metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 68| Part 1| January 2012| Pages m21-m22

Poly[[hexa­aqua­(μ2-oxalato-κ4O1,O2:O1′,O2′)bis­(μ3-pyridine-2,4-di­carboxyl­ato-κ4N,O1:O1′:O4)dicerium(III)] monohydrate]

aDepartment of Biotechnology, Yuanpei University, HsinChu 30015, Taiwan, and bDepartment of General Education Center, Yuanpei University, HsinChu 30015, Taiwan
*Correspondence e-mail: lush@mail.ypu.edu.tw

(Received 28 November 2011; accepted 1 December 2011; online 7 December 2011)

In the polymeric title compound, {[Ce2(C7H3NO4)2(C2O4)(H2O)6]·H2O}n, the Ce3+ cation is nine-coordinated in a distorted CeNO8 tricapped trigonal–prismatic geometry, formed by three pyridine-2,4-dicarboxyl­ate anions, one oxalate anion and three water mol­ecules. The mid-point of the oxalate anion is located on an inversion center. The oxalate and pyridine-2,4-dicarboxyl­ate anions bridge the Ce3+ cations, forming a two-dimensional polymeric complex parallel to (010). Inter­molecular classical O—H⋯O hydrogen bonding and weak C—H⋯O hydrogen bonding are present in the crystal structure and ππ stacking [centroid–centroid distance = 3.558 (2) Å] is observed between parallel pyridine rings of adjacent mol­ecules. The uncoordinated water mol­ecule shows an occupancy of 0.5.

Related literature

For the isotypic La3+ complex, see: Shen & Lush (2011[Shen, F. M. & Lush, S. F. (2011). Acta Cryst. E67, m1731-m1732.]). For related pyridine-2,4-dicarboxyl­ate complexes, see: Aghabozorg et al. (2011[Aghabozorg, H., Jafarbak, F., Mirzaei, M. & Notash, B. (2011). Acta Cryst. E67, m435-m436.]); Li et al. (2007[Li, X.-M., Niu, Y.-L., Wang, Q.-W. & Liu, B. (2007). Acta Cryst. E63, m487-m488.]); Wang et al. (2009[Wang, G.-H., Li, Z.-G., Jia, H.-Q., Hu, N.-H. & Xu, J.-W. (2009). Acta Cryst. E65, m1568-m1569.]).

[Scheme 1]

Experimental

Crystal data
  • [Ce2(C7H3NO4)2(C2O4)(H2O)6]·H2O

  • Mr = 824.58

  • Triclinic, [P \overline 1]

  • a = 6.4160 (5) Å

  • b = 6.6486 (6) Å

  • c = 13.9920 (12) Å

  • α = 89.917 (1)°

  • β = 85.588 (1)°

  • γ = 73.676 (1)°

  • V = 570.98 (8) Å3

  • Z = 1

  • Mo Kα radiation

  • μ = 4.04 mm−1

  • T = 294 K

  • 0.30 × 0.10 × 0.10 mm

Data collection
  • Bruker SMART 1000 CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.639, Tmax = 0.937

  • 6072 measured reflections

  • 2664 independent reflections

  • 2416 reflections with I > 2σ(I)

  • Rint = 0.030

Refinement
  • R[F2 > 2σ(F2)] = 0.028

  • wR(F2) = 0.081

  • S = 1.10

  • 2664 reflections

  • 177 parameters

  • H-atom parameters constrained

  • Δρmax = 2.75 e Å−3

  • Δρmin = −2.70 e Å−3

Table 1
Selected bond lengths (Å)

Ce—N1 2.684 (3)
Ce—O1i 2.409 (4)
Ce—O3ii 2.505 (3)
Ce—O4 2.511 (3)
Ce—O5 2.508 (3)
Ce—O6iii 2.515 (3)
Ce—O7 2.568 (5)
Ce—O8 2.515 (4)
Ce—O9 2.582 (5)
Symmetry codes: (i) -x+1, -y+1, -z+1; (ii) x-1, y, z; (iii) -x+1, -y+1, -z+2.

