metal-organic compounds
μ2-m-Xylylenebis(salicylaldiminato)-bis(η4-1,5-cyclooctadiene)dirhodium(I) dichloromethane solvate
aDepartment of Chemistry, Louisiana State University, Baton Rouge LA 70803-1804 USA
*Correspondence e-mail: ffroncz@lsu.edu
In the title solvate, [Rh2(C22H18N2O2)(C8H12)2]·CH2Cl2, each organometallic molecule is composed of two RhI cations, the tetradentate dianion α,α′-bis(salicylaldiminato)-m-xylene and two 1,5-cyclooctadiene (COD) ligands. Each RhI atom is coordinated by one O atom [Rh—O = 2.044 (2) and 2.026 (2) Å], one N atom [Rh—N = 2.083 (2) and 2.090 (2) Å], and one COD ligand via two η2-bonds, each directed toward the mid-point of a C=C bond (Cg): Rh—Cg = 2.007 (2), 2.013 (2), 2.000 (2) and 2.021 (2) Å. Each RhI atom has a quasi-square-planar coordination geometry, with average r.m.s. deviations of 0.159 (1) and 0.204 (1) Å from the mean planes defined by Rh and the termini of its four coordinating bonds. The two COD ligands have quasi-C2 symmetry, twisted from ideal C2v symmetry by 30.0 (3) and −33.1 (3)°, and are quasi-enantiomers of one another. The intramolecular Rh⋯Rh distance of 5.9432 (3) Å suggests that there is no direct metal–metal interaction.
Related literature
For related structures, see: Mosae Selvakumar et al. (2011); Maverick et al. (2005); Nakamura et al. (2001). For the synthesis, see: Brunner & Fisch (1987). For the Universal Force Field procedure, see: Rappe et al. (1992).
Experimental
Crystal data
|
Data collection: COLLECT (Nonius, 2000); cell HKL SCALEPACK (Otwinowski & Minor, 1997); data reduction: HKL DENZO (Otwinowski & Minor, 1997) and SCALEPACK; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999) and GAUSSIAN09 (Frisch et al., 2009).
Supporting information
https://doi.org/10.1107/S1600536812040603/cv5334sup1.cif
contains datablocks global, I. DOI:Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536812040603/cv5334Isup2.hkl
The synthesis of (SIX)Rh2(COD)2 was similar to that employed for (salicylimino)Rh(COD) complexes (Brunner & Fisch, 1987). Rh2(COD)2Cl2 was suspended in diethyl ether and a stoichiometric amount of solid SIXH2 (Maverick et al., 2005) was added. The mixture was cooled to 0 °C, a slight excess of 1M NaOH(aq) was added, and the mixture stirred for 1 h. The organic layer was dried over anhydrous NaSO4, filtered, and the solvent was removed to give bright yellow flaky solid. Crystals were obtained by slow evaporation from dichloromethane.
All H atoms were placed in calculated positions, guided by difference maps, with C—H bond distances 0.95 (Csp2) and 0.99 (Csp3) Å, and Uiso=1.2Ueq, thereafter refined as riding.
Schiff-base ligands such as SIXH2 (C22H20N2O2, CAS 51540–97–7, Maverick et al., 2005) are typically formed by condensation of a primary amine with an aldehyde, resulting in an imine, R1HC=N—R2, which is particularly useful for binding metal ions. The title compound, (SIX)Rh2(COD)2.DCM, C38H42N2O2Rh2.CH2Cl2, consists of one DCM molecule for each organometallic dimer. The latter is composed of tetradentate dianion α,α'-bis(salicylimino)-m-xylene (SIX) coordinated to two Rh(I) ions. Each Rh is bonded to an oxygen (Rh1—O1 = 2.044 (2), Rh2—O2 = 2.026 (2) Å), a nitrogen (Rh1—N1 = 2.083 (2), Rh2—N2 = 2.090 (2) Å), and a 1,5-cyclooctadiene (COD) ligand via two η2-bonds (each directed toward the center of a C═C bond): Rh1—(C1 & C2) = 2.007 (2), Rh1— (C5 & C6) = 2.013 (2), Rh2—(C9 & C10) = 2.000 (2), Rh2—(C13 & C14) = 2.021 (2) Å.
Each COD has quasi-C2 molecular symmetry as judged by close equivalencies of putatively equal intraannular bond lengths, bond angles and torsion angles. One measure of the twist of each ring from idealized C2v molecular symmetry is the torsion angle of four atom-pair centroids: C1 & C2, C3 & C8, C4 & C7, C5 & C6 (+30.0 (3)°) and C9 & C10, C11 & C16, C12 & C15, C13 & C14 (-33.1 (3)°). The signs of the two twist angles, together with the signs of equivalent intraannular torsion angles, indicates that the two COD moieties are near enantiomorphs. The observed molecular measurements are very close to those for the minimum energy conformer calculated in Gaussian09 (Frisch et al., 2009) using the UFF procedure (Rappe et al., 1992). This conformer has exact C2 symmetry and twist angle ±30.8°.
The four bonds about each Rh form a quasi-square planar environment. For example, deviations δr.m.s. from the mean planes defined by each metal atom and the termini of its four bonds are Rh1: 0.159 (1) and Rh2: 0.204 (1) Å. The intramolecular Rh···Rh distance of 5.943 (1) Å suggests that there is no direct metal-metal interaction.
For related structures, see: Mosae Selvakumar et al. (2011); Maverick et al. (2005); Nakamura et al. (2001). For the synthesis, see: Brunner & Fisch (1987). For the UFF procedure, see: Rappe et al. (1992).
