Bis(μ-nitrato-κ2O:O)bis­{[1,2-bis­(diiso­propyl­phosphan­yl)-1,2-dicarba-closo-dodeca­borane-κ2P,P′]silver(I)} di­chloro­methane disolvate

Yang, L.

doi:10.1107/S1600536814006084

metal-organic compounds

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ISSN: 2056-9890

Volume 70| Part 4| April 2014| Page m141

doi:10.1107/S1600536814006084

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Bis(μ-nitrato-κ²O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ²P,P′]silver(I)} dichloromethane disolvate

Liguo Yang ^a ^*

^aDepartment of Chemistry, University of Science and Technology Beijing, Beijing 100083, People's Republic of China
^*Correspondence e-mail: yangliguo116@163.com

(Received 16 March 2014; accepted 19 March 2014; online 22 March 2014)

The title compound, [Ag₂(NO₃)₂(C₁₄H₃₈B₁₀P₂)₂]·2CH₂Cl₂, was synthesized by the reaction of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane with AgNO₃. The resulting dinuclear molecule has crystallographically imposed inversion symmetry. The diisopropylphosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag^I atom through the two P atoms. The distorted tetrahedral coordination of the metal is completed by two O atoms of two bridging nitrate anions. The separation between the two Ag^I atoms is 3.8913 (5) Å. C—H⋯O hydrogen bonds are observed involving the dichloromethane solvent molecule and the nitrate anion.

CCDC reference: 992556

Related literature

For related structures, see: Zhang et al. (2006 ); Paavola et al. (2002 , 2002a ,b ). For the synthesis and structure of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane, see: Kivekäs et al. (1995 ).

Experimental

Crystal data

[Ag₂(NO₃)₂(C₁₄H₃₈B₁₀P₂)₂]·2CH₂Cl₂
M_r = 1262.58
Monoclinic, P 2₁ /n
a = 13.9256 (15) Å
b = 10.3003 (10) Å
c = 21.8075 (19) Å
β = 107.734 (2)°
V = 2979.4 (5) Å³
Z = 2
Mo Kα radiation
μ = 0.98 mm⁻¹
T = 298 K
0.43 × 0.36 × 0.31 mm

Data collection

Bruker SMART1000 CCD diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ) T_min = 0.677, T_max = 0.751
14624 measured reflections
5264 independent reflections
3849 reflections with I > 2σ(I)
R_int = 0.027

Refinement

R[F² > 2σ(F²)] = 0.034
wR(F²) = 0.091
S = 1.05
5264 reflections
315 parameters
6 restraints
H-atom parameters constrained
Δρ_max = 0.37 e Å⁻³
Δρ_min = −0.41 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C15—H15A⋯O3ⁱ	0.97	2.48	3.203 (6)	132
C15—H15A⋯O1ⁱ	0.97	2.48	3.389 (8)	155
Symmetry code: (i) -x+1, -y, -z.

Data collection: SMART (Siemens, 1996 ); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supporting information

CCDC reference: 992556

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536814006084/rz5111sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536814006084/rz5111Isup2.hkl

checkCIF report

Comment top

The synthesis and structure of 1,2-(PⁱPr₂)₂-1,2-C₂B₁₀H₁₀ was reported by Kivekäs et al. (1995). Since then, only a few complexes of this ligand with Pt(II) and Pd(II) have been described (Paavola, Kivekäs et al., 2002; Paavola et al., 2002a,b). Here we report the structure of this ligand combined with Ag and nitrate anions.

As shown in Fig. 1, the coordination of the Ag atom is distorted tetrahedral, formed by two O atom from two NO₃ anions and the P atoms of the diisopropylphosphanyl-closo-carborane ligand. The two P—Ag bond lengths are slightly shorter than the corresponding bond lengths in the complex [Ag₂Cl₂(C₂₆H₃₀B₁₀P₂)₂].2CH₂Cl₂ (2.5052 (14) Å; Zhang et al., 2006). The P—Ag—P angle is slightly larger than the corresponding value of 89.80 (5) Å for the complex [Ag₂Cl₂(C₂₆H₃₀B₁₀P₂)₂].2CH₂Cl₂ (Zhang et al., 2006). The five-memebered chelate ring formed by the silver atom, two phosphorus atoms and two carbon atoms of the carborane skeleton is strongly flattened with a maximum deviation of 0.088 (3) Å for atom C2. The torsion angle P1—C1—C2—P2 is -2.7 (3)°, viz. smaller than that of 12.1 (2)° in the free ligand (Kivekäs et al., 1995). In the crystal, intermolecular C—H···O hydrogen bonds involving the nitrate anion and the dichloromethane solvent molecule are observed (Table 1).

Related literature top

For related structures, see: Zhang et al. (2006); Paavola et al. (2002, 2002a,b). For the synthesis and structure of 1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane, see: Kivekäs et al. (1995).

Experimental top

The title compound was synthesizd by the reaction of 1 mmol AgNO₃ and 1 mmol 1,2-(PⁱPr₂)₂-1,2-C₂B₁₀H₁₀ in 10 ml dichloromethane under the protection of N₂, refluxed for 4 h, then a colourless solution formed, and crystals suitable for X-ray diffraction were obtained from a dichloromethane- n-hexane (1:3 v/v solution (yield 60.7%, m.p. 553–555 K). FTIR (KBr) v (cm^-1): 2989, 2966, 2930, 2872 (C—H); 2614, 2602, 2585, 2556 (B—H); 1071 (C—P).

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

Fig. 1. The molecular structure of the title compound with 30% probability displacement ellipsoids for non-H atoms. H atoms are omitted for clarity. Symmetry code: (A) -x + 1,-y,-z.

Bis(µ-nitrato-κ²O:O)bis{[1,2-bis(diisopropylphosphanyl)-1,2-dicarba-closo-dodecaborane-κ²P,P']silver(I)} dichloromethane disolvate top

Crystal data top

[Ag₂(NO₃)₂(C₁₄H₃₈B₁₀P₂)₂]·2CH₂Cl₂	F(000) = 1288
M_r = 1262.58	D_x = 1.407 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 5416 reflections
a = 13.9256 (15) Å	θ = 2.5–26.4°
b = 10.3003 (10) Å	µ = 0.98 mm⁻¹
c = 21.8075 (19) Å	T = 298 K
β = 107.734 (2)°	Block, yellow
V = 2979.4 (5) Å³	0.43 × 0.36 × 0.31 mm
Z = 2

Data collection top

Bruker SMART1000 CCD diffractometer	5264 independent reflections
Radiation source: fine-focus sealed tube	3849 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.027
phi and ω scans	θ_max = 25.0°, θ_min = 1.6°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −13→16
T_min = 0.677, T_max = 0.751	k = −12→11
14624 measured reflections	l = −25→25

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.034	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.091	H-atom parameters constrained
S = 1.05	w = 1/[σ²(F_o²) + (0.0346P)² + 2.5405P] where P = (F_o² + 2F_c²)/3
5264 reflections	(Δ/σ)_max = 0.001
315 parameters	Δρ_max = 0.37 e Å⁻³
6 restraints	Δρ_min = −0.41 e Å⁻³

Crystal data top

[Ag₂(NO₃)₂(C₁₄H₃₈B₁₀P₂)₂]·2CH₂Cl₂	V = 2979.4 (5) Å³
M_r = 1262.58	Z = 2
Monoclinic, P2₁/n	Mo Kα radiation
a = 13.9256 (15) Å	µ = 0.98 mm⁻¹
b = 10.3003 (10) Å	T = 298 K
c = 21.8075 (19) Å	0.43 × 0.36 × 0.31 mm
β = 107.734 (2)°

