metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 67| Part 8| August 2011| Pages m1141-m1142

Bis[μ2-bis­­(di­phenyl­phosphan­yl)methane-κ2P:P′]bis­­(μ4-di­phenyl­phosphinato-κ4O:O:O′:O′)bis­­[μ2-tri­fluoro­methane­sulfonato­(0.546/0.454)]-κ2O:O′;κ2O:O-tetra­silver(I) aceto­nitrile disolvate

aCollege of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China, bSichuan College of Chemical Technology, Luzhou 646005, People's Republic of China, and cSchool of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China
*Correspondence e-mail: xjl_2003@yahoo.com.cn

(Received 1 July 2011; accepted 20 July 2011; online 23 July 2011)

In the centrosymmetric tetra­nuclear title compound, [Ag4(C12H10O2P)2(CF3O3S)2(C25H22P2)2]·2CH3CN, the AgI atom is coordinated by one P atom from a bis­(diphenyl­phosphan­yl)methane (dppm) ligand, two O atoms from two diphenyl­phosphinate (dpp) ligands and one O atom from a trifluoro­methane­sulfonate (OTf) anion in a highly distorted tetra­hedral geometry. Four AgI atoms are bridged by two dppm ligands, two dpp ligands and two OTf anions, forming a tetra­nuclear complex. An weak intra­molecular Ag⋯Ag [3.2692 (14) Å] inter­action is observed. The OTf anion and one of the phenyl groups in the dppm ligand are disordered over two sets of positions in a 0.546 (4):0.454 (4) ratio. The 0.546-occupied OTf is bonded to two Ag atoms in a μ-(κ2O:O′) mode, while the 0.454-occupied OTf is bonded in a μ-(κ2O:O) mode. The methyl group of the acetonitrile solvent mol­ecule is also disordered over two positions with equal occupancy factors.

Related literature

For related structures, see: Fournier et al. (2004[Fournier, É., Lebrun, F., Drouin, M., Decken, A. & Harvey, P. D. (2004). Inorg. Chem. 43, 3127-3135.]); Matsumoto et al. (2001[Matsumoto, K., Tanaka, R., Shimomura, R., Matsumoto, C. & Nakao, Y. (2001). Inorg. Chim. Acta, 322, 125-129.]); Sun et al. (2011[Sun, D., Luo, G.-G., Zhang, N., Huang, R.-B. & Zheng, L.-S. (2011). Chem. Commun. 47, 1461-1463.]); Wei et al. (2004[Wei, Q.-H., Yin, G.-Q., Zhang, L.-Y., Shi, L.-X., Mao, Z.-W. & Chen, Z.-N. (2004). Inorg. Chem. 43, 3484-3491.]).

[Scheme 1]

Experimental

Crystal data
  • [Ag4(C12H10O2P)2(CF3O3S)2(C25H22P2)2]·2C2H3N

  • Mr = 2014.80

  • Monoclinic, P 21 /n

  • a = 11.730 (7) Å

  • b = 15.169 (9) Å

  • c = 23.688 (12) Å

  • β = 96.967 (7)°

  • V = 4184 (4) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 1.16 mm−1

  • T = 296 K

  • 0.23 × 0.19 × 0.16 mm

Data collection
  • Rigaku Mercury CCD diffractometer

  • Absorption correction: multi-scan (CrystalClear; Rigaku, 2005[Rigaku (2005). CrystalClear. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.777, Tmax = 0.837

  • 41763 measured reflections

  • 9645 independent reflections

  • 7705 reflections with I > 2σ(I)

  • Rint = 0.055

Refinement
  • R[F2 > 2σ(F2)] = 0.055

  • wR(F2) = 0.144

  • S = 1.01

  • 9645 reflections

  • 610 parameters

  • 1173 restraints

  • H-atom parameters constrained

  • Δρmax = 0.64 e Å−3

  • Δρmin = −0.61 e Å−3

Table 1
Selected bond lengths (Å)

Ag1—O1 2.270 (3)
Ag1—O2i 2.435 (3)
Ag1—O3 2.557 (8)
Ag1—O3B 2.672 (11)
Ag1—P2 2.3554 (15)
Ag2—O1i 2.451 (3)
Ag2—O2 2.280 (3)
Ag2—O5i 2.619 (8)
Ag2—O3Bi 2.795 (10)
Ag2—P3 2.3676 (16)
Symmetry code: (i) -x+1, -y+1, -z+1.

Data collection: CrystalClear (Rigaku, 2005[Rigaku (2005). CrystalClear. Rigaku Corporation, Tokyo, Japan.]); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supporting information


Comment top

Silver clusters have been intensively reported in many fields of chemistry (Fournier et al., 2004; Wei et al., 2004). Phosphine ligands, especially the type Ph2P(CH2)nPPh2 ligands, which are known to function as 'stabilizing units' on silver(I) centers, have been used in metal-rich silver chalcogenide clusters (Sun et al., 2011). Information on the structures of tetranuclear silver(I) compounds by the reactions between silver(I) salt and bis(diphenylphosphine)methane (dppm) ligand continues to be reported (Matsumoto et al., 2001).

In the title tetranuclear compound, the dppm ligand links two AgI atoms through the P atoms (Fig. 1). The AgI atom adopts a highly distorted tetrahedral geometry. The Ag—P bond distances are 2.3554 (15) and 2.3676 (16) Å and the Ag—O distances are in the range of 2.270 (3)–2.795 (10) Å (Table 1). An intramolecular Ag···Ag distance is 3.2692 (14) Å. The trifluoromethanesulfonate (OTf) anion and one of the phenyl groups in the dppm ligand are disordered over two sets of positions in an occupancy ratio of 0.546 (4):0.454 (4). The 0.546-occupied OTf is bonded to two Ag atoms in a µ-(κ2O:O') mode, while the 0.454-occupied OTf in a µ-(κ2O:O) mode (Fig. 1).

Related literature top

For related structures, see: Fournier et al. (2004); Matsumoto et al. (2001); Sun et al. (2011); Wei et al. (2004).

Experimental top

Silver trifluoromethanesulfonate (0.052 g, 0.2 mmol) was added with stirring to a solution of diphenylphosphinic acid (0.022 g, 0.1 mmol) and bis(diphenylphosphine)methane (0.038 g, 0.1 mmol) in CH3CN (5 ml). The resulting colorless solution was allowed to stir for 1 h. By slow diffusion of diethyl ether into the solution, prismatic colorless crystals were formed suitable for X-ray diffraction analysis (yield: 20%).