Data collection: COLLECT (Nonius, 2000); cell
HKL SCALEPACK (Otwinowski & Minor, 1997); data reduction: HKL DENZO and SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999) and GAUSSIAN09 (Frisch et al., 2009).Fig. 1. View of (I) showing the atomic labeling and 50% probability displacement ellipsoids. The solvent molecule and H atoms were omitted for clarity. |
[Rh2(C22H18N2O2)(C8H12)2]·CH2Cl2 | F(000) = 1728 |
Mr = 849.48 | Dx = 1.677 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 9881 reflections |
a = 16.0829 (4) Å | θ = 2.6–31.0° |
b = 18.8607 (4) Å | µ = 1.18 mm−1 |
c = 11.2352 (2) Å | T = 90 K |
β = 99.081 (1)° | Lath, yellow |
V = 3365.31 (13) Å3 | 0.30 × 0.12 × 0.12 mm |
Z = 4 |
Nonius KappaCCD diffractometer | 10328 independent reflections |
Radiation source: Enraf Nonius FR590 | 8682 reflections with I > 2σ(I) |
Horizonally mounted graphite crystal monochromator | Rint = 0.025 |
Detector resolution: 9 pixels mm-1 | θmax = 30.8°, θmin = 2.6° |
CCD rotation images, thick slices scans | h = −23→23 |
Absorption correction: multi-scan (HKL SCALEPACK; Otwinowski & Minor 1997) | k = −27→20 |
Tmin = 0.631, Tmax = 0.912 | l = −15→15 |
17250 measured reflections |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.032 | H-atom parameters constrained |
wR(F2) = 0.077 | w = 1/[σ2(Fo2) + (0.0322P)2 + 4.6131P] where P = (Fo2 + 2Fc2)/3 |
S = 1.02 | (Δ/σ)max = 0.003 |
10328 reflections | Δρmax = 0.93 e Å−3 |
425 parameters | Δρmin = −0.96 e Å−3 |
0 restraints | Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
0 constraints | Extinction coefficient: 0.00049 (10) |
Primary atom site location: structure-invariant direct methods |
[Rh2(C22H18N2O2)(C8H12)2]·CH2Cl2 | V = 3365.31 (13) Å3 |
Mr = 849.48 | Z = 4 |
Monoclinic, P21/c | Mo Kα radiation |
a = 16.0829 (4) Å | µ = 1.18 mm−1 |
b = 18.8607 (4) Å | T = 90 K |
c = 11.2352 (2) Å | 0.30 × 0.12 × 0.12 mm |
β = 99.081 (1)° |
Nonius KappaCCD diffractometer | 10328 independent reflections |
Absorption correction: multi-scan (HKL SCALEPACK; Otwinowski & Minor 1997) | 8682 reflections with I > 2σ(I) |
Tmin = 0.631, Tmax = 0.912 | Rint = 0.025 |
17250 measured reflections |
R[F2 > 2σ(F2)] = 0.032 | 0 restraints |
wR(F2) = 0.077 | H-atom parameters constrained |
S = 1.02 | Δρmax = 0.93 e Å−3 |
10328 reflections | Δρmin = −0.96 e Å−3 |
425 parameters |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
C1 | 0.32235 (14) | 0.67047 (12) | 0.42132 (19) | 0.0144 (4) | |
H1 | 0.316 | 0.6493 | 0.4961 | 0.017* | |
C2 | 0.40469 (14) | 0.68544 (12) | 0.40159 (19) | 0.0144 (4) | |
H2 | 0.4504 | 0.6714 | 0.4611 | 0.017* | |
C3 | 0.42401 (15) | 0.72324 (13) | 0.2890 (2) | 0.0180 (4) | |
H3A | 0.4744 | 0.7535 | 0.3111 | 0.022* | |
H3B | 0.3761 | 0.7545 | 0.2573 | 0.022* | |
C4 | 0.43978 (15) | 0.67113 (13) | 0.1897 (2) | 0.0183 (4) | |
H4A | 0.4226 | 0.6936 | 0.11 | 0.022* | |
H4B | 0.5008 | 0.6608 | 0.1986 | 0.022* | |
C5 | 0.39205 (15) | 0.60237 (12) | 0.19427 (18) | 0.0147 (4) | |
H5 | 0.4224 | 0.5594 | 0.1911 | 0.018* | |
C6 | 0.30668 (15) | 0.59744 (12) | 0.20276 (18) | 0.0150 (4) | |
H6 | 0.2832 | 0.5516 | 0.2085 | 0.018* | |
C7 | 0.24899 (15) | 0.66143 (13) | 0.2033 (2) | 0.0181 (4) | |
H7A | 0.1921 | 0.6492 | 0.1608 | 0.022* | |
H7B | 0.2709 | 0.701 | 0.1594 | 0.022* | |
C8 | 0.24272 (14) | 0.68541 (13) | 0.3328 (2) | 0.0179 (4) | |
H8A | 0.2309 | 0.7369 | 0.3325 | 0.022* | |
H8B | 0.1948 | 0.6607 | 0.3602 | 0.022* | |
C9 | −0.03645 (14) | 0.67669 (13) | 0.53838 (19) | 0.0156 (4) | |
H9 | −0.04 | 0.6301 | 0.5695 | 0.019* | |
C10 | 0.04403 (14) | 0.70502 (12) | 0.53404 (19) | 0.0148 (4) | |
H10 | 0.0915 | 0.6772 | 0.5666 | 0.018* | |
C11 | 0.06048 (15) | 0.77664 (13) | 0.4812 (2) | 0.0169 (4) | |
H11A | 0.1204 | 0.7795 | 0.471 | 0.02* | |
H11B | 0.0499 | 0.8143 | 0.5383 | 0.02* | |
C12 | 0.00494 (15) | 0.79022 (13) | 0.3585 (2) | 0.0192 (4) | |
H12A | −0.0482 | 0.8132 | 0.3718 | 0.023* | |
H12B | 0.0345 | 0.823 | 0.3105 | 0.023* | |
C13 | −0.01528 (15) | 0.72200 (13) | 0.28883 (19) | 0.0169 (4) | |
H13 | 0.0242 | 0.7059 | 0.2402 | 0.02* | |