Data collection top

Bruker SMART1000 CCD diffractometer	5264 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	3849 reflections with I > 2σ(I)
T_min = 0.677, T_max = 0.751	R_int = 0.027
14624 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.034	6 restraints
wR(F²) = 0.091	H-atom parameters constrained
S = 1.05	Δρ_max = 0.37 e Å⁻³
5264 reflections	Δρ_min = −0.41 e Å⁻³
315 parameters

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Ag1	0.64127 (2)	0.05086 (3)	0.027639 (15)	0.05747 (12)
P1	0.78280 (7)	0.00794 (9)	0.12339 (4)	0.0422 (2)
P2	0.72744 (7)	0.21677 (9)	−0.01656 (4)	0.0446 (2)
C1	0.8795 (2)	0.1294 (3)	0.11955 (16)	0.0440 (8)
C9	0.7616 (3)	0.0450 (4)	0.20219 (18)	0.0593 (10)
H9	0.7704	0.1390	0.2084	0.071*
B1	0.9356 (3)	0.1167 (4)	0.05903 (19)	0.0444 (10)
H1	0.9201	0.0326	0.0264	0.053*
N1	0.5539 (3)	−0.1960 (3)	−0.05564 (16)	0.0570 (8)
C2	0.8493 (2)	0.2413 (3)	0.04724 (16)	0.0416 (8)
C10	0.8432 (3)	−0.1537 (4)	0.13410 (18)	0.0573 (10)
H10	0.8990	−0.1541	0.1744	0.069*
B2	1.0566 (3)	0.1903 (6)	0.0910 (2)	0.0707 (15)
H2	1.1236	0.1544	0.0796	0.085*
C3	0.7665 (3)	0.1644 (4)	−0.08742 (17)	0.0561 (10)
H3	0.8300	0.1170	−0.0699	0.067*
B3	0.9592 (3)	0.2734 (5)	0.0328 (2)	0.0561 (11)
H3A	0.9641	0.2913	−0.0159	0.067*
C11	0.8355 (4)	−0.0186 (5)	0.26173 (19)	0.0807 (14)
H11A	0.8263	0.0183	0.3000	0.121*
H11B	0.9034	−0.0035	0.2615	0.121*
H11C	0.8230	−0.1103	0.2609	0.121*
C4	0.6685 (3)	0.3796 (4)	−0.0364 (2)	0.0689 (12)
H4	0.7133	0.4354	−0.0518	0.083*
C5	0.6447 (4)	0.4463 (5)	0.0192 (3)	0.0957 (18)
H5A	0.6085	0.5252	0.0042	0.143*
H5B	0.7064	0.4659	0.0522	0.143*
H5C	0.6042	0.3899	0.0362	0.143*
B4	0.9034 (4)	0.3850 (5)	0.0729 (2)	0.0642 (13)
H4A	0.8710	0.4777	0.0511	0.077*
B5	1.0043 (3)	0.1015 (6)	0.1427 (2)	0.0632 (13)
H5	1.0375	0.0091	0.1644	0.076*
C12	0.7628 (4)	−0.2512 (4)	0.1399 (2)	0.0877 (15)
H12A	0.7069	−0.2500	0.1011	0.132*
H12B	0.7399	−0.2278	0.1757	0.132*
H12C	0.7914	−0.3368	0.1466	0.132*
B6	0.8485 (4)	0.2899 (4)	0.1227 (2)	0.0564 (12)
H6	0.7772	0.3170	0.1311	0.068*
B7	0.9491 (4)	0.2154 (5)	0.1833 (2)	0.0691 (14)
H7	0.9461	0.1996	0.2326	0.083*
B8	1.0358 (4)	0.3580 (6)	0.1012 (3)	0.0831 (18)
H8	1.0901	0.4327	0.0973	0.100*
B9	0.9660 (5)	0.3716 (6)	0.1566 (3)	0.0857 (18)
H9A	0.9730	0.4561	0.1885	0.103*
C6	0.6908 (4)	0.0662 (5)	−0.1280 (2)	0.0913 (16)
H6A	0.6276	0.1087	−0.1477	0.137*
H6B	0.6812	−0.0028	−0.1008	0.137*
H6C	0.7162	0.0312	−0.1608	0.137*
C7	0.7878 (4)	0.2708 (5)	−0.1299 (2)	0.0828 (14)
H7A	0.8179	0.2334	−0.1600	0.124*
H7B	0.8331	0.3333	−0.1036	0.124*
H7C	0.7258	0.3128	−0.1530	0.124*
B10	1.0634 (4)	0.2546 (7)	0.1678 (3)	0.0881 (19)
H10A	1.1353	0.2624	0.2067	0.106*
C13	0.6523 (4)	0.0158 (6)	0.1985 (2)	0.0881 (15)
H13A	0.6403	−0.0759	0.1932	0.132*
H13B	0.6077	0.0611	0.1625	0.132*
H13C	0.6403	0.0440	0.2375	0.132*
C8	0.5700 (4)	0.3571 (6)	−0.0918 (3)	0.111 (2)
H8A	0.5254	0.3032	−0.0769	0.166*
H8B	0.5853	0.3150	−0.1270	0.166*
H8C	0.5381	0.4390	−0.1060	0.166*
C14	0.8825 (4)	−0.1983 (4)	0.0795 (2)	0.0742 (13)
H14A	0.8987	−0.2891	0.0845	0.111*
H14B	0.9419	−0.1498	0.0807	0.111*
H14C	0.8317	−0.1841	0.0390	0.111*
Cl1	0.32691 (14)	0.43727 (14)	0.21349 (8)	0.1137 (5)
Cl2	0.42679 (13)	0.19019 (16)	0.24175 (8)	0.1185 (5)
O2	0.52475 (19)	−0.0987 (3)	−0.03220 (15)	0.0713 (8)
O3	0.6446 (2)	−0.2156 (3)	−0.04215 (16)	0.0875 (10)
O1	0.4915 (3)	−0.2662 (3)	−0.09218 (17)	0.0919 (11)
C15	0.3518 (5)	0.2913 (6)	0.1839 (2)	0.1077 (19)
H15A	0.3848	0.3072	0.1513	0.129*
H15B	0.2885	0.2476	0.1632	0.129*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.03991 (16)	0.0667 (2)	0.0621 (2)	−0.01337 (14)	0.01007 (13)	0.00590 (16)
P1	0.0444 (5)	0.0431 (5)	0.0413 (5)	−0.0005 (4)	0.0163 (4)	0.0016 (4)
P2	0.0398 (5)	0.0418 (5)	0.0504 (5)	0.0021 (4)	0.0111 (4)	0.0074 (4)
C1	0.0428 (19)	0.048 (2)	0.0401 (18)	−0.0014 (16)	0.0118 (15)	−0.0069 (16)
C9	0.067 (3)	0.068 (3)	0.051 (2)	0.003 (2)	0.031 (2)	0.001 (2)
B1	0.034 (2)	0.052 (3)	0.048 (2)	0.0008 (18)	0.0145 (18)	−0.002 (2)
N1	0.058 (2)	0.054 (2)	0.064 (2)	−0.0071 (18)	0.0267 (18)	−0.0053 (18)
C2	0.0419 (19)	0.0362 (19)	0.050 (2)	−0.0049 (15)	0.0188 (16)	−0.0041 (16)
C10	0.074 (3)	0.044 (2)	0.054 (2)	0.010 (2)	0.019 (2)	0.0049 (18)
B2	0.039 (2)	0.097 (4)	0.072 (3)	−0.014 (3)	0.011 (2)	−0.004 (3)
C3	0.062 (2)	0.061 (3)	0.044 (2)	−0.005 (2)	0.0133 (18)	0.0022 (18)
B3	0.048 (3)	0.059 (3)	0.066 (3)	−0.015 (2)	0.025 (2)	−0.002 (2)
C11	0.101 (4)	0.100 (4)	0.043 (2)	0.009 (3)	0.024 (2)	0.005 (2)
C4	0.059 (3)	0.056 (3)	0.094 (3)	0.017 (2)	0.027 (2)	0.022 (2)
C5	0.091 (4)	0.064 (3)	0.150 (5)	0.035 (3)	0.062 (4)	0.021 (3)
B4	0.075 (3)	0.043 (3)	0.082 (3)	−0.022 (2)	0.034 (3)	−0.013 (2)
B5	0.039 (2)	0.086 (4)	0.054 (3)	−0.002 (2)	−0.001 (2)	−0.001 (3)
C12	0.130 (5)	0.050 (3)	0.095 (4)	−0.010 (3)	0.052 (3)	0.010 (3)
B6	0.072 (3)	0.047 (3)	0.056 (3)	−0.009 (2)	0.028 (2)	−0.017 (2)
B7	0.067 (3)	0.088 (4)	0.048 (3)	−0.026 (3)	0.010 (2)	−0.022 (3)
B8	0.070 (3)	0.094 (4)	0.083 (4)	−0.045 (3)	0.020 (3)	−0.019 (3)
B9	0.102 (5)	0.080 (4)	0.077 (4)	−0.045 (4)	0.029 (3)	−0.038 (3)
C6	0.116 (4)	0.088 (4)	0.062 (3)	−0.031 (3)	0.015 (3)	−0.014 (3)
C7	0.102 (4)	0.089 (4)	0.063 (3)	−0.010 (3)	0.033 (3)	0.014 (3)
B10	0.062 (3)	0.121 (5)	0.070 (3)	−0.040 (3)	0.003 (3)	−0.018 (3)
C13	0.079 (3)	0.123 (4)	0.079 (3)	0.004 (3)	0.049 (3)	0.011 (3)
C8	0.073 (3)	0.118 (5)	0.124 (5)	0.029 (3)	0.004 (3)	0.047 (4)
C14	0.097 (4)	0.046 (2)	0.087 (3)	0.015 (2)	0.039 (3)	−0.001 (2)
Cl1	0.1405 (14)	0.0763 (9)	0.1027 (10)	−0.0029 (9)	0.0049 (9)	0.0015 (8)
Cl2	0.1154 (12)	0.1009 (11)	0.1187 (12)	0.0243 (9)	0.0050 (9)	−0.0136 (9)
O2	0.0384 (14)	0.0748 (18)	0.101 (2)	−0.0155 (11)	0.0213 (11)	−0.0315 (15)
O3	0.066 (2)	0.099 (3)	0.097 (2)	0.0177 (18)	0.0253 (18)	−0.013 (2)
O1	0.093 (2)	0.085 (2)	0.101 (2)	−0.035 (2)	0.035 (2)	−0.040 (2)
C15	0.107 (4)	0.136 (5)	0.070 (3)	0.010 (4)	0.014 (3)	−0.028 (3)