Refinement top

H atoms were positioned geometrically and refined as riding atoms, with C—H = 0.93 (CH), 0.97 (CH2) and 0.96 (CH3) Å and with Uiso(H) = 1.2(1.5 for methyl)Ueq(C).

Computing details top

Data collection: CrystalClear (Rigaku, 2005); cell refinement: CrystalClear (Rigaku, 2005); data reduction: CrystalClear (Rigaku, 2005); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title complex. Displacement ellipsoids are drawn at the 50% probability level. The 0.454-occupied OTf anion and phenyl group are shown with open bonds. [Symmetry code: (i) 1-x, 1-y, 1-z.]
Bis[µ2-bis(diphenylphosphanyl)methane-κ2P:P']bis(µ4- diphenylphosphinato-κ4O:O:O':O')bis[µ2- trifluoromethanesulfonato(0.546/0.454)]- κ2O:O';κ2O:O-tetrasilver(I) acetonitrile disolvate top
Crystal data top
[Ag4(C12H10O2P)2(CF3O3S)2(C25H22P2)2]·2C2H3NF(000) = 2016
Mr = 2014.80Dx = 1.599 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 9952 reflections
a = 11.730 (7) Åθ = 1.6–27.5°
b = 15.169 (9) ŵ = 1.16 mm1
c = 23.688 (12) ÅT = 296 K
β = 96.967 (7)°Prism, colorless
V = 4184 (4) Å30.23 × 0.19 × 0.16 mm
Z = 2
Data collection top
Rigaku Mercury CCD
diffractometer
9645 independent reflections
Radiation source: fine-focus sealed tube7705 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.055
Detector resolution: 13.6612 pixels mm-1θmax = 27.6°, θmin = 2.5°
ω scansh = 1515
Absorption correction: multi-scan
(CrystalClear; Rigaku, 2005)
k = 1919
Tmin = 0.777, Tmax = 0.837l = 3030
41763 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.055Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.144H-atom parameters constrained
S = 1.01 w = 1/[σ2(Fo2) + (0.0595P)2 + 6.765P]
where P = (Fo2 + 2Fc2)/3
9645 reflections(Δ/σ)max = 0.001
610 parametersΔρmax = 0.64 e Å3
1173 restraintsΔρmin = 0.61 e Å3
Crystal data top
[Ag4(C12H10O2P)2(CF3O3S)2(C25H22P2)2]·2C2H3NV = 4184 (4) Å3
Mr = 2014.80Z = 2
Monoclinic, P21/nMo Kα radiation
a = 11.730 (7) ŵ = 1.16 mm1
b = 15.169 (9) ÅT = 296 K
c = 23.688 (12) Å0.23 × 0.19 × 0.16 mm
β = 96.967 (7)°
Data collection top
Rigaku Mercury CCD
diffractometer
9645 independent reflections
Absorption correction: multi-scan
(CrystalClear; Rigaku, 2005)
7705 reflections with I > 2σ(I)
Tmin = 0.777, Tmax = 0.837Rint = 0.055
41763 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0551173 restraints
wR(F2) = 0.144H-atom parameters constrained
S = 1.01Δρmax = 0.64 e Å3
9645 reflectionsΔρmin = 0.61 e Å3
610 parameters
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.47428 (3)0.41739 (2)0.415893 (15)0.05183 (11)
Ag20.33273 (3)0.42158 (2)0.526552 (16)0.05416 (12)
P10.37541 (9)0.60694 (7)0.45735 (5)0.0427 (2)
P20.37149 (10)0.28791 (7)0.38828 (5)0.0456 (2)
P30.24066 (9)0.28840 (7)0.49519 (5)0.0461 (2)
O10.4690 (2)0.5658 (2)0.42767 (13)0.0487 (7)
O20.3558 (3)0.56941 (19)0.51457 (13)0.0501 (7)
C10.4054 (4)0.7227 (3)0.46521 (19)0.0502 (10)
C20.3628 (5)0.7712 (4)0.5078 (3)0.0739 (16)
H2A0.32610.74370.53570.089*
C30.3774 (6)0.8633 (5)0.5072 (4)0.102 (3)
H3A0.34960.89730.53520.122*
C40.4314 (8)0.9038 (5)0.4663 (5)0.115 (3)
H4A0.43800.96480.46590.138*
C50.4748 (7)0.8553 (5)0.4268 (4)0.105 (3)
H5A0.51390.88350.40000.126*
C60.4632 (5)0.7655 (4)0.4246 (2)0.0687 (14)
H6A0.49340.73320.39650.082*
C70.2421 (4)0.6076 (3)0.41141 (19)0.0499 (10)
C80.2426 (6)0.6155 (5)0.3537 (2)0.093 (2)
H8A0.31090.61320.33750.111*
C90.1359 (7)0.6272 (7)0.3197 (3)0.127 (3)
H9A0.13480.63580.28070.153*
C100.0358 (6)0.6261 (6)0.3424 (4)0.109 (3)
H10A0.03370.62990.31900.131*
C110.0372 (5)0.6195 (5)0.3986 (3)0.091 (2)
H11A0.03160.62040.41430.109*
C120.1395 (4)0.6114 (4)0.4336 (3)0.0700 (14)
H12A0.13890.60850.47280.084*
