Crystal structure of bis­{1-[(E)-(2-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ3O,N2,O′}copper(II) containing an unknown solvate

Chetioui, S.; Hamdouni, N.; Rouag, D.-A.; Bouaoud, S.E.; Merazig, H.

doi:10.1107/S2056989015019817

metal-organic compounds

CRYSTALLOGRAPHIC
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ISSN: 2056-9890

Volume 71| Part 11| November 2015| Pages m207-m208

https://doi.org/10.1107/S2056989015019817

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Crystal structure of bis{1-[(E)-(2-methoxyphenyl)diazenyl]naphthalen-2-olato-κ³O,N²,O′}copper(II) containing an unknown solvate

Souheyla Chetioui,^a ^* Noudjoud Hamdouni,^b Djamil-Azzeddine Rouag,^a Salah Eddine Bouaoud ^a and Hocine Merazig ^a

^aUnité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1, Constantine 25000, Algeria, and ^bLaboratoire de Cristallographie, Département de Physique, Université Constantine 1, Constantine 25000, Algeria
^*Correspondence e-mail: souheilachetioui@yahoo.fr

Edited by A. M. Chippindale, University of Reading, England (Received 20 September 2015; accepted 20 October 2015; online 31 October 2015)

The title complex, [Cu(C₁₇H₁₃N₂O₂)₂], crystallizes with two independent molecules in the asymmetric unit. Each Cu^II atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-methoxyphenyl)diazenyl]naphthalen-2-olate ligands. In the crystal, the two molecules are linked via weak C—H⋯O hydrogen bonds which in turn stack parallel to [010]. A region of disordered electron density, most probably disordered methanol solvent molecules, was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Acta Cryst. C71, 9–18]. Their formula mass and unit-cell characteristics were not taken into account during refinement.

Keywords: crystal structure; naphthalen-2-olate; copper(II) complex; octahedral coordination; azo compounds.

CCDC reference: 1432227

1. Related literature

For applications of azo compounds, see: Millington et al. (2007 ); Hallas & Choi (1999 ); Ho et al. (1995 ); Sharma et al. (2008 ). For related structures, see: Tai et al. (2010 ); Lin et al. (2010 ).

2. Experimental

2.1. Crystal data

[Cu(C₁₇H₁₃N₂O₂)₂]
M_r = 618.13
Monoclinic P 2₁ /c
a = 29.749 (2) Å
b = 12.5171 (9) Å
c = 15.3565 (12) Å
β = 92.969 (5)°
V = 5710.7 (8) Å³
Z = 8
Mo Kα radiation
μ = 0.81 mm⁻¹
T = 100 K
0.02 × 0.01 × 0.01 mm

2.2. Data collection

Bruker APEXII diffractometer
76488 measured reflections
20125 independent reflections
9009 reflections with I > 2σ(I)
R_int = 0.122

2.3. Refinement

R[F² > 2σ(F²)] = 0.074
wR(F²) = 0.168
S = 1.01
20125 reflections
775 parameters
H-atom parameters constrained
Δρ_max = 0.55 e Å⁻³
Δρ_min = −1.01 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C3B—H3B⋯O4A	0.93	2.48	3.270 (5)	143

Data collection: APEX2 (Bruker, 2006 ); cell refinement: APEX2; data reduction: APEX2; program(s) used to solve structure: SIR92 (Giacovazzo et al., 1992 ); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015 ); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012 ); software used to prepare material for publication: WinGX (Farrugia, 2012) and SQUEEZE in PLATON (Spek, 2015 ).

Supporting information

CCDC reference: 1432227

Crystal structure: contains datablocks Chetioui_enrt_0m, I. DOI: https://doi.org/10.1107/S2056989015019817/cq2017sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989015019817/cq2017Isup2.hkl

checkCIF report

Comment top

Azo compounds are highly colored and commonly utilized in textile industries (Millington et al., 2007; Hallas & Choi, 1999), optical data storage (Ho et al.,1995) and as sensitizers in dye-sensitized solar cells (DSSCs)(Sharma et al.,2008). In previous work, the chelating ligand, (E)-1-(o-tolyldiazenyl)naphthalen-2-ol, has been used to form complexes on reaction with Cu(OAc)₂·H₂O (Tai et al., 2010) and Pd(OAc)₂ (Lin et al., 2010). Herein, we report the synthesis and crystal structure of a novel copper(II) complex formed on reaction of a similar azoic ligand, (E)-1-((2-methoxyphenyl)diazenyl)naphthalen-2-ol (C₁₇H₁₄N₂O₂), with Cu(OAc)₂·H₂O.

The molecular structure of the title compound is shown in Figure 1. There are two independent molecules (A and B) in the asymmetric unit, each consisting of a Cu^II atom coordinated by two N atoms and four O atoms from two tridentate (E)-1-((2-methoxyphenyl)diazenyl)naphthalen-2-ol ligands. The octahedral geometry formed around the Cu^II atom (Table 1) is distorted from the ideal due to the Jahn-Teller effect.

Within each molecule, there are C—H···N interactions (Table 1). In the crystal, the two independent molecules are linked via weak C—H····O hydrogen bonds (Table 1). These pairs of molecules then stack to form bi-dimensional molecular chains running parallel to [010], as shown in Figure 2.

Related literature top

For applications of azo compounds, see: Millington et al. (2007); Hallas & Choi (1999); Ho et al.(1995); Sharma et al. (2008). For related structures, see: Tai et al. (2010); Lin et al. (2010).

Experimental top

The title compound (I) was synthesized by the following procedure: (E)-1-((2-methoxyphenyl)diazenyl)naphthalen-2-ol (0.55 g, 2.0 mmol) and Cu(OAc)₂·H₂O (0.20 g, 1.0 mmol) were stirred at 298 K in methanol (10 ml) for 48 h. Volatile materials were removed under vacuum and the residue was washed twice with CH₂Cl₂/hexane (1:5) solution to give a dark solid. Black crystals of the title compound were formed on recrystallization in CH₂Cl₂.

Structure description top

For applications of azo compounds, see: Millington et al. (2007); Hallas & Choi (1999); Ho et al.(1995); Sharma et al. (2008). For related structures, see: Tai et al. (2010); Lin et al. (2010).

Computing details top

Data collection: APEX2 (Bruker, 2006); cell refinement: APEX2 (Bruker, 2006); data reduction: APEX2 (Bruker, 2006); program(s) used to solve structure: SIR92 (Giacovazzo et al., 1992); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012); software used to prepare material for publication: WinGX (Farrugia, 2012) and SQUEEZE in PLATON (Spek, 2015).

Figures top

	Fig. 1. The molecular structure of (I), with displacement ellipsoids for non-H atoms shown at 50% probability.
	Fig. 2. Partial view along the b axis of the crystal packing of the title compound.

Bis{1-[(E)-(2-methoxyphenyl)diazenyl]naphthalen-2-olato-κ³O,N²,O'}copper(II) top

Crystal data top

[Cu(C₁₇H₁₃N₂O₂)₂]	F(000) = 2552
M_r = 618.13	D_x = 1.438 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 2052 reflections
a = 29.749 (2) Å	θ = 3.1–28.6°
b = 12.5171 (9) Å	µ = 0.81 mm⁻¹
c = 15.3565 (12) Å	T = 100 K
β = 92.969 (5)°	Block, black
V = 5710.7 (8) Å³	0.02 × 0.01 × 0.01 mm
Z = 8

Data collection top

Bruker APEXII diffractometer	9009 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	R_int = 0.122
Graphite monochromator	θ_max = 32.3°, θ_min = 2.2°
CCD rotation images, thin slices ω scans	h = −44→44
76488 measured reflections	k = −16→18
20125 independent reflections	l = −21→23

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.074	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.168	H-atom parameters constrained
S = 1.01	w = 1/[σ²(F_o²) + (0.0532P)² + 4.1986P] where P = (F_o² + 2F_c²)/3
20125 reflections	(Δ/σ)_max < 0.001
775 parameters	Δρ_max = 0.55 e Å⁻³
0 restraints	Δρ_min = −1.01 e Å⁻³

Crystal data top

[Cu(C₁₇H₁₃N₂O₂)₂]	V = 5710.7 (8) Å³
M_r = 618.13	Z = 8
Monoclinic, P2₁/c	Mo Kα radiation
a = 29.749 (2) Å	µ = 0.81 mm⁻¹
b = 12.5171 (9) Å	T = 100 K
c = 15.3565 (12) Å	0.02 × 0.01 × 0.01 mm
β = 92.969 (5)°

Data collection top

Bruker APEXII diffractometer	9009 reflections with I > 2σ(I)
76488 measured reflections	R_int = 0.122
20125 independent reflections

Refinement top

R[F² > 2σ(F²)] = 0.074	0 restraints
wR(F²) = 0.168	H-atom parameters constrained
S = 1.01	Δρ_max = 0.55 e Å⁻³
20125 reflections	Δρ_min = −1.01 e Å⁻³
775 parameters

