Issue contents
Download PDF of article
Download CIF
3D view
Navigation
Highlighting
Dictionary of Crystallography reference
IUPAC Gold Book reference
more ...
Download citation
FormatBIBTeX
EndNote
RefMan
Refer
Medline
CIF
SGML
Plain Text
share
Previous article
Next article
Previous article
Issue contents
Download PDF of article
Download CIF
3D view
Navigation
Highlighting
Dictionary of Crystallography reference
IUPAC Gold Book reference
more ...
Download citation
FormatBIBTeX
EndNote
RefMan
Refer
Medline
CIF
SGML
Plain Text
share
Next article

metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 69| Part 5| May 2013| Pages m248-m249
https://doi.org/10.1107/S1600536813008945

trans-Di­chlorido­tetra­kis­[(di­methyl­phosphor­yl)methanaminium-κO]cobalt(II) tetra­chloridocobaltate(II)

Guido J. Reissa*

aInstitut für Anorganische Chemie und Strukturchemie, Lehrstuhl II: Material- und Strukturforschung, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, D-40225 Düsseldorf, Germany
*Correspondence e-mail: reissg@hhu.de

(Received 26 March 2013; accepted 2 April 2013; online 10 April 2013)

The asymmetric unit of the title structure, [CoCl2(C3H11NOP)4][CoCl4]2, consists of one half of the trans-dichlorido­tetra­kis­[(di­methyl­phosphor­yl)methanaminium]cobalt(II) tetra­cation lying on an inversion center and one tetra­chloridocobaltate(II) dianion on a general position. Four O-coordinated cationic (di­methyl­phosphor­yl)methanaminium (dpmaH+) ligands occupy the equatorial coordination sites, whereas the chloride ligands occupy axial positions of the roughly o­cta­hedral coordination polyhedron of the cobalt metal center. Intra­molecular hydrogen bonds between the aminium groups and the O atom of the phosphoryl groups and additional hydrogen bonds between the aminium groups and the chloride ligands are present. Furthermore, four of the six H atoms not involved in intra­molecular bonding of each cobalt(II) tetra­cation form weak hydrogen bonds to four adjacent tetra­chloridocobaltate(II) counter-anions. By these inter­molecular hydrogen bonds, one-dimensional polymeric strands are formed along the b-axis direction. The hydrogen bonding is analyzed using the graph-set method and the structural similarity with dpmaHCl is discussed.

Related literature

For related dpma compounds, see: Dodoff et al. (1990[Dodoff, N., Macicek, J., Angelova, O., Varbanov, S. G. & Spassovska, N. (1990). J. Coord. Chem. 22, 219-228.]); Borisov et al. (1994[Borisov, G., Varbanov, S. G., Venanzi, L. M., Albinati, A. & Demartin, F. (1994). Inorg. Chem. 33, 5430-5437.]); Trendafilova et al. (1997[Trendafilova, N., Georgieva, I., Bauer, G., Varbanov, S. G. & Dodoff, N. (1997). Spectrochim. Acta, A53, 819-828.]); Kochel (2009[Kochel, A. (2009). Inorg. Chim. Acta, 362, 1379-1382.]); Reiss & Jörgens (2012[Reiss, G. J. & Jörgens, S. (2012). Acta Cryst. E68, o2899-o2900.]); van Megen et al. (2013[Megen, M. van, Prömper, S. & Reiss, G. J. (2013). Acta Cryst. E69, m217.]). For a definition of the term tecton, see: Brunet et al. (1997[Brunet, P., Simard, M. & Wuest, J. D. (1997). J. Am. Chem. Soc. 119, 2737-2738.]). For related methyl­phosphinic acids and their derivatives, see: Reiss & Engel (2008[Reiss, G. J. & Engel, J. S. (2008). Acta Cryst. E64, o400.]); Meyer et al. (2010[Meyer, M. K., Graf, J. & Reiss, G. J. (2010). Z. Naturforsch. Teil B, 65, 1462-1466.]). For graph-set theory and its applications, see: Etter et al. (1990[Etter, M. C., MacDonald, J. C. & Bernstein, J. (1990). Acta Cryst. B46, 256-262.]); Bernstein et al. (1995[Bernstein, J., Davis, R. E., Shimoni, L. & Chang, N.-L. (1995). Angew. Chem. Int. Ed. 34, 1555-1573.]); Grell et al. (2002[Grell, J., Bernstein, J. & Tinhofer, G. (2002). Crystallogr. Rev. 8, 1-56.]). For related cobalt complexes, see: Kubíčk et al. (2003[Kubíčk, V., Vojtíšk, P., Rudovský, J., Hermann, P. & Lukeš, I. (2003). Dalton Trans. pp. 3927-3938.]); Girma et al. (2005[Girma, K. B., Lorenz, V., Blaurock, S. & Edelmann, F. T. (2005). Z. Anorg. Allg. Chem. 631, 1419-1422.]); Guzei et al. (2010[Guzei, I. A., Spencer, L. C., Ainooson, M. K. & Darkwa, J. (2010). Acta Cryst. C66, m89-m96.]).