Geometric parameters (Å, º) top

Ag1—O2	2.328 (3)	C4—C8	1.545 (6)
Ag1—O2ⁱ	2.395 (3)	C4—H4	0.9800
Ag1—P1	2.4357 (9)	C5—H5A	0.9600
Ag1—P2	2.4482 (10)	C5—H5B	0.9600
P1—C10	1.848 (4)	C5—H5C	0.9600
P1—C1	1.859 (4)	B4—B9	1.773 (8)
P1—C9	1.869 (4)	B4—B8	1.779 (8)
P2—C2	1.855 (3)	B4—B6	1.797 (7)
P2—C4	1.860 (4)	B4—H4A	1.1000
P2—C3	1.867 (4)	B5—B7	1.779 (7)
C1—B5	1.679 (5)	B5—B10	1.786 (8)
C1—B7	1.684 (5)	B5—H5	1.1000
C1—B6	1.716 (6)	C12—H12A	0.9600
C1—B1	1.731 (5)	C12—H12B	0.9600
C1—C2	1.894 (5)	C12—H12C	0.9600
C9—C13	1.530 (6)	B6—B7	1.782 (7)
C9—C11	1.536 (6)	B6—B9	1.788 (7)
C9—H9	0.9800	B6—H6	1.1000
B1—C2	1.722 (5)	B7—B9	1.752 (8)
B1—B3	1.776 (6)	B7—B10	1.771 (8)
B1—B2	1.785 (6)	B7—H7	1.1000
B1—B5	1.791 (6)	B8—B10	1.748 (9)
B1—H1	1.1000	B8—B9	1.772 (8)
N1—O1	1.221 (4)	B8—H8	1.1000
N1—O3	1.223 (4)	B9—B10	1.775 (9)
N1—O2	1.248 (4)	B9—H9A	1.1000
C2—B4	1.678 (5)	C6—H6A	0.9600
C2—B3	1.686 (5)	C6—H6B	0.9600
C2—B6	1.723 (5)	C6—H6C	0.9600
C10—C14	1.525 (5)	C7—H7A	0.9600
C10—C12	1.537 (6)	C7—H7B	0.9600
C10—H10	0.9800	C7—H7C	0.9600
B2—B3	1.771 (7)	B10—H10A	1.1000
B2—B5	1.772 (7)	C13—H13A	0.9600
B2—B8	1.776 (9)	C13—H13B	0.9600
B2—B10	1.777 (8)	C13—H13C	0.9600
B2—H2	1.1000	C8—H8A	0.9600
C3—C7	1.522 (5)	C8—H8B	0.9600
C3—C6	1.532 (6)	C8—H8C	0.9600
C3—H3	0.9800	C14—H14A	0.9600
B3—B4	1.761 (7)	C14—H14B	0.9600
B3—B8	1.776 (7)	C14—H14C	0.9600
B3—H3A	1.1000	Cl1—C15	1.713 (6)
C11—H11A	0.9600	Cl2—C15	1.721 (6)
C11—H11B	0.9600	O2—Ag1ⁱ	2.395 (3)
C11—H11C	0.9600	C15—H15A	0.9700
C4—C5	1.514 (6)	C15—H15B	0.9700