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
O7—H7A⋯O4ii 0.86 2.03 2.879 (6) 171
O7—H7B⋯O10iv 0.83 1.84 2.569 (10) 146
O8—H8A⋯O6v 0.92 2.00 2.910 (5) 170
O8—H8B⋯O2vi 0.86 1.84 2.655 (6) 159
O9—H9A⋯O6v 0.99 2.01 2.987 (6) 169
O9—H9B⋯O10 0.84 1.93 2.440 (10) 118
O10—H10A⋯O5ii 0.84 2.12 2.844 (9) 143
O10—H10A⋯O8ii 0.84 2.39 2.913 (10) 121
O10—H10B⋯O9vii 0.94 1.63 2.501 (11) 153
C5—H5A⋯O3ii 0.93 2.46 3.131 (5) 129
Symmetry codes: (ii) x-1, y, z; (iv) x, y+1, z; (v) -x+1, -y, -z+2; (vi) -x+2, -y, -z+1; (vii) -x, -y, -z+2.

Data collection: SMART (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]); software used to prepare material for publication: PLATON.

Supporting information


Comment top

The pyridine-2,4-dicarboxylic acid (pdcH2) has important coordination functions to metals by either carboxylate bridges between metal centers, to form dimeric complexes or tridentate (O, N, O') chelation to metal ions. Some pydc complexes have been reported (Li et al., 2007; Wang et al., 2009; Aghabozorg et al., 2011).

The title complex is isomorphous with the La3+ complex (Shen & Lush, 2011). The CeIII is nine-coordinated in a distorted tricapped trigonal prismatic geometry formed by N and O atoms from a pydc ligand, two O atoms from two pydc ligands, two O atoms from one oxalate ligand and three O atoms from coordinated water molecules (shown as Fig. 1, Table 1). The mid-point of the oxalate anion is located on an inversion center. The oxalate and pyridinedicarboxylate anions bridge the Ce3+ cations to form the polymeric complex (Fig. 2).

The crystal structure contains O—H···O and weak C—H···O hydrogen bonds. The π-π stacking between two pyridine rings of (pydc) anion fragments with centroids distance of 3.558 (2) Å (1 - x, 1 - y, 1 - z) are observed. The uncoordinated water molecule shows half-occupation.

Related literature top

For the isotypic La3+ complex, see: Shen & Lush (2011). For related pyridine-2,4-dicarboxylate complexes, see: Aghabozorg et al. (2011); Li et al. (2007); Wang et al. (2009).

Experimental top

Ce(NO3)3.6H2O (0.1086 g, 0.25 mmole), pydridine-2,4-dicarboxylic acid (0.0418 g, 0.25 mmol) and 4,4'-dipyridine (0.0464 g, 0.25 mmol) were mixed in 10 ml of deionized water. After stirring for 30 min, the mixture was placed in a 23 ml Teflon-lined reactor which was heated under autogenous pressure to 418 K for 48 h and then allowed to cool to room temperature. The colorless transparent single crystals were obtained in 35.6% yield (based on Ce).

Refinement top

The site occupancy factor of the lattice water O10 was refined to 0.486 (15), and was set as 0.5 at the final cycles of refinement. Water H atoms were fixed in chemical sensible positions, thermal parameters were fixed as 0.08 Å2. Other H atoms were positioned geometrically with C—H = 0.93 Å (aromatic) and refined using a riding model with Uiso(H) = 1.2Ueq(C).

Computing details top

Data collection: SMART (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: PLATON (Spek, 2009); software used to prepare material for publication: PLATON (Spek, 2009).

