Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­idene)hydrazine]bis­[(nitrato-κO)silver(I)] aceto­nitrile disolvate

Guo, Y.; Cai, H.

doi:10.1107/S1600536813024021

metal-organic compounds

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ISSN: 2056-9890

Volume 69| Part 10| October 2013| Page m525

doi:10.1107/S1600536813024021

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Bis[μ-1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine]bis[(nitrato-κO)silver(I)] acetonitrile disolvate

Ying Guo ^a and Hua Cai ^a ^*

^aCollege of Science, Civil Aviation University of China, Tianjin 300300, People's Republic of China
^*Correspondence e-mail: caihua-1109@163.com

(Received 20 August 2013; accepted 27 August 2013; online 4 September 2013)

In the centrosymmetric binuclear title complex, [Ag₂(NO₃)₂(C₁₁H₈Cl₂N₄)₂]·2CH₃CN, the Ag^I atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine ligands and one O atom from a nitrate anion. Intermolecular N—H⋯O hydrogen bonds link the complex molecules, resulting in a two-dimensional supramolecular structure parallel to (001).

Related literature

For background to compounds with metal–organic framework structures, see: Barnett & Champness (2003 ); Roesky & Andruh (2003 ); Zaworotko (2000 ).

Experimental

Crystal data

[Ag₂(NO₃)₂(C₁₁H₈Cl₂N₄)₂]·2C₂H₃N
M_r = 956.10
Orthorhombic, P b c a
a = 15.3862 (19) Å
b = 8.2397 (10) Å
c = 27.198 (4) Å
V = 3448.1 (8) Å³
Z = 4
Mo Kα radiation
μ = 1.51 mm⁻¹
T = 296 K
0.32 × 0.28 × 0.22 mm

Data collection

Bruker APEXII CCD diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ) T_min = 0.645, T_max = 0.733
16325 measured reflections
3041 independent reflections
2498 reflections with I > 2σ(I)
R_int = 0.029

Refinement

R[F² > 2σ(F²)] = 0.039
wR(F²) = 0.113
S = 1.08
3041 reflections
227 parameters
H-atom parameters constrained
Δρ_max = 0.66 e Å⁻³
Δρ_min = −0.50 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N2—H2⋯O3ⁱ	0.86	2.09	2.909 (5)	158
Symmetry code: (i) $[x+{\script{1\over 2}}, -y+{\script{3\over 2}}, -z+1]$ .

Data collection: APEX2 (Bruker, 2007 ); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: XP in SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg & Berndt, 1999 ); software used to prepare material for publication: SHELXTL.

Supporting information

Crystal structure: contains datablocks lxl, I. DOI: 10.1107/S1600536813024021/hy2636sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536813024021/hy2636Isup2.hkl

checkCIF report

Comment top

Neutral organic ligands containing rigid or flexible spacers, such as 4,4'-bipyridine, 1,2-bis(4-pyridyl)ethane, 1,2-bis(4-pyridyl)propane and many others, have been used to generate a rich variety of metal-organic architectures with different metal ions by various reaction procedure (Barnett & Champness, 2003; Roesky & Andruh, 2003; Zaworotko, 2000). In our recent research, we have initiated a synthetic approach employing 1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine (L) upon reaction with differnent metal ions to construct new functional frameworks. To explore this series, we synthesized the title compound, a new Ag(I) complex based on the L ligand.

In the title complex (Fig. 1), the Ag^I atom is four-coordinated and exhibits a highly distorted tetrahedral geometry defined by three N atoms from two L ligands and one O from a nitrate anion. The L ligands bridge two Ag^I atoms, resulting in a centrosymmetric binuclear unit. The 2-pyridyl and 3-pyridyl rings in the ligand are not coplanar, with a dihedral angle of 25.74 (16)°. Intermolecular N—H···O hydrogen bonds (Table 1) extend the binuclear units into a two-dimensional supramolecular structure parallel to (001), as shown in Fig. 2.

Related literature top

For background to metal-organic architectures, see: Barnett & Champness (2003); Roesky & Andruh (2003); Zaworotko (2000).

Experimental top

AgNO₃ (17.0 mg, 0.1 mmol) and 1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethyl)diazene (22.2 mg, 0.1 mmol) were mixed in a CH₃CN/H₂O (20 ml, 1:1 v/v) solution with vigorous stirring for ca 30 min. The resulting solution was filtered and left to stand at room temperature. Colorless block crystals of the title compound suitable for X-ray analysis were obtained in 85% yield by slow evaporation of the solvent over a period of 1 week. Analysis, calculated for C₂₆H₂₂Ag₂Cl₄N₁₂O₆: C 50.42, H 5.14, N 8.40%; found: C 50.45, H 5.03, N 8.32%.