[Scheme 1]

Experimental

Crystal data

  • [CoCl2(C3H11NOP)4][CoCl4]2

  • Mr = 963.68

  • Triclinic, [P \overline 1]

  • a = 7.7748 (3) Å

  • b = 11.1557 (5) Å

  • c = 12.1205 (5) Å

  • α = 110.738 (4)°

  • β = 97.688 (4)°

  • γ = 104.331 (5)°

  • V = 923.66 (8) Å3

  • Z = 1

  • Mo Kα radiation

  • μ = 2.25 mm−1

  • T = 173 K

  • 0.76 × 0.33 × 0.08 mm
Data collection

  • Oxford Xcalibur diffractometer

  • Absorption correction: analytical [CrysAlis PRO (Oxford Diffraction, 2009[Oxford Diffraction (2009). CrysAlis PRO. Oxford Diffraction Ltd, Yarnton, England.]), based on expressions derived by Clark & Reid (1995[Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897.])] Tmin = 0.402, Tmax = 0.838

  • 15687 measured reflections

  • 4920 independent reflections

  • 4552 reflections with I > 2σ(I)

  • Rint = 0.020
Refinement

  • R[F2 > 2σ(F2)] = 0.018

  • wR(F2) = 0.042

  • S = 1.09

  • 4920 reflections

  • 197 parameters

  • H atoms treated by a mixture of independent and constrained refinement

  • Δρmax = 0.49 e Å−3

  • Δρmin = −0.38 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A D⋯A D—H⋯A
N1—H11⋯Cl1 0.867 (19) 2.437 (19) 3.1879 (12) 145.3 (16)
N1—H11⋯Cl24i 0.867 (19) 2.730 (19) 3.2573 (13) 120.5 (15)
N1—H12⋯O2ii 0.88 (2) 2.16 (2) 2.9504 (16) 150.3 (17)
N1—H13⋯Cl23ii 0.87 (2) 2.38 (2) 3.2403 (12) 171.3 (17)
N2—H22⋯Cl1 0.920 (19) 2.250 (19) 3.1697 (13) 177.8 (15)
N2—H21⋯Cl21iii 0.924 (19) 2.288 (19) 3.2124 (12) 177.8 (16)
N2—H23⋯Cl22i 0.86 (2) 2.71 (2) 3.3612 (13) 134.0 (16)
N2—H23⋯Cl24i 0.86 (2) 2.70 (2) 3.2989 (12) 128.1 (16)
Symmetry codes: (i) x, y, z+1; (ii) -x, -y, -z+1; (iii) -x, -y+1, -z+1.

Data collection: CrysAlis PRO (Oxford Diffraction, 2009[Oxford Diffraction (2009). CrysAlis PRO. Oxford Diffraction Ltd, Yarnton, England.]); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: DIAMOND (Brandenburg, 2012[Brandenburg, K. (2012). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).

Supporting information

Crystal structure: contains datablocks I, global. DOI: https://doi.org/10.1107/S1600536813008945/sj5313sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S1600536813008945/sj5313Isup2.hkl

checkCIF report


Comment top

It is well known that the dpma ligand (dpma = (dimethylphosphoryl)methanamine) is able to coordinate a variety of transition metals (Kochel, 2009; Trendafilova et al., 1997; Borisov et al., 1994; Dodoff et al., 1990.). Recently, it has been shown that the mono-protonated dpmaH+ cation is a potent tecton (for the term tecton, see Brunet et al., 1997) to construct hydrogen bonded polymeric structures (Reiss & Jörgens, 2012; van Megen et al., 2013). This study is part of our continuing interest in the construction of hydrogen bonded architectures using tectons based on phosphinic acid derivatives (Reiss & Engel, 2008; Meyer et al., 2010).