Figures top
[Figure 1] Fig. 1. View of the title compound with the atom numbering scheme. Displacement ellipsoids for non-H atoms are drawn at the 50% probability level. All H atoms have been omitted for clarity. [Symmetry code: (i) x - 1, y, z; (ii) -x + 1, -y + 1, -z + 1; (iii) -x + 1, -y + 1, -z + 2.]
[Figure 2] Fig. 2. The crystal packing of (I) viewed along the c axis. Hydrogen bonds are shown as dashed lines.
Poly[[hexaaqua(µ2-oxalato- κ4O1,O2:O1',O2')bis(µ3-pyridine- 2,4-dicarboxylato- κ4N,O1:O1':O4)dicerium(III)] monohydrate] top
Crystal data top
[Ce2(C7H3NO4)2(C2O4)(H2O)6]·H2OZ = 1
Mr = 824.58F(000) = 398
Triclinic, P1Dx = 2.398 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 6.4160 (5) ÅCell parameters from 4490 reflections
b = 6.6486 (6) Åθ = 2.5–25.0°
c = 13.9920 (12) ŵ = 4.04 mm1
α = 89.917 (1)°T = 294 K
β = 85.588 (1)°Columnar, colorless
γ = 73.676 (1)°0.30 × 0.10 × 0.10 mm
V = 570.98 (8) Å3
Data collection top
Bruker SMART 1000 CCD area-detector
diffractometer
2664 independent reflections
Radiation source: fine-focus sealed tube2416 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.030
Detector resolution: 9 pixels mm-1θmax = 27.8°, θmin = 1.5°
ϕ and ω scansh = 88
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
k = 88
Tmin = 0.639, Tmax = 0.937l = 1818
6072 measured reflections
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.028H-atom parameters constrained
wR(F2) = 0.081 w = 1/[σ2(Fo2) + (0.0523P)2 + 0.4154P]
where P = (Fo2 + 2Fc2)/3
S = 1.10(Δ/σ)max = 0.019
2664 reflectionsΔρmax = 2.75 e Å3
177 parametersΔρmin = 2.70 e Å3
0 restraintsExtinction correction: SHELXTL (Sheldrick, 2008), FC*=KFC[1+0.001XFC2Λ3/SIN(2Θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.0071 (15)
Crystal data top
[Ce2(C7H3NO4)2(C2O4)(H2O)6]·H2Oγ = 73.676 (1)°
Mr = 824.58V = 570.98 (8) Å3
Triclinic, P1Z = 1
a = 6.4160 (5) ÅMo Kα radiation
b = 6.6486 (6) ŵ = 4.04 mm1
c = 13.9920 (12) ÅT = 294 K
α = 89.917 (1)°0.30 × 0.10 × 0.10 mm
β = 85.588 (1)°
Data collection top
Bruker SMART 1000 CCD area-detector
diffractometer
2664 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
2416 reflections with I > 2σ(I)
Tmin = 0.639, Tmax = 0.937Rint = 0.030
6072 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0280 restraints
wR(F2) = 0.081H-atom parameters constrained
S = 1.10Δρmax = 2.75 e Å3
2664 reflectionsΔρmin = 2.70 e Å3
177 parameters
Special details top

