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organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 69| Part 5| May 2013| Page o817
https://doi.org/10.1107/S1600536813011392

2,5-Di­methyl-3-(4-methyl­phenyl­sulfon­yl)-1-benzo­furan

Hong Dae Choi,a Pil Ja Seoa and Uk Leeb*

aDepartment of Chemistry, Dongeui University, San 24 Kaya-dong, Busanjin-gu, Busan 614-714, Republic of Korea, and bDepartment of Chemistry, Pukyong National University, 599-1 Daeyeon 3-dong, Nam-gu, Busan 608-737, Republic of Korea
*Correspondence e-mail: uklee@pknu.ac.kr

(Received 24 April 2013; accepted 26 April 2013; online 30 April 2013)

In the title compound, C17H16O3S, the dihedral angle between the 4-methyl­phenyl ring and the mean plane [r.m.s. deviation = 0.011 (1) Å] of the benzo­furan ring system is 71.47 (5)°. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, and by slipped π–π inter­actions between the benzo­furan ring systems of neighbouring mol­ecules [centroid–centroid distances = 3.638 (2) and 3.766 (2) Å, inter­planar distances = 3.564 (2) and 3.454 (2) Å, and slippages = 0.730 (2) and 1.501 (2) Å], forming a three-dimensional network.

Related literature

For background information and the crystal structures of related compounds, see: Choi et al. (2010[Choi, H. D., Seo, P. J., Son, B. W. & Lee, U. (2010). Acta Cryst. E66, o3065.], 2012[Choi, H. D., Seo, P. J. & Lee, U. (2012). Acta Cryst. E68, o1410.]).

[Scheme 1]

Experimental

Crystal data

  • C17H16O3S

  • Mr = 300.36

  • Triclinic, [P \overline 1]

  • a = 7.3481 (3) Å

  • b = 10.2285 (4) Å

  • c = 11.0625 (4) Å

  • α = 114.134 (2)°

  • β = 91.056 (2)°

  • γ = 106.624 (2)°

  • V = 718.30 (5) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 0.23 mm−1

  • T = 173 K

  • 0.31 × 0.25 × 0.12 mm
Data collection

  • Bruker SMART APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2009[Bruker (2009). APEX2, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.684, Tmax = 0.746

  • 13104 measured reflections

  • 3545 independent reflections

  • 2977 reflections with I > 2σ(I)

  • Rint = 0.029
Refinement

  • R[F2 > 2σ(F2)] = 0.041

  • wR(F2) = 0.108

  • S = 1.04

  • 3545 reflections

  • 193 parameters

  • H-atom parameters constrained

  • Δρmax = 0.39 e Å−3

  • Δρmin = −0.47 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A D⋯A D—H⋯A
C12—H12⋯O2i 0.95 2.48 3.224 (2) 135
C16—H16⋯O3ii 0.95 2.44 3.301 (2) 151
Symmetry codes: (i) -x+1, -y, -z+1; (ii) -x+1, -y, -z.

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2009[Bruker (2009). APEX2, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012[Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.]) and DIAMOND (Brandenburg, 1998[Brandenburg, K. (1998). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: SHELXL97.

Supporting information

Crystal structure: contains datablocks global, I. DOI: https://doi.org/10.1107/S1600536813011392/is5267sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536813011392/is5267Isup2.hkl

Supporting information file. DOI: https://doi.org/10.1107/S1600536813011392/is5267Isup3.cml

checkCIF report


Comment top

As a part of our continuing study of 2,5-dimethyl-1-benzofuran derivatives containing 4-chlorophenylsulfonyl (Choi et al., 2010) and 4-methylphenylsulfinyl (Choi et al., 2012) substituents in 3-position, we report herein the crystal structure of the title compound.