Special details top

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Cu1A	0.16768 (2)	0.07675 (3)	0.64956 (3)	0.0232 (1)
Cu1B	0.39838 (2)	−0.19075 (3)	0.89627 (3)	0.0326 (2)
O1A	0.16618 (9)	0.21278 (19)	0.52348 (17)	0.0337 (9)
O2A	0.20122 (8)	−0.05309 (18)	0.63672 (17)	0.0299 (8)
O3A	0.10965 (8)	−0.02672 (19)	0.75606 (17)	0.0317 (8)
O4A	0.21587 (8)	0.14849 (18)	0.71091 (16)	0.0259 (7)
N1A	0.12605 (9)	0.0277 (2)	0.55555 (18)	0.0230 (9)
N2A	0.11374 (9)	−0.0690 (2)	0.53966 (18)	0.0245 (9)
N3A	0.12467 (9)	0.1701 (2)	0.70536 (18)	0.0199 (8)
N4A	0.13093 (9)	0.2621 (2)	0.73992 (18)	0.0209 (8)
C1A	0.10128 (12)	0.1064 (3)	0.5062 (2)	0.0241 (11)
O1B	0.33502 (10)	−0.1213 (2)	0.77943 (17)	0.0401 (10)
C2A	0.12232 (12)	0.2030 (3)	0.4912 (2)	0.0273 (11)
O2B	0.42588 (9)	−0.32864 (19)	0.88982 (18)	0.0375 (9)
C3A	0.09907 (14)	0.2836 (3)	0.4443 (2)	0.0335 (12)
O3B	0.41311 (12)	−0.1922 (2)	1.06631 (19)	0.0529 (11)
C4A	0.05525 (14)	0.2654 (3)	0.4142 (2)	0.0377 (14)
O4B	0.44442 (10)	−0.12394 (19)	0.83389 (18)	0.0398 (9)
C5A	0.03422 (13)	0.1695 (3)	0.4281 (2)	0.0358 (12)
C6A	0.05760 (12)	0.0891 (3)	0.4741 (2)	0.0296 (12)
C7A	0.13682 (12)	−0.1512 (3)	0.5794 (2)	0.0245 (11)
C8A	0.17995 (13)	−0.1418 (3)	0.6235 (2)	0.0281 (11)
C9A	0.20128 (14)	−0.2385 (3)	0.6544 (3)	0.0352 (12)
C10A	0.18092 (15)	−0.3349 (3)	0.6458 (3)	0.0388 (14)
C11A	0.13786 (14)	−0.3473 (3)	0.6018 (2)	0.0323 (11)
C12A	0.11583 (13)	−0.2555 (3)	0.5668 (2)	0.0276 (11)
C13A	0.07372 (13)	−0.2685 (3)	0.5231 (2)	0.0322 (12)
C14A	0.05408 (15)	−0.3673 (3)	0.5138 (3)	0.0414 (16)
C15A	0.07519 (15)	−0.4576 (3)	0.5488 (3)	0.0437 (16)
C16A	0.11664 (15)	−0.4483 (3)	0.5921 (3)	0.0386 (14)
C17A	0.19126 (13)	0.3024 (3)	0.4981 (3)	0.0413 (14)
C18A	0.07892 (11)	0.1361 (3)	0.7077 (2)	0.0214 (10)
C19A	0.07148 (12)	0.0310 (3)	0.7350 (2)	0.0272 (11)
C20A	0.02787 (13)	−0.0053 (3)	0.7408 (3)	0.0375 (14)
C21A	−0.00766 (13)	0.0621 (3)	0.7191 (3)	0.0435 (15)
C22A	−0.00064 (13)	0.1652 (3)	0.6906 (3)	0.0385 (14)
C23A	0.04326 (12)	0.2023 (3)	0.6857 (2)	0.0281 (11)
C24A	0.17326 (11)	0.3020 (3)	0.7538 (2)	0.0200 (10)
C25A	0.21382 (12)	0.2433 (3)	0.7440 (2)	0.0239 (10)
C26A	0.25519 (11)	0.2914 (3)	0.7758 (2)	0.0263 (11)
C27A	0.25627 (12)	0.3900 (3)	0.8121 (2)	0.0287 (11)
C28A	0.21688 (11)	0.4523 (3)	0.8219 (2)	0.0241 (10)
C29A	0.17510 (11)	0.4079 (3)	0.7938 (2)	0.0206 (10)
C30A	0.13577 (12)	0.4678 (3)	0.8058 (2)	0.0258 (11)
C31A	0.13853 (13)	0.5680 (3)	0.8430 (2)	0.0298 (11)
C32A	0.18007 (13)	0.6118 (3)	0.8693 (2)	0.0308 (11)
C33A	0.21841 (13)	0.5555 (3)	0.8589 (2)	0.0302 (11)
C34A	0.10465 (15)	−0.1339 (3)	0.7874 (3)	0.0422 (16)
N1B	0.33990 (10)	−0.2579 (2)	0.91158 (18)	0.0262 (9)
N2B	0.33177 (10)	−0.3523 (2)	0.93963 (18)	0.0244 (9)
N3B	0.38421 (11)	−0.0532 (2)	0.94794 (19)	0.0312 (10)
N4B	0.38770 (10)	0.0405 (2)	0.91424 (19)	0.0290 (10)
C1B	0.30027 (13)	−0.1936 (3)	0.8996 (2)	0.0271 (11)
C2B	0.29852 (14)	−0.1203 (3)	0.8302 (2)	0.0320 (13)
C3B	0.26207 (16)	−0.0518 (3)	0.8190 (3)	0.0426 (14)
C4B	0.22736 (15)	−0.0582 (3)	0.8740 (3)	0.0456 (16)
C5B	0.22840 (15)	−0.1309 (3)	0.9410 (3)	0.0427 (16)
C6B	0.26509 (13)	−0.1983 (3)	0.9542 (3)	0.0321 (11)
C7B	0.36599 (12)	−0.4239 (3)	0.9547 (2)	0.0237 (10)
C8B	0.41092 (13)	−0.4115 (3)	0.9292 (2)	0.0294 (11)
C9B	0.44149 (13)	−0.4989 (3)	0.9475 (3)	0.0366 (14)
C10B	0.42835 (14)	−0.5886 (3)	0.9872 (3)	0.0372 (12)
C11B	0.38393 (13)	−0.6047 (3)	1.0121 (2)	0.0296 (11)
C12B	0.35182 (12)	−0.5231 (3)	0.9956 (2)	0.0250 (10)
C13B	0.30741 (14)	−0.5394 (3)	1.0198 (2)	0.0312 (11)
C14B	0.29580 (15)	−0.6325 (3)	1.0607 (2)	0.0379 (14)
C15B	0.32742 (17)	−0.7124 (3)	1.0774 (3)	0.0440 (14)
C16B	0.37014 (16)	−0.6997 (3)	1.0526 (3)	0.0418 (14)
C17B	0.33199 (18)	−0.0546 (4)	0.7037 (3)	0.0554 (18)
C18B	0.36165 (14)	−0.0562 (3)	1.0280 (2)	0.0328 (13)
C19B	0.37675 (17)	−0.1327 (3)	1.0892 (3)	0.0431 (14)
C20B	0.3548 (2)	−0.1444 (4)	1.1660 (3)	0.0578 (19)
C21B	0.3191 (2)	−0.0810 (4)	1.1818 (3)	0.064 (2)
C22B	0.30399 (18)	−0.0044 (3)	1.1220 (3)	0.0541 (18)
C23B	0.32578 (15)	0.0080 (3)	1.0446 (3)	0.0408 (14)
C24B	0.41257 (12)	0.0529 (3)	0.8422 (2)	0.0269 (11)
C25B	0.44239 (13)	−0.0247 (3)	0.8100 (2)	0.0311 (11)
C26B	0.47397 (13)	0.0098 (3)	0.7488 (3)	0.0357 (11)
C27B	0.47482 (13)	0.1117 (3)	0.7195 (2)	0.0323 (12)
C28B	0.44358 (12)	0.1905 (3)	0.7450 (2)	0.0251 (10)
C29B	0.41151 (12)	0.1612 (3)	0.8060 (2)	0.0235 (10)
C30B	0.38008 (12)	0.2379 (3)	0.8295 (2)	0.0280 (11)
C31B	0.38085 (13)	0.3392 (3)	0.7941 (3)	0.0317 (11)
C32B	0.41280 (13)	0.3679 (3)	0.7359 (2)	0.0301 (11)
C33B	0.44360 (13)	0.2955 (3)	0.7117 (2)	0.0315 (12)
C34B	0.4358 (2)	−0.2576 (5)	1.1305 (4)	0.079 (2)
H3A	0.11300	0.34840	0.43360	0.0400*
H4A	0.03960	0.31920	0.38390	0.0450*
H5A	0.00470	0.15850	0.40710	0.0430*
H6A	0.04380	0.02370	0.48320	0.0350*
H9A	0.23000	−0.23480	0.68100	0.0420*
H10A	0.19540	−0.39490	0.66940	0.0470*
H13A	0.05870	−0.20890	0.49990	0.0390*
H14A	0.02630	−0.37390	0.48370	0.0500*
H15A	0.06140	−0.52410	0.54310	0.0530*
H16A	0.13090	−0.50890	0.61530	0.0460*
H17A	0.22100	0.29900	0.52520	0.0620*
H17B	0.19310	0.30240	0.43580	0.0620*
H17C	0.17670	0.36660	0.51590	0.0620*
H20A	0.02250	−0.07470	0.75920	0.0450*
H21A	−0.03700	0.03760	0.72370	0.0520*
H22A	−0.02490	0.20920	0.67500	0.0460*
H23A	0.04850	0.27190	0.66760	0.0340*
H26A	0.28200	0.25400	0.77130	0.0320*
H27A	0.28390	0.41810	0.83150	0.0350*
H30A	0.10780	0.43960	0.78850	0.0310*
H31A	0.11240	0.60670	0.85060	0.0360*
H32A	0.18150	0.67960	0.89410	0.0370*
H33A	0.24610	0.58530	0.87640	0.0360*
H34A	0.13380	−0.16480	0.79960	0.0640*
H34B	0.08830	−0.13280	0.83970	0.0640*
H34C	0.08840	−0.17570	0.74380	0.0640*
H3B	0.26120	−0.00170	0.77430	0.0510*
H4B	0.20280	−0.01280	0.86590	0.0550*
H5B	0.20450	−0.13490	0.97750	0.0520*
H6B	0.26590	−0.24680	1.00010	0.0380*
H9B	0.47110	−0.49310	0.93150	0.0440*
H10B	0.44950	−0.64220	0.99880	0.0440*
H13B	0.28580	−0.48700	1.00820	0.0370*
H14B	0.26640	−0.64200	1.07730	0.0450*
H15B	0.31930	−0.77460	1.10570	0.0530*
H16B	0.39080	−0.75470	1.06250	0.0500*
H17D	0.35910	−0.06100	0.67280	0.0830*
H17E	0.30670	−0.07630	0.66650	0.0830*
H17F	0.32810	0.01840	0.72110	0.0830*
H20B	0.36450	−0.19550	1.20670	0.0700*
H21B	0.30450	−0.08910	1.23350	0.0760*
H22B	0.27950	0.03840	1.13350	0.0650*
H23B	0.31600	0.05960	1.00430	0.0490*
H26B	0.49450	−0.03910	0.72860	0.0430*
H27B	0.49670	0.13110	0.68130	0.0390*
H30B	0.35860	0.22050	0.86910	0.0340*
H31B	0.35950	0.38900	0.80960	0.0380*
H32B	0.41310	0.43690	0.71350	0.0360*
H33B	0.46500	0.31520	0.67260	0.0380*
H34D	0.46030	−0.29410	1.10510	0.1180*