C14 | −0.08689 (14) | 0.68111 (13) | 0.2903 (2) | 0.0168 (4) | |
H14 | −0.0936 | 0.6403 | 0.2402 | 0.02* | |
C15 | −0.15524 (15) | 0.69641 (14) | 0.3656 (2) | 0.0206 (5) | |
H15A | −0.1913 | 0.6539 | 0.3666 | 0.025* | |
H15B | −0.191 | 0.7357 | 0.3283 | 0.025* | |
C16 | −0.11809 (15) | 0.71664 (14) | 0.4959 (2) | 0.0198 (5) | |
H16A | −0.1071 | 0.7683 | 0.5004 | 0.024* | |
H16B | −0.1594 | 0.7055 | 0.5498 | 0.024* | |
C17 | 0.40803 (14) | 0.58867 (13) | 0.65856 (19) | 0.0156 (4) | |
H17A | 0.4215 | 0.6372 | 0.6339 | 0.019* | |
H17B | 0.4547 | 0.5725 | 0.7207 | 0.019* | |
C18 | 0.32686 (14) | 0.59036 (12) | 0.71220 (18) | 0.0128 (4) | |
C19 | 0.32798 (14) | 0.61215 (12) | 0.83111 (19) | 0.0149 (4) | |
H19 | 0.3792 | 0.6278 | 0.8777 | 0.018* | |
C20 | 0.25437 (15) | 0.61109 (13) | 0.88182 (19) | 0.0175 (4) | |
H20 | 0.2555 | 0.6261 | 0.9628 | 0.021* | |
C21 | 0.17942 (14) | 0.58825 (12) | 0.81466 (19) | 0.0158 (4) | |
H21 | 0.1298 | 0.5863 | 0.8506 | 0.019* | |
C22 | 0.17638 (14) | 0.56802 (12) | 0.69440 (19) | 0.0133 (4) | |
C23 | 0.25022 (14) | 0.56963 (12) | 0.64469 (19) | 0.0136 (4) | |
H23 | 0.2485 | 0.5563 | 0.5628 | 0.016* | |
C24 | 0.09392 (14) | 0.54057 (13) | 0.62580 (19) | 0.0157 (4) | |
H24A | 0.0882 | 0.4898 | 0.6456 | 0.019* | |
H24B | 0.047 | 0.5664 | 0.6537 | 0.019* | |
C25 | 0.40126 (14) | 0.47439 (13) | 0.5820 (2) | 0.0157 (4) | |
H25 | 0.4112 | 0.4648 | 0.6661 | 0.019* | |
C26 | 0.38851 (14) | 0.41316 (12) | 0.5056 (2) | 0.0154 (4) | |
C27 | 0.38728 (13) | 0.41557 (12) | 0.3777 (2) | 0.0144 (4) | |
C28 | 0.38042 (15) | 0.34953 (13) | 0.3159 (2) | 0.0181 (4) | |
H28 | 0.3838 | 0.3488 | 0.2323 | 0.022* | |
C29 | 0.36906 (15) | 0.28658 (13) | 0.3732 (2) | 0.0206 (5) | |
H29 | 0.3636 | 0.2437 | 0.3283 | 0.025* | |
C30 | 0.36537 (16) | 0.28506 (13) | 0.4979 (2) | 0.0221 (5) | |
H30 | 0.3554 | 0.2419 | 0.537 | 0.027* | |
C31 | 0.37645 (15) | 0.34719 (13) | 0.5613 (2) | 0.0193 (4) | |
H31 | 0.3761 | 0.3462 | 0.6457 | 0.023* | |
C32 | 0.12119 (14) | 0.49715 (12) | 0.4418 (2) | 0.0157 (4) | |
H32 | 0.148 | 0.4618 | 0.4947 | 0.019* | |
C33 | 0.12575 (14) | 0.48665 (12) | 0.3159 (2) | 0.0157 (4) | |
C34 | 0.17486 (15) | 0.42879 (13) | 0.2857 (2) | 0.0193 (4) | |
H34 | 0.204 | 0.4004 | 0.3487 | 0.023* | |
C35 | 0.18162 (16) | 0.41255 (13) | 0.1683 (2) | 0.0215 (5) | |
H35 | 0.215 | 0.3736 | 0.1504 | 0.026* | |
C36 | 0.13822 (16) | 0.45477 (14) | 0.0750 (2) | 0.0219 (5) | |
H36 | 0.1419 | 0.4438 | −0.0065 | 0.026* | |
C37 | 0.09040 (15) | 0.51187 (13) | 0.1008 (2) | 0.0191 (4) | |
H37 | 0.0624 | 0.54 | 0.0366 | 0.023* | |
C38 | 0.08211 (14) | 0.52949 (13) | 0.22172 (19) | 0.0161 (4) | |
N1 | 0.40120 (11) | 0.54087 (10) | 0.55282 (16) | 0.0130 (3) | |
N2 | 0.08572 (12) | 0.54799 (11) | 0.49311 (16) | 0.0144 (3) | |
O1 | 0.39194 (10) | 0.47352 (9) | 0.31685 (13) | 0.0155 (3) | |
O2 | 0.03491 (11) | 0.58322 (9) | 0.23851 (14) | 0.0174 (3) | |
Rh1 | 0.379269 (10) | 0.575178 (9) | 0.374373 (14) | 0.01104 (5) | |
Rh2 | 0.017893 (10) | 0.629409 (9) | 0.395686 (14) | 0.01219 (5) | |
C39 | 0.35225 (17) | 0.44841 (14) | −0.0064 (2) | 0.0236 (5) | |
H39A | 0.3258 | 0.4464 | 0.0673 | 0.028* | |
H39B | 0.3566 | 0.4988 | −0.0291 | 0.028* | |
Cl1 | 0.28848 (5) | 0.40257 (4) | −0.12430 (7) | 0.03484 (16) | |
Cl2 | 0.45414 (4) | 0.41086 (4) | 0.02361 (6) | 0.03307 (16) |
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.0170 (10) | 0.0127 (10) | 0.0140 (9) | 0.0003 (8) | 0.0040 (8) | −0.0027 (8) |
C2 | 0.0174 (10) | 0.0132 (10) | 0.0127 (9) | 0.0001 (8) | 0.0029 (8) | −0.0017 (8) |
C3 | 0.0198 (11) | 0.0155 (10) | 0.0195 (11) | −0.0041 (9) | 0.0057 (8) | −0.0009 (8) |
C4 | 0.0216 (11) | 0.0188 (11) | 0.0159 (10) | −0.0029 (9) | 0.0076 (8) | −0.0007 (8) |
C5 | 0.0202 (11) | 0.0146 (10) | 0.0091 (9) | 0.0011 (8) | 0.0018 (8) | −0.0006 (8) |
C6 | 0.0200 (11) | 0.0153 (10) | 0.0089 (9) | 0.0004 (8) | −0.0009 (8) | 0.0009 (8) |
C7 | 0.0166 (10) | 0.0201 (11) | 0.0167 (10) | 0.0016 (9) | 0.0004 (8) | 0.0018 (9) |
C8 | 0.0162 (10) | 0.0188 (11) | 0.0192 (10) | 0.0017 (9) | 0.0040 (8) | −0.0001 (9) |
C9 | 0.0167 (10) | 0.0175 (11) | 0.0127 (9) | −0.0003 (8) | 0.0030 (8) | −0.0005 (8) |