In the title molecule (Fig. 1), the benzofuran unit is essentially planar, with a mean deviation of 0.011 (1) Å from the least-squares plane defined by the nine constituent atoms. The dihedral angle between the 4-methylphenyl ring and the mean plane of the benzofuran fragment is 71.47 (5)°. In the crystal structure (Fig. 2), molecules are connected by weak C—H···O hydrogen bonds (Table 1), and by slipped π–π interactions between the furan and benzene rings of neighbouring molecules, with Cg1···Cg2iii and Cg1···Cg2iv distances of 3.638 (2) Å & 3.766 (2) Å, and interplanar distances of 3.564 (2) Å & 3.454 (2) Å resulting in slippages of 0.730 (2) Å & 1.501 (2) Å (Cg1 and Cg2 are the centroids of the C1/C2/C7/O1/C8 furan ring and the C2–C7 benzene ring, respectively).

Related literature top

For background information and the crystal structures of related compounds, see: Choi et al. (2010, 2012).

Experimental top

3-Chloroperoxybenzoic acid (77%, 560 mg, 2.5 mmol) was added in small portions to a stirred solution of 2,5-dimethyl-3-(4-methylphenylsulfanyl)-1-benzofuran (322 mg, 1.2 mmol) in dichloromethane (40 mL) at 273 K. After being stirred at room temperature for 8h, the mixture was washed with saturated sodium bicarbonate solution and the organic layer was separated, dried over magnesium sulfate, filtered and concentrated at reduced pressure. The residue was purified by column chromatography (hexane-ethyl acetate, 4:1 v/v) to afford the title compound as a colorless solid [yield 73%, m.p. 406–407 K; Rf = 0.48 (hexane–ethyl acetate, 4:1 v/v)]. Single crystals suitable for X-ray diffraction were prepared by slow evaporation of a solution of the title compound in acetone at room temperature.

Refinement top

All H atoms were positioned geometrically and refined using a riding model, with C—H = 0.95 Å for aryl and 0.98 Å for methyl H atoms, and with Uiso(H) = 1.2Ueq(C) for aryl and 1.5Ueq(C) for methyl H atoms. The positions of methyl hydrogens were optimized rotationally.

Structure description top

As a part of our continuing study of 2,5-dimethyl-1-benzofuran derivatives containing 4-chlorophenylsulfonyl (Choi et al., 2010) and 4-methylphenylsulfinyl (Choi et al., 2012) substituents in 3-position, we report herein the crystal structure of the title compound.

In the title molecule (Fig. 1), the benzofuran unit is essentially planar, with a mean deviation of 0.011 (1) Å from the least-squares plane defined by the nine constituent atoms. The dihedral angle between the 4-methylphenyl ring and the mean plane of the benzofuran fragment is 71.47 (5)°. In the crystal structure (Fig. 2), molecules are connected by weak C—H···O hydrogen bonds (Table 1), and by slipped π–π interactions between the furan and benzene rings of neighbouring molecules, with Cg1···Cg2iii and Cg1···Cg2iv distances of 3.638 (2) Å & 3.766 (2) Å, and interplanar distances of 3.564 (2) Å & 3.454 (2) Å resulting in slippages of 0.730 (2) Å & 1.501 (2) Å (Cg1 and Cg2 are the centroids of the C1/C2/C7/O1/C8 furan ring and the C2–C7 benzene ring, respectively).

For background information and the crystal structures of related compounds, see: Choi et al. (2010, 2012).

