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Figure 1 Single-crystal X-ray structure of Mn(II)(O2CH)2[15-MCMn(III)N(shi)-5](Im)5(MeOH).3.36MeOH.0.65H2O (1). The thermal ellipsoid plot of 1 is at a 50% probability level. Hydrogen atoms and the lattice solvent molecules have been omitted for clarity. The disordered atoms of the imidazole attached to Mn2 are only shown at the higher occupancy positions. Color scheme for all figures: purple - Mn(II) and Mn(III), red - oxygen, blue - nitrogen, and gray - carbon. |