C10 | 0.0160 (10) | 0.0174 (10) | 0.0108 (9) | 0.0000 (8) | 0.0015 (7) | −0.0008 (8) |
C11 | 0.0172 (10) | 0.0185 (11) | 0.0149 (10) | −0.0033 (9) | 0.0016 (8) | −0.0008 (8) |
C12 | 0.0220 (11) | 0.0175 (11) | 0.0175 (10) | −0.0022 (9) | 0.0015 (9) | 0.0006 (9) |
C13 | 0.0185 (10) | 0.0190 (11) | 0.0122 (9) | 0.0023 (9) | −0.0007 (8) | 0.0031 (8) |
C14 | 0.0162 (10) | 0.0187 (11) | 0.0136 (10) | 0.0009 (8) | −0.0033 (8) | −0.0002 (8) |
C15 | 0.0147 (10) | 0.0236 (12) | 0.0223 (11) | 0.0009 (9) | −0.0009 (8) | 0.0004 (9) |
C16 | 0.0154 (10) | 0.0247 (12) | 0.0199 (11) | 0.0007 (9) | 0.0042 (8) | −0.0008 (9) |
C17 | 0.0139 (10) | 0.0221 (11) | 0.0105 (9) | −0.0023 (8) | 0.0013 (7) | −0.0032 (8) |
C18 | 0.0133 (9) | 0.0148 (10) | 0.0108 (9) | −0.0005 (8) | 0.0031 (7) | 0.0011 (7) |
C19 | 0.0162 (10) | 0.0174 (10) | 0.0105 (9) | 0.0012 (8) | −0.0003 (8) | −0.0005 (8) |
C20 | 0.0229 (11) | 0.0203 (11) | 0.0092 (9) | 0.0040 (9) | 0.0023 (8) | −0.0007 (8) |
C21 | 0.0161 (10) | 0.0197 (11) | 0.0121 (9) | 0.0040 (8) | 0.0034 (8) | 0.0026 (8) |
C22 | 0.0130 (9) | 0.0147 (10) | 0.0122 (9) | 0.0015 (8) | 0.0020 (7) | 0.0027 (7) |
C23 | 0.0143 (10) | 0.0158 (10) | 0.0110 (9) | −0.0008 (8) | 0.0026 (7) | 0.0007 (8) |
C24 | 0.0130 (10) | 0.0214 (11) | 0.0128 (9) | −0.0018 (8) | 0.0021 (7) | 0.0032 (8) |
C25 | 0.0125 (10) | 0.0196 (11) | 0.0150 (10) | 0.0003 (8) | 0.0021 (8) | 0.0011 (8) |
C26 | 0.0128 (10) | 0.0153 (10) | 0.0179 (10) | 0.0017 (8) | 0.0017 (8) | 0.0021 (8) |
C27 | 0.0104 (9) | 0.0143 (10) | 0.0185 (10) | 0.0007 (8) | 0.0026 (8) | 0.0005 (8) |
C28 | 0.0169 (11) | 0.0162 (11) | 0.0218 (11) | 0.0006 (8) | 0.0048 (8) | −0.0021 (9) |
C29 | 0.0180 (11) | 0.0148 (11) | 0.0289 (12) | 0.0002 (9) | 0.0041 (9) | −0.0018 (9) |
C30 | 0.0222 (12) | 0.0162 (11) | 0.0288 (12) | −0.0007 (9) | 0.0066 (10) | 0.0050 (9) |
C31 | 0.0183 (11) | 0.0184 (11) | 0.0215 (11) | 0.0012 (9) | 0.0040 (9) | 0.0050 (9) |
C32 | 0.0122 (9) | 0.0180 (11) | 0.0157 (10) | −0.0035 (8) | −0.0013 (8) | 0.0001 (8) |
C33 | 0.0124 (9) | 0.0175 (10) | 0.0173 (10) | −0.0041 (8) | 0.0026 (8) | −0.0021 (8) |
C34 | 0.0144 (10) | 0.0184 (11) | 0.0247 (11) | −0.0029 (9) | 0.0018 (9) | −0.0014 (9) |
C35 | 0.0181 (11) | 0.0199 (12) | 0.0274 (12) | −0.0034 (9) | 0.0061 (9) | −0.0089 (9) |
C36 | 0.0210 (12) | 0.0261 (13) | 0.0195 (11) | −0.0054 (10) | 0.0057 (9) | −0.0082 (9) |
C37 | 0.0180 (11) | 0.0229 (12) | 0.0163 (10) | −0.0043 (9) | 0.0023 (8) | −0.0034 (9) |
C38 | 0.0129 (10) | 0.0199 (11) | 0.0154 (10) | −0.0041 (8) | 0.0015 (8) | −0.0030 (8) |
N1 | 0.0102 (8) | 0.0178 (9) | 0.0108 (8) | −0.0006 (7) | 0.0018 (6) | −0.0019 (7) |
N2 | 0.0120 (8) | 0.0183 (9) | 0.0125 (8) | −0.0030 (7) | 0.0007 (6) | 0.0013 (7) |
O1 | 0.0190 (8) | 0.0139 (7) | 0.0141 (7) | 0.0012 (6) | 0.0042 (6) | −0.0003 (6) |
O2 | 0.0192 (8) | 0.0197 (8) | 0.0130 (7) | 0.0020 (6) | 0.0017 (6) | −0.0014 (6) |
Rh1 | 0.01149 (8) | 0.01228 (8) | 0.00945 (8) | −0.00042 (6) | 0.00196 (5) | −0.00103 (6) |
Rh2 | 0.01157 (8) | 0.01501 (8) | 0.00967 (8) | −0.00147 (6) | 0.00068 (6) | −0.00002 (6) |
C39 | 0.0268 (13) | 0.0208 (12) | 0.0216 (11) | 0.0053 (10) | −0.0014 (9) | −0.0037 (9) |
Cl1 | 0.0298 (3) | 0.0381 (4) | 0.0335 (3) | 0.0075 (3) | −0.0045 (3) | −0.0158 (3) |
Cl2 | 0.0229 (3) | 0.0498 (4) | 0.0269 (3) | 0.0069 (3) | 0.0051 (2) | −0.0056 (3) |
C1—C2 | 1.405 (3) | C17—H17B | 0.99 |
C1—C8 | 1.519 (3) | C18—C19 | 1.395 (3) |
C1—Rh1 | 2.121 (2) | C18—C23 | 1.397 (3) |
C1—H1 | 0.95 | C19—C20 | 1.393 (3) |
C2—C3 | 1.526 (3) | C19—H19 | 0.95 |
C2—Rh1 | 2.132 (2) | C20—C21 | 1.386 (3) |
C2—H2 | 0.95 | C20—H20 | 0.95 |
C3—C4 | 1.538 (3) | C21—C22 | 1.397 (3) |
C3—H3A | 0.99 | C21—H21 | 0.95 |
C3—H3B | 0.99 | C22—C23 | 1.390 (3) |
C4—C5 | 1.512 (3) | C22—C24 | 1.516 (3) |
C4—H4A | 0.99 | C23—H23 | 0.95 |
C4—H4B | 0.99 | C24—N2 | 1.482 (3) |
C5—C6 | 1.394 (3) | C24—H24A | 0.99 |
C5—Rh1 | 2.129 (2) | C24—H24B | 0.99 |
C5—H5 | 0.95 | C25—N1 | 1.296 (3) |
C6—C7 | 1.523 (3) | C25—C26 | 1.434 (3) |
C6—Rh1 | 2.132 (2) | C25—H25 | 0.95 |
C6—H6 | 0.95 | C26—C31 | 1.420 (3) |