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement on F2 for ALL reflections except those flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The observed criterion of F2 > σ(F2) is used only for calculating -R-factor-obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ce0.36484 (3)0.33000 (3)0.80343 (1)0.0198 (1)
O10.7620 (6)0.3463 (6)0.2798 (2)0.0356 (11)
O21.0901 (6)0.2177 (7)0.3373 (3)0.0438 (13)
O31.0817 (5)0.2746 (6)0.7009 (2)0.0350 (10)
O40.7595 (5)0.3214 (7)0.7822 (2)0.0380 (13)
O50.5054 (7)0.2476 (5)0.9655 (2)0.0408 (13)
O60.5773 (6)0.3678 (5)1.1047 (2)0.0360 (10)
O70.0036 (8)0.5134 (8)0.8992 (4)0.0729 (14)
O80.5654 (6)0.0533 (6)0.7844 (3)0.0419 (11)
O90.1789 (8)0.0870 (8)0.8994 (4)0.0729 (14)
N10.5723 (5)0.2600 (6)0.6274 (2)0.0208 (9)
C10.7770 (7)0.2748 (6)0.6150 (3)0.0218 (11)
C20.5683 (7)0.2406 (7)0.4556 (3)0.0248 (11)
C30.7772 (7)0.2622 (7)0.4439 (3)0.0227 (11)
C40.8836 (7)0.2747 (7)0.5250 (3)0.0251 (11)
C50.4745 (7)0.2392 (7)0.5484 (3)0.0256 (12)
C60.8875 (8)0.2745 (7)0.3451 (3)0.0275 (12)
C70.8828 (7)0.2921 (7)0.7052 (3)0.0246 (11)
C80.5247 (7)0.3884 (6)1.0201 (3)0.0237 (11)
O100.1094 (13)0.0862 (13)0.9223 (7)0.050 (3)0.500
H2A0.493000.227400.402900.039 (15)*
H4A1.026300.282900.519100.0300*
H5A0.334900.222800.556000.0300*
H7A0.078000.470600.863200.0800*
H7B0.025000.636800.882800.0800*
H8A0.536700.162000.818200.0800*
H8B0.654200.095000.734900.0800*
H9A0.243600.067400.894200.0800*
H9B0.065000.090500.873000.0800*
H10A0.219700.007900.907600.0800*0.500
H10B0.125200.129600.985600.0800*0.500
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ce0.0191 (2)0.0294 (2)0.0134 (1)0.0113 (1)0.0006 (1)0.0005 (1)
O10.0380 (19)0.044 (2)0.0238 (16)0.0092 (16)0.0055 (14)0.0092 (14)
O20.0270 (18)0.064 (3)0.0303 (19)0.0011 (17)0.0068 (15)0.0078 (17)
O30.0199 (15)0.061 (2)0.0274 (17)0.0163 (15)0.0040 (13)0.0028 (15)
O40.0268 (17)0.075 (3)0.0185 (15)0.0250 (17)0.0004 (13)0.0012 (16)
O50.074 (3)0.0266 (17)0.0225 (16)0.0142 (17)0.0080 (17)0.0003 (13)
O60.058 (2)0.0306 (17)0.0222 (16)0.0141 (16)0.0143 (15)0.0071 (13)
O70.055 (2)0.061 (2)0.088 (3)0.0018 (16)0.0304 (19)0.0251 (19)
O80.048 (2)0.0333 (19)0.041 (2)0.0115 (16)0.0176 (17)0.0007 (15)
O90.055 (2)0.061 (2)0.088 (3)0.0018 (16)0.0304 (19)0.0251 (19)
N10.0174 (16)0.0268 (17)0.0193 (16)0.0077 (13)0.0030 (13)0.0001 (13)
C10.0197 (19)0.024 (2)0.022 (2)0.0068 (16)0.0017 (15)0.0017 (15)
C20.028 (2)0.030 (2)0.0179 (19)0.0099 (17)0.0049 (16)0.0011 (16)