O2—Ag1—O2ⁱ	69.06 (12)	B8—B4—B6	106.9 (4)
O2—Ag1—P1	127.18 (8)	C2—B4—H4A	122.6
O2ⁱ—Ag1—P1	122.75 (8)	B3—B4—H4A	122.5
O2—Ag1—P2	125.65 (8)	B9—B4—H4A	121.4
O2ⁱ—Ag1—P2	117.89 (8)	B8—B4—H4A	122.1
P1—Ag1—P2	95.65 (3)	B6—B4—H4A	122.7
C10—P1—C1	107.71 (17)	C1—B5—B2	108.0 (3)
C10—P1—C9	105.13 (18)	C1—B5—B7	58.2 (2)
C1—P1—C9	102.90 (17)	B2—B5—B7	107.5 (4)
C10—P1—Ag1	119.34 (13)	C1—B5—B10	106.2 (4)
C1—P1—Ag1	104.33 (11)	B2—B5—B10	59.9 (3)
C9—P1—Ag1	115.98 (13)	B7—B5—B10	59.6 (3)
C2—P2—C4	106.85 (18)	C1—B5—B1	59.7 (2)
C2—P2—C3	103.26 (16)	B2—B5—B1	60.1 (2)
C4—P2—C3	106.71 (19)	B7—B5—B1	105.8 (3)
C2—P2—Ag1	104.24 (11)	B10—B5—B1	106.8 (4)
C4—P2—Ag1	119.11 (14)	C1—B5—H5	122.6
C3—P2—Ag1	115.17 (13)	B2—B5—H5	121.3
B5—C1—B7	63.9 (3)	B7—B5—H5	123.0
B5—C1—B6	113.8 (3)	B10—B5—H5	122.5
B7—C1—B6	63.2 (3)	B1—B5—H5	122.5
B5—C1—B1	63.3 (2)	C10—C12—H12A	109.5
B7—C1—B1	113.0 (3)	C10—C12—H12B	109.5
B6—C1—B1	106.3 (3)	H12A—C12—H12B	109.5
B5—C1—P1	124.6 (3)	C10—C12—H12C	109.5
B7—C1—P1	124.0 (3)	H12A—C12—H12C	109.5
B6—C1—P1	116.9 (3)	H12B—C12—H12C	109.5
B1—C1—P1	119.0 (2)	C1—B6—C2	66.8 (2)
B5—C1—C2	107.6 (3)	C1—B6—B7	57.5 (2)
B7—C1—C2	107.1 (3)	C2—B6—B7	110.5 (3)
B6—C1—C2	56.8 (2)	C1—B6—B9	105.1 (4)
B1—C1—C2	56.53 (19)	C2—B6—B9	105.1 (3)
P1—C1—C2	117.8 (2)	B7—B6—B9	58.8 (3)
C13—C9—C11	111.1 (4)	C1—B6—B4	110.0 (3)
C13—C9—P1	110.2 (3)	C2—B6—B4	56.9 (2)
C11—C9—P1	115.9 (3)	B7—B6—B4	107.5 (4)
C13—C9—H9	106.3	B9—B6—B4	59.3 (3)
C11—C9—H9	106.3	C1—B6—H6	120.2
P1—C9—H9	106.3	C2—B6—H6	120.2
C2—B1—C1	66.5 (2)	B7—B6—H6	122.1
C2—B1—B3	57.6 (2)	B9—B6—H6	124.8
C1—B1—B3	110.3 (3)	B4—B6—H6	122.4
C2—B1—B2	105.9 (3)	C1—B7—B9	108.1 (4)
C1—B1—B2	105.1 (3)	C1—B7—B10	106.6 (3)
B3—B1—B2	59.6 (3)	B9—B7—B10	60.5 (3)
C2—B1—B5	110.4 (3)	C1—B7—B5	57.9 (2)
C1—B1—B5	56.9 (2)	B9—B7—B5	108.5 (4)
B3—B1—B5	108.3 (3)	B10—B7—B5	60.4 (3)
B2—B1—B5	59.4 (3)	C1—B7—B6	59.3 (2)
C2—B1—H1	120.0	B9—B7—B6	60.8 (3)
C1—B1—H1	120.6	B10—B7—B6	108.0 (4)
B3—B1—H1	121.7	B5—B7—B6	106.0 (3)
B2—B1—H1	124.3	C1—B7—H7	123.0
B5—B1—H1	122.0	B9—B7—H7	120.7
O1—N1—O3	122.5 (4)	B10—B7—H7	121.6
O1—N1—O2	119.1 (4)	B5—B7—H7	122.7
O3—N1—O2	118.3 (3)	B6—B7—H7	122.2
B4—C2—B3	63.1 (3)	B10—B8—B9	60.6 (4)
B4—C2—B1	112.7 (3)	B10—B8—B3	108.9 (4)
B3—C2—B1	62.8 (2)	B9—B8—B3	107.3 (3)
B4—C2—B6	63.8 (3)	B10—B8—B2	60.6 (3)
B3—C2—B6	113.1 (3)	B9—B8—B2	107.9 (4)
B1—C2—B6	106.4 (3)	B3—B8—B2	59.8 (3)
B4—C2—P2	125.8 (3)	B10—B8—B4	109.1 (4)
B3—C2—P2	124.2 (3)	B9—B8—B4	59.9 (3)
B1—C2—P2	116.6 (2)	B3—B8—B4	59.4 (3)
B6—C2—P2	119.0 (2)	B2—B8—B4	107.5 (3)
B4—C2—C1	107.2 (3)	B10—B8—H8	120.5
B3—C2—C1	106.9 (3)	B9—B8—H8	121.9
B1—C2—C1	57.0 (2)	B3—B8—H8	122.0
B6—C2—C1	56.4 (2)	B2—B8—H8	121.9
P2—C2—C1	117.5 (2)	B4—B8—H8	121.8
C14—C10—C12	108.2 (3)	B7—B9—B8	108.1 (4)
C14—C10—P1	115.5 (3)	B7—B9—B4	109.9 (3)
C12—C10—P1	106.5 (3)	B8—B9—B4	60.2 (3)
C14—C10—H10	108.8	B7—B9—B10	60.3 (3)
C12—C10—H10	108.8	B8—B9—B10	59.0 (4)
P1—C10—H10	108.8	B4—B9—B10	108.1 (4)
B3—B2—B5	109.4 (3)	B7—B9—B6	60.4 (3)
B3—B2—B8	60.1 (3)	B8—B9—B6	107.6 (3)
B5—B2—B8	107.9 (4)	B4—B9—B6	60.6 (3)
B3—B2—B10	107.8 (4)	B10—B9—B6	107.6 (4)
B5—B2—B10	60.4 (3)	B7—B9—H9A	120.7
B8—B2—B10	58.9 (3)	B8—B9—H9A	122.3
B3—B2—B1	59.9 (2)	B4—B9—H9A	120.7
B5—B2—B1	60.4 (2)	B10—B9—H9A	122.3
B8—B2—B1	106.9 (4)	B6—B9—H9A	121.8
B10—B2—B1	107.4 (3)	C3—C6—H6A	109.5
B3—B2—H2	121.2	C3—C6—H6B	109.5
B5—B2—H2	120.8	H6A—C6—H6B	109.5
B8—B2—H2	122.5	C3—C6—H6C	109.5
B10—B2—H2	122.3	H6A—C6—H6C	109.5
B1—B2—H2	122.2	H6B—C6—H6C	109.5
C7—C3—C6	110.6 (3)	C3—C7—H7A	109.5
C7—C3—P2	117.1 (3)	C3—C7—H7B	109.5
C6—C3—P2	110.2 (3)	H7A—C7—H7B	109.5
C7—C3—H3	106.1	C3—C7—H7C	109.5
C6—C3—H3	106.1	H7A—C7—H7C	109.5
P2—C3—H3	106.1	H7B—C7—H7C	109.5
C2—B3—B4	58.2 (2)	B8—B10—B7	108.3 (4)
C2—B3—B2	108.2 (3)	B8—B10—B9	60.4 (4)
B4—B3—B2	108.5 (4)	B7—B10—B9	59.2 (3)
C2—B3—B8	106.7 (3)	B8—B10—B2	60.5 (3)
B4—B3—B8	60.4 (3)	B7—B10—B2	107.6 (3)
B2—B3—B8	60.1 (3)	B9—B10—B2	107.7 (4)
C2—B3—B1	59.6 (2)	B8—B10—B5	108.6 (4)
B4—B3—B1	106.3 (3)	B7—B10—B5	60.0 (3)
B2—B3—B1	60.4 (3)	B9—B10—B5	107.2 (4)
B8—B3—B1	107.3 (4)	B2—B10—B5	59.7 (3)
C2—B3—H3A	122.7	B8—B10—H10A	120.9
B4—B3—H3A	122.4	B7—B10—H10A	122.0
B2—B3—H3A	120.9	B9—B10—H10A	122.3
B8—B3—H3A	122.0	B2—B10—H10A	121.9
B1—B3—H3A	122.3	B5—B10—H10A	121.9
C9—C11—H11A	109.5	C9—C13—H13A	109.5
C9—C11—H11B	109.5	C9—C13—H13B	109.5
H11A—C11—H11B	109.5	H13A—C13—H13B	109.5
C9—C11—H11C	109.5	C9—C13—H13C	109.5
H11A—C11—H11C	109.5	H13A—C13—H13C	109.5
H11B—C11—H11C	109.5	H13B—C13—H13C	109.5
C5—C4—C8	109.6 (4)	C4—C8—H8A	109.5
C5—C4—P2	114.3 (3)	C4—C8—H8B	109.5
C8—C4—P2	105.7 (3)	H8A—C8—H8B	109.5
C5—C4—H4	109.0	C4—C8—H8C	109.5
C8—C4—H4	109.0	H8A—C8—H8C	109.5
P2—C4—H4	109.0	H8B—C8—H8C	109.5
C4—C5—H5A	109.5	C10—C14—H14A	109.5
C4—C5—H5B	109.5	C10—C14—H14B	109.5
H5A—C5—H5B	109.5	H14A—C14—H14B	109.5
C4—C5—H5C	109.5	C10—C14—H14C	109.5
H5A—C5—H5C	109.5	H14A—C14—H14C	109.5
H5B—C5—H5C	109.5	H14B—C14—H14C	109.5
C2—B4—B3	58.6 (2)	N1—O2—Ag1	120.2 (2)
C2—B4—B9	107.7 (4)	N1—O2—Ag1ⁱ	128.4 (2)
B3—B4—B9	107.9 (4)	Ag1—O2—Ag1ⁱ	110.94 (12)
C2—B4—B8	106.9 (4)	Cl1—C15—Cl2	113.7 (3)
B3—B4—B8	60.2 (3)	Cl1—C15—H15A	108.8
B9—B4—B8	59.8 (3)	Cl2—C15—H15A	108.8
C2—B4—B6	59.3 (2)	Cl1—C15—H15B	108.8
B3—B4—B6	106.1 (3)	Cl2—C15—H15B	108.8
B9—B4—B6	60.1 (3)	H15A—C15—H15B	107.7