C7—C8 | 1.541 (3) | C26—C27 | 1.434 (3) |
C7—H7A | 0.99 | C27—O1 | 1.298 (3) |
C7—H7B | 0.99 | C27—C28 | 1.422 (3) |
C8—H8A | 0.99 | C28—C29 | 1.376 (3) |
C8—H8B | 0.99 | C28—H28 | 0.95 |
C9—C10 | 1.408 (3) | C29—C30 | 1.413 (3) |
C9—C16 | 1.524 (3) | C29—H29 | 0.95 |
C9—Rh2 | 2.138 (2) | C30—C31 | 1.368 (3) |
C9—H9 | 0.95 | C30—H30 | 0.95 |
C10—C11 | 1.516 (3) | C31—H31 | 0.95 |
C10—Rh2 | 2.102 (2) | C32—N2 | 1.297 (3) |
C10—H10 | 0.95 | C32—C33 | 1.442 (3) |
C11—C12 | 1.540 (3) | C32—H32 | 0.95 |
C11—H11A | 0.99 | C33—C34 | 1.419 (3) |
C11—H11B | 0.99 | C33—C38 | 1.425 (3) |
C12—C13 | 1.515 (3) | C34—C35 | 1.375 (3) |
C12—H12A | 0.99 | C34—H34 | 0.95 |
C12—H12B | 0.99 | C35—C36 | 1.411 (4) |
C13—C14 | 1.388 (3) | C35—H35 | 0.95 |
C13—Rh2 | 2.139 (2) | C36—C37 | 1.380 (4) |
C13—H13 | 0.95 | C36—H36 | 0.95 |
C14—C15 | 1.517 (3) | C37—C38 | 1.425 (3) |
C14—Rh2 | 2.136 (2) | C37—H37 | 0.95 |
C14—H14 | 0.95 | C38—O2 | 1.298 (3) |
C15—C16 | 1.540 (3) | N1—Rh1 | 2.0831 (18) |
C15—H15A | 0.99 | N2—Rh2 | 2.0903 (19) |
C15—H15B | 0.99 | O1—Rh1 | 2.0437 (16) |
C16—H16A | 0.99 | O2—Rh2 | 2.0260 (16) |
C16—H16B | 0.99 | C39—Cl1 | 1.768 (3) |
C17—N1 | 1.482 (3) | C39—Cl2 | 1.768 (3) |
C17—C18 | 1.522 (3) | C39—H39A | 0.99 |
C17—H17A | 0.99 | C39—H39B | 0.99 |
C2—C1—C8 | 125.3 (2) | C20—C19—H19 | 119.9 |
C2—C1—Rh1 | 71.13 (12) | C18—C19—H19 | 119.9 |
C8—C1—Rh1 | 110.28 (14) | C21—C20—C19 | 120.3 (2) |
C2—C1—H1 | 117.4 | C21—C20—H20 | 119.9 |
C8—C1—H1 | 117.4 | C19—C20—H20 | 119.9 |
Rh1—C1—H1 | 88.6 | C20—C21—C22 | 120.4 (2) |
C1—C2—C3 | 123.0 (2) | C20—C21—H21 | 119.8 |
C1—C2—Rh1 | 70.28 (13) | C22—C21—H21 | 119.8 |
C3—C2—Rh1 | 113.35 (14) | C23—C22—C21 | 118.7 (2) |
C1—C2—H2 | 118.5 | C23—C22—C24 | 122.51 (19) |
C3—C2—H2 | 118.5 | C21—C22—C24 | 118.62 (19) |
Rh1—C2—H2 | 86.5 | C22—C23—C18 | 121.6 (2) |
C2—C3—C4 | 112.42 (19) | C22—C23—H23 | 119.2 |
C2—C3—H3A | 109.1 | C18—C23—H23 | 119.2 |
C4—C3—H3A | 109.1 | N2—C24—C22 | 114.26 (17) |
C2—C3—H3B | 109.1 | N2—C24—H24A | 108.7 |
C4—C3—H3B | 109.1 | C22—C24—H24A | 108.7 |
H3A—C3—H3B | 107.9 | N2—C24—H24B | 108.7 |
C5—C4—C3 | 112.38 (18) | C22—C24—H24B | 108.7 |
C5—C4—H4A | 109.1 | H24A—C24—H24B | 107.6 |
C3—C4—H4A | 109.1 | N1—C25—C26 | 129.3 (2) |
C5—C4—H4B | 109.1 | N1—C25—H25 | 115.4 |
C3—C4—H4B | 109.1 | C26—C25—H25 | 115.4 |
H4A—C4—H4B | 107.9 | C31—C26—C27 | 119.2 (2) |
C6—C5—C4 | 124.8 (2) | C31—C26—C25 | 117.3 (2) |
C6—C5—Rh1 | 71.03 (12) | C27—C26—C25 | 123.5 (2) |
C4—C5—Rh1 | 111.38 (14) | O1—C27—C28 | 119.1 (2) |
C6—C5—H5 | 117.6 | O1—C27—C26 | 124.2 (2) |
C4—C5—H5 | 117.6 | C28—C27—C26 | 116.7 (2) |
Rh1—C5—H5 | 87.6 | C29—C28—C27 | 122.2 (2) |
C5—C6—C7 | 123.7 (2) | C29—C28—H28 | 118.9 |
C5—C6—Rh1 | 70.76 (12) | C27—C28—H28 | 118.9 |
C7—C6—Rh1 | 113.52 (14) | C28—C29—C30 | 120.7 (2) |
C5—C6—H6 | 118.2 | C28—C29—H29 | 119.6 |
C7—C6—H6 | 118.2 | C30—C29—H29 | 119.6 |
Rh1—C6—H6 | 85.8 | C31—C30—C29 | 118.4 (2) |
C6—C7—C8 | 111.54 (18) | C31—C30—H30 | 120.8 |
C6—C7—H7A | 109.3 | C29—C30—H30 | 120.8 |
C8—C7—H7A | 109.3 | C30—C31—C26 | 122.5 (2) |
C6—C7—H7B | 109.3 | C30—C31—H31 | 118.8 |
C8—C7—H7B | 109.3 | C26—C31—H31 | 118.8 |
H7A—C7—H7B | 108 | N2—C32—C33 | 129.2 (2) |
C1—C8—C7 | 112.93 (18) | N2—C32—H32 | 115.4 |
C1—C8—H8A | 109 | C33—C32—H32 | 115.4 |
C7—C8—H8A | 109 | C34—C33—C38 | 119.1 (2) |
C1—C8—H8B | 109 | C34—C33—C32 | 117.2 (2) |
C7—C8—H8B | 109 | C38—C33—C32 | 123.7 (2) |
H8A—C8—H8B | 107.8 | C35—C34—C33 | 122.1 (2) |
C10—C9—C16 | 123.6 (2) | C35—C34—H34 | 118.9 |
C10—C9—Rh2 | 69.24 (12) | C33—C34—H34 | 118.9 |
C16—C9—Rh2 | 113.92 (15) | C34—C35—C36 | 118.8 (2) |
C10—C9—H9 | 118.2 | C34—C35—H35 | 120.6 |
C16—C9—H9 | 118.2 | C36—C35—H35 | 120.6 |
Rh2—C9—H9 | 86.9 | C37—C36—C35 | 120.7 (2) |
C9—C10—C11 | 124.7 (2) | C37—C36—H36 | 119.6 |
C9—C10—Rh2 | 71.98 (13) | C35—C36—H36 | 119.6 |
C11—C10—Rh2 | 109.97 (14) | C36—C37—C38 | 121.4 (2) |
C9—C10—H10 | 117.6 | C36—C37—H37 | 119.3 |
C11—C10—H10 | 117.6 | C38—C37—H37 | 119.3 |
Rh2—C10—H10 | 88 | O2—C38—C33 | 124.5 (2) |
C10—C11—C12 | 112.72 (19) | O2—C38—C37 | 117.8 (2) |