C30.024 (2)0.025 (2)0.0162 (18)0.0024 (16)0.0005 (15)0.0042 (15)
C40.0172 (19)0.035 (2)0.022 (2)0.0057 (17)0.0003 (16)0.0045 (17)
C50.022 (2)0.031 (2)0.026 (2)0.0110 (17)0.0029 (16)0.0014 (17)
C60.033 (2)0.029 (2)0.017 (2)0.0045 (18)0.0037 (17)0.0004 (16)
C70.0196 (19)0.033 (2)0.025 (2)0.0129 (17)0.0041 (16)0.0032 (17)
C80.028 (2)0.023 (2)0.0189 (19)0.0052 (16)0.0027 (16)0.0009 (15)
O100.037 (4)0.042 (4)0.072 (6)0.010 (3)0.013 (4)0.009 (4)
Geometric parameters (Å, º) top
Ce—N12.684 (3)O8—H8B0.8600
Ce—O1i2.409 (4)O9—H9B0.8400
Ce—O3ii2.505 (3)O9—H9A0.9900
Ce—O42.511 (3)O10—H10A0.8400
Ce—O52.508 (3)O10—H10B0.9400
Ce—O6iii2.515 (3)N1—C51.338 (5)
Ce—O72.568 (5)N1—C11.343 (6)
Ce—O82.515 (4)C1—C41.386 (6)
Ce—O92.582 (5)C1—C71.498 (6)
O1—C61.268 (6)C2—C31.385 (7)
O2—C61.244 (7)C2—C51.390 (6)
O3—C71.245 (6)C3—C61.517 (6)
O4—C71.268 (5)C3—C41.383 (6)
O5—C81.248 (5)C8—C8iii1.543 (5)
O6—C81.253 (5)C2—H2A0.9300
O7—H7B0.8300C4—H4A0.9300
O7—H7A0.8600C5—H5A0.9300
O8—H8A0.9200
O4—Ce—O574.74 (12)Ce—O5—C8121.3 (3)
O4—Ce—O7142.54 (15)Ceiii—O6—C8120.9 (3)
O4—Ce—O875.62 (14)Ce—O7—H7B105.00
O4—Ce—O9130.01 (15)H7A—O7—H7B99.00
O4—Ce—N161.02 (10)Ce—O7—H7A96.00
O3ii—Ce—O4137.32 (10)Ce—O8—H8A127.00
O1i—Ce—O494.76 (13)H8A—O8—H8B113.00
O4—Ce—O6iii70.50 (13)Ce—O8—H8B119.00
O5—Ce—O784.31 (15)Ce—O9—H9A120.00
O5—Ce—O878.05 (12)H9A—O9—H9B96.00
O5—Ce—O967.22 (15)Ce—O9—H9B107.00
O5—Ce—N1130.72 (12)H10A—O10—H10B112.00
O3ii—Ce—O5141.57 (12)Ce—N1—C5123.6 (3)
O1i—Ce—O5132.71 (11)Ce—N1—C1118.7 (2)
O5—Ce—O6iii64.05 (10)C1—N1—C5117.1 (3)
O7—Ce—O8130.23 (15)N1—C1—C4122.5 (4)
O7—Ce—O964.30 (16)N1—C1—C7115.4 (4)
O7—Ce—N1144.66 (14)C4—C1—C7122.1 (4)
O3ii—Ce—O776.31 (14)C3—C2—C5118.1 (4)
O1i—Ce—O776.97 (15)C2—C3—C6121.4 (4)
O6iii—Ce—O772.47 (15)C4—C3—C6120.3 (4)
O8—Ce—O965.94 (15)C2—C3—C4118.3 (4)
O8—Ce—N171.24 (12)C1—C4—C3119.8 (4)
O3ii—Ce—O889.53 (13)N1—C5—C2124.1 (4)
O1i—Ce—O8144.86 (12)O1—C6—O2127.1 (4)
O6iii—Ce—O8134.19 (12)O2—C6—C3116.8 (4)
O9—Ce—N1127.54 (14)O1—C6—C3116.0 (4)
O3ii—Ce—O974.47 (14)O4—C7—C1116.2 (4)
O1i—Ce—O9134.92 (15)O3—C7—C1119.4 (4)
O6iii—Ce—O9116.36 (14)O3—C7—O4124.4 (4)
O3ii—Ce—N176.35 (10)O5—C8—O6126.7 (4)
O1i—Ce—N174.55 (11)O5—C8—C8iii116.7 (4)
O6iii—Ce—N1114.97 (11)O6—C8—C8iii116.6 (4)
O1i—Ce—O3ii74.72 (12)C5—C2—H2A121.00
O3ii—Ce—O6iii136.22 (12)C3—C2—H2A121.00
O1i—Ce—O6iii68.95 (11)C1—C4—H4A120.00
Cei—O1—C6138.2 (3)C3—C4—H4A120.00
Ceiv—O3—C7140.1 (3)N1—C5—H5A118.00
Ce—O4—C7127.9 (3)C2—C5—H5A118.00