The asymmetric unit of the title structure consists of one half of a fourfold charged trans-dichloridotetrakis((dimethylphosphoryl)methanaminium)cobalt(II) complex located on a center of inversion and a tetrachloridocobaltate(II) dianion at a general position. In the complex cation the four O-coordinated dpmaH+ ligands occupy the equatorial coordination sites, whereas the chlorido ligands occupy axial positions in this roughly octahedral complex cation. The Co—O and Co—Cl distances are in the expected ranges (Girma et al., 2005, Guzei et al., 2010). The same applies to the geometrical parameters of the two crystallographically independent dpmaH ligands which are very similar and are in accord with the dpmaH+ cation in dpmaHCl (Reiss & Jörgens, 2012). Each chlorido ligand of the cationic complex accepts two intramolecular hydrogen bonds of two neighbouring aminium groups (N1 and N2). There is at least one more example of the occurrence of such an intramolecular hydrogen bond between a chlorido ligand and the aminium group of a coordinated ligand at the same metal center (Kubíčk et al., 2003). Furthermore, intramolecular hydrogen bonding occurs between two crystallographically dependent aminium groups (N1, N1') each donating a hydrogen bond to the O-atoms (O2 and O2') of the two other dpmaH+ ligands (Table 1, Fig. 1). Significantly different Co–O bond lengths (Co–O1 = 2.0738 (9) Å and Co–O2 = 2.1673 (9) Å) may be caused by this hydrogen bonding situation. Four of the six hydrogen atoms of aminium groups of each cationic complex, which are not involved in intramolecular hydrogen bonds, form hydrogen bonds to four adjacent tetrachloridocobaltate(II) dianions (Fig. 1). The tetrachloridocobaltate(II) dianion shows a seriously distorted tetrahedral geometry with Co–Cl distances from 2.2487 (4) Å to 2.3024 (4) Å and angles between 104.23 (1)° to 119.35 (1)°. Also for this ion the longest Co–Cl distances are associated with the chlorido ligands involved in hydrogen bonds. Cationic and anionic tectons construct a one-dimensional, hydrogen-bonded polymer along the b direction. The hydrogen bonding motifs can be classified using graph-set descriptors (Etter et al., 1990, Bernstein et al., 1995) as S22(6) and S11(7) for the intramolecular rings and as C34(10) for the backbone connection along the strands (Fig. 2). A third level graph-set is found (R66(22)) for the rings formed within the strands (Fig. 2). As these graph-sets seem to be unique to this class of compounds they alone are of limited value for a comparison with related structures. A better method to work out the key features of a structure is the use of the so-called constructor-graph representation (Grell et al., 2002). In this case, the complex cation can be reduced to a tecton that is able to donate at least four hydrogen bonds and the tetrachloridocobalte to a tecton that accepts at least two hydrogen bonds. Thus, the close relation of the title structure with the structure of dpmaHCl is inevitably clear (Fig. 3).

Related literature top

For related dpma compounds, see: Dodoff et al. (1990); Borisov et al. (1994); Trendafilova et al. (1997); Kochel (2009); Reiss & Jörgens (2012); van Megen et al. (2013). For a definition of the term tecton, see: Brunet et al. (1997). For related methylphosphinic acids and their derivatives, see: Reiss & Engel (2008); Meyer et al. (2010). For graph-set theory and its applications, see: Etter et al. (1990); Bernstein et al. (1995); Grell et al. (2002). For related cobalt complexes, see: Kubíčk et al. (2003); Girma et al. (2005); Guzei et al. (2010).

Experimental top

For the synthesis of the title compound, equimolar amounts of dpma and cobalt(II)chloride tetrahydrate were dissolved in concentrated hydrochloric acid. Slow evaporation of this solution at room temperature yielded crystals suitable for a crystallographic structure determination.

Refinement top

H atoms at the methyl groups were identified in difference syntheses, idealized and refined using rigid groups allowed to rotate about the P—C bond (AFIX 137 option of the SHELXL program; Uiso(H) = 1.5Ueq(C)) H-Atom at the methylene group using a riding model (AFIX 23 option of the SHELXL program; Uiso(H) = 1.2Ueq(C)). The coordinates of hydrogen atoms at the aminium groups were refined unrestrictedly with individual Uisovalues.

Structure description top

It is well known that the dpma ligand (dpma = (dimethylphosphoryl)methanamine) is able to coordinate a variety of transition metals (Kochel, 2009; Trendafilova et al., 1997; Borisov et al., 1994; Dodoff et al., 1990.). Recently, it has been shown that the mono-protonated dpmaH+ cation is a potent tecton (for the term tecton, see Brunet et al., 1997) to construct hydrogen bonded polymeric structures (Reiss & Jörgens, 2012; van Megen et al., 2013). This study is part of our continuing interest in the construction of hydrogen bonded architectures using tectons based on phosphinic acid derivatives (Reiss & Engel, 2008; Meyer et al., 2010).