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: XP in SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg & Berndt, 1999); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

	Fig. 1. The molecular structure of the title compound. Displacement ellipsoids are shown at the 30% probability level. [Symmetry code: (A) 1-x, 2-y, 1-z.]
	Fig. 2. The two-dimensional supramolecular structure of the title compound, showing N—H···O hydrogen bonds as red dashed lines.

Bis[µ-1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine]bis[(nitrato-κO)silver(I)] acetonitrile disolvate top

Crystal data top

[Ag₂(NO₃)₂(C₁₁H₈Cl₂N₄)₂]·2C₂H₃N	F(000) = 1888
M_r = 956.10	D_x = 1.842 Mg m⁻³
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 6506 reflections
a = 15.3862 (19) Å	θ = 2.7–29.1°
b = 8.2397 (10) Å	µ = 1.51 mm⁻¹
c = 27.198 (4) Å	T = 296 K
V = 3448.1 (8) Å³	Block, colorless
Z = 4	0.32 × 0.28 × 0.22 mm

Data collection top

Bruker APEXII CCD diffractometer	3041 independent reflections
Radiation source: fine-focus sealed tube	2498 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.029
ϕ and ω scans	θ_max = 25.0°, θ_min = 1.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −15→18
T_min = 0.645, T_max = 0.733	k = −6→9
16325 measured reflections	l = −32→26

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.039	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.113	H-atom parameters constrained
S = 1.08	w = 1/[σ²(F_o²) + (0.038P)² + 14.4907P] where P = (F_o² + 2F_c²)/3
3041 reflections	(Δ/σ)_max = 0.001
227 parameters	Δρ_max = 0.66 e Å⁻³
0 restraints	Δρ_min = −0.50 e Å⁻³

Crystal data top

[Ag₂(NO₃)₂(C₁₁H₈Cl₂N₄)₂]·2C₂H₃N	V = 3448.1 (8) Å³
M_r = 956.10	Z = 4
Orthorhombic, Pbca	Mo Kα radiation
a = 15.3862 (19) Å	µ = 1.51 mm⁻¹
b = 8.2397 (10) Å	T = 296 K
c = 27.198 (4) Å	0.32 × 0.28 × 0.22 mm