C10—C11—H11A | 109 | C33—C38—C37 | 117.8 (2) |
C12—C11—H11A | 109 | C25—N1—C17 | 112.87 (18) |
C10—C11—H11B | 109 | C25—N1—Rh1 | 122.51 (15) |
C12—C11—H11B | 109 | C17—N1—Rh1 | 124.24 (15) |
H11A—C11—H11B | 107.8 | C32—N2—C24 | 113.69 (19) |
C13—C12—C11 | 111.59 (19) | C32—N2—Rh2 | 122.71 (15) |
C13—C12—H12A | 109.3 | C24—N2—Rh2 | 123.52 (15) |
C11—C12—H12A | 109.3 | C27—O1—Rh1 | 127.33 (14) |
C13—C12—H12B | 109.3 | C38—O2—Rh2 | 128.69 (14) |
C11—C12—H12B | 109.3 | O1—Rh1—N1 | 90.16 (7) |
H12A—C12—H12B | 108 | O1—Rh1—C1 | 160.40 (8) |
C14—C13—C12 | 125.2 (2) | N1—Rh1—C1 | 92.18 (8) |
C14—C13—Rh2 | 70.94 (13) | O1—Rh1—C5 | 84.03 (7) |
C12—C13—Rh2 | 112.91 (15) | N1—Rh1—C5 | 164.29 (8) |
C14—C13—H13 | 117.4 | C1—Rh1—C5 | 98.19 (8) |
C12—C13—H13 | 117.4 | O1—Rh1—C6 | 88.08 (8) |
Rh2—C13—H13 | 86.1 | N1—Rh1—C6 | 156.47 (8) |
C13—C14—C15 | 125.2 (2) | C1—Rh1—C6 | 82.06 (9) |
C13—C14—Rh2 | 71.15 (13) | C5—Rh1—C6 | 38.20 (9) |
C15—C14—Rh2 | 110.83 (15) | O1—Rh1—C2 | 159.06 (7) |
C13—C14—H14 | 117.4 | N1—Rh1—C2 | 99.52 (8) |
C15—C14—H14 | 117.4 | C1—Rh1—C2 | 38.59 (8) |
Rh2—C14—H14 | 88 | C5—Rh1—C2 | 81.73 (8) |
C14—C15—C16 | 111.77 (19) | C6—Rh1—C2 | 90.16 (9) |
C14—C15—H15A | 109.3 | O2—Rh2—N2 | 90.54 (7) |
C16—C15—H15A | 109.3 | O2—Rh2—C10 | 153.81 (8) |
C14—C15—H15B | 109.3 | N2—Rh2—C10 | 94.83 (8) |
C16—C15—H15B | 109.3 | O2—Rh2—C14 | 85.21 (8) |
H15A—C15—H15B | 107.9 | N2—Rh2—C14 | 157.89 (8) |
C9—C16—C15 | 111.17 (19) | C10—Rh2—C14 | 98.53 (9) |
C9—C16—H16A | 109.4 | O2—Rh2—C9 | 163.81 (8) |
C15—C16—H16A | 109.4 | N2—Rh2—C9 | 98.92 (8) |
C9—C16—H16B | 109.4 | C10—Rh2—C9 | 38.78 (8) |
C15—C16—H16B | 109.4 | C14—Rh2—C9 | 81.09 (9) |
H16A—C16—H16B | 108 | O2—Rh2—C13 | 85.29 (8) |
N1—C17—C18 | 111.75 (18) | N2—Rh2—C13 | 163.18 (8) |
N1—C17—H17A | 109.3 | C10—Rh2—C13 | 82.20 (9) |
C18—C17—H17A | 109.3 | C14—Rh2—C13 | 37.91 (9) |
N1—C17—H17B | 109.3 | C9—Rh2—C13 | 89.14 (9) |
C18—C17—H17B | 109.3 | Cl1—C39—Cl2 | 110.95 (14) |
H17A—C17—H17B | 107.9 | Cl1—C39—H39A | 109.4 |
C19—C18—C23 | 118.6 (2) | Cl2—C39—H39A | 109.4 |
C19—C18—C17 | 120.20 (19) | Cl1—C39—H39B | 109.4 |
C23—C18—C17 | 121.16 (18) | Cl2—C39—H39B | 109.4 |
C20—C19—C18 | 120.3 (2) | H39A—C39—H39B | 108 |
C8—C1—C2—C3 | 3.7 (3) | C25—N1—Rh1—C5 | −79.9 (4) |
Rh1—C1—C2—C3 | 105.6 (2) | C17—N1—Rh1—C5 | 107.7 (3) |
C8—C1—C2—Rh1 | −101.9 (2) | C25—N1—Rh1—C6 | 73.6 (3) |
C1—C2—C3—C4 | −93.4 (3) | C17—N1—Rh1—C6 | −98.7 (2) |
Rh1—C2—C3—C4 | −12.5 (2) | C25—N1—Rh1—C2 | −173.26 (17) |
C2—C3—C4—C5 | 29.4 (3) | C17—N1—Rh1—C2 | 14.36 (17) |
C3—C4—C5—C6 | 48.7 (3) | C2—C1—Rh1—O1 | −160.82 (19) |
C3—C4—C5—Rh1 | −32.5 (2) | C8—C1—Rh1—O1 | −39.2 (3) |
C4—C5—C6—C7 | 2.6 (3) | C2—C1—Rh1—N1 | 102.58 (13) |
Rh1—C5—C6—C7 | 106.0 (2) | C8—C1—Rh1—N1 | −135.81 (15) |
C4—C5—C6—Rh1 | −103.3 (2) | C2—C1—Rh1—C5 | −65.59 (14) |
C5—C6—C7—C8 | −93.9 (2) | C8—C1—Rh1—C5 | 56.03 (16) |
Rh1—C6—C7—C8 | −12.1 (2) | C2—C1—Rh1—C6 | −100.34 (14) |
C2—C1—C8—C7 | 46.4 (3) | C8—C1—Rh1—C6 | 21.28 (15) |
Rh1—C1—C8—C7 | −34.3 (2) | C8—C1—Rh1—C2 | 121.6 (2) |
C6—C7—C8—C1 | 30.5 (3) | C6—C5—Rh1—O1 | 94.49 (14) |
C16—C9—C10—C11 | −3.4 (3) | C4—C5—Rh1—O1 | −144.64 (17) |
Rh2—C9—C10—C11 | 102.2 (2) | C6—C5—Rh1—N1 | 163.3 (3) |
C16—C9—C10—Rh2 | −105.6 (2) | C4—C5—Rh1—N1 | −75.8 (3) |
C9—C10—C11—C12 | −45.4 (3) | C6—C5—Rh1—C1 | −65.89 (14) |
Rh2—C10—C11—C12 | 36.1 (2) | C4—C5—Rh1—C1 | 54.98 (17) |
C10—C11—C12—C13 | −31.3 (3) | C4—C5—Rh1—C6 | 120.9 (2) |
C11—C12—C13—C14 | 93.8 (3) | C6—C5—Rh1—C2 | −100.91 (14) |
C11—C12—C13—Rh2 | 11.6 (2) | C4—C5—Rh1—C2 | 19.96 (16) |
C12—C13—C14—C15 | −2.4 (4) | C5—C6—Rh1—O1 | −82.79 (13) |
Rh2—C13—C14—C15 | 102.7 (2) | C7—C6—Rh1—O1 | 157.97 (17) |
C12—C13—C14—Rh2 | −105.1 (2) | C5—C6—Rh1—N1 | −168.77 (18) |
C13—C14—C15—C16 | −44.8 (3) | C7—C6—Rh1—N1 | 72.0 (3) |
Rh2—C14—C15—C16 | 36.3 (2) | C5—C6—Rh1—C1 | 114.19 (14) |
C10—C9—C16—C15 | 96.1 (3) | C7—C6—Rh1—C1 | −5.05 (16) |
Rh2—C9—C16—C15 | 15.9 (2) | C7—C6—Rh1—C5 | −119.2 (2) |
C14—C15—C16—C9 | −34.0 (3) | C5—C6—Rh1—C2 | 76.34 (14) |
N1—C17—C18—C19 | 158.9 (2) | C7—C6—Rh1—C2 | −42.90 (17) |
N1—C17—C18—C23 | −20.4 (3) | C1—C2—Rh1—O1 | 162.04 (18) |