The asymmetric unit of the title structure consists of one half of a fourfold charged trans-dichloridotetrakis((dimethylphosphoryl)methanaminium)cobalt(II) complex located on a center of inversion and a tetrachloridocobaltate(II) dianion at a general position. In the complex cation the four O-coordinated dpmaH+ ligands occupy the equatorial coordination sites, whereas the chlorido ligands occupy axial positions in this roughly octahedral complex cation. The Co—O and Co—Cl distances are in the expected ranges (Girma et al., 2005, Guzei et al., 2010). The same applies to the geometrical parameters of the two crystallographically independent dpmaH ligands which are very similar and are in accord with the dpmaH+ cation in dpmaHCl (Reiss & Jörgens, 2012). Each chlorido ligand of the cationic complex accepts two intramolecular hydrogen bonds of two neighbouring aminium groups (N1 and N2). There is at least one more example of the occurrence of such an intramolecular hydrogen bond between a chlorido ligand and the aminium group of a coordinated ligand at the same metal center (Kubíčk et al., 2003). Furthermore, intramolecular hydrogen bonding occurs between two crystallographically dependent aminium groups (N1, N1') each donating a hydrogen bond to the O-atoms (O2 and O2') of the two other dpmaH+ ligands (Table 1, Fig. 1). Significantly different Co–O bond lengths (Co–O1 = 2.0738 (9) Å and Co–O2 = 2.1673 (9) Å) may be caused by this hydrogen bonding situation. Four of the six hydrogen atoms of aminium groups of each cationic complex, which are not involved in intramolecular hydrogen bonds, form hydrogen bonds to four adjacent tetrachloridocobaltate(II) dianions (Fig. 1). The tetrachloridocobaltate(II) dianion shows a seriously distorted tetrahedral geometry with Co–Cl distances from 2.2487 (4) Å to 2.3024 (4) Å and angles between 104.23 (1)° to 119.35 (1)°. Also for this ion the longest Co–Cl distances are associated with the chlorido ligands involved in hydrogen bonds. Cationic and anionic tectons construct a one-dimensional, hydrogen-bonded polymer along the b direction. The hydrogen bonding motifs can be classified using graph-set descriptors (Etter et al., 1990, Bernstein et al., 1995) as S22(6) and S11(7) for the intramolecular rings and as C34(10) for the backbone connection along the strands (Fig. 2). A third level graph-set is found (R66(22)) for the rings formed within the strands (Fig. 2). As these graph-sets seem to be unique to this class of compounds they alone are of limited value for a comparison with related structures. A better method to work out the key features of a structure is the use of the so-called constructor-graph representation (Grell et al., 2002). In this case, the complex cation can be reduced to a tecton that is able to donate at least four hydrogen bonds and the tetrachloridocobalte to a tecton that accepts at least two hydrogen bonds. Thus, the close relation of the title structure with the structure of dpmaHCl is inevitably clear (Fig. 3).

For related dpma compounds, see: Dodoff et al. (1990); Borisov et al. (1994); Trendafilova et al. (1997); Kochel (2009); Reiss & Jörgens (2012); van Megen et al. (2013). For a definition of the term tecton, see: Brunet et al. (1997). For related methylphosphinic acids and their derivatives, see: Reiss & Engel (2008); Meyer et al. (2010). For graph-set theory and its applications, see: Etter et al. (1990); Bernstein et al. (1995); Grell et al. (2002). For related cobalt complexes, see: Kubíčk et al. (2003); Girma et al. (2005); Guzei et al. (2010).

Computing details top

Data collection: CrysAlis PRO (Oxford Diffraction, 2009); cell refinement: CrysAlis PRO (Oxford Diffraction, 2009); data reduction: CrysAlis PRO (Oxford Diffraction, 2009); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2012); software used to prepare material for publication: publCIF (Westrip, 2010).

Figures top
[Figure 1] Fig. 1. The title structure consisting of [CoCl2(dpmaH)4] cations which form hydrogen bonds to neighbouring [CoCl4]- anions is shown (ellipsoids are drawn at the 50% probability level, the asymmetric unit is labeled).
[Figure 2] Fig. 2. Wireframe sketch of the title structure showing the basic graph-sets (blue numbers: S22(6), red numbers: S11(7), green numbers: C34(10), black numbers: R66(22)).
[Figure 3] Fig. 3. Constructor-graphs of the title structure and of dpmaHCl are shown in the context of their real structures to illustrate the structural similarity.
trans-Dichloridotetrakis[(dimethylphosphoryl)methanaminium-κO]cobalt(II) bis[tetrachloridocobaltate(II)] top
Crystal data top
[CoCl2(C3H11NOP)4][CoCl4]2Z = 1
Mr = 963.68F(000) = 487
Triclinic, P1Dx = 1.732 Mg m−3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 7.7748 (3) ÅCell parameters from 13303 reflections
b = 11.1557 (5) Åθ = 2.9–32.6°
c = 12.1205 (5) ŵ = 2.25 mm−1
α = 110.738 (4)°T = 173 K
β = 97.688 (4)°Block, blue
γ = 104.331 (5)°0.76 × 0.33 × 0.08 mm
V = 923.66 (8) Å3
Data collection top
Oxford Xcalibur
diffractometer		4920 independent reflections
Graphite monochromator4552 reflections with I > 2σ(I)
Detector resolution: 16.2711 pixels mm-1Rint = 0.020
ω scansθmax = 29.0°, θmin = 2.9°
Absorption correction: analytical
[CrysAlis PRO (Oxford Diffraction, 2009), based on expressions derived by Clark & Reid (1995)]		h = −10→10
Tmin = 0.402, Tmax = 0.838k = −15→15
15687 measured reflectionsl = −16→16
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.018Hydrogen site location: difference Fourier map
wR(F2) = 0.042H atoms treated by a mixture of independent and constrained refinement
S = 1.09 w = 1/[σ2(Fo2) + (0.012P)2 + 0.5P],
where P = (Fo2 + 2Fc2)/3
4920 reflections(Δ/σ)max = 0.001
197 parametersΔρmax = 0.49 e Å−3
0 restraintsΔρmin = −0.38 e Å−3
Crystal data top
[CoCl2(C3H11NOP)4][CoCl4]2γ = 104.331 (5)°
Mr = 963.68V = 923.66 (8) Å3
Triclinic, P1Z = 1
a = 7.7748 (3) ÅMo Kα radiation
b = 11.1557 (5) ŵ = 2.25 mm−1
c = 12.1205 (5) ÅT = 173 K
α = 110.738 (4)°0.76 × 0.33 × 0.08 mm
β = 97.688 (4)°
Data collection top
Oxford Xcalibur
diffractometer		4920 independent reflections
Absorption correction: analytical
[CrysAlis PRO (Oxford Diffraction, 2009), based on expressions derived by Clark & Reid (1995)]		4552 reflections with I > 2σ(I)
Tmin = 0.402, Tmax = 0.838Rint = 0.020
15687 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0180 restraints
wR(F2) = 0.042H atoms treated by a mixture of independent and constrained refinement
S = 1.09Δρmax = 0.49 e Å−3
4920 reflectionsΔρmin = −0.38 e Å−3
197 parameters
Special details top