Data collection top

Bruker APEXII CCD diffractometer	3041 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	2498 reflections with I > 2σ(I)
T_min = 0.645, T_max = 0.733	R_int = 0.029
16325 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.039	0 restraints
wR(F²) = 0.113	H-atom parameters constrained
S = 1.08	w = 1/[σ²(F_o²) + (0.038P)² + 14.4907P] where P = (F_o² + 2F_c²)/3
3041 reflections	Δρ_max = 0.66 e Å⁻³
227 parameters	Δρ_min = −0.50 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Ag1	0.56792 (2)	0.75776 (5)	0.548365 (16)	0.04728 (16)
Cl1	0.91981 (8)	0.6283 (2)	0.62236 (6)	0.0593 (4)
Cl2	0.65242 (12)	0.4004 (2)	0.73037 (5)	0.0635 (4)
O1	0.5766 (3)	0.6995 (6)	0.45874 (17)	0.0733 (14)
O2	0.5395 (3)	0.5169 (6)	0.40845 (17)	0.0692 (12)
O3	0.4486 (2)	0.5938 (6)	0.46331 (16)	0.0665 (13)
N1	0.6643 (3)	0.6706 (5)	0.60951 (15)	0.0399 (10)
N2	0.7784 (2)	0.7820 (5)	0.56417 (15)	0.0362 (9)
H2	0.8333	0.7953	0.5598	0.043*
N3	0.7204 (2)	0.8532 (5)	0.53260 (14)	0.0342 (9)
N4	0.5645 (2)	1.1349 (5)	0.43586 (15)	0.0384 (9)
N5	0.5217 (3)	0.6047 (5)	0.44344 (16)	0.0419 (10)
N6	0.1005 (11)	0.4204 (14)	0.2093 (4)	0.186 (6)
C1	0.6359 (3)	0.5835 (6)	0.6484 (2)	0.0445 (12)
H1	0.5764	0.5707	0.6530	0.053*
C2	0.6916 (4)	0.5135 (7)	0.68122 (19)	0.0444 (12)
C3	0.7808 (4)	0.5264 (6)	0.67384 (19)	0.0445 (12)
H3	0.8198	0.4768	0.6952	0.053*
C4	0.8098 (3)	0.6139 (6)	0.63428 (19)	0.0394 (11)
C5	0.7495 (3)	0.6900 (6)	0.60256 (17)	0.0341 (10)
C6	0.7533 (3)	0.9297 (6)	0.49620 (17)	0.0352 (10)
H6	0.8134	0.9331	0.4929	0.042*
C7	0.6992 (3)	1.0122 (6)	0.45957 (17)	0.0332 (10)
C8	0.7328 (3)	1.0400 (7)	0.41291 (19)	0.0455 (13)
H8	0.7896	1.0107	0.4053	0.055*
C9	0.6801 (4)	1.1120 (8)	0.3781 (2)	0.0531 (14)
H9	0.7006	1.1303	0.3464	0.064*
C10	0.5973 (3)	1.1562 (7)	0.3907 (2)	0.0478 (13)
H10	0.5622	1.2032	0.3668	0.057*
C11	0.6150 (3)	1.0632 (6)	0.46957 (18)	0.0344 (10)
H11	0.5928	1.0468	0.5010	0.041*
C12	0.1048 (8)	0.5540 (14)	0.2028 (3)	0.107 (3)
C13	0.1061 (8)	0.7257 (12)	0.1945 (5)	0.134 (4)
H13A	0.1004	0.7470	0.1599	0.201*
H13B	0.1600	0.7698	0.2061	0.201*
H13C	0.0586	0.7755	0.2117	0.201*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.0295 (2)	0.0536 (3)	0.0587 (3)	0.00328 (18)	−0.00426 (17)	0.0089 (2)
Cl1	0.0305 (6)	0.0752 (10)	0.0723 (10)	0.0088 (7)	−0.0074 (6)	0.0185 (8)
Cl2	0.0796 (11)	0.0639 (10)	0.0469 (8)	−0.0064 (8)	0.0057 (7)	0.0126 (7)
O1	0.072 (3)	0.073 (3)	0.075 (3)	−0.039 (3)	0.007 (2)	−0.017 (2)
O2	0.057 (3)	0.073 (3)	0.078 (3)	−0.001 (2)	0.003 (2)	−0.024 (3)
O3	0.034 (2)	0.095 (4)	0.070 (3)	0.008 (2)	0.0116 (19)	0.024 (3)
N1	0.032 (2)	0.042 (2)	0.045 (2)	−0.0037 (18)	−0.0038 (18)	0.006 (2)
N2	0.0230 (19)	0.038 (2)	0.047 (2)	0.0018 (16)	−0.0047 (17)	0.0053 (18)
N3	0.029 (2)	0.033 (2)	0.040 (2)	0.0026 (17)	−0.0061 (17)	0.0009 (18)
N4	0.030 (2)	0.042 (2)	0.042 (2)	0.0005 (18)	−0.0047 (17)	0.0069 (19)
N5	0.035 (2)	0.042 (2)	0.049 (3)	0.001 (2)	−0.0004 (19)	0.006 (2)
N6	0.354 (18)	0.105 (7)	0.099 (7)	0.039 (10)	−0.090 (9)	−0.002 (6)
C1	0.035 (3)	0.045 (3)	0.054 (3)	−0.004 (2)	0.003 (2)	0.005 (3)
C2	0.055 (3)	0.041 (3)	0.037 (3)	−0.003 (3)	0.002 (2)	0.003 (2)
C3	0.050 (3)	0.041 (3)	0.042 (3)	0.006 (2)	−0.011 (2)	0.004 (2)
C4	0.029 (2)	0.041 (3)	0.048 (3)	0.002 (2)	−0.006 (2)	−0.002 (2)
C5	0.035 (2)	0.029 (2)	0.038 (2)	0.002 (2)	−0.007 (2)	−0.002 (2)
C6	0.023 (2)	0.037 (3)	0.045 (3)	0.0032 (19)	−0.003 (2)	0.000 (2)
C7	0.028 (2)	0.029 (2)	0.042 (3)	−0.0029 (19)	−0.0025 (19)	0.003 (2)
C8	0.026 (3)	0.056 (3)	0.054 (3)	0.005 (2)	0.005 (2)	0.006 (3)
C9	0.051 (3)	0.070 (4)	0.039 (3)	0.008 (3)	0.007 (2)	0.012 (3)
C10	0.041 (3)	0.056 (3)	0.046 (3)	0.003 (3)	−0.009 (2)	0.010 (3)
C11	0.026 (2)	0.035 (3)	0.041 (3)	0.0004 (19)	0.000 (2)	0.002 (2)
C12	0.134 (9)	0.095 (7)	0.091 (6)	0.016 (7)	−0.054 (6)	−0.013 (6)
C13	0.123 (9)	0.090 (8)	0.189 (12)	0.015 (6)	−0.057 (8)	−0.022 (7)