C23—C18—C19—C20 | 1.9 (3) | C3—C2—Rh1—O1 | 43.6 (3) |
C17—C18—C19—C20 | −177.5 (2) | C1—C2—Rh1—N1 | −81.46 (13) |
C18—C19—C20—C21 | 0.1 (4) | C3—C2—Rh1—N1 | 160.13 (16) |
C19—C20—C21—C22 | −1.9 (4) | C3—C2—Rh1—C1 | −118.4 (2) |
C20—C21—C22—C23 | 1.6 (3) | C1—C2—Rh1—C5 | 114.39 (14) |
C20—C21—C22—C24 | 177.6 (2) | C3—C2—Rh1—C5 | −4.02 (16) |
C21—C22—C23—C18 | 0.5 (3) | C1—C2—Rh1—C6 | 76.99 (13) |
C24—C22—C23—C18 | −175.4 (2) | C3—C2—Rh1—C6 | −41.41 (17) |
C19—C18—C23—C22 | −2.2 (3) | C38—O2—Rh2—N2 | −8.29 (19) |
C17—C18—C23—C22 | 177.2 (2) | C38—O2—Rh2—C10 | 93.8 (2) |
C23—C22—C24—N2 | −27.7 (3) | C38—O2—Rh2—C14 | −166.6 (2) |
C21—C22—C24—N2 | 156.5 (2) | C38—O2—Rh2—C9 | −134.3 (3) |
N1—C25—C26—C31 | −168.7 (2) | C38—O2—Rh2—C13 | 155.4 (2) |
N1—C25—C26—C27 | 11.2 (4) | C32—N2—Rh2—O2 | 3.22 (18) |
C31—C26—C27—O1 | 175.1 (2) | C24—N2—Rh2—O2 | −173.31 (17) |
C25—C26—C27—O1 | −4.7 (3) | C32—N2—Rh2—C10 | −151.12 (18) |
C31—C26—C27—C28 | −4.8 (3) | C24—N2—Rh2—C10 | 32.36 (17) |
C25—C26—C27—C28 | 175.3 (2) | C32—N2—Rh2—C14 | 81.8 (3) |
O1—C27—C28—C29 | −175.2 (2) | C24—N2—Rh2—C14 | −94.8 (3) |
C26—C27—C28—C29 | 4.8 (3) | C32—N2—Rh2—C9 | 170.02 (18) |
C27—C28—C29—C30 | −1.3 (4) | C24—N2—Rh2—C9 | −6.50 (18) |
C28—C29—C30—C31 | −2.4 (4) | C32—N2—Rh2—C13 | −72.1 (3) |
C29—C30—C31—C26 | 2.2 (4) | C24—N2—Rh2—C13 | 111.3 (3) |
C27—C26—C31—C30 | 1.4 (4) | C9—C10—Rh2—O2 | 160.62 (16) |
C25—C26—C31—C30 | −178.7 (2) | C11—C10—Rh2—O2 | 39.3 (3) |
N2—C32—C33—C34 | 175.0 (2) | C9—C10—Rh2—N2 | −98.24 (13) |
N2—C32—C33—C38 | −6.9 (4) | C11—C10—Rh2—N2 | 140.46 (15) |
C38—C33—C34—C35 | −0.1 (3) | C9—C10—Rh2—C14 | 64.10 (14) |
C32—C33—C34—C35 | 178.0 (2) | C11—C10—Rh2—C14 | −57.21 (17) |
C33—C34—C35—C36 | −0.1 (4) | C11—C10—Rh2—C9 | −121.3 (2) |
C34—C35—C36—C37 | 0.6 (4) | C9—C10—Rh2—C13 | 98.42 (14) |
C35—C36—C37—C38 | −1.0 (4) | C11—C10—Rh2—C13 | −22.88 (16) |
C34—C33—C38—O2 | 179.4 (2) | C13—C14—Rh2—O2 | −88.47 (14) |
C32—C33—C38—O2 | 1.3 (4) | C15—C14—Rh2—O2 | 150.06 (17) |
C34—C33—C38—C37 | −0.2 (3) | C13—C14—Rh2—N2 | −168.04 (18) |
C32—C33—C38—C37 | −178.2 (2) | C15—C14—Rh2—N2 | 70.5 (3) |
C36—C37—C38—O2 | −178.9 (2) | C13—C14—Rh2—C10 | 65.42 (14) |
C36—C37—C38—C33 | 0.7 (3) | C15—C14—Rh2—C10 | −56.05 (18) |
C26—C25—N1—C17 | 174.0 (2) | C13—C14—Rh2—C9 | 100.18 (14) |
C26—C25—N1—Rh1 | 0.9 (3) | C15—C14—Rh2—C9 | −21.28 (17) |
C18—C17—N1—C25 | −72.5 (2) | C15—C14—Rh2—C13 | −121.5 (2) |
C18—C17—N1—Rh1 | 100.54 (19) | C10—C9—Rh2—O2 | −148.3 (3) |
C33—C32—N2—C24 | 179.8 (2) | C16—C9—Rh2—O2 | −29.7 (4) |
C33—C32—N2—Rh2 | 3.0 (3) | C10—C9—Rh2—N2 | 86.60 (14) |
C22—C24—N2—C32 | 83.3 (2) | C16—C9—Rh2—N2 | −154.80 (16) |
C22—C24—N2—Rh2 | −99.9 (2) | C16—C9—Rh2—C10 | 118.6 (2) |
C28—C27—O1—Rh1 | 167.14 (15) | C10—C9—Rh2—C14 | −115.78 (14) |
C26—C27—O1—Rh1 | −12.8 (3) | C16—C9—Rh2—C14 | 2.82 (17) |
C33—C38—O2—Rh2 | 7.2 (3) | C10—C9—Rh2—C13 | −78.57 (14) |
C37—C38—O2—Rh2 | −173.22 (15) | C16—C9—Rh2—C13 | 40.03 (17) |
C27—O1—Rh1—N1 | 18.17 (18) | C14—C13—Rh2—O2 | 88.26 (14) |
C27—O1—Rh1—C1 | −78.8 (3) | C12—C13—Rh2—O2 | −150.67 (17) |
C27—O1—Rh1—C5 | −176.45 (19) | C14—C13—Rh2—N2 | 164.4 (2) |
C27—O1—Rh1—C6 | −138.36 (19) | C12—C13—Rh2—N2 | −74.6 (3) |
C27—O1—Rh1—C2 | 136.2 (2) | C14—C13—Rh2—C10 | −114.81 (14) |
C25—N1—Rh1—O1 | −11.91 (17) | C12—C13—Rh2—C10 | 6.26 (16) |
C17—N1—Rh1—O1 | 175.71 (16) | C12—C13—Rh2—C14 | 121.1 (2) |
C25—N1—Rh1—C1 | 148.62 (18) | C14—C13—Rh2—C9 | −76.52 (14) |
C17—N1—Rh1—C1 | −23.75 (17) | C12—C13—Rh2—C9 | 44.55 (17) |
Experimental details
Crystal data | |
Chemical formula | [Rh2(C22H18N2O2)(C8H12)2]·CH2Cl2 |
Mr | 849.48 |
Crystal system, space group | Monoclinic, P21/c |
Temperature (K) | 90 |
a, b, c (Å) | 16.0829 (4), 18.8607 (4), 11.2352 (2) |
β (°) | 99.081 (1) |
V (Å3) | 3365.31 (13) |
Z | 4 |
Radiation type | Mo Kα |
µ (mm−1) | 1.18 |
Crystal size (mm) | 0.30 × 0.12 × 0.12 |
Data collection | |
Diffractometer | Nonius KappaCCD |
Absorption correction | Multi-scan (HKL SCALEPACK; Otwinowski & Minor 1997) |
Tmin, Tmax | 0.631, 0.912 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 17250, 10328, 8682 |