Experimental. CrysAlisPro, Oxford Diffraction Ltd., Version 1.171.34.44 Analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid. (Clark & Reid, 1995).

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Co10.00000.00000.50000.00707 (5)
Cl1−0.22848 (4)0.05961 (3)0.61151 (3)0.01037 (6)
P10.27356 (4)−0.01270 (3)0.73117 (3)0.00824 (6)
C110.48106 (18)0.09673 (14)0.84045 (13)0.0149 (3)
H11A0.57140.12380.79970.022*
H11B0.52410.05030.88580.022*
H11C0.45990.17530.89490.022*
C120.31916 (19)−0.15805 (14)0.63526 (13)0.0149 (3)
H12A0.2069−0.22290.58000.022*
H12B0.3725−0.19730.68410.022*
H12C0.4027−0.13230.58990.022*
C130.11865 (17)−0.06627 (14)0.81714 (12)0.0117 (2)
H13A0.1385−0.14370.82930.014*
H13B0.14170.00640.89630.014*
N1−0.07340 (15)−0.10285 (12)0.74832 (11)0.0112 (2)
H11−0.093 (2)−0.0313 (19)0.7437 (17)0.022 (5)*
H12−0.094 (3)−0.162 (2)0.6731 (19)0.026 (5)*
H13−0.149 (3)−0.1352 (19)0.7854 (18)0.024 (5)*
O10.18513 (12)0.05528 (9)0.66322 (8)0.00960 (17)
P20.25797 (4)0.32277 (3)0.61086 (3)0.00895 (6)
C210.2810 (2)0.47433 (13)0.58704 (13)0.0158 (3)
H21A0.30160.46030.50770.024*
H21B0.38270.54610.64770.024*
H21C0.17100.49810.59290.024*
C220.47331 (18)0.29394 (14)0.61459 (13)0.0152 (3)
H22A0.45930.20390.60920.023*
H22B0.55910.35810.68940.023*
H22C0.51770.30430.54720.023*
C230.22948 (18)0.36089 (13)0.76527 (12)0.0119 (2)
H23A0.26370.29670.79330.014*
H23B0.31220.45040.81830.014*
N20.03979 (16)0.35581 (12)0.77545 (11)0.0122 (2)
H210.003 (2)0.4202 (18)0.7562 (17)0.019 (4)*
H22−0.041 (2)0.2708 (19)0.7275 (17)0.018 (4)*
H230.035 (3)0.3711 (19)0.8492 (19)0.026 (5)*
O20.10036 (12)0.20618 (9)0.51575 (8)0.00961 (17)
Co20.17901 (2)0.34799 (2)0.10713 (2)0.01000 (4)
Cl210.08194 (5)0.41433 (3)0.28405 (3)0.01496 (7)
Cl220.27225 (5)0.53299 (3)0.06796 (3)0.01464 (7)
Cl230.38534 (4)0.24331 (3)0.14315 (3)0.01438 (7)
Cl24−0.04975 (4)0.19017 (3)−0.05026 (3)0.01361 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.00685 (11)0.00721 (11)0.00612 (11)0.00138 (8)0.00071 (9)0.00240 (9)
Cl10.00962 (13)0.01193 (13)0.00975 (14)0.00396 (11)0.00322 (11)0.00394 (11)
P10.00786 (14)0.00935 (14)0.00738 (15)0.00274 (11)0.00126 (11)0.00342 (12)
C110.0116 (6)0.0186 (7)0.0110 (6)0.0019 (5)−0.0005 (5)0.0053 (5)
C120.0174 (7)0.0158 (6)0.0134 (7)0.0098 (5)0.0037 (5)0.0050 (5)
C130.0104 (6)0.0144 (6)0.0115 (6)0.0030 (5)0.0023 (5)0.0073 (5)
N10.0106 (5)0.0111 (5)0.0128 (6)0.0026 (4)0.0036 (4)0.0060 (5)
O10.0100 (4)0.0099 (4)0.0087 (4)0.0029 (3)0.0014 (3)0.0040 (3)
P20.00928 (15)0.00761 (14)0.00711 (15)0.00123 (11)0.00126 (12)0.00099 (12)
C210.0194 (7)0.0099 (6)0.0156 (7)0.0016 (5)0.0030 (5)0.0048 (5)
C220.0098 (6)0.0157 (6)0.0147 (7)0.0026 (5)0.0017 (5)0.0015 (5)
C230.0132 (6)0.0131 (6)0.0086 (6)0.0059 (5)0.0020 (5)0.0027 (5)
N20.0149 (6)0.0124 (5)0.0101 (6)0.0047 (4)0.0046 (5)0.0045 (5)
O20.0094 (4)0.0082 (4)0.0087 (4)0.0008 (3)0.0005 (3)0.0024 (3)
Co20.01132 (8)0.00894 (8)0.00817 (8)0.00225 (6)0.00091 (7)0.00285 (7)
Cl210.02275 (16)0.01359 (14)0.01120 (15)0.00812 (12)0.00686 (12)0.00548 (12)
Cl220.01898 (16)0.01075 (14)0.01158 (15)0.00080 (12)0.00219 (12)0.00476 (12)
Cl230.01173 (14)0.01845 (15)0.01554 (16)0.00614 (12)0.00327 (12)0.00890 (13)
Cl240.01358 (14)0.01152 (14)0.01105 (15)0.00125 (11)−0.00131 (11)0.00264 (12)