Geometric parameters (Å, º) top

Ag1—N4ⁱ	2.262 (4)	C1—H1	0.9300
Ag1—N1	2.341 (4)	C2—C3	1.391 (8)
Ag1—O1	2.488 (5)	C3—C4	1.370 (7)
Ag1—N3	2.511 (4)	C3—H3	0.9300
Cl1—C4	1.727 (5)	C4—C5	1.415 (7)
Cl2—C2	1.738 (5)	C6—C7	1.465 (6)
O1—N5	1.224 (6)	C6—H6	0.9300
O2—N5	1.227 (6)	C7—C8	1.389 (7)
O3—N5	1.251 (6)	C7—C11	1.389 (6)
N1—C5	1.334 (6)	C8—C9	1.381 (7)
N1—C1	1.352 (6)	C8—H8	0.9300
N2—C5	1.365 (6)	C9—C10	1.368 (8)
N2—N3	1.370 (5)	C9—H9	0.9300
N2—H2	0.8600	C10—H10	0.9300
N3—C6	1.278 (6)	C11—H11	0.9300
N4—C10	1.339 (7)	C12—C13	1.433 (14)
N4—C11	1.339 (6)	C13—H13A	0.9600
N4—Ag1ⁱ	2.262 (4)	C13—H13B	0.9600
N6—C12	1.117 (13)	C13—H13C	0.9600
C1—C2	1.365 (7)

N4ⁱ—Ag1—N1	123.76 (15)	C3—C4—C5	119.9 (5)
N4ⁱ—Ag1—O1	108.04 (16)	C3—C4—Cl1	120.2 (4)
N1—Ag1—O1	127.07 (17)	C5—C4—Cl1	119.9 (4)
N4ⁱ—Ag1—N3	138.70 (14)	N1—C5—N2	119.7 (4)
N1—Ag1—N3	68.01 (13)	N1—C5—C4	120.4 (4)
O1—Ag1—N3	80.96 (13)	N2—C5—C4	119.9 (4)
N5—O1—Ag1	114.8 (3)	N3—C6—C7	122.1 (4)
C5—N1—C1	119.5 (4)	N3—C6—H6	118.9
C5—N1—Ag1	119.0 (3)	C7—C6—H6	118.9
C1—N1—Ag1	120.9 (3)	C8—C7—C11	118.4 (4)
C5—N2—N3	120.3 (4)	C8—C7—C6	119.1 (4)
C5—N2—H2	119.8	C11—C7—C6	122.4 (4)
N3—N2—H2	119.8	C9—C8—C7	118.6 (5)
C6—N3—N2	116.1 (4)	C9—C8—H8	120.7
C6—N3—Ag1	131.0 (3)	C7—C8—H8	120.7
N2—N3—Ag1	111.5 (3)	C10—C9—C8	119.3 (5)
C10—N4—C11	117.8 (4)	C10—C9—H9	120.4
C10—N4—Ag1ⁱ	117.5 (3)	C8—C9—H9	120.4
C11—N4—Ag1ⁱ	124.4 (3)	N4—C10—C9	123.1 (5)
O1—N5—O2	119.1 (5)	N4—C10—H10	118.4
O1—N5—O3	121.3 (5)	C9—C10—H10	118.4
O2—N5—O3	119.6 (5)	N4—C11—C7	122.7 (5)
N1—C1—C2	122.2 (5)	N4—C11—H11	118.6
N1—C1—H1	118.9	C7—C11—H11	118.6
C2—C1—H1	118.9	N6—C12—C13	177.4 (16)
C1—C2—C3	119.6 (5)	C12—C13—H13A	109.5
C1—C2—Cl2	120.7 (4)	C12—C13—H13B	109.5
C3—C2—Cl2	119.6 (4)	H13A—C13—H13B	109.5
C4—C3—C2	118.4 (5)	C12—C13—H13C	109.5
C4—C3—H3	120.8	H13A—C13—H13C	109.5
C2—C3—H3	120.8	H13B—C13—H13C	109.5

