Figure 3
Cavity (left) and hydrogen-bonding linkages (right) in tetrawickmanite. (a) Wickmanite-like cavity with isolated four-membered ring motif O3—H5⋯O3 and linkages O1—H1⋯O1 at the top and bottom of the cavity. (b) Sets of <100> crankshaft-type motifs with the isolated four-membered rings lining in the plane perpendicular to the c axis. Yellow, grey and red spheres represent Mn, Sn and O atoms. Blue, purple, pink, aquamarine and orange spheres represent H1, H2, H3, H4 and H5 hydrogen atoms, respectively. |