H34E	0.44720	−0.21380	1.17800	0.1180*
H34F	0.41510	−0.30900	1.15190	0.1180*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Cu1A	0.0208 (2)	0.0217 (2)	0.0270 (2)	0.0036 (2)	0.0015 (2)	−0.0017 (2)
Cu1B	0.0482 (3)	0.0193 (2)	0.0317 (3)	−0.0050 (2)	0.0153 (2)	0.0016 (2)
O1A	0.0329 (15)	0.0269 (14)	0.0412 (16)	−0.0035 (11)	0.0016 (13)	0.0066 (12)
O2A	0.0243 (13)	0.0241 (13)	0.0410 (16)	0.0042 (11)	−0.0008 (12)	−0.0036 (11)
O3A	0.0276 (14)	0.0257 (13)	0.0420 (16)	−0.0005 (11)	0.0050 (12)	0.0062 (12)
O4A	0.0198 (12)	0.0252 (12)	0.0323 (14)	0.0055 (10)	−0.0014 (11)	−0.0037 (11)
N1A	0.0249 (15)	0.0220 (15)	0.0221 (15)	0.0021 (12)	0.0028 (12)	0.0010 (12)
N2A	0.0259 (15)	0.0237 (15)	0.0242 (15)	0.0022 (13)	0.0040 (12)	−0.0052 (12)
N3A	0.0174 (14)	0.0203 (14)	0.0222 (15)	−0.0009 (11)	0.0027 (12)	0.0004 (11)
N4A	0.0186 (14)	0.0209 (14)	0.0236 (15)	−0.0004 (12)	0.0053 (12)	0.0023 (12)
C1A	0.0278 (19)	0.0244 (18)	0.0205 (18)	0.0045 (15)	0.0057 (15)	0.0004 (14)
O1B	0.062 (2)	0.0337 (15)	0.0253 (14)	0.0052 (14)	0.0095 (14)	0.0089 (12)
C2A	0.030 (2)	0.0293 (19)	0.0229 (19)	0.0050 (16)	0.0051 (16)	−0.0021 (15)
O2B	0.0415 (16)	0.0250 (14)	0.0476 (17)	−0.0048 (12)	0.0188 (14)	0.0020 (12)
C3A	0.047 (2)	0.028 (2)	0.026 (2)	0.0077 (18)	0.0069 (18)	0.0006 (16)
O3B	0.081 (2)	0.0451 (18)	0.0324 (17)	0.0039 (17)	0.0005 (16)	0.0106 (14)
C4A	0.047 (3)	0.040 (2)	0.026 (2)	0.018 (2)	0.0022 (19)	0.0026 (17)
O4B	0.0539 (18)	0.0217 (13)	0.0459 (17)	0.0025 (13)	0.0224 (14)	0.0108 (12)
C5A	0.032 (2)	0.046 (2)	0.029 (2)	0.0153 (19)	−0.0009 (17)	−0.0020 (18)
C6A	0.030 (2)	0.031 (2)	0.028 (2)	0.0048 (16)	0.0026 (16)	−0.0051 (16)
C7A	0.031 (2)	0.0194 (17)	0.0234 (18)	0.0014 (15)	0.0051 (15)	−0.0032 (14)
C8A	0.036 (2)	0.0242 (19)	0.0243 (19)	0.0077 (16)	0.0049 (16)	−0.0071 (15)
C9A	0.039 (2)	0.027 (2)	0.039 (2)	0.0142 (18)	−0.0026 (18)	−0.0011 (17)
C10A	0.056 (3)	0.026 (2)	0.034 (2)	0.0132 (19)	−0.002 (2)	−0.0044 (17)
C11A	0.043 (2)	0.0247 (19)	0.030 (2)	0.0051 (17)	0.0086 (18)	−0.0039 (16)
C12A	0.038 (2)	0.0255 (19)	0.0200 (18)	0.0023 (16)	0.0089 (16)	−0.0042 (14)
C13A	0.032 (2)	0.032 (2)	0.033 (2)	0.0043 (17)	0.0064 (18)	−0.0031 (17)
C14A	0.043 (3)	0.036 (2)	0.046 (3)	−0.003 (2)	0.009 (2)	−0.009 (2)
C15A	0.054 (3)	0.029 (2)	0.049 (3)	−0.012 (2)	0.011 (2)	−0.0098 (19)
C16A	0.057 (3)	0.0210 (19)	0.039 (2)	0.0036 (18)	0.014 (2)	−0.0021 (17)
C17A	0.033 (2)	0.034 (2)	0.057 (3)	−0.0068 (18)	0.004 (2)	0.009 (2)
C18A	0.0191 (17)	0.0231 (17)	0.0223 (17)	−0.0023 (14)	0.0046 (14)	−0.0065 (14)
C19A	0.0253 (19)	0.0302 (19)	0.0265 (19)	−0.0021 (16)	0.0043 (16)	−0.0079 (15)
C20A	0.033 (2)	0.033 (2)	0.047 (3)	−0.0105 (18)	0.0069 (19)	−0.0050 (19)
C21A	0.0205 (19)	0.049 (3)	0.061 (3)	−0.0148 (19)	0.0031 (19)	−0.016 (2)
C22A	0.022 (2)	0.044 (2)	0.049 (3)	0.0046 (18)	−0.0024 (18)	−0.013 (2)
C23A	0.0256 (19)	0.0271 (19)	0.031 (2)	0.0011 (16)	−0.0035 (16)	−0.0065 (16)
C24A	0.0196 (17)	0.0198 (16)	0.0207 (17)	−0.0013 (14)	0.0010 (14)	0.0018 (13)
C25A	0.0253 (18)	0.0264 (18)	0.0202 (18)	0.0013 (15)	0.0028 (15)	0.0030 (14)
C26A	0.0171 (17)	0.032 (2)	0.030 (2)	0.0020 (15)	0.0024 (15)	−0.0008 (16)
C27A	0.0215 (18)	0.033 (2)	0.032 (2)	−0.0058 (15)	0.0047 (16)	−0.0006 (16)
C28A	0.0243 (18)	0.0280 (18)	0.0204 (17)	−0.0064 (15)	0.0052 (14)	0.0011 (14)
C29A	0.0250 (17)	0.0215 (17)	0.0154 (16)	−0.0040 (14)	0.0032 (14)	0.0015 (13)
C30A	0.0234 (18)	0.0249 (18)	0.029 (2)	−0.0061 (15)	0.0013 (15)	−0.0014 (15)
C31A	0.032 (2)	0.0270 (19)	0.031 (2)	0.0040 (17)	0.0083 (16)	−0.0007 (16)
C32A	0.035 (2)	0.0274 (19)	0.030 (2)	−0.0083 (17)	0.0018 (17)	−0.0073 (16)
C33A	0.032 (2)	0.032 (2)	0.0266 (19)	−0.0077 (17)	0.0028 (16)	−0.0035 (16)
C34A	0.053 (3)	0.030 (2)	0.045 (3)	0.001 (2)	0.016 (2)	0.0089 (19)
N1B	0.0393 (18)	0.0193 (14)	0.0204 (15)	−0.0003 (13)	0.0059 (13)	0.0026 (12)
N2B	0.0352 (17)	0.0185 (14)	0.0195 (15)	−0.0012 (13)	0.0004 (13)	0.0033 (12)
N3B	0.046 (2)	0.0238 (16)	0.0246 (16)	−0.0053 (14)	0.0101 (15)	0.0012 (13)
N4B	0.0372 (18)	0.0228 (15)	0.0277 (17)	−0.0073 (13)	0.0093 (14)	0.0008 (13)
C1B	0.034 (2)	0.0208 (17)	0.0264 (19)	0.0017 (16)	−0.0001 (16)	−0.0059 (15)
C2B	0.050 (3)	0.0202 (18)	0.025 (2)	0.0039 (17)	−0.0042 (18)	0.0014 (15)
C3B	0.067 (3)	0.026 (2)	0.033 (2)	0.002 (2)	−0.016 (2)	−0.0009 (17)
C4B	0.046 (3)	0.033 (2)	0.056 (3)	0.015 (2)	−0.014 (2)	−0.007 (2)
C5B	0.041 (3)	0.038 (2)	0.049 (3)	0.003 (2)	0.001 (2)	−0.013 (2)
C6B	0.037 (2)	0.0258 (19)	0.033 (2)	−0.0012 (17)	−0.0021 (18)	−0.0051 (16)
C7B	0.0325 (19)	0.0178 (16)	0.0205 (17)	−0.0008 (15)	0.0000 (15)	0.0008 (14)
C8B	0.038 (2)	0.0217 (18)	0.029 (2)	−0.0043 (16)	0.0055 (17)	−0.0013 (15)
C9B	0.031 (2)	0.033 (2)	0.046 (3)	0.0019 (18)	0.0036 (19)	0.0016 (18)
C10B	0.042 (2)	0.030 (2)	0.039 (2)	0.0066 (18)	−0.0032 (19)	0.0049 (18)
C11B	0.044 (2)	0.0201 (18)	0.0240 (19)	−0.0012 (16)	−0.0051 (17)	0.0027 (14)
C12B	0.038 (2)	0.0179 (17)	0.0190 (17)	−0.0040 (15)	0.0020 (16)	−0.0022 (14)
C13B	0.045 (2)	0.0281 (19)	0.0208 (18)	−0.0070 (17)	0.0040 (17)	−0.0022 (15)
C14B	0.056 (3)	0.030 (2)	0.029 (2)	−0.015 (2)	0.0139 (19)	−0.0025 (17)
C15B	0.076 (3)	0.023 (2)	0.034 (2)	−0.013 (2)	0.012 (2)	−0.0007 (17)
C16B	0.069 (3)	0.023 (2)	0.033 (2)	0.003 (2)	−0.001 (2)	0.0083 (17)
C17B	0.077 (4)	0.057 (3)	0.032 (2)	−0.009 (3)	0.000 (2)	0.018 (2)
C18B	0.053 (3)	0.0209 (18)	0.0258 (19)	−0.0163 (18)	0.0133 (18)	−0.0050 (15)
C19B	0.076 (3)	0.028 (2)	0.026 (2)	−0.017 (2)	0.009 (2)	−0.0039 (17)
C20B	0.118 (5)	0.034 (2)	0.023 (2)	−0.025 (3)	0.020 (3)	−0.0029 (19)
C21B	0.115 (5)	0.039 (3)	0.040 (3)	−0.039 (3)	0.039 (3)	−0.014 (2)
C22B	0.080 (4)	0.037 (2)	0.049 (3)	−0.021 (2)	0.038 (3)	−0.015 (2)
C23B	0.068 (3)	0.0243 (19)	0.032 (2)	−0.013 (2)	0.020 (2)	−0.0066 (17)
C24B	0.034 (2)	0.0242 (18)	0.0229 (18)	−0.0057 (15)	0.0054 (16)	0.0031 (14)
C25B	0.037 (2)	0.0262 (19)	0.031 (2)	−0.0033 (17)	0.0103 (17)	0.0035 (16)
C26B	0.039 (2)	0.0267 (19)	0.043 (2)	0.0047 (17)	0.0182 (19)	0.0041 (17)
C27B	0.032 (2)	0.032 (2)	0.034 (2)	−0.0023 (17)	0.0118 (17)	0.0028 (17)
C28B	0.0255 (18)	0.0227 (17)	0.0274 (19)	−0.0033 (15)	0.0045 (15)	0.0011 (15)
C29B	0.0251 (18)	0.0215 (17)	0.0238 (18)	−0.0045 (14)	0.0016 (15)	−0.0001 (14)
C30B	0.0273 (19)	0.0269 (19)	0.030 (2)	−0.0033 (16)	0.0047 (16)	0.0015 (16)
C31B	0.029 (2)	0.0271 (19)	0.039 (2)	0.0022 (16)	0.0009 (18)	0.0012 (16)
C32B	0.037 (2)	0.0210 (18)	0.032 (2)	−0.0026 (16)	−0.0014 (17)	0.0052 (16)
C33B	0.030 (2)	0.031 (2)	0.034 (2)	−0.0062 (17)	0.0064 (17)	0.0084 (17)
C34B	0.088 (4)	0.083 (4)	0.062 (4)	0.006 (3)	−0.019 (3)	0.036 (3)