Computing details top

Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012) and DIAMOND (Brandenburg, 1998); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure of the title compound with the atom numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. H atoms are presented as small spheres of arbitrary radius.
[Figure 2] Fig. 2. A view of the C—H···O and π–π interactions (dotted lines) in the crystal structure of the title compound. H atoms non-participating in hydrogen-bonding were omitted for clarity. [Symmetry codes: (i) -x + 1, -y, -z + 1; (ii) -x + 1, -y, -z; (iii) -x + 1, -y + 1, -z + 1; (iv) -x + 2, -y + 1, -z + 1.]
2,5-Dimethyl-3-(4-methylphenylsulfonyl)-1-benzofuran top
Crystal data top
C17H16O3SZ = 2
Mr = 300.36F(000) = 316
Triclinic, P1Dx = 1.389 Mg m−3
Hall symbol: -P 1Melting point = 406–407 K
a = 7.3481 (3) ÅMo Kα radiation, λ = 0.71073 Å
b = 10.2285 (4) ÅCell parameters from 5770 reflections
c = 11.0625 (4) Åθ = 2.3–28.3°
α = 114.134 (2)°µ = 0.23 mm−1
β = 91.056 (2)°T = 173 K
γ = 106.624 (2)°Block, colourless
V = 718.30 (5) Å30.31 × 0.25 × 0.12 mm
Data collection top
Bruker SMART APEXII CCD
diffractometer		3545 independent reflections
Radiation source: rotating anode2977 reflections with I > 2σ(I)
Graphite multilayer monochromatorRint = 0.029
Detector resolution: 10.0 pixels mm-1θmax = 28.3°, θmin = 2.0°
φ and ω scansh = −9→9
Absorption correction: multi-scan
(SADABS; Bruker, 2009)		k = −13→13
Tmin = 0.684, Tmax = 0.746l = −13→14
13104 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.041Hydrogen site location: difference Fourier map
wR(F2) = 0.108H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.046P)2 + 0.3774P]
where P = (Fo2 + 2Fc2)/3
3545 reflections(Δ/σ)max < 0.001
193 parametersΔρmax = 0.39 e Å−3
0 restraintsΔρmin = −0.47 e Å−3
Crystal data top
C17H16O3Sγ = 106.624 (2)°
Mr = 300.36V = 718.30 (5) Å3
Triclinic, P1Z = 2
a = 7.3481 (3) ÅMo Kα radiation
b = 10.2285 (4) ŵ = 0.23 mm−1
c = 11.0625 (4) ÅT = 173 K
α = 114.134 (2)°0.31 × 0.25 × 0.12 mm
β = 91.056 (2)°
Data collection top
Bruker SMART APEXII CCD
diffractometer		3545 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2009)		2977 reflections with I > 2σ(I)
Tmin = 0.684, Tmax = 0.746Rint = 0.029
13104 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0410 restraints
wR(F2) = 0.108H-atom parameters constrained
S = 1.04Δρmax = 0.39 e Å−3
3545 reflectionsΔρmin = −0.47 e Å−3
193 parameters
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
S10.50135 (6)0.10427 (4)0.27607 (4)0.02799 (12)
O10.81392 (17)0.52143 (13)0.36169 (13)0.0350 (3)
O20.38652 (17)0.08356 (13)0.37433 (12)0.0334 (3)
O30.40868 (17)0.05919 (14)0.14334 (12)0.0371 (3)
C10.6363 (2)0.29425 (18)0.34342 (16)0.0279 (3)
C20.6791 (2)0.39740 (18)0.48433 (16)0.0278 (3)
C30.6357 (2)0.38832 (19)0.60305 (16)0.0306 (3)
