.7 (5)
C21A—C22A—C23A—C24A1.9 (14)C21B—C22B—C23B—C24B0.2 (11)
C22A—C23A—C24A—C25A1.4 (13)C22B—C23B—C24B—C25B1.5 (11)
C23A—C24A—C25A—C26A0.6 (12)C23B—C24B—C25B—C26B1.4 (11)
C24A—C25A—C26A—C21A0.3 (12)C24B—C25B—C26B—C21B0.0 (10)
C22A—C21A—C26A—C25A0.8 (10)C22B—C21B—C26B—C25B1.3 (9)
P2A—C21A—C26A—C25A173.1 (6)P2B—C21B—C26B—C25B178.6 (5)
C33A—Sb1A—C27A—C28A143.9 (4)C39B—Sb1B—C27B—C28B78.7 (5)
C39A—Sb1A—C27A—C28A43.4 (4)C33B—Sb1B—C27B—C28B24.9 (5)
Ru3A—Sb1A—C27A—C28A79.3 (4)Ru3B—Sb1B—C27B—C28B158.7 (4)
C33A—Sb1A—C27A—C32A43.4 (5)C39B—Sb1B—C27B—C32B100.1 (4)
C39A—Sb1A—C27A—C32A143.9 (4)C33B—Sb1B—C27B—C32B156.3 (4)
Ru3A—Sb1A—C27A—C32A93.3 (4)Ru3B—Sb1B—C27B—C32B22.5 (4)
C32A—C27A—C28A—C29A0.6 (8)C32B—C27B—C28B—C29B2.1 (9)
Sb1A—C27A—C28A—C29A172.5 (4)Sb1B—C27B—C28B—C29B176.8 (5)
C27A—C28A—C29A—C30A0.4 (8)C27B—C28B—C29B—C30B1.1 (11)
C28A—C29A—C30A—C31A0.3 (9)C28B—C29B—C30B—C31B0.1 (10)
C29A—C30A—C31A—C32A0.4 (10)C29B—C30B—C31B—C32B0.3 (9)
C28A—C27A—C32A—C31A0.7 (8)C30B—C31B—C32B—C27B0.7 (9)
Sb1A—C27A—C32A—C31A171.8 (4)C28B—C27B—C32B—C31B1.9 (8)
C30A—C31A—C32A—C27A0.6 (9)Sb1B—C27B—C32B—C31B177.0 (4)
C39A—Sb1A—C33A—C38A39.5 (5)C39B—Sb1B—C33B—C34B170.1 (4)
C27A—Sb1A—C33A—C38A139.3 (5)C27B—Sb1B—C33B—C34B89.4 (4)
Ru3A—Sb1A—C33A—C38A85.9 (5)Ru3B—Sb1B—C33B—C34B37.9 (4)
C39A—Sb1A—C33A—C34A147.6 (4)C39B—Sb1B—C33B—C38B19.3 (4)
C27A—Sb1A—C33A—C34A47.7 (5)C27B—Sb1B—C33B—C38B81.2 (4)
Ru3A—Sb1A—C33A—C34A87.0 (4)Ru3B—Sb1B—C33B—C38B151.5 (3)
C38A—C33A—C34A—C35A4.1 (9)C38B—C33B—C34B—C35B0.4 (7)
Sb1A—C33A—C34A—C35A177.0 (4)Sb1B—C33B—C34B—C35B171.1 (4)
C33A—C34A—C35A—C36A1.2 (9)C33B—C34B—C35B—C36B1.0 (8)
C34A—C35A—C36A—C37A3.6 (10)C34B—C35B—C36B—C37B1.1 (8)
C35A—C36A—C37A—C38A5.3 (11)C35B—C36B—C37B—C38B0.7 (8)
C34A—C33A—C38A—C37A2.4 (10)C36B—C37B—C38B—C33B0.1 (8)
Sb1A—C33A—C38A—C37A175.7 (5)C34B—C33B—C38B—C37B0.0 (8)
C36A—C37A—C38A—C33A2.4 (11)Sb1B—C33B—C38B—C37B170.6 (4)
C33A—Sb1A—C39A—C40A122.7 (4)C27B—Sb1B—C39B—C40B146.7 (4)
C27A—Sb1A—C39A—C40A130.3 (4)C33B—Sb1B—C39B—C40B46.7 (4)
Ru3A—Sb1A—C39A—C40A6.4 (4)Ru3B—Sb1B—C39B—C40B90.9 (4)
C33A—Sb1A—C39A—C44A56.4 (4)C27B—Sb1B—C39B—C44B40.5 (4)
C27A—Sb1A—C39A—C44A50.6 (4)C33B—Sb1B—C39B—C44B140.5 (3)
Ru3A—Sb1A—C39A—C44A174.5 (4)Ru3B—Sb1B—C39B—C44B81.9 (4)
C44A—C39A—C40A—C41A1.7 (8)C44B—C39B—C40B—C41B0.4 (7)
Sb1A—C39A—C40A—C41A177.4 (4)Sb1B—C39B—C40B—C41B172.2 (4)
C39A—C40A—C41A—C42A0.9 (9)C39B—C40B—C41B—C42B0.7 (9)
C40A—C41A—C42A—C43A0.9 (9)C40B—C41B—C42B—C43B1.5 (9)
C41A—C42A—C43A—C44A1.9 (9)C41B—C42B—C43B—C44B1.1 (9)
C42A—C43A—C44A—C39A1.1 (8)C42B—C43B—C44B—C39B0.1 (8)
C40A—C39A—C44A—C43A0.7 (8)C40B—C39B—C44B—C43B0.9 (7)
Sb1A—C39A—C44A—C43A178.4 (4)Sb1B—C39B—C44B—C43B172.2 (4)
Hydrogen-bond geometry (Å, º) top
Cg1, Cg2 and Cg3 are the centroids of the C21B–C26B, C39B–C44B and C15A–C20A benzene rings, respectively.
D—H···AD—HH···AD···AD—H···A
C18A—H18A···O7Bi0.932.553.337 (7)142
C34A—H34A···O2A0.932.563.375 (7)147
C34B—H34B···O8Bi0.932.573.414 (7)151
C5B—H5BA···Cg1ii0.933.003.723 (9)136
C25B—H25B···Cg2iii0.932.953.856 (8)166
C43A—H43A···Cg3iii0.932.913.624 (6)135
Symmetry codes: (i) x+1, y+1, z+1; (ii) x, y, z+1; (iii) x1, y, z.