Geometric parameters (Å, º) top

Cu1A—O1A	2.577 (3)	C15A—H15A	0.9300
Cu1A—O2A	1.923 (2)	C16A—H16A	0.9300
Cu1A—O3A	2.761 (3)	C17A—H17C	0.9600
Cu1A—O4A	1.900 (2)	C17A—H17B	0.9600
Cu1A—N1A	1.952 (3)	C17A—H17A	0.9600
Cu1A—N3A	1.962 (3)	C20A—H20A	0.9300
Cu1B—N3B	1.951 (3)	C21A—H21A	0.9300
Cu1B—O3B	2.625 (3)	C22A—H22A	0.9300
Cu1B—O1B	2.679 (3)	C23A—H23A	0.9300
Cu1B—O2B	1.915 (2)	C26A—H26A	0.9300
Cu1B—O4B	1.905 (3)	C27A—H27A	0.9300
Cu1B—N1B	1.957 (3)	C30A—H30A	0.9300
O1A—C17A	1.413 (5)	C31A—H31A	0.9300
O1A—C2A	1.377 (4)	C32A—H32A	0.9300
O2A—C8A	1.289 (4)	C33A—H33A	0.9300
O3A—C34A	1.436 (5)	C34A—H34A	0.9600
O3A—C19A	1.370 (4)	C34A—H34B	0.9600
O4A—C25A	1.294 (4)	C34A—H34C	0.9600
N1A—C1A	1.425 (4)	C1B—C2B	1.405 (5)
N1A—N2A	1.284 (4)	C1B—C6B	1.376 (5)
N2A—C7A	1.364 (4)	C2B—C3B	1.386 (6)
N3A—N4A	1.278 (4)	C3B—C4B	1.370 (7)
N3A—C18A	1.428 (4)	C4B—C5B	1.373 (6)
N4A—C24A	1.361 (4)	C5B—C6B	1.386 (6)
C1A—C6A	1.383 (5)	C7B—C8B	1.421 (5)
C1A—C2A	1.386 (5)	C7B—C12B	1.463 (5)
O1B—C2B	1.369 (5)	C8B—C9B	1.441 (5)
O1B—C17B	1.431 (5)	C9B—C10B	1.345 (6)
C2A—C3A	1.401 (5)	C10B—C11B	1.409 (6)
O2B—C8B	1.291 (4)	C11B—C12B	1.412 (5)
C3A—C4A	1.379 (6)	C11B—C16B	1.413 (5)
O3B—C19B	1.374 (6)	C12B—C13B	1.406 (5)
O3B—C34B	1.424 (7)	C13B—C14B	1.376 (5)
C4A—C5A	1.375 (5)	C14B—C15B	1.388 (6)
O4B—C25B	1.296 (4)	C15B—C16B	1.355 (7)
C5A—C6A	1.395 (5)	C18B—C19B	1.399 (6)
C7A—C8A	1.424 (5)	C18B—C23B	1.370 (6)
C7A—C12A	1.456 (5)	C19B—C20B	1.385 (7)
C8A—C9A	1.436 (5)	C20B—C21B	1.358 (8)
C9A—C10A	1.354 (5)	C21B—C22B	1.386 (7)
C10A—C11A	1.426 (6)	C22B—C23B	1.392 (7)
C11A—C16A	1.418 (5)	C24B—C25B	1.421 (5)
C11A—C12A	1.415 (5)	C24B—C29B	1.465 (5)
C12A—C13A	1.400 (5)	C25B—C26B	1.430 (5)
C13A—C14A	1.372 (5)	C26B—C27B	1.353 (5)
C14A—C15A	1.388 (6)	C27B—C28B	1.424 (5)
C15A—C16A	1.375 (6)	C28B—C29B	1.419 (5)
C18A—C23A	1.374 (5)	C28B—C33B	1.410 (5)
C18A—C19A	1.402 (5)	C29B—C30B	1.400 (5)
C19A—C20A	1.382 (5)	C30B—C31B	1.380 (5)
C20A—C21A	1.380 (5)	C31B—C32B	1.385 (5)
C21A—C22A	1.382 (5)	C32B—C33B	1.354 (5)
C22A—C23A	1.392 (5)	C3B—H3B	0.9300
C24A—C25A	1.427 (5)	C4B—H4B	0.9300
C24A—C29A	1.461 (5)	C5B—H5B	0.9300
C25A—C26A	1.433 (5)	C6B—H6B	0.9300
C26A—C27A	1.354 (5)	C9B—H9B	0.9300
C27A—C28A	1.422 (5)	C10B—H10B	0.9300
C28A—C29A	1.409 (5)	C13B—H13B	0.9300
C28A—C33A	1.411 (5)	C14B—H14B	0.9300
C29A—C30A	1.410 (5)	C15B—H15B	0.9300
C30A—C31A	1.379 (5)	C16B—H16B	0.9300
C31A—C32A	1.393 (5)	C17B—H17D	0.9600
C32A—C33A	1.357 (5)	C17B—H17E	0.9600
N1B—C1B	1.432 (5)	C17B—H17F	0.9600
N1B—N2B	1.285 (4)	C20B—H20B	0.9300
N2B—C7B	1.367 (5)	C21B—H21B	0.9300
C3A—H3A	0.9300	C22B—H22B	0.9300
N3B—N4B	1.288 (4)	C23B—H23B	0.9300
N3B—C18B	1.431 (5)	C26B—H26B	0.9300
C4A—H4A	0.9300	C27B—H27B	0.9300
N4B—C24B	1.371 (4)	C30B—H30B	0.9300
C5A—H5A	0.9300	C31B—H31B	0.9300
C6A—H6A	0.9300	C32B—H32B	0.9300
C9A—H9A	0.9300	C33B—H33B	0.9300
C10A—H10A	0.9300	C34B—H34D	0.9600
C13A—H13A	0.9300	C34B—H34E	0.9600
C14A—H14A	0.9300	C34B—H34F	0.9600

