(Acetonitrile){2-[bis­(pyridin-2-ylmethyl-κ2N)amino-κN]-N-(2,6-dimethyl­phen­yl)acetamide-κO}(perchlorato-κO)zinc (acetonitrile){2-[bis­(pyridin-2-ylmethyl-κ2N)amino-κN]-N-(2,6-dimethyl­phen­yl)acetamide-κO}zinc tris­(perchlorate)

Åstrand, O.A.H.; Görbitz, C.H.; Kristoffersen, K.A.; Rongved, P.

doi:10.1107/S1600536813001396

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 2 Octahedral geometry at Zn1A (left) and trigonal bipyramidal geometry at Zn1B (right). In-plane bond angles (°) have been indicated. N3—Zn1—N4 undergoes an opening of 27.4° from B to A to accommodate the extra perchlorate ligand O1D. In both complexes the N5—Zn1—N3/N4/O1 angles are slightly larger than the N2—Zn1—N3/N4/O1 angles, with ranges 96.0 − 102.8° and 78.7 − 80.3°, respectively.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 69| Part 2| January 2013| Pages m112-m113

doi:10.1107/S1600536813001396

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