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Figure 1 Single-crystal X-ray structure of Mn(II)(OAc)2[15-MCMn(III)N(shi)-5](Me—Im)4.62(DMF)1.38.diethyl ether·DMF·MeOH·0.49H2O (1). The thermal ellipsoid plot of 1 is at a 50% probability level. For Mn4 only the 1-methylimidazole is shown bound to the MnIII, since 1-methylimidazole possess a higher occupancy ratio compared to the coordinated DMF (0.62 (2):0.38 (2)). Hydrogen atoms and the lattice solvent molecules have been omitted for clarity. Color scheme for all figures: green - MnII and MnIII, red - oxygen, blue - nitrogen, and gray - carbon. |