O1A—Cu1A—O2A	118.06 (10)	O1A—C17A—H17B	109.00
O1A—Cu1A—O3A	140.16 (8)	O1A—C17A—H17C	109.00
O1A—Cu1A—O4A	92.50 (9)	H17A—C17A—H17B	109.00
O1A—Cu1A—N1A	70.52 (10)	H17A—C17A—H17C	109.00
O1A—Cu1A—N3A	87.04 (10)	H17B—C17A—H17C	109.00
O2A—Cu1A—O3A	90.46 (9)	C19A—C20A—H20A	120.00
O2A—Cu1A—O4A	93.91 (10)	C21A—C20A—H20A	120.00
O2A—Cu1A—N1A	88.34 (11)	C20A—C21A—H21A	119.00
O2A—Cu1A—N3A	154.40 (11)	C22A—C21A—H21A	119.00
O3A—Cu1A—O4A	114.01 (9)	C21A—C22A—H22A	120.00
O3A—Cu1A—N1A	84.17 (10)	C23A—C22A—H22A	120.00
O3A—Cu1A—N3A	65.09 (9)	C18A—C23A—H23A	120.00
O4A—Cu1A—N1A	161.64 (11)	C22A—C23A—H23A	120.00
O4A—Cu1A—N3A	89.68 (11)	C25A—C26A—H26A	119.00
N1A—Cu1A—N3A	96.15 (11)	C27A—C26A—H26A	119.00
O1B—Cu1B—N1B	67.72 (10)	C26A—C27A—H27A	119.00
O1B—Cu1B—N3B	80.02 (11)	C28A—C27A—H27A	119.00
O2B—Cu1B—O3B	89.74 (10)	C29A—C30A—H30A	120.00
O2B—Cu1B—O4B	92.83 (11)	C31A—C30A—H30A	120.00
O2B—Cu1B—N1B	90.23 (11)	C30A—C31A—H31A	120.00
O2B—Cu1B—N3B	156.69 (12)	C32A—C31A—H31A	120.00
O3B—Cu1B—O4B	114.58 (11)	C31A—C32A—H32A	120.00
O3B—Cu1B—N1B	88.92 (11)	C33A—C32A—H32A	120.00
O3B—Cu1B—N3B	68.29 (10)	C28A—C33A—H33A	120.00
O4B—Cu1B—N1B	156.30 (12)	C32A—C33A—H33A	120.00
O4B—Cu1B—N3B	89.61 (12)	O3A—C34A—H34A	110.00
N1B—Cu1B—N3B	96.78 (12)	O3A—C34A—H34B	109.00
O1B—Cu1B—O2B	123.06 (10)	O3A—C34A—H34C	109.00
O1B—Cu1B—O3B	138.05 (10)	H34A—C34A—H34B	110.00
O1B—Cu1B—O4B	91.15 (11)	H34A—C34A—H34C	110.00
Cu1A—O1A—C17A	138.0 (2)	H34B—C34A—H34C	109.00
C2A—O1A—C17A	118.4 (3)	N1B—C1B—C2B	117.6 (3)
Cu1A—O1A—C2A	101.01 (19)	N1B—C1B—C6B	123.0 (3)
Cu1A—O2A—C8A	119.4 (2)	C2B—C1B—C6B	119.4 (4)
Cu1A—O3A—C19A	98.56 (19)	O1B—C2B—C1B	115.3 (3)
Cu1A—O3A—C34A	135.7 (2)	O1B—C2B—C3B	125.0 (3)
C19A—O3A—C34A	118.2 (3)	C1B—C2B—C3B	119.7 (4)
Cu1A—O4A—C25A	125.4 (2)	C2B—C3B—C4B	119.8 (4)
Cu1A—N1A—C1A	117.8 (2)	C3B—C4B—C5B	120.8 (4)
N2A—N1A—C1A	114.6 (3)	C4B—C5B—C6B	120.0 (4)
Cu1A—N1A—N2A	126.9 (2)	C1B—C6B—C5B	120.2 (4)
N1A—N2A—C7A	119.6 (3)	N2B—C7B—C8B	125.8 (3)
N4A—N3A—C18A	112.1 (3)	N2B—C7B—C12B	113.6 (3)
Cu1A—N3A—C18A	118.5 (2)	C8B—C7B—C12B	120.5 (3)
Cu1A—N3A—N4A	129.3 (2)	O2B—C8B—C7B	124.7 (3)
N3A—N4A—C24A	120.6 (3)	O2B—C8B—C9B	118.2 (3)
N1A—C1A—C2A	117.8 (3)	C7B—C8B—C9B	117.2 (3)
N1A—C1A—C6A	122.1 (3)	C8B—C9B—C10B	121.8 (4)
C2A—C1A—C6A	120.1 (3)	C9B—C10B—C11B	122.8 (4)
C2B—O1B—C17B	116.1 (3)	C10B—C11B—C12B	118.9 (3)
Cu1B—O1B—C2B	100.0 (2)	C10B—C11B—C16B	122.5 (4)
Cu1B—O1B—C17B	138.3 (3)	C12B—C11B—C16B	118.6 (4)
O1A—C2A—C1A	116.4 (3)	C7B—C12B—C11B	118.9 (3)
O1A—C2A—C3A	123.7 (3)	C7B—C12B—C13B	122.2 (3)
C1A—C2A—C3A	119.9 (3)	C11B—C12B—C13B	118.9 (3)
Cu1B—O2B—C8B	122.8 (2)	C12B—C13B—C14B	120.3 (4)
C2A—C3A—C4A	119.1 (3)	C13B—C14B—C15B	120.7 (4)
Cu1B—O3B—C19B	99.1 (2)	C14B—C15B—C16B	120.0 (4)
Cu1B—O3B—C34B	137.8 (3)	C11B—C16B—C15B	121.4 (4)
C19B—O3B—C34B	119.1 (4)	N3B—C18B—C19B	116.5 (4)
C3A—C4A—C5A	121.5 (3)	N3B—C18B—C23B	123.3 (3)
Cu1B—O4B—C25B	122.6 (2)	C19B—C18B—C23B	120.2 (4)
C4A—C5A—C6A	119.3 (3)	O3B—C19B—C18B	115.4 (4)
C1A—C6A—C5A	120.2 (3)	O3B—C19B—C20B	124.9 (4)
N2A—C7A—C8A	124.8 (3)	C18B—C19B—C20B	119.7 (4)
C8A—C7A—C12A	120.5 (3)	C19B—C20B—C21B	119.9 (4)
N2A—C7A—C12A	114.5 (3)	C20B—C21B—C22B	121.0 (5)
O2A—C8A—C7A	124.7 (3)	C21B—C22B—C23B	119.6 (4)
O2A—C8A—C9A	118.0 (3)	C18B—C23B—C22B	119.7 (4)
C7A—C8A—C9A	117.3 (3)	N4B—C24B—C25B	125.2 (3)
C8A—C9A—C10A	122.1 (4)	N4B—C24B—C29B	114.1 (3)
C9A—C10A—C11A	122.0 (4)	C25B—C24B—C29B	120.1 (3)
C12A—C11A—C16A	119.3 (4)	O4B—C25B—C24B	125.3 (3)
C10A—C11A—C12A	118.6 (3)	O4B—C25B—C26B	116.9 (3)
C10A—C11A—C16A	122.1 (4)	C24B—C25B—C26B	117.7 (3)
C7A—C12A—C11A	119.4 (3)	C25B—C26B—C27B	121.8 (4)
C7A—C12A—C13A	122.4 (3)	C26B—C27B—C28B	122.5 (3)
C11A—C12A—C13A	118.2 (3)	C27B—C28B—C29B	118.2 (3)
C12A—C13A—C14A	121.4 (4)	C27B—C28B—C33B	122.2 (3)
C13A—C14A—C15A	120.8 (4)	C29B—C28B—C33B	119.5 (3)
C14A—C15A—C16A	119.7 (4)	C24B—C29B—C28B	119.2 (3)
C11A—C16A—C15A	120.6 (4)	C24B—C29B—C30B	122.6 (3)
N3A—C18A—C19A	116.9 (3)	C28B—C29B—C30B	118.3 (3)
N3A—C18A—C23A	122.6 (3)	C29B—C30B—C31B	120.2 (3)
C19A—C18A—C23A	120.5 (3)	C30B—C31B—C32B	121.2 (4)
O3A—C19A—C18A	115.1 (3)	C31B—C32B—C33B	120.0 (3)
O3A—C19A—C20A	125.5 (3)	C28B—C33B—C32B	120.7 (3)
C18A—C19A—C20A	119.4 (3)	C2B—C3B—H3B	120.00
C19A—C20A—C21A	119.6 (4)	C4B—C3B—H3B	120.00
C20A—C21A—C22A	121.4 (4)	C3B—C4B—H4B	120.00
C21A—C22A—C23A	119.1 (4)	C5B—C4B—H4B	120.00
C18A—C23A—C22A	120.0 (3)	C4B—C5B—H5B	120.00
N4A—C24A—C29A	114.4 (3)	C6B—C5B—H5B	120.00
C25A—C24A—C29A	119.9 (3)	C1B—C6B—H6B	120.00
N4A—C24A—C25A	125.1 (3)	C5B—C6B—H6B	120.00
O4A—C25A—C24A	124.8 (3)	C8B—C9B—H9B	119.00
C24A—C25A—C26A	117.6 (3)	C10B—C9B—H9B	119.00
O4A—C25A—C26A	117.5 (3)	C9B—C10B—H10B	119.00
C25A—C26A—C27A	121.7 (3)	C11B—C10B—H10B	119.00
C26A—C27A—C28A	122.8 (3)	C12B—C13B—H13B	120.00
C27A—C28A—C29A	118.0 (3)	C14B—C13B—H13B	120.00
C27A—C28A—C33A	122.4 (3)	C13B—C14B—H14B	120.00
C29A—C28A—C33A	119.6 (3)	C15B—C14B—H14B	120.00
C28A—C29A—C30A	118.4 (3)	C14B—C15B—H15B	120.00
C24A—C29A—C30A	121.6 (3)	C16B—C15B—H15B	120.00
C24A—C29A—C28A	120.0 (3)	C11B—C16B—H16B	119.00
C29A—C30A—C31A	120.4 (3)	C15B—C16B—H16B	119.00
C30A—C31A—C32A	120.7 (3)	O1B—C17B—H17D	110.00
C31A—C32A—C33A	120.0 (3)	O1B—C17B—H17E	109.00
C28A—C33A—C32A	120.9 (3)	O1B—C17B—H17F	109.00
Cu1B—N1B—N2B	128.3 (2)	H17D—C17B—H17E	110.00
Cu1B—N1B—C1B	118.3 (2)	H17D—C17B—H17F	109.00
N2B—N1B—C1B	113.1 (3)	H17E—C17B—H17F	109.00
N1B—N2B—C7B	120.5 (3)	C19B—C20B—H20B	120.00
C2A—C3A—H3A	120.00	C21B—C20B—H20B	120.00
C4A—C3A—H3A	120.00	C20B—C21B—H21B	120.00
N4B—N3B—C18B	114.8 (3)	C22B—C21B—H21B	119.00
Cu1B—N3B—N4B	128.1 (2)	C21B—C22B—H22B	120.00
Cu1B—N3B—C18B	116.6 (2)	C23B—C22B—H22B	120.00
C5A—C4A—H4A	119.00	C18B—C23B—H23B	120.00
C3A—C4A—H4A	119.00	C22B—C23B—H23B	120.00
N3B—N4B—C24B	119.0 (3)	C25B—C26B—H26B	119.00
C4A—C5A—H5A	120.00	C27B—C26B—H26B	119.00
C6A—C5A—H5A	120.00	C26B—C27B—H27B	119.00
C1A—C6A—H6A	120.00	C28B—C27B—H27B	119.00
C5A—C6A—H6A	120.00	C29B—C30B—H30B	120.00
C10A—C9A—H9A	119.00	C31B—C30B—H30B	120.00
C8A—C9A—H9A	119.00	C30B—C31B—H31B	119.00
C9A—C10A—H10A	119.00	C32B—C31B—H31B	119.00
C11A—C10A—H10A	119.00	C31B—C32B—H32B	120.00
C14A—C13A—H13A	119.00	C33B—C32B—H32B	120.00
C12A—C13A—H13A	119.00	C28B—C33B—H33B	120.00
C13A—C14A—H14A	120.00	C32B—C33B—H33B	120.00
C15A—C14A—H14A	120.00	O3B—C34B—H34D	110.00
C16A—C15A—H15A	120.00	O3B—C34B—H34E	109.00
C14A—C15A—H15A	120.00	O3B—C34B—H34F	109.00
C15A—C16A—H16A	120.00	H34D—C34B—H34E	110.00
C11A—C16A—H16A	120.00	H34D—C34B—H34F	110.00
O1A—C17A—H17A	109.00	H34E—C34B—H34F	109.00