C130.4580 (4)0.2064 (3)0.35683 (19)0.0542 (11)
C140.5547 (5)0.2354 (5)0.3329 (3)0.0808 (17)
H14A0.57370.29490.33430.097*
C150.6219 (6)0.1770 (7)0.3075 (3)0.103 (2)
H15A0.68560.19730.29160.124*
C160.5964 (8)0.0908 (6)0.3056 (3)0.106 (3)
H16A0.64240.05190.28820.127*
C170.5038 (8)0.0600 (4)0.3288 (3)0.100 (3)
H17A0.48770.00010.32770.121*
C180.4324 (6)0.1178 (4)0.3544 (2)0.0771 (16)
H18A0.36830.09650.36960.093*
C190.3169 (4)0.2252 (3)0.44563 (18)0.0484 (9)
H19A0.26550.17990.42850.058*
H19B0.38130.19560.46730.058*
C200.2295 (4)0.2085 (3)0.5520 (2)0.0575 (11)
C210.2167 (6)0.1196 (4)0.5430 (3)0.0844 (18)
H21A0.21400.09690.50640.101*
C220.2077 (7)0.0631 (5)0.5885 (4)0.111 (3)
H22A0.19820.00290.58200.134*
C230.2127 (8)0.0948 (6)0.6421 (4)0.125 (4)
H23A0.20800.05660.67250.150*
C240.2245 (7)0.1826 (7)0.6513 (3)0.109 (3)
H24A0.22670.20430.68810.130*
C250.2334 (5)0.2407 (5)0.6069 (2)0.0773 (16)
H25A0.24180.30090.61390.093*
C260.0955 (4)0.2986 (3)0.4593 (2)0.0548 (11)
C270.0297 (6)0.2276 (5)0.4417 (4)0.122 (3)
H27A0.05800.17100.44920.146*
C280.0801 (6)0.2391 (6)0.4125 (5)0.135 (4)
H28A0.12460.19000.40130.162*
C290.1217 (5)0.3196 (6)0.4006 (3)0.094 (2)
H29A0.19380.32670.38000.112*
C300.0595 (6)0.3893 (5)0.4184 (4)0.107 (3)
H30A0.08970.44530.41100.128*
C310.0496 (5)0.3807 (4)0.4478 (3)0.0821 (18)
H31A0.09170.43070.45970.099*
C320.2483 (6)0.3084 (5)0.3333 (3)0.062 (2)0.546 (4)
C330.1831 (7)0.3845 (5)0.3358 (3)0.083 (3)0.546 (4)
H33A0.20570.42750.36280.100*0.546 (4)
C340.0843 (7)0.3964 (5)0.2978 (4)0.092 (3)0.546 (4)
H34A0.04070.44730.29940.111*0.546 (4)
C350.0506 (7)0.3321 (6)0.2574 (4)0.109 (3)0.546 (4)
H35A0.01550.34000.23200.131*0.546 (4)
C360.1158 (8)0.2560 (6)0.2549 (4)0.107 (3)0.546 (4)
H36A0.09320.21300.22780.129*0.546 (4)
C370.2146 (8)0.2441 (5)0.2928 (4)0.102 (3)0.546 (4)
H37A0.25820.19320.29120.122*0.546 (4)
C32A0.2485 (8)0.3032 (7)0.3374 (4)0.069 (3)0.454 (4)
C33A0.2426 (9)0.3856 (7)0.3116 (5)0.106 (3)0.454 (4)
H33B0.30250.42560.31960.127*0.454 (4)
C34A0.1473 (11)0.4083 (6)0.2737 (5)0.109 (3)0.454 (4)
H34B0.14330.46340.25640.131*0.454 (4)
C35A0.0578 (9)0.3486 (7)0.2616 (5)0.109 (3)0.454 (4)
H35B0.00610.36370.23630.131*0.454 (4)
C36A0.0636 (8)0.2661 (7)0.2875 (5)0.095 (3)0.454 (4)
H36B0.00370.22620.27940.114*0.454 (4)
C37A0.1590 (9)0.2435 (6)0.3254 (4)0.087 (3)0.454 (4)
H37B0.16290.18830.34260.104*0.454 (4)
S30.6892 (4)0.4984 (3)0.3233 (2)0.0534 (9)0.546 (4)
F10.5949 (11)0.5743 (8)0.2281 (4)0.129 (3)0.546 (4)
F20.4775 (11)0.5059 (10)0.2761 (5)0.171 (4)0.546 (4)
F30.5531 (10)0.6323 (7)0.3112 (4)0.116 (3)0.546 (4)
O30.6061 (8)0.4384 (7)0.3385 (4)0.105 (2)0.546 (4)
O40.7736 (8)0.4696 (7)0.2896 (4)0.089 (2)0.546 (4)
O50.7325 (7)0.5485 (6)0.3733 (3)0.090 (2)0.546 (4)
C380.5805 (10)0.5538 (7)0.2844 (4)0.112 (3)0.546 (4)
S3B0.6771 (9)0.5015 (6)0.3148 (4)0.101 (3)0.454 (4)
F1B0.5476 (12)0.5333 (11)0.2273 (6)0.128 (4)0.454 (4)
F2B0.6761 (10)0.6489 (7)0.2723 (5)0.131 (3)0.454 (4)
F3B0.4952 (11)0.5877 (11)0.2957 (6)0.128 (4)0.454 (4)
O3B0.6535 (9)0.4851 (8)0.3711 (4)0.085 (3)0.454 (4)
O4B0.7099 (14)0.4260 (9)0.2841 (5)0.113 (3)0.454 (4)
O5B0.7712 (12)0.5619 (10)0.3130 (6)0.139 (4)0.454 (4)
C38B0.6009 (10)0.5791 (9)0.2748 (6)0.112 (4)0.454 (4)
N10.1746 (8)1.0190 (5)0.4011 (4)0.148 (3)
C390.1507 (8)0.9478 (8)0.3896 (6)0.163 (5)
C40A0.150 (2)0.8812 (15)0.3496 (14)0.212 (9)0.50
H40A0.20940.83950.36150.318*0.50
H40B0.16240.90600.31350.318*0.50
H40C0.07670.85180.34590.318*0.50
C40B0.1071 (16)0.8694 (11)0.4110 (12)0.162 (7)0.50
H40D0.04060.85060.38630.243*0.50
H40E0.08630.87990.44840.243*0.50
H40F0.16490.82430.41290.243*0.50
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0551 (2)0.0487 (2)0.0512 (2)0.00963 (15)0.00500 (15)0.00754 (14)