O5—Ce—O4—C7158.0 (4)N1—Ce—O1i—C6i73.5 (5)
O7—Ce—O4—C7143.7 (4)O4—Ce—O6iii—C8iii87.9 (4)
O8—Ce—O4—C776.7 (4)O5—Ce—O6iii—C8iii5.9 (3)
O9—Ce—O4—C7116.9 (4)O7—Ce—O6iii—C8iii86.3 (4)
N1—Ce—O4—C70.5 (4)O8—Ce—O6iii—C8iii43.3 (4)
O3ii—Ce—O4—C73.6 (5)O9—Ce—O6iii—C8iii37.9 (4)
O1i—Ce—O4—C768.9 (4)N1—Ce—O6iii—C8iii130.9 (3)
O6iii—Ce—O4—C7134.6 (4)Cei—O1—C6—O276.7 (7)
O4—Ce—O5—C880.8 (4)Cei—O1—C6—C3101.7 (5)
O7—Ce—O5—C867.9 (4)Ceiv—O3—C7—O412.4 (8)
O8—Ce—O5—C8158.9 (4)Ceiv—O3—C7—C1168.6 (3)
O9—Ce—O5—C8132.4 (4)Ce—O4—C7—O3174.5 (3)
N1—Ce—O5—C8106.9 (4)Ce—O4—C7—C14.5 (6)
O3ii—Ce—O5—C8127.4 (4)Ce—O5—C8—O6174.3 (4)
O1i—Ce—O5—C81.5 (5)Ce—O5—C8—C8iii4.7 (6)
O6iii—Ce—O5—C85.4 (4)Ceiii—O6—C8—O5175.0 (4)
O4—Ce—N1—C16.1 (3)Ceiii—O6—C8—C8iii6.0 (5)
O4—Ce—N1—C5176.6 (4)Ce—N1—C1—C4169.4 (3)
O5—Ce—N1—C135.2 (4)Ce—N1—C1—C710.5 (5)
O5—Ce—N1—C5154.3 (3)C5—N1—C1—C41.7 (6)
O7—Ce—N1—C1135.9 (3)C5—N1—C1—C7178.4 (4)
O7—Ce—N1—C534.6 (5)Ce—N1—C5—C2168.0 (3)
O8—Ce—N1—C189.7 (3)C1—N1—C5—C22.7 (7)
O8—Ce—N1—C599.8 (4)N1—C1—C4—C31.0 (6)
O9—Ce—N1—C1126.2 (3)C7—C1—C4—C3178.8 (4)
O9—Ce—N1—C563.3 (4)N1—C1—C7—O3169.2 (4)
O3ii—Ce—N1—C1176.1 (3)N1—C1—C7—O49.8 (6)
O3ii—Ce—N1—C55.6 (3)C4—C1—C7—O311.0 (6)
O1i—Ce—N1—C198.5 (3)C4—C1—C7—O4170.0 (4)
O1i—Ce—N1—C572.0 (3)C5—C2—C3—C42.0 (6)
O6iii—Ce—N1—C141.2 (3)C5—C2—C3—C6177.4 (4)
O6iii—Ce—N1—C5129.3 (3)C3—C2—C5—N10.9 (7)
O4—Ce—O3ii—C7ii172.6 (4)C2—C3—C4—C12.8 (7)
O5—Ce—O3ii—C7ii49.5 (6)C6—C3—C4—C1176.5 (4)
O7—Ce—O3ii—C7ii12.4 (5)C2—C3—C6—O127.1 (6)
O8—Ce—O3ii—C7ii119.4 (5)C2—C3—C6—O2154.4 (5)
O9—Ce—O3ii—C7ii54.3 (5)C4—C3—C6—O1152.3 (4)
N1—Ce—O3ii—C7ii169.8 (5)C4—C3—C6—O226.3 (6)
O4—Ce—O1i—C6i131.6 (5)O5—C8—C8iii—O5iii180.0 (5)
O5—Ce—O1i—C6i154.8 (4)O5—C8—C8iii—O6iii0.9 (6)
O7—Ce—O1i—C6i85.4 (5)O6—C8—C8iii—O5iii0.9 (6)
O8—Ce—O1i—C6i60.0 (6)O6—C8—C8iii—O6iii180.0 (4)
O9—Ce—O1i—C6i54.6 (5)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x1, y, z; (iii) x+1, y+1, z+2; (iv) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O7—H7A···O4ii0.862.032.879 (6)171.00
O7—H7B···O10v0.831.842.569 (10)146.00
O8—H8A···O6vi0.922.002.910 (5)170.00
O8—H8B···O2vii0.861.842.655 (6)159.00
O9—H9A···O6vi0.992.012.987 (6)169.00
O9—H9B···O100.841.932.440 (10)118.00
O10—H10A···O5ii0.842.122.844 (9)143.00
O10—H10A···O8ii0.842.392.913 (10)121.00
O10—H10B···O9viii0.941.632.501 (11)153.00
C5—H5A···O3ii0.932.463.131 (5)129
Symmetry codes: (ii) x1, y, z; (v) x, y+1, z; (vi) x+1, y, z+2; (vii) x+2, y, z+1; (viii) x, y, z+2.