Geometric parameters (Å, º) top
Co1—O1i2.0737 (9)N1—H130.87 (2)
Co1—O12.0737 (9)P2—O21.5144 (9)
Co1—O2i2.1671 (9)P2—C221.7791 (14)
Co1—O22.1671 (9)P2—C211.7843 (14)
Co1—Cl1i2.4525 (3)P2—C231.8238 (14)
Co1—Cl12.4526 (3)C21—H21A0.9600
P1—O11.5083 (9)C21—H21B0.9600
P1—C111.7763 (14)C21—H21C0.9600
P1—C121.7794 (14)C22—H22A0.9600
P1—C131.8204 (13)C22—H22B0.9600
C11—H11A0.9600C22—H22C0.9600
C11—H11B0.9600C23—N21.4852 (17)
C11—H11C0.9600C23—H23A0.9700
C12—H12A0.9600C23—H23B0.9700
C12—H12B0.9600N2—H210.924 (19)
C12—H12C0.9600N2—H220.920 (19)
C13—N11.4886 (17)N2—H230.86 (2)
C13—H13A0.9700Co2—Cl222.2485 (4)
C13—H13B0.9700Co2—Cl242.2507 (4)
N1—H110.867 (19)Co2—Cl232.2866 (4)
N1—H120.88 (2)Co2—Cl212.3024 (4)
O1i—Co1—O1180.00 (4)C13—N1—H13109.9 (13)
O1i—Co1—O2i88.92 (3)H11—N1—H13109.5 (17)
O1—Co1—O2i91.08 (3)H12—N1—H13109.9 (17)
O1i—Co1—O291.08 (3)P1—O1—Co1138.08 (6)
O1—Co1—O288.92 (3)O2—P2—C22113.83 (6)
O2i—Co1—O2180.0O2—P2—C21111.21 (6)
O1i—Co1—Cl1i89.89 (3)C22—P2—C21107.23 (7)
O1—Co1—Cl1i90.11 (3)O2—P2—C23112.87 (6)
O2i—Co1—Cl1i89.54 (3)C22—P2—C23104.79 (6)
O2—Co1—Cl1i90.46 (3)C21—P2—C23106.37 (6)
O1i—Co1—Cl190.11 (3)P2—C21—H21A109.5
O1—Co1—Cl189.88 (3)P2—C21—H21B109.5
O2i—Co1—Cl190.46 (3)H21A—C21—H21B109.5
O2—Co1—Cl189.54 (3)P2—C21—H21C109.5
Cl1i—Co1—Cl1180.0H21A—C21—H21C109.5
O1—P1—C11113.52 (6)H21B—C21—H21C109.5
O1—P1—C12113.89 (6)P2—C22—H22A109.5
C11—P1—C12107.60 (7)P2—C22—H22B109.5
O1—P1—C13108.03 (6)H22A—C22—H22B109.5
C11—P1—C13105.63 (6)P2—C22—H22C109.5
C12—P1—C13107.70 (7)H22A—C22—H22C109.5
P1—C11—H11A109.5H22B—C22—H22C109.5
P1—C11—H11B109.5N2—C23—P2113.44 (9)
H11A—C11—H11B109.5N2—C23—H23A108.9
P1—C11—H11C109.5P2—C23—H23A108.9
H11A—C11—H11C109.5N2—C23—H23B108.9
H11B—C11—H11C109.5P2—C23—H23B108.9
P1—C12—H12A109.5H23A—C23—H23B107.7
P1—C12—H12B109.5C23—N2—H21112.8 (11)
H12A—C12—H12B109.5C23—N2—H22110.3 (11)
P1—C12—H12C109.5H21—N2—H22110.3 (16)
H12A—C12—H12C109.5C23—N2—H23108.5 (13)
H12B—C12—H12C109.5H21—N2—H23107.4 (17)
N1—C13—P1108.91 (9)H22—N2—H23107.3 (17)
N1—C13—H13A109.9P2—O2—Co1128.45 (5)
P1—C13—H13A109.9Cl22—Co2—Cl24108.699 (15)
N1—C13—H13B109.9Cl22—Co2—Cl23119.352 (15)
P1—C13—H13B109.9Cl24—Co2—Cl23106.345 (14)
H13A—C13—H13B108.3Cl22—Co2—Cl21106.654 (14)
C13—N1—H11109.2 (12)Cl24—Co2—Cl21111.513 (15)
C13—N1—H12111.8 (12)Cl23—Co2—Cl21104.233 (14)
H11—N1—H12106.4 (17)
O1—P1—C13—N132.47 (10)O2—P2—C23—N2−41.65 (11)
C11—P1—C13—N1154.27 (9)C22—P2—C23—N2−166.05 (9)
C12—P1—C13—N1−90.96 (10)C21—P2—C23—N280.57 (10)
C11—P1—O1—Co1158.09 (8)C22—P2—O2—Co160.81 (9)
C12—P1—O1—Co134.48 (10)C21—P2—O2—Co1−177.94 (7)
C13—P1—O1—Co1−85.12 (9)C23—P2—O2—Co1−58.48 (8)
Symmetry code: (i) −x, −y, −z+1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H11···Cl10.867 (19)2.437 (19)3.1879 (12)145.3 (16)
N1—H11···Cl24ii0.867 (19)2.730 (19)3.2573 (13)120.5 (15)
N1—H12···O2i0.88 (2)2.16 (2)2.9504 (16)150.3 (17)
N1—H13···Cl23i0.87 (2)2.38 (2)3.2403 (12)171.3 (17)
N2—H22···Cl10.920 (19)2.250 (19)3.1697 (13)177.8 (15)
N2—H21···Cl21iii0.924 (19)2.288 (19)3.2124 (12)177.8 (16)
N2—H23···Cl22ii0.86 (2)2.71 (2)3.3612 (13)134.0 (16)
N2—H23···Cl24ii0.86 (2)2.70 (2)3.2989 (12)128.1 (16)
Symmetry codes: (i) −x, −y, −z+1; (ii) x, y, z+1; (iii) −x, −y+1, −z+1.