Ag20.0505 (2)0.0516 (2)0.0602 (2)0.00592 (15)0.00608 (15)0.00487 (15)
P10.0388 (5)0.0407 (5)0.0469 (6)0.0029 (4)0.0016 (4)0.0006 (4)
P20.0493 (6)0.0425 (6)0.0446 (6)0.0038 (5)0.0038 (4)0.0052 (4)
P30.0407 (5)0.0460 (6)0.0517 (6)0.0020 (4)0.0063 (4)0.0041 (5)
O10.0421 (15)0.0478 (16)0.0559 (17)0.0036 (12)0.0049 (12)0.0051 (13)
O20.0537 (17)0.0481 (17)0.0466 (16)0.0017 (13)0.0021 (13)0.0021 (12)
C10.045 (2)0.041 (2)0.061 (3)0.0041 (18)0.0083 (19)0.0002 (18)
C20.067 (3)0.056 (3)0.094 (4)0.012 (3)0.009 (3)0.024 (3)
C30.086 (5)0.067 (4)0.142 (7)0.027 (4)0.027 (4)0.042 (4)
C40.109 (6)0.043 (3)0.176 (9)0.007 (4)0.055 (6)0.008 (4)
C50.115 (6)0.059 (4)0.130 (6)0.018 (4)0.031 (5)0.036 (4)
C60.073 (3)0.057 (3)0.072 (3)0.009 (3)0.008 (3)0.020 (2)
C70.045 (2)0.049 (2)0.053 (2)0.0040 (19)0.0026 (18)0.0054 (19)
C80.076 (4)0.146 (6)0.053 (3)0.007 (4)0.006 (3)0.010 (4)
C90.097 (6)0.210 (10)0.064 (4)0.013 (6)0.031 (4)0.004 (5)
C100.067 (4)0.147 (7)0.103 (6)0.017 (4)0.036 (4)0.010 (5)
C110.045 (3)0.107 (5)0.115 (6)0.011 (3)0.011 (3)0.010 (4)
C120.052 (3)0.076 (4)0.078 (4)0.011 (3)0.006 (2)0.009 (3)
C130.062 (3)0.054 (3)0.047 (2)0.006 (2)0.0042 (19)0.0079 (19)
C140.070 (4)0.091 (4)0.086 (4)0.001 (3)0.025 (3)0.023 (3)
C150.085 (5)0.140 (7)0.089 (5)0.027 (5)0.031 (4)0.015 (5)
C160.130 (7)0.121 (7)0.066 (4)0.071 (6)0.015 (4)0.004 (4)
C170.176 (8)0.062 (4)0.063 (4)0.039 (4)0.014 (4)0.003 (3)
C180.117 (5)0.053 (3)0.065 (3)0.009 (3)0.025 (3)0.005 (2)
C190.044 (2)0.044 (2)0.057 (2)0.0055 (18)0.0060 (18)0.0000 (18)
C200.052 (3)0.062 (3)0.060 (3)0.007 (2)0.015 (2)0.016 (2)
C210.099 (5)0.069 (4)0.091 (4)0.006 (3)0.039 (4)0.024 (3)
C220.121 (6)0.079 (5)0.145 (7)0.018 (4)0.060 (5)0.054 (5)
C230.133 (7)0.130 (7)0.125 (7)0.052 (6)0.066 (6)0.081 (6)
C240.103 (5)0.159 (8)0.069 (4)0.048 (5)0.029 (4)0.042 (5)
C250.074 (4)0.101 (5)0.058 (3)0.014 (3)0.016 (3)0.022 (3)
C260.038 (2)0.061 (3)0.066 (3)0.006 (2)0.0057 (19)0.005 (2)
C270.061 (4)0.062 (4)0.227 (10)0.007 (3)0.045 (5)0.003 (5)
C280.064 (4)0.104 (6)0.222 (10)0.020 (4)0.045 (5)0.005 (6)
C290.050 (3)0.119 (6)0.107 (5)0.005 (4)0.011 (3)0.027 (4)
C300.072 (4)0.088 (5)0.149 (7)0.013 (4)0.034 (4)0.025 (5)
C310.065 (3)0.066 (4)0.108 (5)0.005 (3)0.019 (3)0.013 (3)
C320.069 (5)0.052 (4)0.060 (4)0.010 (4)0.012 (4)0.001 (4)
C330.089 (5)0.072 (5)0.079 (5)0.002 (5)0.026 (4)0.003 (4)
C340.092 (5)0.085 (5)0.091 (5)0.004 (5)0.023 (5)0.012 (5)
C350.106 (6)0.094 (5)0.112 (6)0.017 (5)0.046 (5)0.010 (5)
C360.107 (6)0.101 (5)0.102 (6)0.009 (5)0.039 (5)0.014 (5)
C370.102 (6)0.087 (5)0.104 (6)0.007 (5)0.039 (5)0.008 (5)
C32A0.075 (5)0.060 (5)0.067 (5)0.013 (5)0.014 (5)0.007 (5)
C33A0.109 (6)0.089 (6)0.106 (6)0.014 (5)0.040 (5)0.023 (5)
C34A0.108 (6)0.096 (6)0.111 (6)0.015 (5)0.036 (5)0.019 (5)
C35A0.107 (6)0.096 (6)0.111 (6)0.014 (5)0.044 (5)0.017 (5)
C36A0.091 (6)0.090 (5)0.095 (6)0.019 (5)0.029 (5)0.003 (5)
C37A0.088 (6)0.079 (5)0.084 (6)0.019 (5)0.030 (5)0.007 (5)
S30.0522 (16)0.0584 (18)0.0537 (18)0.0065 (14)0.0231 (14)0.0032 (14)
F10.153 (8)0.160 (8)0.076 (5)0.043 (6)0.025 (5)0.049 (5)
F20.154 (7)0.197 (8)0.151 (7)0.012 (7)0.027 (6)0.005 (7)
F30.136 (7)0.114 (6)0.099 (5)0.042 (5)0.014 (5)0.004 (4)
O30.113 (5)0.118 (6)0.093 (5)0.016 (5)0.049 (4)0.005 (4)
O40.090 (5)0.114 (6)0.072 (4)0.023 (5)0.049 (4)0.009 (4)
O50.100 (5)0.099 (5)0.073 (5)0.000 (5)0.022 (4)0.007 (4)
C380.105 (6)0.138 (7)0.094 (6)0.051 (5)0.015 (5)0.040 (6)
S3B0.114 (5)0.113 (5)0.078 (4)0.020 (4)0.025 (3)0.001 (3)
F1B0.116 (8)0.157 (9)0.110 (7)0.004 (7)0.008 (6)0.003 (7)
F2B0.151 (7)0.123 (7)0.125 (6)0.012 (6)0.043 (6)0.038 (5)
F3B0.109 (7)0.162 (9)0.122 (7)0.061 (6)0.045 (6)0.020 (7)