O2A—Cu1A—O1A—C2A	109.2 (2)	C4A—C5A—C6A—C1A	0.8 (5)
O2A—Cu1A—O1A—C17A	−90.9 (3)	C12A—C7A—C8A—O2A	179.2 (3)
O3A—Cu1A—O1A—C2A	−21.5 (2)	N2A—C7A—C8A—O2A	5.1 (5)
O3A—Cu1A—O1A—C17A	138.4 (3)	N2A—C7A—C8A—C9A	−174.1 (3)
O4A—Cu1A—O1A—C2A	−155.0 (2)	N2A—C7A—C12A—C13A	−4.7 (5)
O4A—Cu1A—O1A—C17A	4.9 (3)	C12A—C7A—C8A—C9A	−0.1 (5)
N1A—Cu1A—O1A—C2A	32.1 (2)	N2A—C7A—C12A—C11A	177.2 (3)
N1A—Cu1A—O1A—C17A	−168.0 (4)	C8A—C7A—C12A—C11A	2.5 (5)
N3A—Cu1A—O1A—C2A	−65.5 (2)	C8A—C7A—C12A—C13A	−179.4 (3)
N3A—Cu1A—O1A—C17A	94.4 (3)	C7A—C8A—C9A—C10A	−2.7 (6)
O1A—Cu1A—O2A—C8A	−107.5 (2)	O2A—C8A—C9A—C10A	178.0 (4)
O3A—Cu1A—O2A—C8A	43.5 (2)	C8A—C9A—C10A—C11A	3.1 (7)
O4A—Cu1A—O2A—C8A	157.6 (2)	C9A—C10A—C11A—C12A	−0.5 (6)
N1A—Cu1A—O2A—C8A	−40.6 (2)	C9A—C10A—C11A—C16A	179.5 (4)
N3A—Cu1A—O2A—C8A	60.2 (4)	C10A—C11A—C16A—C15A	−179.6 (4)
O1A—Cu1A—O3A—C19A	−11.0 (2)	C10A—C11A—C12A—C7A	−2.3 (5)
O1A—Cu1A—O3A—C34A	136.0 (3)	C10A—C11A—C12A—C13A	179.5 (3)
O2A—Cu1A—O3A—C19A	−149.1 (2)	C16A—C11A—C12A—C7A	177.8 (3)
O2A—Cu1A—O3A—C34A	−2.1 (3)	C16A—C11A—C12A—C13A	−0.4 (5)
O4A—Cu1A—O3A—C19A	116.43 (19)	C12A—C11A—C16A—C15A	0.3 (6)
O4A—Cu1A—O3A—C34A	−96.6 (3)	C11A—C12A—C13A—C14A	−0.2 (5)
N1A—Cu1A—O3A—C19A	−60.8 (2)	C7A—C12A—C13A—C14A	−178.4 (3)
N1A—Cu1A—O3A—C34A	86.2 (3)	C12A—C13A—C14A—C15A	1.0 (6)
N3A—Cu1A—O3A—C19A	38.77 (19)	C13A—C14A—C15A—C16A	−1.1 (7)
N3A—Cu1A—O3A—C34A	−174.2 (4)	C14A—C15A—C16A—C11A	0.4 (7)
O1A—Cu1A—O4A—C25A	65.7 (3)	C23A—C18A—C19A—O3A	−179.3 (3)
O2A—Cu1A—O4A—C25A	−176.0 (3)	N3A—C18A—C19A—O3A	−0.2 (4)
O3A—Cu1A—O4A—C25A	−83.7 (3)	N3A—C18A—C19A—C20A	178.3 (3)
N3A—Cu1A—O4A—C25A	−21.3 (3)	C19A—C18A—C23A—C22A	0.1 (5)
O1A—Cu1A—N1A—N2A	155.7 (3)	C23A—C18A—C19A—C20A	−0.9 (5)
O1A—Cu1A—N1A—C1A	−34.3 (2)	N3A—C18A—C23A—C22A	−179.0 (3)
O2A—Cu1A—N1A—N2A	35.0 (3)	O3A—C19A—C20A—C21A	178.7 (4)
O2A—Cu1A—N1A—C1A	−154.9 (2)	C18A—C19A—C20A—C21A	0.4 (6)
O3A—Cu1A—N1A—N2A	−55.6 (3)	C19A—C20A—C21A—C22A	0.8 (7)
O3A—Cu1A—N1A—C1A	114.5 (2)	C20A—C21A—C22A—C23A	−1.5 (7)
N3A—Cu1A—N1A—N2A	−119.7 (3)	C21A—C22A—C23A—C18A	1.1 (6)
N3A—Cu1A—N1A—C1A	50.4 (2)	C25A—C24A—C29A—C28A	0.6 (5)
O1A—Cu1A—N3A—N4A	−70.8 (3)	N4A—C24A—C25A—O4A	8.6 (5)
O1A—Cu1A—N3A—C18A	107.3 (2)	N4A—C24A—C25A—C26A	−169.3 (3)
O2A—Cu1A—N3A—N4A	120.1 (3)	C29A—C24A—C25A—O4A	178.8 (3)
O2A—Cu1A—N3A—C18A	−61.8 (4)	C29A—C24A—C25A—C26A	1.0 (5)
O3A—Cu1A—N3A—N4A	138.6 (3)	N4A—C24A—C29A—C28A	171.8 (3)
O3A—Cu1A—N3A—C18A	−43.4 (2)	N4A—C24A—C29A—C30A	−7.8 (4)
O4A—Cu1A—N3A—N4A	21.7 (3)	C25A—C24A—C29A—C30A	−179.1 (3)
O4A—Cu1A—N3A—C18A	−160.2 (2)	C24A—C25A—C26A—C27A	−1.5 (5)
N1A—Cu1A—N3A—N4A	−140.8 (3)	O4A—C25A—C26A—C27A	−179.5 (3)
N1A—Cu1A—N3A—C18A	37.3 (2)	C25A—C26A—C27A—C28A	0.5 (5)
N3B—Cu1B—O4B—C25B	−29.2 (3)	C26A—C27A—C28A—C33A	−179.3 (3)
O1B—Cu1B—N1B—N2B	148.5 (3)	C26A—C27A—C28A—C29A	1.2 (5)
O1B—Cu1B—N1B—C1B	−38.8 (2)	C27A—C28A—C29A—C24A	−1.6 (5)
O2B—Cu1B—N1B—N2B	22.5 (3)	C33A—C28A—C29A—C30A	−1.6 (5)
O2B—Cu1B—N1B—C1B	−164.8 (2)	C27A—C28A—C29A—C30A	178.0 (3)
O3B—Cu1B—N1B—N2B	−67.3 (3)	C33A—C28A—C29A—C24A	178.8 (3)
O3B—Cu1B—N1B—C1B	105.5 (2)	C27A—C28A—C33A—C32A	−178.4 (3)
O4B—Cu1B—N1B—N2B	120.1 (3)	C29A—C28A—C33A—C32A	1.3 (5)
O4B—Cu1B—N1B—C1B	−67.2 (4)	C28A—C29A—C30A—C31A	1.0 (5)
N3B—Cu1B—N1B—N2B	−135.2 (3)	C24A—C29A—C30A—C31A	−179.4 (3)
N3B—Cu1B—N1B—C1B	37.5 (2)	C29A—C30A—C31A—C32A	0.0 (5)
O1B—Cu1B—N3B—N4B	−59.9 (3)	C30A—C31A—C32A—C33A	−0.4 (5)
O1B—Cu1B—N3B—C18B	111.0 (3)	C31A—C32A—C33A—C28A	−0.3 (5)
O2B—Cu1B—N3B—N4B	127.6 (3)	Cu1B—N1B—N2B—C7B	−6.9 (4)
O2B—Cu1B—N3B—C18B	−61.5 (5)	C1B—N1B—N2B—C7B	−179.9 (3)
O3B—Cu1B—N3B—N4B	148.1 (3)	Cu1B—N1B—C1B—C2B	40.6 (4)
O3B—Cu1B—N3B—C18B	−41.0 (3)	Cu1B—N1B—C1B—C6B	−137.3 (3)
O4B—Cu1B—N3B—N4B	31.3 (3)	N2B—N1B—C1B—C2B	−145.6 (3)
O4B—Cu1B—N3B—C18B	−157.7 (3)	N2B—N1B—C1B—C6B	36.5 (5)
N1B—Cu1B—N3B—N4B	−125.8 (3)	N1B—N2B—C7B—C8B	−10.9 (5)
N1B—Cu1B—N3B—C18B	45.2 (3)	N1B—N2B—C7B—C12B	173.5 (3)
O2B—Cu1B—O3B—C19B	−149.0 (2)	Cu1B—N3B—N4B—C24B	−15.2 (5)
O2B—Cu1B—O3B—C34B	6.3 (5)	C18B—N3B—N4B—C24B	173.7 (3)
O4B—Cu1B—O3B—C19B	118.0 (2)	Cu1B—N3B—C18B—C19B	41.6 (4)
O4B—Cu1B—O3B—C34B	−86.7 (5)	Cu1B—N3B—C18B—C23B	−135.6 (3)
N1B—Cu1B—O3B—C19B	−58.8 (2)	N4B—N3B—C18B—C19B	−146.3 (4)
N1B—Cu1B—O3B—C34B	96.5 (5)	N4B—N3B—C18B—C23B	36.5 (5)
N3B—Cu1B—O3B—C19B	38.9 (2)	N3B—N4B—C24B—C25B	−12.8 (5)