O2—Ag1—P1—C10	28.73 (18)	P1—C1—B6—C2	−107.1 (2)
O2ⁱ—Ag1—P1—C10	116.12 (17)	B5—C1—B6—B7	−40.4 (3)
P2—Ag1—P1—C10	−115.38 (15)	B1—C1—B6—B7	−107.9 (3)
O2—Ag1—P1—C1	148.98 (14)	P1—C1—B6—B7	116.5 (3)
O2ⁱ—Ag1—P1—C1	−123.63 (14)	C2—C1—B6—B7	−136.4 (3)
P2—Ag1—P1—C1	4.87 (12)	B5—C1—B6—B9	−4.2 (4)
O2—Ag1—P1—C9	−98.64 (18)	B7—C1—B6—B9	36.2 (3)
O2ⁱ—Ag1—P1—C9	−11.25 (18)	B1—C1—B6—B9	−71.8 (4)
P2—Ag1—P1—C9	117.25 (15)	P1—C1—B6—B9	152.7 (3)
O2—Ag1—P2—C2	−151.07 (14)	C2—C1—B6—B9	−100.3 (3)
O2ⁱ—Ag1—P2—C2	125.72 (13)	B5—C1—B6—B4	58.1 (4)
P1—Ag1—P2—C2	−6.15 (11)	B7—C1—B6—B4	98.5 (4)
O2—Ag1—P2—C4	90.0 (2)	B1—C1—B6—B4	−9.4 (4)
O2ⁱ—Ag1—P2—C4	6.79 (19)	P1—C1—B6—B4	−145.0 (3)
P1—Ag1—P2—C4	−125.08 (17)	C2—C1—B6—B4	−38.0 (3)
O2—Ag1—P2—C3	−38.70 (17)	B4—C2—B6—C1	−136.4 (3)
O2ⁱ—Ag1—P2—C3	−121.91 (16)	B3—C2—B6—C1	−95.6 (3)
P1—Ag1—P2—C3	106.22 (14)	B1—C2—B6—C1	−28.7 (3)
C10—P1—C1—B5	−15.7 (3)	P2—C2—B6—C1	105.4 (3)
C9—P1—C1—B5	95.0 (3)	B4—C2—B6—B7	−98.0 (4)
Ag1—P1—C1—B5	−143.5 (3)	B3—C2—B6—B7	−57.2 (4)
C10—P1—C1—B7	−95.4 (3)	B1—C2—B6—B7	9.7 (4)
C9—P1—C1—B7	15.4 (4)	P2—C2—B6—B7	143.8 (3)
Ag1—P1—C1—B7	136.8 (3)	C1—C2—B6—B7	38.4 (3)
C10—P1—C1—B6	−169.9 (3)	B4—C2—B6—B9	−36.1 (4)
C9—P1—C1—B6	−59.1 (3)	B3—C2—B6—B9	4.7 (4)
Ag1—P1—C1—B6	62.4 (3)	B1—C2—B6—B9	71.5 (4)
C10—P1—C1—B1	60.3 (3)	P2—C2—B6—B9	−154.3 (3)
C9—P1—C1—B1	171.0 (3)	C1—C2—B6—B9	100.2 (4)
Ag1—P1—C1—B1	−67.5 (3)	B3—C2—B6—B4	40.8 (3)
C10—P1—C1—C2	125.4 (2)	B1—C2—B6—B4	107.7 (3)
C9—P1—C1—C2	−123.8 (2)	P2—C2—B6—B4	−118.2 (3)
Ag1—P1—C1—C2	−2.3 (2)	C1—C2—B6—B4	136.4 (3)
C10—P1—C9—C13	−99.3 (3)	C2—B4—B6—C1	42.5 (3)
C1—P1—C9—C13	148.0 (3)	B3—B4—B6—C1	5.7 (4)
Ag1—P1—C9—C13	34.8 (4)	B9—B4—B6—C1	−96.0 (4)
C10—P1—C9—C11	27.9 (4)	B8—B4—B6—C1	−57.4 (4)
C1—P1—C9—C11	−84.7 (4)	B3—B4—B6—C2	−36.8 (3)
Ag1—P1—C9—C11	162.1 (3)	B9—B4—B6—C2	−138.5 (4)
B5—C1—B1—C2	−137.5 (3)	B8—B4—B6—C2	−99.9 (4)
B7—C1—B1—C2	−95.9 (3)	C2—B4—B6—B7	103.5 (3)
B6—C1—B1—C2	−28.6 (3)	B3—B4—B6—B7	66.7 (4)
P1—C1—B1—C2	105.9 (3)	B9—B4—B6—B7	−35.0 (4)
B5—C1—B1—B3	−99.1 (3)	B8—B4—B6—B7	3.6 (4)
B7—C1—B1—B3	−57.5 (4)	C2—B4—B6—B9	138.5 (4)
B6—C1—B1—B3	9.7 (4)	B3—B4—B6—B9	101.7 (4)
P1—C1—B1—B3	144.2 (3)	B8—B4—B6—B9	38.6 (4)
C2—C1—B1—B3	38.3 (2)	B5—C1—B7—B9	101.0 (4)
B5—C1—B1—B2	−36.4 (3)	B6—C1—B7—B9	−37.7 (4)
B7—C1—B1—B2	5.2 (4)	B1—C1—B7—B9	59.6 (5)
B6—C1—B1—B2	72.5 (4)	P1—C1—B7—B9	−143.4 (3)
P1—C1—B1—B2	−153.1 (3)	C2—C1—B7—B9	−0.6 (4)
C2—C1—B1—B2	101.1 (3)	B5—C1—B7—B10	37.3 (4)
B7—C1—B1—B5	41.6 (4)	B6—C1—B7—B10	−101.4 (4)
B6—C1—B1—B5	108.9 (3)	B1—C1—B7—B10	−4.1 (5)
P1—C1—B1—B5	−116.7 (3)	P1—C1—B7—B10	152.9 (3)
C2—C1—B1—B5	137.5 (3)	C2—C1—B7—B10	−64.3 (4)
C1—B1—C2—B4	96.4 (3)	B6—C1—B7—B5	−138.7 (3)
B3—B1—C2—B4	−40.1 (3)	B1—C1—B7—B5	−41.3 (3)
B2—B1—C2—B4	−3.6 (4)	P1—C1—B7—B5	115.6 (3)
B5—B1—C2—B4	59.2 (4)	C2—C1—B7—B5	−101.6 (3)
C1—B1—C2—B3	136.4 (3)	B5—C1—B7—B6	138.7 (3)
B2—B1—C2—B3	36.5 (3)	B1—C1—B7—B6	97.3 (3)
B5—B1—C2—B3	99.2 (3)	P1—C1—B7—B6	−105.7 (3)
C1—B1—C2—B6	28.5 (3)	C2—C1—B7—B6	37.1 (3)
B3—B1—C2—B6	−108.0 (3)	B2—B5—B7—C1	100.7 (3)
B2—B1—C2—B6	−71.4 (3)	B10—B5—B7—C1	138.1 (4)
B5—B1—C2—B6	−8.7 (4)	B1—B5—B7—C1	37.6 (3)
C1—B1—C2—P2	−106.9 (2)	C1—B5—B7—B9	−100.1 (4)
B3—B1—C2—P2	116.7 (3)	B2—B5—B7—B9	0.6 (4)
B2—B1—C2—P2	153.2 (3)	B10—B5—B7—B9	38.0 (4)