O3B0.086 (6)0.115 (7)0.060 (5)0.006 (5)0.029 (4)0.005 (5)
O4B0.140 (8)0.126 (8)0.078 (6)0.040 (7)0.033 (6)0.011 (6)
O5B0.134 (8)0.156 (8)0.133 (8)0.034 (7)0.047 (7)0.001 (7)
C38B0.119 (7)0.133 (7)0.091 (7)0.019 (7)0.049 (6)0.028 (7)
N10.151 (7)0.080 (5)0.205 (8)0.016 (5)0.011 (6)0.017 (5)
C390.092 (6)0.102 (7)0.276 (13)0.005 (5)0.052 (7)0.025 (8)
C40A0.176 (17)0.173 (17)0.27 (2)0.027 (15)0.042 (17)0.088 (16)
C40B0.092 (11)0.120 (13)0.261 (19)0.028 (10)0.032 (13)0.057 (14)
Geometric parameters (Å, º) top
Ag1—O12.270 (3)C22—H22A0.9300
Ag1—O2i2.435 (3)C23—C241.353 (13)
Ag1—O32.557 (8)C23—H23A0.9300
Ag1—O3B2.672 (11)C24—C251.386 (9)
Ag1—P22.3554 (15)C24—H24A0.9300
Ag2—O1i2.451 (3)C25—H25A0.9300
Ag2—O22.280 (3)C26—C271.360 (8)
Ag2—O5i2.619 (8)C26—C311.371 (5)
Ag2—O3Bi2.795 (10)C27—C281.396 (9)
Ag2—P32.3676 (16)C27—H27A0.9300
Ag1—Ag23.2692 (14)C28—C291.333 (11)
P1—O11.509 (3)C28—H28A0.9300
P1—O21.513 (3)C29—C301.324 (10)
P1—C71.794 (4)C29—H29A0.9300
P1—C11.796 (5)C30—C311.387 (8)
P2—C32A1.779 (7)C30—H30A0.9300
P2—C131.816 (5)C31—H31A0.9300
P2—C191.836 (4)C32—C331.3900
P2—C321.851 (6)C32—C371.3900
P3—C261.815 (5)C33—C341.3900
P3—C201.827 (5)C33—H33A0.9300
P3—C191.831 (5)C34—C351.3900
C1—C21.389 (7)C34—H34A0.9300
C1—C61.402 (7)C35—C361.3900
C2—C31.409 (9)C35—H35A0.9300
C2—H2A0.9300C36—C371.3900
C3—C41.366 (12)C36—H36A0.9300
C3—H3A0.9300C37—H37A0.9300
C4—C51.337 (12)C32A—C33A1.3900
C4—H4A0.9300C32A—C37A1.3900
C5—C61.370 (9)C33A—C34A1.3900
C5—H5A0.9300C33A—H33B0.9300
C6—H6A0.9300C34A—C35A1.3900
C7—C121.371 (7)C34A—H34B0.9300
C7—C81.373 (7)C35A—C36A1.3900
C8—C91.415 (9)C35A—H35B0.9300
C8—H8A0.9300C36A—C37A1.3900
C9—C101.350 (11)C36A—H36B0.9300
C9—H9A0.9300C37A—H37B0.9300
C10—C111.332 (10)S3—O31.412 (8)
C10—H10A0.9300S3—O41.415 (6)
C11—C121.379 (7)S3—O51.446 (7)
C11—H11A0.9300S3—C381.702 (10)
C12—H12A0.9300F1—C381.399 (8)
C13—C181.376 (7)F2—C381.402 (8)
C13—C141.399 (8)F3—C381.405 (8)
C14—C151.372 (9)S3B—O3B1.416 (9)
C14—H14A0.9300S3B—O4B1.434 (8)
C15—C161.340 (12)S3B—O5B1.439 (8)
C15—H15A0.9300S3B—C38B1.696 (12)
C16—C171.359 (12)F1B—C38B1.403 (8)
C16—H16A0.9300F2B—C38B1.384 (8)
C17—C181.401 (9)F3B—C38B1.396 (8)
C17—H17A0.9300N1—C391.141 (11)
C18—H18A0.9300C39—C40A1.39 (2)
C19—H19A0.9700C39—C40B1.413 (19)
C19—H19B0.9700C40A—H40A0.9600
C20—C211.372 (8)C40A—H40B0.9600
C20—C251.385 (8)C40A—H40C0.9600
C21—C221.390 (9)C40B—H40D0.9600
C21—H21A0.9300C40B—H40E0.9600
C22—C231.353 (13)C40B—H40F0.9600
O1—Ag1—P2147.19 (8)C20—C21—C22120.2 (7)
O1—Ag1—O2i82.38 (10)C20—C21—H21A119.9
P2—Ag1—O2i127.29 (8)C22—C21—H21A119.9
O1—Ag1—O389.6 (2)C23—C22—C21120.6 (8)
P2—Ag1—O3103.8 (2)C23—C22—H22A119.7
O2i—Ag1—O387.6 (3)C21—C22—H22A119.7
O1—Ag1—Ag281.85 (8)C24—C23—C22119.5 (7)
P2—Ag1—Ag286.92 (4)C24—C23—H23A120.2
O2i—Ag1—Ag284.82 (9)C22—C23—H23A120.2
O3—Ag1—Ag2169.2 (2)C23—C24—C25121.3 (8)
O2—Ag2—P3148.93 (8)C23—C24—H24A119.3
O2—Ag2—O1i81.83 (10)C25—C24—H24A119.3
P3—Ag2—O1i125.28 (8)C20—C25—C24119.4 (7)
O2—Ag2—Ag180.79 (8)C20—C25—H25A120.3
P3—Ag2—Ag189.34 (4)C24—C25—H25A120.3
O1i—Ag2—Ag179.01 (8)C27—C26—C31117.6 (5)
O1—P1—O2117.39 (19)C27—C26—P3122.8 (4)
O1—P1—C7110.5 (2)C31—C26—P3119.6 (4)
O2—P1—C7109.2 (2)C26—C27—C28120.5 (7)
O1—P1—C1107.9 (2)C26—C27—H27A119.7
O2—P1—C1108.9 (2)C28—C27—H27A119.7
C7—P1—C1101.7 (2)C29—C28—C27120.8 (7)
C32A—P2—C13105.0 (4)C29—C28—H28A119.6
C32A—P2—C19104.0 (4)C27—C28—H28A119.6
C13—P2—C19102.3 (2)C30—C29—C28119.3 (6)
C13—P2—C32104.6 (3)C30—C29—H29A120.3
C19—P2—C32107.2 (3)C28—C29—H29A120.3
C32A—P2—Ag1115.2 (3)C29—C30—C31121.7 (7)
C13—P2—Ag1112.91 (17)C29—C30—H30A119.2
C19—P2—Ag1116.07 (15)C31—C30—H30A119.2
C32—P2—Ag1112.7 (3)C26—C31—C30120.1 (6)
C26—P3—C20104.8 (2)C26—C31—H31A120.0
