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Figure 5 First coordination sphere about the MnIII ions Mn5 and Mn6 of 1. a) Mn5 with planar configuration and 1-methylimidazole bound (0.68 (1) occupancy) b) Mn5 with planar configuration and DMF bound (0.32 (1) occupancy) and c) Mn6 with Λ configuration. The thermal ellipsoid plots are at a 50% probability level. Hydrogen atoms have been omitted for clarity. |