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Crystal structure of SrGeO3 in the high-pressure perovskite-type phase

aGraduate School of Science and Engineering, Yamaguchi University, Ube 755-8611, Japan, bInstitute for Materials Research, Tohoku University, Sendai 980-8577, Japan, cGraduate School of Science, Osaka University, Toyonaka 560-0043, Japan, and dGraduate School of Science and Technology, Kumamoto University, Kumamoto 860-8555, Japan
*Correspondence e-mail: tuka@yamaguchi-u.ac.jp

Edited by M. Weil, Vienna University of Technology, Austria (Received 19 March 2015; accepted 11 April 2015; online 18 April 2015)

Single crystals of the SrGeO3 (strontium germanium trioxide) high-pressure phase have been synthesized successfully at 6 GPa and 1223 K. The compound crystallizes with the ideal cubic perovskite-type structure (space group Pm-3m), which consists of a network of corner-linked regular GeO6 octa­hedra (point-group symmetry m-3m), with the larger Sr atoms located at the centers of cavities in the form of SrO12 cubocta­hedra (point-group symmetry m-3m) in the network. The degrees of covalencies included in the Sr—O and the Ge—O bonds calculated from bond valences are 20.4 and 48.9%, respectively. Thus, the Ge—O bond of the GeO6 octa­hedron in the SrGeO3 perovskite has a strong covalency, comparable to those of the Si—O bonds of the SiO4 tetra­hedra in silicates with about 50% covalency. The thermal vibrations of the O atoms in the title compound are remarkably suppressed in the directions of the Ge—O bonds. This anisotropy ranks among the largest observed in stoichiometric cubic perovskites.

1. Chemical context

The phase transitions of the perovskite-type compounds ABO3 have long attracted much attention for various industrial applications, as represented in ferroelectric substances such as BaTiO3. The strontium germanate SrGeO3 undergoes a sequence of phase transitions at high pressures and high temperatures of pyroxenoid (pseudowollastonite) type → walstromite type → perovskite type (Shimizu et al., 1970[Shimizu, Y., Syono, Y. & Akimoto, S. (1970). High Temp. High Press. 2, 113-120.]; Akaogi et al., 2005[Akaogi, M., Kojitani, H., Yusa, H., Yamamoto, R., Kido, M. & Koyama, K. (2005). Phys. Chem. Miner. 32, 603-613.]). In a recent study (Mizoguchi et al., 2011[Mizoguchi, H., Kamiya, T., Matsuishi, S. & Hosono, H. (2011). Nat. Comms, 2, 470.]), it was reported that the high-pressure perovskite-type phase of SrGeO3 is a promising transparent electronic conductor. A detailed structural study of this perovskite-type phase is important to elucidate the origin of the conduction mechanism. Despite such importance, the high-pressure perovskite-type phase has been studied so far only on the basis of polycrystalline samples and its powder X-ray diffraction pattern has only suggested that it adopts the ideal cubic perovskite structure. Perovskite-type compounds are well-known to have various symmetries owing to a slight tilting of the BO6 octa­hedra (Glazer, 1972[Glazer, A. M. (1972). Acta Cryst. B28, 3384-3392.], 1975[Glazer, A. M. (1975). Acta Cryst. A31, 756-762.]). However, it is often difficult to determine their actual symmetries from powder X-ray diffraction techniques. Thus, more precise data based on single crystal X-ray diffraction are indispensable for the determination of the crystal structure of the SrGeO3 high-pressure perovskite-type phase. We recently succeeded in the growth of SrGeO3 perovskite-type single crystals at high pressure and high temperature. The crystal structure refined from single-crystal X-ray diffraction data is reported here.