C26—P3—C19104.3 (2)C30—C31—H31A120.0
C20—P3—C19102.1 (2)C33—C32—C37120.0
C26—P3—Ag2116.15 (16)C33—C32—P2119.7 (4)
C20—P3—Ag2113.91 (18)C37—C32—P2120.0 (4)
C19—P3—Ag2114.10 (14)C32—C33—C34120.0
P1—O1—Ag1119.96 (17)C32—C33—H33A120.0
P1—O1—Ag2i117.81 (16)C34—C33—H33A120.0
Ag1—O1—Ag2i95.36 (10)C33—C34—C35120.0
P1—O2—Ag2120.97 (17)C33—C34—H34A120.0
P1—O2—Ag1i111.96 (17)C35—C34—H34A120.0
Ag2—O2—Ag1i95.53 (10)C36—C35—C34120.0
C2—C1—C6120.0 (5)C36—C35—H35A120.0
C2—C1—P1120.6 (4)C34—C35—H35A120.0
C6—C1—P1119.1 (4)C35—C36—C37120.0
C1—C2—C3117.6 (7)C35—C36—H36A120.0
C1—C2—H2A121.2C37—C36—H36A120.0
C3—C2—H2A121.2C36—C37—C32120.0
C4—C3—C2121.3 (7)C36—C37—H37A120.0
C4—C3—H3A119.3C32—C37—H37A120.0
C2—C3—H3A119.3C33A—C32A—C37A120.0
C5—C4—C3119.9 (7)C33A—C32A—P2114.1 (6)
C5—C4—H4A120.1C37A—C32A—P2125.8 (6)
C3—C4—H4A120.1C34A—C33A—C32A120.0
C4—C5—C6121.9 (8)C34A—C33A—H33B120.0
C4—C5—H5A119.1C32A—C33A—H33B120.0
C6—C5—H5A119.1C33A—C34A—C35A120.0
C5—C6—C1119.2 (7)C33A—C34A—H34B120.0
C5—C6—H6A120.4C35A—C34A—H34B120.0
C1—C6—H6A120.4C36A—C35A—C34A120.0
C12—C7—C8119.2 (5)C36A—C35A—H35B120.0
C12—C7—P1120.6 (4)C34A—C35A—H35B120.0
C8—C7—P1119.7 (4)C37A—C36A—C35A120.0
C7—C8—C9117.9 (7)C37A—C36A—H36B120.0
C7—C8—H8A121.1C35A—C36A—H36B120.0
C9—C8—H8A121.1C36A—C37A—C32A120.0
C10—C9—C8121.6 (7)C36A—C37A—H37B120.0
C10—C9—H9A119.2C32A—C37A—H37B120.0
C8—C9—H9A119.2O3—S3—O4119.8 (7)
C11—C10—C9119.5 (6)O3—S3—O5108.4 (7)
C11—C10—H10A120.2O4—S3—O5115.1 (7)
C9—C10—H10A120.2O3—S3—C3887.8 (7)
C10—C11—C12120.8 (7)O4—S3—C38112.1 (6)
C10—C11—H11A119.6O5—S3—C38110.4 (6)
C12—C11—H11A119.6S3—O3—Ag1139.4 (7)
C7—C12—C11120.9 (6)F1—C38—F2100.5 (10)
C7—C12—H12A119.6F1—C38—F3107.5 (10)
C11—C12—H12A119.6F2—C38—F3105.2 (10)
C18—C13—C14118.3 (5)F1—C38—S3117.2 (8)
C18—C13—P2123.5 (4)F2—C38—S3113.3 (9)
C14—C13—P2118.2 (4)F3—C38—S3111.8 (8)
C15—C14—C13120.8 (7)O3B—S3B—O4B115.6 (10)
C15—C14—H14A119.6O3B—S3B—O5B112.3 (10)
C13—C14—H14A119.6O4B—S3B—O5B103.8 (11)
C16—C15—C14120.4 (8)O3B—S3B—C38B119.9 (8)
C16—C15—H15A119.8O4B—S3B—C38B115.2 (9)
C14—C15—H15A119.8O5B—S3B—C38B84.0 (9)
C15—C16—C17120.5 (7)F2B—C38B—F3B122.8 (14)
C15—C16—H16A119.7F2B—C38B—F1B124.6 (13)
C17—C16—H16A119.7F3B—C38B—F1B90.2 (12)
C16—C17—C18120.6 (7)F2B—C38B—S3B105.0 (9)
C16—C17—H17A119.7F3B—C38B—S3B107.3 (10)
C18—C17—H17A119.7F1B—C38B—S3B104.9 (11)
C13—C18—C17119.4 (7)N1—C39—C40A147 (2)
C13—C18—H18A120.3N1—C39—C40B143 (2)
C17—C18—H18A120.3C40A—C39—C40B70.0 (17)
P3—C19—P2116.4 (2)C39—C40A—H40A109.5
P3—C19—H19A108.2C39—C40A—H40B109.5
P2—C19—H19A108.2C39—C40A—H40C109.5
P3—C19—H19B108.2C39—C40B—H40D109.5
P2—C19—H19B108.2C39—C40B—H40E109.5
H19A—C19—H19B107.3H40D—C40B—H40E109.5
C21—C20—C25118.9 (5)C39—C40B—H40F109.5
C21—C20—P3123.7 (4)H40D—C40B—H40F109.5
C25—C20—P3117.4 (4)H40E—C40B—H40F109.5
O1—Ag1—Ag2—O20.50 (10)P2—C13—C14—C15178.7 (5)
P2—Ag1—Ag2—O2148.59 (8)C13—C14—C15—C160.5 (11)
O2i—Ag1—Ag2—O283.53 (11)C14—C15—C16—C170.2 (12)
O3—Ag1—Ag2—O238.0 (13)C15—C16—C17—C181.0 (12)
O1—Ag1—Ag2—P3150.92 (8)C14—C13—C18—C170.6 (9)
P2—Ag1—Ag2—P31.83 (4)P2—C13—C18—C17179.4 (5)
O2i—Ag1—Ag2—P3126.06 (8)C16—C17—C18—C131.2 (10)
O3—Ag1—Ag2—P3171.6 (13)C26—P3—C19—P282.8 (3)
O1—Ag1—Ag2—O1i82.88 (11)C20—P3—C19—P2168.3 (2)
P2—Ag1—Ag2—O1i128.03 (8)Ag2—P3—C19—P245.0 (3)
O2i—Ag1—Ag2—O1i0.14 (10)C32A—P2—C19—P379.4 (5)
O3—Ag1—Ag2—O1i45.4 (13)C13—P2—C19—P3171.6 (2)
O1—Ag1—P2—C32A27.5 (5)C32—P2—C19—P378.7 (4)
O2i—Ag1—P2—C32A178.4 (5)Ag1—P2—C19—P348.2 (3)
O3—Ag1—P2—C32A84.0 (5)C26—P3—C20—C2174.9 (5)
Ag2—Ag1—P2—C32A97.3 (5)C19—P3—C20—C2133.6 (5)
O1—Ag1—P2—C13148.0 (2)Ag2—P3—C20—C21157.1 (4)
O2i—Ag1—P2—C1361.1 (2)C26—P3—C20—C25104.5 (4)
O3—Ag1—P2—C1336.6 (3)C19—P3—C20—C25147.0 (4)
Ag2—Ag1—P2—C13142.17 (16)Ag2—P3—C20—C2523.5 (4)