Experimental details

Crystal data
Chemical formula[CoCl2(C3H11NOP)4][CoCl4]2
Mr963.68
Crystal system, space groupTriclinic, P1
Temperature (K)173
a, b, c (Å)7.7748 (3), 11.1557 (5), 12.1205 (5)
α, β, γ (°)110.738 (4), 97.688 (4), 104.331 (5)
V (Å3)923.66 (8)
Z1
Radiation typeMo Kα
µ (mm−1)2.25
Crystal size (mm)0.76 × 0.33 × 0.08
Data collection
DiffractometerOxford Xcalibur
Absorption correctionAnalytical
[CrysAlis PRO (Oxford Diffraction, 2009), based on expressions derived by Clark & Reid (1995)]
Tmin, Tmax0.402, 0.838
No. of measured, independent and
observed [I > 2σ(I)] reflections		15687, 4920, 4552
Rint0.020
(sin θ/λ)max (Å−1)0.682
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.018, 0.042, 1.09
No. of reflections4920
No. of parameters197
H-atom treatmentH atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å−3)0.49, −0.38

Computer programs: CrysAlis PRO (Oxford Diffraction, 2009), SHELXS97 (Sheldrick, 2008), SHELXL2013 (Sheldrick, 2008), DIAMOND (Brandenburg, 2012), publCIF (Westrip, 2010).

Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H11···Cl10.867 (19)2.437 (19)3.1879 (12)145.3 (16)
N1—H11···Cl24i0.867 (19)2.730 (19)3.2573 (13)120.5 (15)
N1—H12···O2ii0.88 (2)2.16 (2)2.9504 (16)150.3 (17)
N1—H13···Cl23ii0.87 (2)2.38 (2)3.2403 (12)171.3 (17)
N2—H22···Cl10.920 (19)2.250 (19)3.1697 (13)177.8 (15)
N2—H21···Cl21iii0.924 (19)2.288 (19)3.2124 (12)177.8 (16)
N2—H23···Cl22i0.86 (2)2.71 (2)3.3612 (13)134.0 (16)
N2—H23···Cl24i0.86 (2)2.70 (2)3.2989 (12)128.1 (16)
Symmetry codes: (i) x, y, z+1; (ii) −x, −y, −z+1; (iii) −x, −y+1, −z+1.
 

Acknowledgements

Technical support by E. Hammes is gratefully acknowledged. Furthermore, I acknowledge support for the publication fee by the Deutsche Forschungsgemeinschaft (DFG) and the open access publication fund of the Heinrich-Heine-Universität Düsseldorf.

References

First citationBernstein, J., Davis, R. E., Shimoni, L. & Chang, N.-L. (1995). Angew. Chem. Int. Ed. 34, 1555–1573.  CrossRef CAS Web of Science Google Scholar
 First citationBorisov, G., Varbanov, S. G., Venanzi, L. M., Albinati, A. & Demartin, F. (1994). Inorg. Chem. 33, 5430–5437.  CSD CrossRef CAS Web of Science Google Scholar
 First citationBrandenburg, K. (2012). DIAMOND. Crystal Impact GbR, Bonn, Germany.  Google Scholar
 First citationBrunet, P., Simard, M. & Wuest, J. D. (1997). J. Am. Chem. Soc. 119, 2737–2738.  CSD CrossRef CAS Web of Science Google Scholar
 First citationClark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887–897.  CrossRef CAS Web of Science IUCr Journals Google Scholar
 First citationDodoff, N., Macicek, J., Angelova, O., Varbanov, S. G. & Spassovska, N. (1990). J. Coord. Chem. 22, 219–228.  CrossRef CAS Google Scholar
 First citationEtter, M. C., MacDonald, J. C. & Bernstein, J. (1990). Acta Cryst. B46, 256–262.  CrossRef CAS Web of Science IUCr Journals Google Scholar
 First citationGirma, K. B., Lorenz, V., Blaurock, S. & Edelmann, F. T. (2005). Z. Anorg. Allg. Chem. 631, 1419–1422.  Web of Science CSD CrossRef CAS Google Scholar
 First citationGrell, J., Bernstein, J. & Tinhofer, G. (2002). Crystallogr. Rev. 8, 1–56.  CrossRef CAS Google Scholar
 First citationGuzei, I. A., Spencer, L. C., Ainooson, M. K. & Darkwa, J. (2010). Acta Cryst. C66, m89–m96.  Web of Science CSD CrossRef CAS IUCr Journals Google Scholar
 First citationKochel, A. (2009). Inorg. Chim. Acta, 362, 1379–1382.  Web of Science CSD CrossRef CAS Google Scholar
 First citationKubíčk, V., Vojtíšk, P., Rudovský, J., Hermann, P. & Lukeš, I. (2003). Dalton Trans. pp. 3927–3938.  Google Scholar
 First citationMeyer, M. K., Graf, J. & Reiss, G. J. (2010). Z. Naturforsch. Teil B, 65, 1462–1466.  CAS Google Scholar
 First citationMegen, M. van, Prömper, S. & Reiss, G. J. (2013). Acta Cryst. E69, m217.  CSD CrossRef IUCr Journals Google Scholar
 First citationOxford Diffraction (2009). CrysAlis PRO. Oxford Diffraction Ltd, Yarnton, England.  Google Scholar
 First citationReiss, G. J. & Engel, J. S. (2008). Acta Cryst. E64, o400.  Web of Science CSD CrossRef IUCr Journals Google Scholar
 First citationReiss, G. J. & Jörgens, S. (2012). Acta Cryst. E68, o2899–o2900.  CSD CrossRef CAS IUCr Journals Google Scholar
 First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
 First citationTrendafilova, N., Georgieva, I., Bauer, G., Varbanov, S. G. & Dodoff, N. (1997). Spectrochim. Acta, A53, 819–828.  CrossRef Google Scholar
 First citationWestrip, S. P. (2010). J. Appl. Cryst. 43, 920–925.  Web of Science CrossRef CAS IUCr Journals Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 69| Part 5| May 2013| Pages m248-m249
https://doi.org/10.1107/S1600536813008945
Follow Acta Cryst. E
Sign up for e-alerts
E-alerts
Follow Acta Cryst. on Twitter
Twitter
Follow us on facebook
Facebook
Sign up for RSS feeds
RSS