N3B—Cu1B—O3B—C34B	−165.7 (5)	N3B—N4B—C24B—C29B	175.9 (3)
O1B—Cu1B—O4B—C25B	50.8 (3)	N1B—C1B—C2B—O1B	2.0 (5)
O2B—Cu1B—O4B—C25B	174.0 (3)	N1B—C1B—C2B—C3B	−176.2 (3)
O3B—Cu1B—O4B—C25B	−95.0 (3)	C6B—C1B—C2B—O1B	180.0 (3)
N1B—Cu1B—O4B—C25B	76.9 (4)	C6B—C1B—C2B—C3B	1.8 (6)
N1B—Cu1B—O2B—C8B	−29.3 (3)	N1B—C1B—C6B—C5B	177.5 (4)
N3B—Cu1B—O2B—C8B	78.6 (4)	C2B—C1B—C6B—C5B	−0.3 (6)
O2B—Cu1B—O1B—C2B	111.1 (2)	O1B—C2B—C3B—C4B	180.0 (4)
O2B—Cu1B—O1B—C17B	−98.9 (4)	C1B—C2B—C3B—C4B	−2.0 (6)
O3B—Cu1B—O1B—C2B	−24.7 (3)	C2B—C3B—C4B—C5B	0.8 (6)
O3B—Cu1B—O1B—C17B	125.4 (4)	C3B—C4B—C5B—C6B	0.6 (6)
O4B—Cu1B—O1B—C2B	−154.8 (2)	C4B—C5B—C6B—C1B	−0.9 (6)
O4B—Cu1B—O1B—C17B	−4.7 (4)	N2B—C7B—C8B—O2B	1.9 (5)
N1B—Cu1B—O1B—C2B	36.3 (2)	N2B—C7B—C8B—C9B	−177.0 (3)
N1B—Cu1B—O1B—C17B	−173.7 (4)	C12B—C7B—C8B—O2B	177.2 (3)
N3B—Cu1B—O1B—C2B	−65.4 (2)	C12B—C7B—C8B—C9B	−1.6 (5)
N3B—Cu1B—O1B—C17B	84.7 (4)	N2B—C7B—C12B—C11B	178.1 (3)
O1B—Cu1B—O2B—C8B	−92.6 (3)	N2B—C7B—C12B—C13B	−2.5 (4)
O3B—Cu1B—O2B—C8B	59.6 (3)	C8B—C7B—C12B—C11B	2.2 (5)
O4B—Cu1B—O2B—C8B	174.2 (3)	C8B—C7B—C12B—C13B	−178.4 (3)
O1B—Cu1B—O3B—C34B	150.5 (4)	O2B—C8B—C9B—C10B	−179.1 (4)
O1B—Cu1B—O3B—C19B	−4.8 (3)	C7B—C8B—C9B—C10B	−0.2 (6)
Cu1A—O1A—C2A—C3A	155.8 (3)	C8B—C9B—C10B—C11B	1.3 (7)
Cu1A—O1A—C2A—C1A	−25.1 (3)	C9B—C10B—C11B—C12B	−0.6 (6)
C17A—O1A—C2A—C3A	−9.1 (5)	C9B—C10B—C11B—C16B	179.0 (4)
C17A—O1A—C2A—C1A	170.0 (3)	C10B—C11B—C12B—C7B	−1.1 (5)
Cu1A—O2A—C8A—C9A	−150.7 (3)	C10B—C11B—C12B—C13B	179.5 (3)
Cu1A—O2A—C8A—C7A	30.0 (4)	C16B—C11B—C12B—C7B	179.2 (3)
Cu1A—O3A—C19A—C18A	−27.6 (3)	C16B—C11B—C12B—C13B	−0.2 (5)
C34A—O3A—C19A—C18A	177.9 (3)	C10B—C11B—C16B—C15B	178.7 (4)
C34A—O3A—C19A—C20A	−0.4 (5)	C12B—C11B—C16B—C15B	−1.6 (6)
Cu1A—O3A—C19A—C20A	154.0 (3)	C7B—C12B—C13B—C14B	−177.9 (3)
Cu1A—O4A—C25A—C26A	−170.3 (2)	C11B—C12B—C13B—C14B	1.5 (5)
Cu1A—O4A—C25A—C24A	11.9 (5)	C12B—C13B—C14B—C15B	−1.1 (5)
Cu1A—N1A—N2A—C7A	−13.4 (4)	C13B—C14B—C15B—C16B	−0.7 (6)
C1A—N1A—N2A—C7A	176.2 (3)	C14B—C15B—C16B—C11B	2.0 (7)
Cu1A—N1A—C1A—C6A	−145.0 (3)	N3B—C18B—C19B—O3B	3.2 (5)
N2A—N1A—C1A—C2A	−154.0 (3)	N3B—C18B—C19B—C20B	−176.3 (4)
Cu1A—N1A—C1A—C2A	34.7 (4)	C23B—C18B—C19B—O3B	−179.5 (4)
N2A—N1A—C1A—C6A	26.3 (4)	C23B—C18B—C19B—C20B	1.1 (6)
N1A—N2A—C7A—C8A	−14.5 (5)	N3B—C18B—C23B—C22B	176.1 (4)
N1A—N2A—C7A—C12A	171.1 (3)	C19B—C18B—C23B—C22B	−1.0 (6)
Cu1A—N3A—C18A—C23A	−133.2 (3)	O3B—C19B—C20B—C21B	−180.0 (5)
N4A—N3A—C18A—C19A	−133.9 (3)	C18B—C19B—C20B—C21B	−0.6 (7)
Cu1A—N3A—C18A—C19A	47.7 (4)	C19B—C20B—C21B—C22B	0.2 (8)
C18A—N3A—N4A—C24A	171.6 (3)	C20B—C21B—C22B—C23B	−0.2 (7)
N4A—N3A—C18A—C23A	45.2 (4)	C21B—C22B—C23B—C18B	0.6 (7)
Cu1A—N3A—N4A—C24A	−10.2 (4)	N4B—C24B—C25B—O4B	13.0 (6)
N3A—N4A—C24A—C25A	−9.3 (5)	N4B—C24B—C25B—C26B	−164.4 (3)
N3A—N4A—C24A—C29A	−180.0 (3)	C29B—C24B—C25B—O4B	−176.1 (3)
N1A—C1A—C6A—C5A	178.3 (3)	C29B—C24B—C25B—C26B	6.4 (5)
C2A—C1A—C6A—C5A	−1.3 (5)	N4B—C24B—C29B—C28B	165.5 (3)
C6A—C1A—C2A—O1A	−178.4 (3)	N4B—C24B—C29B—C30B	−14.2 (5)
N1A—C1A—C2A—O1A	2.0 (4)	C25B—C24B—C29B—C28B	−6.3 (5)
N1A—C1A—C2A—C3A	−178.9 (3)	C25B—C24B—C29B—C30B	174.1 (3)
C6A—C1A—C2A—C3A	0.7 (5)	O4B—C25B—C26B—C27B	−180.0 (4)
C17B—O1B—C2B—C1B	174.3 (3)	C24B—C25B—C26B—C27B	−2.3 (6)
Cu1B—O1B—C2B—C1B	−27.4 (3)	C25B—C26B—C27B—C28B	−2.2 (6)
Cu1B—O1B—C2B—C3B	150.7 (3)	C26B—C27B—C28B—C29B	2.4 (5)
C17B—O1B—C2B—C3B	−7.6 (5)	C26B—C27B—C28B—C33B	−177.6 (4)
O1A—C2A—C3A—C4A	179.5 (3)	C27B—C28B—C29B—C24B	1.8 (5)
C1A—C2A—C3A—C4A	0.4 (5)	C27B—C28B—C29B—C30B	−178.5 (3)
Cu1B—O2B—C8B—C7B	23.5 (5)	C33B—C28B—C29B—C24B	−178.2 (3)
Cu1B—O2B—C8B—C9B	−157.7 (3)	C33B—C28B—C29B—C30B	1.5 (5)
C2A—C3A—C4A—C5A	−1.0 (5)	C27B—C28B—C33B—C32B	178.6 (3)
C34B—O3B—C19B—C18B	168.6 (4)	C29B—C28B—C33B—C32B	−1.4 (5)
C34B—O3B—C19B—C20B	−12.1 (7)	C24B—C29B—C30B—C31B	179.3 (3)
Cu1B—O3B—C19B—C18B	−30.1 (4)	C28B—C29B—C30B—C31B	−0.4 (5)
Cu1B—O3B—C19B—C20B	149.2 (4)	C29B—C30B—C31B—C32B	−0.9 (6)
C3A—C4A—C5A—C6A	0.4 (5)	C30B—C31B—C32B—C33B	1.1 (6)
Cu1B—O4B—C25B—C24B	15.0 (5)	C31B—C32B—C33B—C28B	0.1 (5)
Cu1B—O4B—C25B—C26B	−167.5 (3)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C3B—H3B···O4A	0.93	2.48	3.270 (5)	143
C13A—H13A···N2A	0.93	2.45	2.773 (5)	100
C13B—H13B···N2B	0.93	2.44	2.760 (4)	100
C30A—H30A···N4A	0.93	2.45	2.767 (4)	100
C30B—H30B···N4B	0.93	2.45	2.796 (4)	100