O1—Ag1—P2—C1994.3 (2)C25—C20—C21—C220.0 (9)
O2i—Ag1—P2—C1956.58 (19)P3—C20—C21—C22179.4 (5)
O3—Ag1—P2—C19154.2 (3)C20—C21—C22—C230.7 (12)
Ag2—Ag1—P2—C1924.53 (16)C21—C22—C23—C241.2 (13)
O1—Ag1—P2—C3229.8 (4)C22—C23—C24—C250.9 (13)
O2i—Ag1—P2—C32179.4 (3)C21—C20—C25—C240.2 (9)
O3—Ag1—P2—C3281.7 (4)P3—C20—C25—C24179.6 (5)
Ag2—Ag1—P2—C3299.5 (3)C23—C24—C25—C200.3 (11)
O2—Ag2—P3—C2630.1 (3)C20—P3—C26—C2749.7 (7)
O1i—Ag2—P3—C26176.92 (19)C19—P3—C26—C2757.2 (7)
Ag1—Ag2—P3—C26100.90 (18)Ag2—P3—C26—C27176.3 (6)
O2—Ag2—P3—C20152.0 (2)C20—P3—C26—C31131.9 (5)
O1i—Ag2—P3—C2061.20 (19)C19—P3—C26—C31121.2 (5)
Ag1—Ag2—P3—C20137.22 (17)Ag2—P3—C26—C315.3 (5)
O2—Ag2—P3—C1991.3 (2)C31—C26—C27—C280.7 (13)
O1i—Ag2—P3—C1955.48 (19)P3—C26—C27—C28177.8 (8)
Ag1—Ag2—P3—C1920.54 (16)C26—C27—C28—C291.0 (16)
O2—P1—O1—Ag151.1 (2)C27—C28—C29—C302.3 (15)
C7—P1—O1—Ag175.0 (2)C28—C29—C30—C312.0 (14)
C1—P1—O1—Ag1174.54 (18)C27—C26—C31—C301.0 (11)
O2—P1—O1—Ag2i64.2 (2)P3—C26—C31—C30177.5 (6)
C7—P1—O1—Ag2i169.74 (19)C29—C30—C31—C260.3 (13)
C1—P1—O1—Ag2i59.3 (2)C32A—P2—C32—C33103 (10)
P2—Ag1—O1—P146.6 (3)C13—P2—C32—C33161.2 (5)
O2i—Ag1—O1—P1110.4 (2)C19—P2—C32—C3390.7 (5)
O3—Ag1—O1—P1162.0 (3)Ag1—P2—C32—C3338.2 (6)
Ag2—Ag1—O1—P124.58 (17)C32A—P2—C32—C3771 (10)
P2—Ag1—O1—Ag2i173.13 (7)C13—P2—C32—C3724.8 (6)
O2i—Ag1—O1—Ag2i16.11 (11)C19—P2—C32—C3783.3 (6)
O3—Ag1—O1—Ag2i71.5 (3)Ag1—P2—C32—C37147.9 (5)
Ag2—Ag1—O1—Ag2i101.93 (9)C37—C32—C33—C340.0
O1—P1—O2—Ag250.8 (3)P2—C32—C33—C34174.0 (7)
C7—P1—O2—Ag275.9 (2)C32—C33—C34—C350.0
C1—P1—O2—Ag2173.76 (18)C33—C34—C35—C360.0
O1—P1—O2—Ag1i60.5 (2)C34—C35—C36—C370.0
C7—P1—O2—Ag1i172.76 (17)C35—C36—C37—C320.0
C1—P1—O2—Ag1i62.5 (2)C33—C32—C37—C360.0
P3—Ag2—O2—P149.5 (3)P2—C32—C37—C36174.0 (7)
O1i—Ag2—O2—P1103.7 (2)C13—P2—C32A—C33A111.7 (6)
Ag1—Ag2—O2—P123.58 (18)C19—P2—C32A—C33A141.2 (6)
P3—Ag2—O2—Ag1i169.22 (8)C32—P2—C32A—C33A27 (10)
O1i—Ag2—O2—Ag1i16.06 (11)Ag1—P2—C32A—C33A13.1 (7)
Ag1—Ag2—O2—Ag1i96.17 (10)C13—P2—C32A—C37A72.7 (8)
O1—P1—C1—C2155.7 (4)C19—P2—C32A—C37A34.4 (9)
O2—P1—C1—C227.2 (4)C32—P2—C32A—C37A157 (11)
C7—P1—C1—C288.0 (4)Ag1—P2—C32A—C37A162.5 (7)
O1—P1—C1—C630.2 (4)C37A—C32A—C33A—C34A0.0
O2—P1—C1—C6158.7 (3)P2—C32A—C33A—C34A175.9 (9)
C7—P1—C1—C686.1 (4)C32A—C33A—C34A—C35A0.0
C6—C1—C2—C31.8 (7)C33A—C34A—C35A—C36A0.0
P1—C1—C2—C3172.3 (4)C34A—C35A—C36A—C37A0.0
C1—C2—C3—C40.0 (9)C35A—C36A—C37A—C32A0.0
C2—C3—C4—C52.0 (11)C33A—C32A—C37A—C36A0.0
C3—C4—C5—C62.4 (11)P2—C32A—C37A—C36A175.4 (10)
C4—C5—C6—C10.7 (10)O4—S3—O3—Ag1155.6 (8)
C2—C1—C6—C51.5 (7)O5—S3—O3—Ag120.7 (12)
P1—C1—C6—C5172.7 (4)C38—S3—O3—Ag190.1 (10)
O1—P1—C7—C12156.6 (4)O1—Ag1—O3—S328.5 (10)
O2—P1—C7—C1226.0 (5)P2—Ag1—O3—S3178.2 (10)
C1—P1—C7—C1289.0 (5)O2i—Ag1—O3—S353.9 (10)
O1—P1—C7—C831.7 (5)Ag2—Ag1—O3—S39 (2)
O2—P1—C7—C8162.2 (5)O3—S3—C38—F1130.0 (11)
C1—P1—C7—C882.7 (5)O4—S3—C38—F18.5 (13)
C12—C7—C8—C90.1 (11)O5—S3—C38—F1121.2 (10)
P1—C7—C8—C9172.0 (7)O3—S3—C38—F213.5 (10)
C7—C8—C9—C103.4 (14)O4—S3—C38—F2107.9 (10)
C8—C9—C10—C114.4 (16)O5—S3—C38—F2122.3 (9)
C9—C10—C11—C121.8 (14)O3—S3—C38—F3105.2 (10)
C8—C7—C12—C112.6 (9)O4—S3—C38—F3133.3 (10)
P1—C7—C12—C11174.4 (5)O5—S3—C38—F33.6 (11)
C10—C11—C12—C71.7 (11)O3B—S3B—C38B—F2B107.0 (12)
C32A—P2—C13—C1875.7 (6)O4B—S3B—C38B—F2B107.8 (12)
C19—P2—C13—C1832.6 (5)O5B—S3B—C38B—F2B5.3 (11)
C32—P2—C13—C1879.1 (5)O3B—S3B—C38B—F3B25.1 (16)
Ag1—P2—C13—C18158.1 (4)O4B—S3B—C38B—F3B120.1 (15)
C32A—P2—C13—C14103.2 (5)O5B—S3B—C38B—F3B137.5 (13)
C19—P2—C13—C14148.5 (4)O3B—S3B—C38B—F1B120.1 (13)
C32—P2—C13—C1499.8 (5)O4B—S3B—C38B—F1B25.1 (14)
Ag1—P2—C13—C1423.1 (5)O5B—S3B—C38B—F1B127.6 (11)
C18—C13—C14—C150.3 (9)
Symmetry code: (i) x+1, y+1, z+1.