H30.56220.29480.60210.037*
C40.7017 (2)0.5182 (2)0.72308 (17)0.0353 (4)
C50.8078 (3)0.6558 (2)0.72172 (19)0.0400 (4)
H50.84980.74430.80430.048*
C60.8531 (3)0.6672 (2)0.60581 (19)0.0383 (4)
H60.92570.76070.60630.046*
C70.7877 (2)0.53589 (19)0.48886 (18)0.0315 (4)
C80.7209 (2)0.37347 (19)0.27511 (18)0.0321 (4)
C90.6603 (3)0.5108 (2)0.85310 (19)0.0485 (5)
H9A0.54860.42190.83550.073*
H9B0.63320.60250.91260.073*
H9C0.77220.50300.89600.073*
C100.7368 (3)0.3328 (2)0.13212 (19)0.0423 (4)
H10A0.70520.40590.10670.064*
H10B0.64730.23120.07700.064*
H10C0.86850.33440.11780.064*
C110.6690 (2)0.00704 (17)0.26085 (15)0.0276 (3)
C120.7065 (3)−0.0350 (2)0.36046 (17)0.0337 (4)
H120.6457−0.00890.43800.040*
C130.8334 (3)−0.1156 (2)0.34560 (19)0.0376 (4)
H130.8570−0.14650.41280.045*
C140.9267 (2)−0.15207 (18)0.23464 (18)0.0337 (4)
C150.8911 (3)−0.1045 (2)0.13838 (17)0.0361 (4)
H150.9576−0.12550.06340.043*
C160.7616 (3)−0.02729 (19)0.14912 (16)0.0337 (4)
H160.73610.00200.08110.040*
C171.0609 (3)−0.2432 (2)0.2168 (2)0.0441 (4)
H17A1.1135−0.22980.30470.066*
H17B1.1661−0.20890.17260.066*
H17C0.9903−0.35050.16160.066*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
S10.0275 (2)0.0299 (2)0.0247 (2)0.00481 (15)0.00166 (15)0.01299 (16)
O10.0319 (6)0.0332 (6)0.0455 (7)0.0079 (5)0.0067 (5)0.0241 (6)
O20.0318 (6)0.0342 (6)0.0320 (6)0.0048 (5)0.0081 (5)0.0160 (5)
O30.0362 (7)0.0431 (7)0.0286 (6)0.0086 (5)−0.0019 (5)0.0155 (5)
C10.0249 (7)0.0302 (8)0.0310 (8)0.0082 (6)0.0034 (6)0.0159 (6)
C20.0234 (7)0.0286 (8)0.0334 (8)0.0098 (6)0.0036 (6)0.0142 (6)
C30.0289 (8)0.0304 (8)0.0324 (8)0.0097 (6)0.0042 (6)0.0134 (7)
C40.0335 (9)0.0373 (9)0.0333 (9)0.0161 (7)0.0040 (7)0.0105 (7)
C50.0375 (9)0.0315 (9)0.0428 (10)0.0139 (7)−0.0023 (8)0.0068 (8)
C60.0315 (9)0.0283 (8)0.0526 (11)0.0088 (7)−0.0002 (8)0.0159 (8)
C70.0259 (8)0.0316 (8)0.0421 (9)0.0108 (6)0.0048 (7)0.0198 (7)
C80.0275 (8)0.0348 (8)0.0393 (9)0.0101 (7)0.0046 (7)0.0211 (7)
C90.0560 (12)0.0507 (12)0.0327 (10)0.0198 (10)0.0069 (9)0.0103 (9)
C100.0434 (10)0.0529 (11)0.0418 (10)0.0139 (9)0.0111 (8)0.0319 (9)
C110.0290 (8)0.0259 (7)0.0245 (7)0.0040 (6)0.0005 (6)0.0109 (6)
C120.0381 (9)0.0368 (9)0.0286 (8)0.0088 (7)0.0073 (7)0.0184 (7)
C130.0413 (10)0.0395 (9)0.0393 (9)0.0111 (8)0.0041 (8)0.0254 (8)
C140.0318 (8)0.0249 (8)0.0391 (9)0.0034 (6)0.0024 (7)0.0128 (7)
C150.0407 (9)0.0352 (9)0.0290 (8)0.0114 (7)0.0083 (7)0.0110 (7)
C160.0413 (9)0.0356 (9)0.0237 (8)0.0104 (7)0.0034 (7)0.0138 (7)
C170.0402 (10)0.0351 (9)0.0599 (12)0.0123 (8)0.0089 (9)0.0230 (9)
Geometric parameters (Å, º) top
S1—O21.4347 (12)C9—H9B0.9800
S1—O31.4360 (12)C9—H9C0.9800
S1—C11.7323 (16)C10—H10A0.9800
S1—C111.7628 (16)C10—H10B0.9800
O1—C81.369 (2)C10—H10C0.9800
O1—C71.376 (2)C11—C121.386 (2)
C1—C81.358 (2)C11—C161.388 (2)
C1—C21.445 (2)C12—C131.382 (2)
