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Figure 1 Single-crystal X-ray structure of MnII(OAc)2[15-MCMnIIIN(shi)-5](EtIm)4(DMF)2·Diethyl ether·DMF·MeOH·0.14H2O (1). The thermal ellipsoid plot of 1 is at a 50% probability level. All atoms composing the MC ring are labeled. Hydrogen atoms and the lattice solvent molecules have been omitted for clarity. Color scheme for all figures: purple - MnII and MnIII, red - oxygen, blue - nitrogen, and gray - carbon. |