2. Structural commentary

The high-pressure phase of SrGeO3 crystallizes with the cubic perovskite-type structure (space group Pm[\overline{3}]m). The crystal structure consists of a network of corner-linked regular GeO6 octa­hedra with the larger Sr atoms located at the centers of cavities in the network, forming SrO12 cubocta­hedra (Fig. 1[link]). As a result of the ideal symmetry, tilts and distortions of the GeO6 octa­hedra are not present. The Sr, Ge and O atoms occupy Wyckoff positions 1a (0, 0, 0), 1b (0.5, 0.5, 0.5) and 3c (0, 0.5, 0.5), respectively, without any freedom of atomic positions. The corresponding site symmetries are m[\overline{3}]m, m[\overline{3}]m and 4/mm.m, respectively. The observed Sr—O distance in the SrO12 cubocta­hedron and the Ge—O distance in the GeO6 octa­hedron are 2.6855 (1) Å and 1.8989 (1) Å, respectively, which are much shorter than the distances expected from the effective ionic radii (Sr—O = 2.84 Å, Ge—O = 1.93 Å; Shannon, 1976[Shannon, R. D. (1976). Acta Cryst. A32, 751-767.]). The ratios of covalency included in the bonds calculated from fc/s (= asM-1) are 20.4% for the Sr—O bond and 48.9% for the Ge—O bond, where fc, given by asM (Brown & Shannon, 1973[Brown, I. D. & Shannon, R. D. (1973). Acta Cryst. A29, 266-282.]), is the covalence in bonds; s is the bond valence; a and M are parameters relating covalence to bond valence. This value of the present Ge—O bond ranks among the largest in B—O bonds of BO6 octa­hedra in A2+B4+O3-type cubic perovskites (A = twelvefold-coordinated cations, B = sixfold-coordinated cations) [cf. 39.8% for the Ti—O bond in SrTiO3 (Abramov et al., 1995[Abramov, Yu. A., Tsirelson, V. G., Zavodnik, V. E., Ivanov, S. A. & Brown, I. D. (1995). Acta Cryst. B51, 942-951.]) and 37.8% for the Zr—O bond in BaZrO3 (Levin et al., 2003[Levin, I., Amos, T. G., Bell, S. M., Farber, L., Vanderah, T. A., Roth, R. S. & Toby, B. H. (2003). J. Solid State Chem. 175, 170-181.])]. It is noteworthy, thus, that the Ge—O bond of the GeO6 octa­hedron in the present crystal has a strong covalency comparable to those of the Si—O bonds of the SiO4 tetra­hedra in silicates with about 50% covalency.

[Figure 1]
Figure 1
Representation of the SrGeO3 perovskite-type structure showing corner-linked GeO6 octa­hedra.

The site-symmetry constraints require that the displacement ellipsoids of the Sr and Ge atoms are always spherical and that of the O atom is an uniaxial ellipsoid with one determinable ellipsoid-axis in the direction of the Ge—O bond and two undeterminable ones in the directions perpendicular to it. The mean-square displacement (MSD) of the O atom is the smallest [〈uS2〉 = 0.0011 (8) Å2] in the former direction and the largest [〈uL2〉 = 0.0077 (7) Å2] in the latter directions. The 〈uS2〉/〈uL2〉 ratio of 0.14 calculated for the present crystal indicates that the displacement ellipsoid of the O atom is remarkably compressed in the former directions, as shown in Fig. 2[link]. Such remarkable anisotropy is commonly observed in cubic perovskites with stoichiometric compositions, and the present 〈uS2〉/〈uL2〉 ratio ranks among the smallest observed [cf.uS2〉/〈uL2〉 = 0.14 for LaAlO3 (Nakatsuka et al., 2005[Nakatsuka, A., Ohtaka, O., Arima, H., Nakayama, N. & Mizota, T. (2005). Acta Cryst. E61, i148-i150.]), 0.43 for SrTiO3 (Abramov et al., 1995[Abramov, Yu. A., Tsirelson, V. G., Zavodnik, V. E., Ivanov, S. A. & Brown, I. D. (1995). Acta Cryst. B51, 942-951.]), 0.38 for KTaO3 (Zhurova et al., 2000[Zhurova, E. A., Ivanov, Y., Zavodnik, V. & Tsirelson, V. (2000). Acta Cryst. B56, 594-600.]), 0.50 for SrFeO3 (Hodges et al., 2000[Hodges, J. P., Short, S., Jorgensen, J. D., Xiong, X., Dabrowski, B., Mini, S. M. & Kimball, C. W. (2000). J. Solid State Chem. 151, 190-209.]) and 0.29 for BaZrO3 (Levin et al., 2003[Levin, I., Amos, T. G., Bell, S. M., Farber, L., Vanderah, T. A., Roth, R. S. & Toby, B. H. (2003). J. Solid State Chem. 175, 170-181.])]. The remarkable anisotropy of the MSD of the O atom in the SrGeO3 perovskite-type structure might be related to the strong covalency of the Ge—O bond.

[Figure 2]
Figure 2
The unit cell of the cubic SrGeO3 perovskite with displacement ellipsoids drawn at the 80% probability level.

3. Synthesis and crystallization

A polycrystalline sample of SrGeO3 pseudowollastonite as the starting material was prepared by solid-state reaction of special grade reagents SrCO3 and GeO2. The resulting SrGeO3 pseudowollastonite material was charged in a gold capsule and then put into a BN sample chamber. As shown in Fig. 3[link], the sample chamber was put between a pair of LaCrO3 disc heaters and encased in a cubic-shaped pressure-transmitting medium made of boron-ep­oxy resin. This cell assembly was compressed with a 700 ton cubic anvil-type press. After being kept at 6 GPa and 1223 K for 1 h, the product was quenched by shutting off the electric power supply. The pressure was then released slowly and the product was recovered at ambient conditions. Single crystals of SrGeO3 perovskite were found in the recovered sample, together with an unknown single-crystal phase.