C2—C31.390 (2)C12—H120.9500
C2—C71.393 (2)C13—C141.386 (3)
C3—C41.389 (2)C13—H130.9500
C3—H30.9500C14—C151.388 (2)
C4—C51.407 (3)C14—C171.504 (2)
C4—C91.503 (3)C15—C161.378 (2)
C5—C61.373 (3)C15—H150.9500
C5—H50.9500C16—H160.9500
C6—C71.377 (2)C17—H17A0.9800
C6—H60.9500C17—H17B0.9800
C8—C101.478 (2)C17—H17C0.9800
C9—H9A0.9800
O2—S1—O3119.29 (7)C4—C9—H9C109.5
O2—S1—C1106.76 (7)H9A—C9—H9C109.5
O3—S1—C1109.07 (8)H9B—C9—H9C109.5
O2—S1—C11107.90 (7)C8—C10—H10A109.5
O3—S1—C11107.52 (7)C8—C10—H10B109.5
C1—S1—C11105.50 (7)H10A—C10—H10B109.5
C8—O1—C7107.01 (12)C8—C10—H10C109.5
C8—C1—C2107.56 (14)H10A—C10—H10C109.5
C8—C1—S1126.87 (13)H10B—C10—H10C109.5
C2—C1—S1125.57 (12)C12—C11—C16120.60 (16)
C3—C2—C7119.29 (15)C12—C11—S1119.59 (13)
C3—C2—C1136.09 (15)C16—C11—S1119.81 (12)
C7—C2—C1104.60 (15)C13—C12—C11119.20 (16)
C4—C3—C2118.91 (16)C13—C12—H12120.4
C4—C3—H3120.5C11—C12—H12120.4
C2—C3—H3120.5C12—C13—C14121.31 (16)
C3—C4—C5119.47 (17)C12—C13—H13119.3
C3—C4—C9119.97 (17)C14—C13—H13119.3
C5—C4—C9120.56 (17)C13—C14—C15118.30 (16)
C6—C5—C4122.60 (17)C13—C14—C17121.26 (16)
C6—C5—H5118.7C15—C14—C17120.44 (17)
C4—C5—H5118.7C16—C15—C14121.53 (16)
C5—C6—C7116.39 (17)C16—C15—H15119.2
C5—C6—H6121.8C14—C15—H15119.2
C7—C6—H6121.8C15—C16—C11119.01 (15)
O1—C7—C6126.27 (16)C15—C16—H16120.5
O1—C7—C2110.39 (14)C11—C16—H16120.5
C6—C7—C2123.32 (17)C14—C17—H17A109.5
C1—C8—O1110.43 (15)C14—C17—H17B109.5
C1—C8—C10133.95 (17)H17A—C17—H17B109.5
O1—C8—C10115.60 (15)C14—C17—H17C109.5
C4—C9—H9A109.5H17A—C17—H17C109.5
C4—C9—H9B109.5H17B—C17—H17C109.5
H9A—C9—H9B109.5
O2—S1—C1—C8−159.43 (14)C1—C2—C7—C6177.78 (15)
O3—S1—C1—C8−29.29 (17)C2—C1—C8—O1−0.70 (18)
C11—S1—C1—C885.95 (16)S1—C1—C8—O1179.36 (11)
O2—S1—C1—C220.64 (15)C2—C1—C8—C10177.32 (18)
O3—S1—C1—C2150.78 (13)S1—C1—C8—C10−2.6 (3)
C11—S1—C1—C2−93.98 (14)C7—O1—C8—C10.23 (17)
C8—C1—C2—C3179.54 (18)C7—O1—C8—C10−178.19 (14)
S1—C1—C2—C3−0.5 (3)O2—S1—C11—C12−17.41 (15)
C8—C1—C2—C70.87 (17)O3—S1—C11—C12−147.28 (13)
S1—C1—C2—C7−179.19 (12)C1—S1—C11—C1296.42 (14)
C7—C2—C3—C40.2 (2)O2—S1—C11—C16162.29 (13)
C1—C2—C3—C4−178.31 (17)O3—S1—C11—C1632.42 (15)
C2—C3—C4—C51.0 (2)C1—S1—C11—C16−83.88 (14)
C2—C3—C4—C9−178.75 (16)C16—C11—C12—C13−1.8 (3)
C3—C4—C5—C6−1.4 (3)S1—C11—C12—C13177.88 (13)
C9—C4—C5—C6178.35 (17)C11—C12—C13—C141.4 (3)
C4—C5—C6—C70.5 (3)C12—C13—C14—C150.6 (3)
C8—O1—C7—C6−178.12 (16)C12—C13—C14—C17−178.38 (16)
C8—O1—C7—C20.35 (17)C13—C14—C15—C16−2.2 (3)
C5—C6—C7—O1179.09 (15)C17—C14—C15—C16176.74 (16)
C5—C6—C7—C20.8 (3)C14—C15—C16—C111.8 (3)
C3—C2—C7—O1−179.69 (13)C12—C11—C16—C150.2 (2)
C1—C2—C7—O1−0.75 (17)S1—C11—C16—C15−179.48 (13)
C3—C2—C7—C6−1.2 (2)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C12—H12···O2i0.952.483.224 (2)135
C16—H16···O3ii0.952.443.301 (2)151
Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x+1, −y, −z.