B5—B1—C2—P2	−144.1 (3)	B1—B5—B7—B9	−62.5 (4)
B3—B1—C2—C1	−136.4 (3)	C1—B5—B7—B10	−138.1 (4)
B2—B1—C2—C1	−99.9 (3)	B2—B5—B7—B10	−37.4 (3)
B5—B1—C2—C1	−37.2 (3)	B1—B5—B7—B10	−100.5 (4)
C4—P2—C2—B4	−9.0 (4)	C1—B5—B7—B6	−36.2 (3)
C3—P2—C2—B4	103.3 (3)	B2—B5—B7—B6	64.5 (4)
Ag1—P2—C2—B4	−136.0 (3)	B10—B5—B7—B6	101.9 (4)
C4—P2—C2—B3	−88.4 (3)	B1—B5—B7—B6	1.5 (4)
C3—P2—C2—B3	23.9 (3)	C2—B6—B7—C1	−42.6 (3)
Ag1—P2—C2—B3	144.6 (3)	B9—B6—B7—C1	−138.2 (4)
C4—P2—C2—B1	−162.3 (3)	B4—B6—B7—C1	−103.0 (3)
C3—P2—C2—B1	−49.9 (3)	C1—B6—B7—B9	138.2 (4)
Ag1—P2—C2—B1	70.7 (2)	C2—B6—B7—B9	95.6 (4)
C4—P2—C2—B6	68.1 (3)	B4—B6—B7—B9	35.2 (3)
C3—P2—C2—B6	−179.6 (3)	C1—B6—B7—B10	99.0 (4)
Ag1—P2—C2—B6	−58.9 (3)	C2—B6—B7—B10	56.5 (4)
C4—P2—C2—C1	133.0 (2)	B9—B6—B7—B10	−39.2 (4)
C3—P2—C2—C1	−114.7 (2)	B4—B6—B7—B10	−4.0 (4)
Ag1—P2—C2—C1	6.0 (2)	C1—B6—B7—B5	35.6 (3)
B5—C1—C2—B4	−67.0 (4)	C2—B6—B7—B5	−7.0 (4)
B7—C1—C2—B4	0.3 (4)	B9—B6—B7—B5	−102.6 (4)
B6—C1—C2—B4	40.4 (3)	B4—B6—B7—B5	−67.4 (4)
B1—C1—C2—B4	−106.3 (3)	C2—B3—B8—B10	64.8 (5)
P1—C1—C2—B4	145.8 (3)	B4—B3—B8—B10	101.5 (4)
B5—C1—C2—B3	−0.5 (4)	B2—B3—B8—B10	−36.9 (4)
B7—C1—C2—B3	66.8 (3)	B1—B3—B8—B10	2.2 (5)
B6—C1—C2—B3	106.8 (3)	C2—B3—B8—B9	0.8 (5)
B1—C1—C2—B3	−39.9 (3)	B4—B3—B8—B9	37.4 (4)
P1—C1—C2—B3	−147.8 (2)	B2—B3—B8—B9	−101.0 (5)
B5—C1—C2—B1	39.3 (3)	B1—B3—B8—B9	−61.9 (5)
B7—C1—C2—B1	106.6 (3)	C2—B3—B8—B2	101.7 (4)
B6—C1—C2—B1	146.7 (3)	B4—B3—B8—B2	138.4 (4)
P1—C1—C2—B1	−107.9 (3)	B1—B3—B8—B2	39.1 (3)
B5—C1—C2—B6	−107.4 (3)	C2—B3—B8—B4	−36.6 (3)
B7—C1—C2—B6	−40.1 (3)	B2—B3—B8—B4	−138.4 (4)
B1—C1—C2—B6	−146.7 (3)	B1—B3—B8—B4	−99.3 (3)
P1—C1—C2—B6	105.4 (3)	B3—B2—B8—B10	139.3 (4)
B5—C1—C2—P2	144.6 (3)	B5—B2—B8—B10	36.8 (3)
B7—C1—C2—P2	−148.1 (3)	B1—B2—B8—B10	100.5 (4)
B6—C1—C2—P2	−108.0 (3)	B3—B2—B8—B9	100.1 (4)
B1—C1—C2—P2	105.3 (3)	B5—B2—B8—B9	−2.4 (5)
P1—C1—C2—P2	−2.7 (3)	B10—B2—B8—B9	−39.2 (4)
C1—P1—C10—C14	−62.2 (3)	B1—B2—B8—B9	61.3 (5)
C9—P1—C10—C14	−171.4 (3)	B5—B2—B8—B3	−102.5 (3)
Ag1—P1—C10—C14	56.3 (4)	B10—B2—B8—B3	−139.3 (4)
C1—P1—C10—C12	177.7 (3)	B1—B2—B8—B3	−38.8 (3)
C9—P1—C10—C12	68.5 (3)	B3—B2—B8—B4	36.8 (3)
Ag1—P1—C10—C12	−63.8 (3)	B5—B2—B8—B4	−65.6 (4)
C2—B1—B2—B3	−35.6 (3)	B10—B2—B8—B4	−102.4 (4)
C1—B1—B2—B3	−105.0 (3)	B1—B2—B8—B4	−2.0 (5)
B5—B1—B2—B3	−140.2 (4)	C2—B4—B8—B10	−64.3 (5)
C2—B1—B2—B5	104.6 (3)	B3—B4—B8—B10	−101.1 (4)
C1—B1—B2—B5	35.3 (3)	B9—B4—B8—B10	36.8 (4)
B3—B1—B2—B5	140.2 (4)	B6—B4—B8—B10	−2.0 (5)
C2—B1—B2—B8	3.3 (4)	C2—B4—B8—B9	−101.1 (4)
C1—B1—B2—B8	−66.1 (4)	B3—B4—B8—B9	−137.9 (4)
B3—B1—B2—B8	38.9 (3)	B6—B4—B8—B9	−38.8 (3)
B5—B1—B2—B8	−101.4 (4)	C2—B4—B8—B3	36.9 (3)
C2—B1—B2—B10	65.2 (4)	B9—B4—B8—B3	137.9 (4)
C1—B1—B2—B10	−4.1 (5)	B6—B4—B8—B3	99.2 (3)
B3—B1—B2—B10	100.8 (4)	C2—B4—B8—B2	−0.1 (5)
B5—B1—B2—B10	−39.4 (4)	B3—B4—B8—B2	−37.0 (3)
C2—P2—C3—C7	−86.8 (3)	B9—B4—B8—B2	100.9 (4)
C4—P2—C3—C7	25.7 (4)	B6—B4—B8—B2	62.2 (4)
Ag1—P2—C3—C7	160.3 (3)	C1—B7—B9—B8	−63.4 (5)
C2—P2—C3—C6	145.7 (3)	B10—B7—B9—B8	35.9 (4)
C4—P2—C3—C6	−101.9 (3)	B5—B7—B9—B8	−2.1 (5)
Ag1—P2—C3—C6	32.8 (3)	B6—B7—B9—B8	−100.4 (4)
B1—C2—B3—B4	−138.3 (3)	C1—B7—B9—B4	0.7 (5)
B6—C2—B3—B4	−41.1 (3)	B10—B7—B9—B4	100.0 (4)
P2—C2—B3—B4	116.7 (3)	B5—B7—B9—B4	62.0 (5)
C1—C2—B3—B4	−101.1 (3)	B6—B7—B9—B4	−36.4 (4)