Experimental details

Crystal data
Chemical formula[Ag4(C12H10O2P)2(CF3O3S)2(C25H22P2)2]·2C2H3N
Mr2014.80
Crystal system, space groupMonoclinic, P21/n
Temperature (K)296
a, b, c (Å)11.730 (7), 15.169 (9), 23.688 (12)
β (°) 96.967 (7)
V3)4184 (4)
Z2
Radiation typeMo Kα
µ (mm1)1.16
Crystal size (mm)0.23 × 0.19 × 0.16
Data collection
DiffractometerRigaku Mercury CCD
diffractometer
Absorption correctionMulti-scan
(CrystalClear; Rigaku, 2005)
Tmin, Tmax0.777, 0.837
No. of measured, independent and
observed [I > 2σ(I)] reflections
41763, 9645, 7705
Rint0.055
(sin θ/λ)max1)0.651
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.055, 0.144, 1.01
No. of reflections9645
No. of parameters610
No. of restraints1173
H-atom treatmentH-atom parameters constrained
Δρmax, Δρmin (e Å3)0.64, 0.61

Computer programs: CrystalClear (Rigaku, 2005), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

Selected bond lengths (Å) top
Ag1—O12.270 (3)Ag2—O1i2.451 (3)
Ag1—O2i2.435 (3)Ag2—O22.280 (3)
Ag1—O32.557 (8)Ag2—O5i2.619 (8)
Ag1—O3B2.672 (11)Ag2—O3Bi2.795 (10)
Ag1—P22.3554 (15)Ag2—P32.3676 (16)
Symmetry code: (i) x+1, y+1, z+1.
 

References

First citationFournier, É., Lebrun, F., Drouin, M., Decken, A. & Harvey, P. D. (2004). Inorg. Chem. 43, 3127–3135.  Web of Science CSD CrossRef PubMed CAS Google Scholar
First citationMatsumoto, K., Tanaka, R., Shimomura, R., Matsumoto, C. & Nakao, Y. (2001). Inorg. Chim. Acta, 322, 125–129.  Web of Science CSD CrossRef CAS Google Scholar
First citationRigaku (2005). CrystalClear. Rigaku Corporation, Tokyo, Japan.  Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationSun, D., Luo, G.-G., Zhang, N., Huang, R.-B. & Zheng, L.-S. (2011). Chem. Commun. 47, 1461–1463.  Web of Science CSD CrossRef CAS Google Scholar
First citationWei, Q.-H., Yin, G.-Q., Zhang, L.-Y., Shi, L.-X., Mao, Z.-W. & Chen, Z.-N. (2004). Inorg. Chem. 43, 3484–3491.  Web of Science CSD CrossRef PubMed CAS Google Scholar

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Volume 67| Part 8| August 2011| Pages m1141-m1142
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