Experimental details

Crystal data
Chemical formulaC17H16O3S
Mr300.36
Crystal system, space groupTriclinic, P1
Temperature (K)173
a, b, c (Å)7.3481 (3), 10.2285 (4), 11.0625 (4)
α, β, γ (°)114.134 (2), 91.056 (2), 106.624 (2)
V (Å3)718.30 (5)
Z2
Radiation typeMo Kα
µ (mm−1)0.23
Crystal size (mm)0.31 × 0.25 × 0.12
Data collection
DiffractometerBruker SMART APEXII CCD
Absorption correctionMulti-scan
(SADABS; Bruker, 2009)
Tmin, Tmax0.684, 0.746
No. of measured, independent and
observed [I > 2σ(I)] reflections		13104, 3545, 2977
Rint0.029
(sin θ/λ)max (Å−1)0.668
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.041, 0.108, 1.04
No. of reflections3545
No. of parameters193
H-atom treatmentH-atom parameters constrained
Δρmax, Δρmin (e Å−3)0.39, −0.47

Computer programs: APEX2 (Bruker, 2009), SAINT (Bruker, 2009), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), ORTEP-3 for Windows (Farrugia, 2012) and DIAMOND (Brandenburg, 1998).

Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C12—H12···O2i0.952.483.224 (2)135
C16—H16···O3ii0.952.443.301 (2)151
Symmetry codes: (i) −x+1, −y, −z+1; (ii) −x+1, −y, −z.
 

Acknowledgements

This work was supported by the Blue-Bio Industry Regional Innovation Center (RIC08-06-07) at Dongeui University as an RIC program under the Ministry of Knowledge Economy and Busan city.

References

First citationBrandenburg, K. (1998). DIAMOND. Crystal Impact GbR, Bonn, Germany.  Google Scholar
 First citationBruker (2009). APEX2, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
 First citationChoi, H. D., Seo, P. J. & Lee, U. (2012). Acta Cryst. E68, o1410.  CSD CrossRef IUCr Journals Google Scholar
 First citationChoi, H. D., Seo, P. J., Son, B. W. & Lee, U. (2010). Acta Cryst. E66, o3065.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationFarrugia, L. J. (2012). J. Appl. Cryst. 45, 849–854.  Web of Science CrossRef CAS IUCr Journals Google Scholar
 First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

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ISSN: 2056-9890
Volume 69| Part 5| May 2013| Page o817
https://doi.org/10.1107/S1600536813011392
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