B4—C2—B3—B2	100.9 (4)	C1—B7—B9—B10	−99.3 (4)
B1—C2—B3—B2	−37.4 (3)	B5—B7—B9—B10	−38.0 (3)
B6—C2—B3—B2	59.8 (4)	B6—B7—B9—B10	−136.3 (4)
P2—C2—B3—B2	−142.4 (3)	C1—B7—B9—B6	37.0 (3)
C1—C2—B3—B2	−0.2 (4)	B10—B7—B9—B6	136.3 (4)
B4—C2—B3—B8	37.6 (4)	B5—B7—B9—B6	98.4 (3)
B1—C2—B3—B8	−100.7 (4)	B10—B8—B9—B7	−36.4 (4)
B6—C2—B3—B8	−3.5 (5)	B3—B8—B9—B7	65.8 (5)
P2—C2—B3—B8	154.3 (3)	B2—B8—B9—B7	2.8 (5)
C1—C2—B3—B8	−63.5 (4)	B4—B8—B9—B7	103.0 (4)
B4—C2—B3—B1	138.3 (3)	B10—B8—B9—B4	−139.5 (4)
B6—C2—B3—B1	97.2 (3)	B3—B8—B9—B4	−37.2 (4)
P2—C2—B3—B1	−105.1 (3)	B2—B8—B9—B4	−100.3 (4)
C1—C2—B3—B1	37.2 (2)	B3—B8—B9—B10	102.3 (4)
B5—B2—B3—C2	0.9 (5)	B2—B8—B9—B10	39.2 (4)
B8—B2—B3—C2	−99.2 (4)	B4—B8—B9—B10	139.5 (4)
B10—B2—B3—C2	−63.2 (4)	B10—B8—B9—B6	−100.3 (4)
B1—B2—B3—C2	37.0 (3)	B3—B8—B9—B6	2.0 (6)
B5—B2—B3—B4	62.5 (4)	B2—B8—B9—B6	−61.1 (5)
B8—B2—B3—B4	−37.5 (3)	B4—B8—B9—B6	39.2 (4)
B10—B2—B3—B4	−1.6 (4)	C2—B4—B9—B7	−0.5 (5)
B1—B2—B3—B4	98.7 (3)	B3—B4—B9—B7	−62.4 (5)
B5—B2—B3—B8	100.0 (4)	B8—B4—B9—B7	−100.0 (5)
B10—B2—B3—B8	35.9 (3)	B6—B4—B9—B7	36.3 (4)
B1—B2—B3—B8	136.2 (4)	C2—B4—B9—B8	99.6 (4)
B5—B2—B3—B1	−36.1 (3)	B3—B4—B9—B8	37.7 (3)
B8—B2—B3—B1	−136.2 (4)	B6—B4—B9—B8	136.3 (4)
B10—B2—B3—B1	−100.2 (4)	C2—B4—B9—B10	63.7 (4)
C1—B1—B3—C2	−42.4 (3)	B3—B4—B9—B10	1.8 (5)
B2—B1—B3—C2	−138.5 (3)	B8—B4—B9—B10	−35.9 (4)
B5—B1—B3—C2	−103.0 (3)	B6—B4—B9—B10	100.4 (4)
C2—B1—B3—B4	36.1 (3)	C2—B4—B9—B6	−36.7 (3)
C1—B1—B3—B4	−6.3 (4)	B3—B4—B9—B6	−98.6 (3)
B2—B1—B3—B4	−102.4 (4)	B8—B4—B9—B6	−136.3 (4)
B5—B1—B3—B4	−66.9 (4)	C1—B6—B9—B7	−35.6 (3)
C2—B1—B3—B2	138.5 (3)	C2—B6—B9—B7	−105.1 (3)
C1—B1—B3—B2	96.1 (3)	B4—B6—B9—B7	−140.2 (4)
B5—B1—B3—B2	35.4 (3)	C1—B6—B9—B8	65.6 (5)
C2—B1—B3—B8	99.5 (4)	C2—B6—B9—B8	−3.9 (5)
C1—B1—B3—B8	57.1 (4)	B7—B6—B9—B8	101.2 (5)
B2—B1—B3—B8	−39.0 (3)	B4—B6—B9—B8	−39.0 (4)
B5—B1—B3—B8	−3.5 (4)	C1—B6—B9—B4	104.6 (3)
C2—P2—C4—C5	−62.1 (4)	C2—B6—B9—B4	35.1 (3)
C3—P2—C4—C5	−172.1 (3)	B7—B6—B9—B4	140.2 (4)
Ag1—P2—C4—C5	55.4 (4)	C1—B6—B9—B10	3.4 (5)
C2—P2—C4—C8	177.2 (3)	C2—B6—B9—B10	−66.2 (4)
C3—P2—C4—C8	67.3 (4)	B7—B6—B9—B10	39.0 (4)
Ag1—P2—C4—C8	−65.2 (4)	B4—B6—B9—B10	−101.2 (4)
B1—C2—B4—B3	39.9 (3)	B9—B8—B10—B7	36.0 (4)
B6—C2—B4—B3	137.6 (3)	B3—B8—B10—B7	−63.7 (5)
P2—C2—B4—B3	−114.3 (3)	B2—B8—B10—B7	−100.3 (4)
C1—C2—B4—B3	100.6 (3)	B4—B8—B10—B7	−0.5 (5)
B3—C2—B4—B9	−100.6 (4)	B3—B8—B10—B9	−99.7 (4)
B1—C2—B4—B9	−60.6 (4)	B2—B8—B10—B9	−136.3 (4)
B6—C2—B4—B9	37.1 (4)	B4—B8—B10—B9	−36.5 (4)
P2—C2—B4—B9	145.2 (3)	B9—B8—B10—B2	136.3 (4)
C1—C2—B4—B9	0.1 (4)	B3—B8—B10—B2	36.6 (4)
B3—C2—B4—B8	−37.6 (3)	B4—B8—B10—B2	99.8 (4)
B1—C2—B4—B8	2.3 (4)	B9—B8—B10—B5	99.7 (4)
B6—C2—B4—B8	100.1 (4)	B3—B8—B10—B5	0.0 (6)
P2—C2—B4—B8	−151.8 (3)	B2—B8—B10—B5	−36.6 (4)
C1—C2—B4—B8	63.1 (4)	B4—B8—B10—B5	63.1 (5)
B3—C2—B4—B6	−137.6 (3)	C1—B7—B10—B8	65.2 (5)
B1—C2—B4—B6	−97.7 (3)	B9—B7—B10—B8	−36.5 (4)
P2—C2—B4—B6	108.1 (3)	B5—B7—B10—B8	101.3 (4)
C1—C2—B4—B6	−37.0 (3)	B6—B7—B10—B8	2.8 (5)
B2—B3—B4—C2	−100.4 (3)	C1—B7—B10—B9	101.7 (4)
B8—B3—B4—C2	−137.7 (4)	B5—B7—B10—B9	137.9 (4)
B1—B3—B4—C2	−36.7 (3)	B6—B7—B10—B9	39.3 (3)
C2—B3—B4—B9	100.2 (3)	C1—B7—B10—B2	1.2 (6)
B2—B3—B4—B9	−0.1 (4)	B9—B7—B10—B2	−100.5 (5)
B8—B3—B4—B9	−37.5 (3)	B5—B7—B10—B2	37.4 (4)