[Figure 3]
Figure 3
Cell assembly used in the synthetic experiment at high pressure.

4. Refinement

The unit-cell parameters of the crystal under investigation assuming a triclinic cell only exhibit a minute deviation from a cubic unit cell [a = 3.7979 (2), b = 3.7978 (3), c = 3.7972 (3) Å, α = 89.984 (6), β = 89.997 (6), γ = 89.988 (5)°]. Systematic absences of reflections also agreed with space group Pm[\overline{3}]m. Indeed, the present crystal was satisfactorily refined in the ideal cubic perovskite structure as judged from the excellent reliability indices (Table 1[link]).

Table 1
Experimental details

Crystal data
Chemical formula SrGeO3
Mr 208.23
Crystal system, space group Cubic, Pm[\overline{3}]m
Temperature (K) 296
a (Å) 3.7978 (2)
V3) 54.78 (1)
Z 1
Radiation type Mo Kα
μ (mm−1) 37.73
Crystal size (mm) 0.10 × 0.08 × 0.08
 
Data collection
Diffractometer Rigaku AFC-7R
Absorption correction ψ scan (North et al., 1968[North, A. C. T., Phillips, D. C. & Mathews, F. S. (1968). Acta Cryst. A24, 351-359.])
Tmin, Tmax 0.037, 0.049
No. of measured, independent and observed [F > 3σ(F)] reflections 521, 116, 66
Rint 0.023
(sin θ/λ)max−1) 1.219
 
Refinement
R[F > 3σ(F)], wR(F), S 0.011, 0.010, 1.95
No. of reflections 64
No. of parameters 6
Δρmax, Δρmin (e Å−3) 1.04, −1.38
Computer programs: WinAFC (Rigaku, 1999[Rigaku (1999). WinAFC. Rigaku Corporation, Tokyo, Japan.]), RADY (Sasaki, 1987[Sasaki, S. (1987). RADY. National Laboratory for High Energy Physics, Japan.]), ATOMS for Windows (Dowty, 2000[Dowty, E. (2000). ATOMS for Windows. Shape Software, Kingsport, Tennessee, USA.]) and publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).

Intensity data were averaged in Laue symmetry m[\overline{3}]m to give 116 independent reflections. Of these, independent reflections with Fo [\leq] 3σ(Fo) were omitted for refinement. Even if independent reflections had intensities of Fo > 3σ(Fo) after averaging, those averaged from a data set of equivalent reflections including reflection(s) with Fo [\leq] 3σ(Fo) were also discarded since these reflections were potentially affected by multiple diffraction. Moreover, independent reflections with (sin θ)/λ < 0.220 Å−1 were eliminated to reduce secondary extinction effects and to avoid dependence on atomic charge as far as possible in the choice of atomic scattering factors. Finally, 64 independent reflections were used in the present refinement. Several correction models for the secondary extinction effects were attempted during the refinement, and the isotropic correction of Type I (Becker & Coppens, 1974a[Becker, P. J. & Coppens, P. (1974a). Acta Cryst. A30, 129-147.],b[Becker, P. J. & Coppens, P. (1974b). Acta Cryst. A30, 148-153.]) with a Gaussian mosaic spread distribution model yielded the best fits. Crystal data, data collection and structure refinement details are summarized in Table 1[link].

Supporting information


Computing details top

Data collection: WinAFC (Rigaku, 1999); cell refinement: WinAFC (Rigaku, 1999); data reduction: RADY (Sasaki, 1987); program(s) used to refine structure: RADY (Sasaki, 1987); molecular graphics: ATOMS for Windows (Dowty, 2000); software used to prepare material for publication: publCIF (Westrip, 2010).