N4ⁱ—Ag1—O1—N5	−59.5 (5)	C2—C3—C4—Cl1	−178.0 (4)
N1—Ag1—O1—N5	108.6 (4)	C1—N1—C5—N2	−178.0 (4)
N3—Ag1—O1—N5	162.0 (4)	Ag1—N1—C5—N2	10.3 (6)
N4ⁱ—Ag1—N1—C5	−145.0 (3)	C1—N1—C5—C4	2.9 (7)
O1—Ag1—N1—C5	48.7 (4)	Ag1—N1—C5—C4	−168.8 (3)
N3—Ag1—N1—C5	−10.2 (3)	N3—N2—C5—N1	−0.5 (7)
N4ⁱ—Ag1—N1—C1	43.4 (4)	N3—N2—C5—C4	178.5 (4)
O1—Ag1—N1—C1	−122.9 (4)	C3—C4—C5—N1	−3.3 (7)
N3—Ag1—N1—C1	178.2 (4)	Cl1—C4—C5—N1	175.5 (4)
C5—N2—N3—C6	−176.3 (4)	C3—C4—C5—N2	177.6 (5)
C5—N2—N3—Ag1	−8.3 (5)	Cl1—C4—C5—N2	−3.6 (7)
N4ⁱ—Ag1—N3—C6	−68.5 (5)	N2—N3—C6—C7	−179.8 (4)
N1—Ag1—N3—C6	174.9 (5)	Ag1—N3—C6—C7	15.0 (7)
O1—Ag1—N3—C6	38.6 (4)	N3—C6—C7—C8	−156.3 (5)
N4ⁱ—Ag1—N3—N2	125.8 (3)	N3—C6—C7—C11	23.3 (7)
N1—Ag1—N3—N2	9.2 (3)	C11—C7—C8—C9	−2.1 (8)
O1—Ag1—N3—N2	−127.1 (3)	C6—C7—C8—C9	177.4 (5)
Ag1—O1—N5—O2	−149.3 (4)	C7—C8—C9—C10	1.1 (9)
Ag1—O1—N5—O3	29.4 (7)	C11—N4—C10—C9	−1.7 (8)
C5—N1—C1—C2	−0.1 (8)	Ag1ⁱ—N4—C10—C9	173.1 (5)
Ag1—N1—C1—C2	171.5 (4)	C8—C9—C10—N4	0.9 (10)
N1—C1—C2—C3	−2.4 (8)	C10—N4—C11—C7	0.6 (7)
N1—C1—C2—Cl2	−179.2 (4)	Ag1ⁱ—N4—C11—C7	−173.8 (3)
C1—C2—C3—C4	2.0 (8)	C8—C7—C11—N4	1.3 (7)
Cl2—C2—C3—C4	178.8 (4)	C6—C7—C11—N4	−178.2 (4)
C2—C3—C4—C5	0.8 (8)

Symmetry code: (i) −x+1, −y+2, −z+1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2···O3ⁱⁱ	0.86	2.09	2.909 (5)	158

Symmetry code: (ii) x+1/2, −y+3/2, −z+1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2···O3ⁱ	0.86	2.09	2.909 (5)	158

Symmetry code: (i) x+1/2, −y+3/2, −z+1.

References

Barnett, S. A. & Champness, N. R. (2003). Coord. Chem. Rev. 246, 145–168. Web of Science CrossRef CAS Google Scholar
Brandenburg, K. & Berndt, M. (1999). DIAMOND. Crystal Impact GbR, Bonn, Germany. Google Scholar
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Roesky, H. W. & Andruh, M. (2003). Coord. Chem. Rev. 236, 91–119. Web of Science CrossRef CAS Google Scholar
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany. Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Zaworotko, M. J. (2000). Chem. Commun. pp. 1–9. Google Scholar

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Volume 69| Part 10| October 2013| Page m525

doi:10.1107/S1600536813024021

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metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Bis[μ-1-(3,5-di­chloro­pyridin-2-yl)-2-(pyridin-3-yl­methyl­­idene)hydrazine]bis­­[(nitrato-κO)silver(I)] aceto­nitrile disolvate

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

References

metal-organic compounds

Bis[μ-1-(3,5-dichloropyridin-2-yl)-2-(pyridin-3-ylmethylidene)hydrazine]bis[(nitrato-κO)silver(I)] acetonitrile disolvate