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Figure 4 First coordination sphere about each MnIII ion of 1. a) Mn2 with distorted square pyramidal geometry b) Mn3 with Λ configuration c) Mn4 with planar configuration and 1-methyl­imidazole bound (0.62 (2) occupancy) d) Mn4 with planar configuration and DMF bound (0.38 (2) occupancy) e) Mn5 with planar configuration and f) Mn6 with Λ configuration. The thermal ellipsoid plots are at a 50% probability level. Hydrogen atoms have been omitted for clarity.

ISSN: 2056-9890
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