Strontium germanium trioxide top
Crystal data top
SrGeO3Dx = 6.315 Mg m3
Mr = 208.23Mo Kα radiation, λ = 0.71069 Å
Cubic, Pm3mCell parameters from 25 reflections
Hall symbol: -P 4 2 3θ = 21.5–25.0°
a = 3.7978 (2) ŵ = 37.73 mm1
V = 54.78 (1) Å3T = 296 K
Z = 1Fragment, colorless
F(000) = 940.10 × 0.08 × 0.08 mm
Data collection top
Rigaku AFC-7R
diffractometer
Rint = 0.023
ω–2θ scansθmax = 60.0°
Absorption correction: ψ scan
(North et al., 1968)
h = 09
Tmin = 0.037, Tmax = 0.049k = 09
521 measured reflectionsl = 09
116 independent reflections3 standard reflections every 150 reflections
66 reflections with F > 3.0σ(F) intensity decay: none
Refinement top
Refinement on FWeighting scheme based on measured s.u.'s w = 1/σ2(F)
R[F2 > 2σ(F2)] = 0.019(Δ/σ)max < 0.001
wR(F2) = 0.020Δρmax = 1.04 e Å3
S = 1.95Δρmin = 1.38 e Å3
64 reflectionsExtinction correction: isotropic Type I (Becker & Coppens, 1974a,b)
6 parametersExtinction coefficient: 0.40 (1)E3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sr0.00000.00000.00000.00300 (9)
Ge0.50000.50000.50000.00182 (9)
O0.00000.50000.50000.0055 (7)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sr0.0030 (2)0.00300.00300.00000.00000.0000
Ge0.0018 (2)0.00180.00180.00000.00000.0000
O0.0011 (8)0.0077 (7)0.00770.00000.00000.0000
Geometric parameters (Å, º) top
Sr—O2.6855 (1)Ge—Oi1.8989 (1)
Sr—Oi2.6855 (1)Ge—Oii1.8989 (1)
Sr—Oii2.6855 (1)Ge—Oxii1.8989 (1)
Sr—Oiii2.6855 (1)Ge—Oxiii1.8989 (1)
Sr—Oiv2.6855 (1)Ge—Oxiv1.8989 (1)
Sr—Ov2.6855 (1)O—Oi2.6855 (1)
Sr—Ovi2.6855 (1)O—Oii2.6855 (1)
Sr—Ovii2.6855 (1)O—Ov2.6855 (1)
Sr—Oviii2.6855 (1)O—Ovi2.6855 (1)
Sr—Oix2.6855 (1)O—Oxv2.6855 (1)
Sr—Ox2.6855 (1)O—Oxvi2.6855 (1)
Sr—Oxi2.6855 (1)O—Oxii2.6855 (1)
Ge—O1.8989 (1)O—Oxiii2.6855 (1)
O—Sr—Oi60.00Sr—O—Ovi60.00
O—Sr—Oii60.00Sr—O—Oxv120.00
O—Sr—Oiii120.00Sr—O—Oxvi120.00
O—Sr—Oiv120.00Sr—O—Oxii120.00
O—Sr—Ov60.00Sr—O—Oxiii120.00
O—Sr—Ovi60.00Ge—O—Gexx180.00
O—Sr—Ovii180.00Ge—O—Oi45.00
O—Sr—Oviii90.00Ge—O—Oii45.00
O—Sr—Oix120.00Ge—O—Ov135.00
O—Sr—Ox90.00Ge—O—Ovi135.00
O—Sr—Oxi120.00Ge—O—Oxv135.00
O—Sri—Oii60.00Ge—O—Oxvi135.00
O—Sri—Oiii120.00Ge—O—Oxii45.00
O—Srii—Oiv120.00Ge—O—Oxiii45.00
O—Ge—Oi90.00Ge—Oxx—Ov45.00
O—Ge—Oii90.00Ge—Oxx—Ovi45.00
O—Ge—Oxii90.00Ge—Oxx—Oxv45.00
O—Ge—Oxiii90.00Ge—Oxx—Oxvi45.00
O—Ge—Oxiv180.00O—Oi—Oii60.00
O—Gei—Oii90.00O—Oi—Oxvi180.00
O—Gei—Oxii90.00O—Oi—Oxii60.00
O—Geii—Oxiii90.00O—Oii—Oxv180.00
Sr—O—Srxvii90.00O—Oii—Oxiii60.00
Sr—O—Srxviii90.00O—Ov—Ovi60.00
Sr—O—Srxix180.00O—Ov—Oxv60.00
Sr—O—Ge90.00O—Ov—Oxiii180.00
Sr—O—Gexx90.00O—Ovi—Oxvi60.00
Sr—O—Oi60.00O—Ovi—Oxii180.00
Sr—O—Oii60.00O—Oxv—Oxvi60.00
Sr—O—Ov60.00O—Oxii—Oxiii60.00
Symmetry codes: (i) z, x, y; (ii) y, z, x; (iii) y1, z1, x; (iv) z1, x, y1; (v) z1, x, y; (vi) y1, z, x; (vii) x, y1, z1; (viii) x, y1, z; (ix) y, z1, x; (x) x, y, z1; (xi) z, x, y1; (xii) y, z, x+1; (xiii) z, x+1, y; (xiv) x+1, y, z; (xv) y1, z, x+1; (xvi) z1, x+1, y; (xvii) x, y, z+1; (xviii) x, y+1, z; (xix) x, y+1, z+1; (xx) x1, y, z.
 

Acknowledgements

This work was partly performed under research project No. 2010G608 at Photon Factory BL-10 A, High Energy Accelerator Research Organization, Tsukuba, Japan. We thank R. Takagaki, F. Yachi and Y. Tashima of Yamaguchi University for their experimental assistance.

References

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