Selected geometric parameters (Å, º) top

Cu1A—O1A	2.577 (3)	N1A—C1A	1.425 (4)
Cu1A—O2A	1.923 (2)	N1A—N2A	1.284 (4)
Cu1A—O3A	2.761 (3)	N2A—C7A	1.364 (4)
Cu1A—O4A	1.900 (2)	N3A—N4A	1.278 (4)
Cu1A—N1A	1.952 (3)	N3A—C18A	1.428 (4)
Cu1A—N3A	1.962 (3)	N4A—C24A	1.361 (4)
Cu1B—N3B	1.951 (3)	O1B—C2B	1.369 (5)
Cu1B—O3B	2.625 (3)	O1B—C17B	1.431 (5)
Cu1B—O1B	2.679 (3)	O2B—C8B	1.291 (4)
Cu1B—O2B	1.915 (2)	O3B—C19B	1.374 (6)
Cu1B—O4B	1.905 (3)	O3B—C34B	1.424 (7)
Cu1B—N1B	1.957 (3)	O4B—C25B	1.296 (4)
O1A—C17A	1.413 (5)	N1B—C1B	1.432 (5)
O1A—C2A	1.377 (4)	N1B—N2B	1.285 (4)
O2A—C8A	1.289 (4)	N2B—C7B	1.367 (5)
O3A—C34A	1.436 (5)	N3B—N4B	1.288 (4)
O3A—C19A	1.370 (4)	N3B—C18B	1.431 (5)
O4A—C25A	1.294 (4)	N4B—C24B	1.371 (4)

O1A—Cu1A—O2A	118.06 (10)	N1A—C1A—C6A	122.1 (3)
O1A—Cu1A—O3A	140.16 (8)	C2B—O1B—C17B	116.1 (3)
O1A—Cu1A—O4A	92.50 (9)	Cu1B—O1B—C2B	100.0 (2)
O1A—Cu1A—N1A	70.52 (10)	Cu1B—O1B—C17B	138.3 (3)
O1A—Cu1A—N3A	87.04 (10)	O1A—C2A—C1A	116.4 (3)
O2A—Cu1A—O3A	90.46 (9)	O1A—C2A—C3A	123.7 (3)
O2A—Cu1A—O4A	93.91 (10)	Cu1B—O2B—C8B	122.8 (2)
O2A—Cu1A—N1A	88.34 (11)	Cu1B—O3B—C19B	99.1 (2)
O2A—Cu1A—N3A	154.40 (11)	Cu1B—O3B—C34B	137.8 (3)
O3A—Cu1A—O4A	114.01 (9)	C19B—O3B—C34B	119.1 (4)
O3A—Cu1A—N1A	84.17 (10)	Cu1B—O4B—C25B	122.6 (2)
O3A—Cu1A—N3A	65.09 (9)	N2A—C7A—C8A	124.8 (3)
O4A—Cu1A—N1A	161.64 (11)	N2A—C7A—C12A	114.5 (3)
O4A—Cu1A—N3A	89.68 (11)	O2A—C8A—C7A	124.7 (3)
N1A—Cu1A—N3A	96.15 (11)	O2A—C8A—C9A	118.0 (3)
O1B—Cu1B—N1B	67.72 (10)	N3A—C18A—C19A	116.9 (3)
O1B—Cu1B—N3B	80.02 (11)	N3A—C18A—C23A	122.6 (3)
O2B—Cu1B—O3B	89.74 (10)	O3A—C19A—C18A	115.1 (3)
O2B—Cu1B—O4B	92.83 (11)	O3A—C19A—C20A	125.5 (3)
O2B—Cu1B—N1B	90.23 (11)	N4A—C24A—C29A	114.4 (3)
O2B—Cu1B—N3B	156.69 (12)	N4A—C24A—C25A	125.1 (3)
O3B—Cu1B—O4B	114.58 (11)	O4A—C25A—C24A	124.8 (3)
O3B—Cu1B—N1B	88.92 (11)	O4A—C25A—C26A	117.5 (3)
O3B—Cu1B—N3B	68.29 (10)	Cu1B—N1B—N2B	128.3 (2)
O4B—Cu1B—N1B	156.30 (12)	Cu1B—N1B—C1B	118.3 (2)
O4B—Cu1B—N3B	89.61 (12)	N2B—N1B—C1B	113.1 (3)
N1B—Cu1B—N3B	96.78 (12)	N1B—N2B—C7B	120.5 (3)
O1B—Cu1B—O2B	123.06 (10)	N4B—N3B—C18B	114.8 (3)
O1B—Cu1B—O3B	138.05 (10)	Cu1B—N3B—N4B	128.1 (2)
O1B—Cu1B—O4B	91.15 (11)	Cu1B—N3B—C18B	116.6 (2)
Cu1A—O1A—C17A	138.0 (2)	N3B—N4B—C24B	119.0 (3)
C2A—O1A—C17A	118.4 (3)	N1B—C1B—C2B	117.6 (3)
Cu1A—O1A—C2A	101.01 (19)	N1B—C1B—C6B	123.0 (3)
Cu1A—O2A—C8A	119.4 (2)	O1B—C2B—C1B	115.3 (3)
Cu1A—O3A—C19A	98.56 (19)	O1B—C2B—C3B	125.0 (3)
Cu1A—O3A—C34A	135.7 (2)	N2B—C7B—C8B	125.8 (3)
C19A—O3A—C34A	118.2 (3)	N2B—C7B—C12B	113.6 (3)
Cu1A—O4A—C25A	125.4 (2)	O2B—C8B—C7B	124.7 (3)
Cu1A—N1A—C1A	117.8 (2)	O2B—C8B—C9B	118.2 (3)
N2A—N1A—C1A	114.6 (3)	N3B—C18B—C19B	116.5 (4)
Cu1A—N1A—N2A	126.9 (2)	N3B—C18B—C23B	123.3 (3)
N1A—N2A—C7A	119.6 (3)	O3B—C19B—C18B	115.4 (4)
N4A—N3A—C18A	112.1 (3)	O3B—C19B—C20B	124.9 (4)
Cu1A—N3A—C18A	118.5 (2)	N4B—C24B—C25B	125.2 (3)
Cu1A—N3A—N4A	129.3 (2)	N4B—C24B—C29B	114.1 (3)
N3A—N4A—C24A	120.6 (3)	O4B—C25B—C24B	125.3 (3)
N1A—C1A—C2A	117.8 (3)	O4B—C25B—C26B	116.9 (3)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C3B—H3B···O4A	0.9300	2.4800	3.270 (5)	143.00
C13A—H13A···N2A	0.9300	2.4500	2.773 (5)	100.00
C13B—H13B···N2B	0.9300	2.4400	2.760 (4)	100.00
C30A—H30A···N4A	0.9300	2.4500	2.767 (4)	100.00
C30B—H30B···N4B	0.9300	2.4500	2.796 (4)	100.00

Acknowledgements

We thank all researchers of the CHEMS Research Unit, University of Constantine, Algeria, for their valuable assistance. Thanks are due to the MESRS (Ministère de l'Enseignement Supérieur et de la Recherche Scientifique, Algérie) for financial support.

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