Experimental details

Crystal data
Chemical formula[Ce2(C7H3NO4)2(C2O4)(H2O)6]·H2O
Mr824.58
Crystal system, space groupTriclinic, P1
Temperature (K)294
a, b, c (Å)6.4160 (5), 6.6486 (6), 13.9920 (12)
α, β, γ (°)89.917 (1), 85.588 (1), 73.676 (1)
V3)570.98 (8)
Z1
Radiation typeMo Kα
µ (mm1)4.04
Crystal size (mm)0.30 × 0.10 × 0.10
Data collection
DiffractometerBruker SMART 1000 CCD area-detector
diffractometer
Absorption correctionMulti-scan
(SADABS; Bruker, 2001)
Tmin, Tmax0.639, 0.937
No. of measured, independent and
observed [I > 2σ(I)] reflections
6072, 2664, 2416
Rint0.030
(sin θ/λ)max1)0.656
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.028, 0.081, 1.10
No. of reflections2664
No. of parameters177
H-atom treatmentH-atom parameters constrained
Δρmax, Δρmin (e Å3)2.75, 2.70

Computer programs: SMART (Bruker, 2007), SAINT (Bruker, 2007), SHELXTL (Sheldrick, 2008), PLATON (Spek, 2009).

Selected bond lengths (Å) top
Ce—N12.684 (3)Ce—O6iii2.515 (3)
Ce—O1i2.409 (4)Ce—O72.568 (5)
Ce—O3ii2.505 (3)Ce—O82.515 (4)
Ce—O42.511 (3)Ce—O92.582 (5)
Ce—O52.508 (3)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x1, y, z; (iii) x+1, y+1, z+2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O7—H7A···O4ii0.862.032.879 (6)171.00
O7—H7B···O10iv0.831.842.569 (10)146.00
O8—H8A···O6v0.922.002.910 (5)170.00
O8—H8B···O2vi0.861.842.655 (6)159.00
O9—H9A···O6v0.992.012.987 (6)169.00
O9—H9B···O100.841.932.440 (10)118.00
O10—H10A···O5ii0.842.122.844 (9)143.00
O10—H10A···O8ii0.842.392.913 (10)121.00
O10—H10B···O9vii0.941.632.501 (11)153.00
C5—H5A···O3ii0.932.463.131 (5)129.00
Symmetry codes: (ii) x1, y, z; (iv) x, y+1, z; (v) x+1, y, z+2; (vi) x+2, y, z+1; (vii) x, y, z+2.
 

Acknowledgements

This work was supported financially by Yuanpei University, Taiwan.

References

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Volume 68| Part 1| January 2012| Pages m21-m22
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