Experimental details

Crystal data
Chemical formula[Ru3(C26H24P2)(C18H15Sb)(CO)9]
Mr1306.74
Crystal system, space groupTriclinic, P1
Temperature (K)100
a, b, c (Å)15.1589 (8), 18.6156 (10), 20.0398 (11)
α, β, γ (°)113.233 (1), 97.986 (1), 97.339 (1)
V3)5041.5 (5)
Z4
Radiation typeMo Kα
µ (mm1)1.53
Crystal size (mm)0.51 × 0.15 × 0.08
Data collection
DiffractometerBruker APEXII DUO CCD area-detector
diffractometer
Absorption correctionMulti-scan
(SADABS; Bruker, 2009)
Tmin, Tmax0.506, 0.885
No. of measured, independent and
observed [I > 2σ(I)] reflections
82542, 28970, 21778
Rint0.033
(sin θ/λ)max1)0.703
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.045, 0.121, 1.11
No. of reflections28970
No. of parameters1225
H-atom treatmentH-atom parameters constrained
w = 1/[σ2(Fo2) + (0.0352P)2 + 25.152P]
where P = (Fo2 + 2Fc2)/3
Δρmax, Δρmin (e Å3)3.47, 2.34

Computer programs: APEX2 (Bruker, 2009), SAINT (Bruker, 2009), SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009).

Hydrogen-bond geometry (Å, º) top
Cg1, Cg2 and Cg3 are the centroids of the C21B–C26B, C39B–C44B and C15A–C20A benzene rings, respectively.
D—H···AD—HH···AD···AD—H···A
C18A—H18A···O7Bi0.932.553.337 (7)142
C34A—H34A···O2A0.932.563.375 (7)147
C34B—H34B···O8Bi0.932.573.414 (7)151
C5B—H5BA···Cg1ii0.933.003.723 (9)136
C25B—H25B···Cg2iii0.932.953.856 (8)166
C43A—H43A···Cg3iii0.932.913.624 (6)135
Symmetry codes: (i) x+1, y+1, z+1; (ii) x, y, z+1; (iii) x1, y, z.
 

Footnotes

Thomson Reuters ResearcherID: B-6034-2009. On secondment to: Multimedia University, Melaka Campus, Jalan Ayer Keroh Lama, 74750 Melaka, Malaysia.

§Thomson Reuters ResearcherID: E-2833-2010. Current address: Department of Chemistry, Gokhale Centenary College, Ankola 581 314, NK, Karnataka, India.

Thomson Reuters ResearcherID: A-5523-2009.

‡‡Thomson Reuters ResearcherID: A-3561-2009. Additional correspondence author, e-mail: hkfun@usm.my.

Acknowledgements

The authors would like to thank the Malaysian Government and Universiti Sains Malaysia (USM) for the Research grant 1001/PJJAUH/811115. IAK is grateful to USM for a Visiting Researcher position and SSS thanks USM for the G A position. HKF and CSY thank USM for the Research University Grant No. 1001/PFIZIK/811160.

References

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Volume 67| Part 2| February 2011| Pages m177-m178
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