Figure 1
Molecular structure of Na2(O2CCH2Cl)2[12-MCMnIIIN(shi)-4](DMF)6·2DMF (top view). The displacement ellipsoid plot is at the 50% probability level. Atom labels for all non-H atoms on one asymmetric unit of the 12-MC-4 framework and selected symmetry-equivalent atoms have been provided. For clarity, atom labels for the axial DMF and chloroacetate ligands have been omitted; those labels may be found in Fig. 2. H atoms and the lattice solvent molecules have been omitted for clarity. Color scheme: green MnIII, yellow Na+, purple chlorine, red oxygen, blue nitrogen, and gray carbon. [Symmetry code: (ii) −x + 1, −y, −z + 1.] |