Rint | 0.025 |
(sin θ/λ)max (Å−1) | 0.721 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.032, 0.077, 1.02 |
No. of reflections | 10328 |
No. of parameters | 425 |
H-atom treatment | H-atom parameters constrained |
Δρmax, Δρmin (e Å−3) | 0.93, −0.96 |
Computer programs: COLLECT (Nonius, 2000), HKL SCALEPACK (Otwinowski & Minor, 1997), HKL DENZO and SCALEPACK (Otwinowski & Minor, 1997), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), ORTEP-3 for Windows (Farrugia, 1997), WinGX (Farrugia, 1999) and GAUSSIAN09 (Frisch et al., 2009).
Acknowledgements
The purchase of the diffractometer was made possible by grant No. LEQSF (1999–2000)-ENH-TR-13, administered by the Louisiana Board of Regents. Part of this work was also supported by an ACS–PRF grant to AWM.
References
Brunner, H. & Fisch, H. J. (1987). Organomet. Chem. 335, 1–14. CAS Google Scholar
Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565. CrossRef IUCr Journals Google Scholar
Farrugia, L. J. (1999). J. Appl. Cryst. 32, 837–838. CrossRef CAS IUCr Journals Google Scholar
Frisch, M. J. et al. (2009). Gaussian09. Gaussian Inc., Wallingford CT, USA. Google Scholar
Maverick, A. W., Laxman, R. K., Hawkins, M. A., Martone, D. P. & Fronczek, F. R. (2005). Dalton Trans. pp. 200–206. Web of Science CSD CrossRef Google Scholar
Mosae Selvakumar, P., Nadella, S., Jeya Prathap, K., Kureshy, R. I., Suresh, E. & Subramanian, P. S. (2011). Inorg. Chim. Acta, 375, 106–113. Web of Science CSD CrossRef CAS Google Scholar
Nakamura, T., Niwa, K., Usugi, S., Asada, H., Fujiwara, M. & Matsushita, T. (2001). Polyhedron, 20, 191–201. Web of Science CSD CrossRef CAS Google Scholar
Nonius (2000). COLLECT. Nonius BV, Delft, The Netherlands. Google Scholar
Otwinowski, Z. & Minor, W. (1997). Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, edited by C. W. Carter Jr & R. M. Sweet, pp. 307–326. New York: Academic Press. Google Scholar
Rappe, A. K., Casewit, C. J., Colwell, K. S., Skiff, W. A. G. III & Skiff, W. M. (1992). J. Am. Chem. Soc. 114, 10024–10035. CrossRef CAS Web of Science Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Schiff-base ligands such as SIXH2 (C22H20N2O2, CAS 51540–97–7, Maverick et al., 2005) are typically formed by condensation of a primary amine with an aldehyde, resulting in an imine, R1HC=N—R2, which is particularly useful for binding metal ions. The title compound, (SIX)Rh2(COD)2.DCM, C38H42N2O2Rh2.CH2Cl2, consists of one DCM molecule for each organometallic dimer. The latter is composed of tetradentate dianion α,α'-bis(salicylimino)-m-xylene (SIX) coordinated to two Rh(I) ions. Each Rh is bonded to an oxygen (Rh1—O1 = 2.044 (2), Rh2—O2 = 2.026 (2) Å), a nitrogen (Rh1—N1 = 2.083 (2), Rh2—N2 = 2.090 (2) Å), and a 1,5-cyclooctadiene (COD) ligand via two η2-bonds (each directed toward the center of a C═C bond): Rh1—(C1 & C2) = 2.007 (2), Rh1— (C5 & C6) = 2.013 (2), Rh2—(C9 & C10) = 2.000 (2), Rh2—(C13 & C14) = 2.021 (2) Å.
Each COD has quasi-C2 molecular symmetry as judged by close equivalencies of putatively equal intraannular bond lengths, bond angles and torsion angles. One measure of the twist of each ring from idealized C2v molecular symmetry is the torsion angle of four atom-pair centroids: C1 & C2, C3 & C8, C4 & C7, C5 & C6 (+30.0 (3)°) and C9 & C10, C11 & C16, C12 & C15, C13 & C14 (-33.1 (3)°). The signs of the two twist angles, together with the signs of equivalent intraannular torsion angles, indicates that the two COD moieties are near enantiomorphs. The observed molecular measurements are very close to those for the minimum energy conformer calculated in Gaussian09 (Frisch et al., 2009) using the UFF procedure (Rappe et al., 1992). This conformer has exact C2 symmetry and twist angle ±30.8°.
The four bonds about each Rh form a quasi-square planar environment. For example, deviations δr.m.s. from the mean planes defined by each metal atom and the termini of its four bonds are Rh1: 0.159 (1) and Rh2: 0.204 (1) Å. The intramolecular Rh···Rh distance of 5.943 (1) Å suggests that there is no direct metal-metal interaction.