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Figure 3 A space filling model of both the D– and L– valine iridium complexes packed from −0.5 → 1.0 along a, −0.5 → 1.0 along b, and −0.5→ 1.0 along c. The L–valine structure (left) shows a void while the D–valine structure (right) shows the dichloromethane in the lattice (68% occupancy). Spheres are shown at full van der Waals radii. |