B1—B3—B4—B9	63.5 (4)	B6—B7—B10—B2	−61.2 (5)
C2—B3—B4—B8	137.7 (4)	C1—B7—B10—B5	−36.2 (3)
B2—B3—B4—B8	37.4 (3)	B9—B7—B10—B5	−137.9 (4)
B1—B3—B4—B8	101.0 (4)	B6—B7—B10—B5	−98.6 (3)
C2—B3—B4—B6	37.1 (3)	B7—B9—B10—B8	139.5 (4)
B2—B3—B4—B6	−63.2 (4)	B4—B9—B10—B8	36.4 (3)
B8—B3—B4—B6	−100.6 (4)	B6—B9—B10—B8	100.4 (4)
B1—B3—B4—B6	0.4 (4)	B8—B9—B10—B7	−139.5 (4)
B7—C1—B5—B2	−99.8 (4)	B4—B9—B10—B7	−103.1 (4)
B6—C1—B5—B2	−59.7 (4)	B6—B9—B10—B7	−39.0 (3)
B1—C1—B5—B2	37.3 (3)	B7—B9—B10—B2	100.3 (4)
P1—C1—B5—B2	145.5 (3)	B8—B9—B10—B2	−39.1 (3)
C2—C1—B5—B2	1.0 (4)	B4—B9—B10—B2	−2.7 (5)
B6—C1—B5—B7	40.1 (3)	B6—B9—B10—B2	61.3 (5)
B1—C1—B5—B7	137.1 (3)	B7—B9—B10—B5	37.5 (3)
P1—C1—B5—B7	−114.7 (3)	B8—B9—B10—B5	−102.0 (4)
C2—C1—B5—B7	100.8 (3)	B4—B9—B10—B5	−65.6 (5)
B7—C1—B5—B10	−36.8 (3)	B6—B9—B10—B5	−1.6 (5)
B6—C1—B5—B10	3.3 (4)	B3—B2—B10—B8	−36.4 (3)
B1—C1—B5—B10	100.3 (4)	B5—B2—B10—B8	−139.1 (4)
P1—C1—B5—B10	−151.5 (3)	B1—B2—B10—B8	−99.6 (4)
C2—C1—B5—B10	64.0 (4)	B3—B2—B10—B7	65.1 (5)
B7—C1—B5—B1	−137.1 (3)	B5—B2—B10—B7	−37.5 (4)
B6—C1—B5—B1	−97.0 (3)	B8—B2—B10—B7	101.5 (5)
P1—C1—B5—B1	108.2 (3)	B1—B2—B10—B7	1.9 (6)
C2—C1—B5—B1	−36.3 (3)	B3—B2—B10—B9	2.6 (5)
B3—B2—B5—C1	−1.2 (5)	B5—B2—B10—B9	−100.0 (4)
B8—B2—B5—C1	62.5 (4)	B8—B2—B10—B9	39.1 (4)
B10—B2—B5—C1	98.7 (4)	B1—B2—B10—B9	−60.5 (5)
B1—B2—B5—C1	−37.1 (3)	B3—B2—B10—B5	102.6 (4)
B3—B2—B5—B7	−62.6 (4)	B8—B2—B10—B5	139.1 (4)
B8—B2—B5—B7	1.2 (4)	B1—B2—B10—B5	39.4 (3)
B10—B2—B5—B7	37.3 (3)	C1—B5—B10—B8	−64.7 (5)
B1—B2—B5—B7	−98.5 (3)	B2—B5—B10—B8	37.0 (4)
B3—B2—B5—B10	−99.9 (4)	B7—B5—B10—B8	−100.9 (5)
B8—B2—B5—B10	−36.2 (4)	B1—B5—B10—B8	−2.1 (5)
B1—B2—B5—B10	−135.8 (4)	C1—B5—B10—B7	36.2 (3)
B3—B2—B5—B1	35.9 (3)	B2—B5—B10—B7	137.9 (4)
B8—B2—B5—B1	99.7 (4)	B1—B5—B10—B7	98.8 (4)
B10—B2—B5—B1	135.8 (4)	C1—B5—B10—B9	−0.9 (5)
C2—B1—B5—C1	41.4 (3)	B2—B5—B10—B9	100.8 (4)
B3—B1—B5—C1	102.8 (3)	B7—B5—B10—B9	−37.1 (4)
B2—B1—B5—C1	138.3 (4)	B1—B5—B10—B9	61.7 (4)
C2—B1—B5—B2	−96.9 (4)	C1—B5—B10—B2	−101.7 (4)
C1—B1—B5—B2	−138.3 (4)	B7—B5—B10—B2	−137.9 (4)
B3—B1—B5—B2	−35.5 (3)	B1—B5—B10—B2	−39.1 (3)
C2—B1—B5—B7	4.5 (4)	O1—N1—O2—Ag1	−172.7 (3)
C1—B1—B5—B7	−36.9 (3)	O3—N1—O2—Ag1	5.6 (5)
B3—B1—B5—B7	65.8 (4)	O1—N1—O2—Ag1ⁱ	16.1 (5)
B2—B1—B5—B7	101.4 (4)	O3—N1—O2—Ag1ⁱ	−165.6 (3)
C2—B1—B5—B10	−57.9 (4)	O2ⁱ—Ag1—O2—N1	−172.6 (4)
C1—B1—B5—B10	−99.3 (4)	P1—Ag1—O2—N1	−56.7 (3)
B3—B1—B5—B10	3.5 (4)	P2—Ag1—O2—N1	77.4 (3)
B2—B1—B5—B10	39.0 (4)	O2ⁱ—Ag1—O2—Ag1ⁱ	0.0
B5—C1—B6—C2	96.1 (3)	P1—Ag1—O2—Ag1ⁱ	115.89 (11)
B7—C1—B6—C2	136.4 (3)	P2—Ag1—O2—Ag1ⁱ	−109.99 (11)
B1—C1—B6—C2	28.5 (3)

Symmetry code: (i) −x+1, −y, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C15—H15A···O3ⁱ	0.97	2.48	3.203 (6)	132
C15—H15A···O1ⁱ	0.97	2.48	3.389 (8)	155

Symmetry code: (i) −x+1, −y, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C15—H15A···O3ⁱ	0.97	2.48	3.203 (6)	132
C15—H15A···O1ⁱ	0.97	2.48	3.389 (8)	155

Symmetry code: (i) −x+1, −y, −z.

Acknowledgements

This work was supported by the Natural Science Foundation of China, National Ministry of Science and Technology of China (grant No. 2012CB224801).

References

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doi:10.1107/S1600536814006084

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