research communications
N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI)
of octakis(aLaboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia, bFaculdade de Medicina, Veterinària, Universidade Tecnica de Lisboa, Avenida da Universidade Tecnica, 1300-477 Lisboa, Portugal, and cREQUIMTE/CQFB Departamento de Quimica, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal
*Correspondence e-mail: gandour_yassine@hotmail.fr
In the title salt, [Eu(C3H7NO)8][PMo12O40], the comprises one α-Keggin-type [PMo12O40]3− polyoxidometalate anion and one distorted dodecahedral [Eu(C3H7NO)8]3+ complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexagonally arranged rows extending parallel to [001]. The complex cations are situated between the rows and are linked to the neighbouring anions through weak C—H⋯O hydrogen-bonding interactions, leading to the formation of a three-dimensional network structure.
CCDC reference: 1456619
1. Chemical context
Polyoxidometalates (POMs) are versatile metal–oxygen complexes which have attracted interest due to their topological properties and their potential applications in catalysis, et al., 2010; Pope & Müller, 2010; Coronado & Gómez-García, 1998). Up to date, a variety of strategies have been developed and used to assemble POM-based hybrid materials by controlling reaction factors such as metal ions, organic ligands, POM species, pH, molar ratio of raw materials or reaction environments (Wang et al., 2013; Liu et al., 2013). Even with these approaches, the design and synthesis of new stable polyoxidomolybdate complexes are still challenging.
electrochromism and magnetism (LongHerein, we report on the synthesis, UV–vis and IR spectra along with the 3H7NO)8][PMo12O40], (I).
of the hybrid europium(III) POM title compound, [Eu(C2. Structural commentary
The structures of the molecular components of compound (I) are illustrated in Fig. 1. The [PMo12O40]3− polyoxidoanion of (I) exhibits a classical α-Keggin-type structure. The central P atom is tetrahedrally surrounded with all four oxygen atoms (Oa) linked to four Mo3O13 moieties. The latter species are fused together by sharing corner atoms (Ob) and consist of three MoO6 octahedra condensed in a triangular arrangement by sharing edges (Oc). There is also a terminal oxygen atom (Od) in every MoO6 octahedron. The P—O bond lengths range from 1.521 (5) Å to 1.536 (4) Å and the Mo—O bond lengths from 1.690 (5) Å to 2.438 (4) Å. The O—P—O angles [109.1 (2)–109.8 (3)°] indicate only a slight distortion of the central PO4 tetrahedron. The EuIII cation is coordinated by eight dimethylformamide ligands through their oxygen atoms with Eu—O distances from 2.369 (5) to 2.416 (6) Å. These values are comparable to those of related oxido-europium(III) species, e.g for the [Eu(thd)3(DMF)2] complex (thd is the ion of 2,2,6,6-tetramethyl-3,5-heptanedione) with Eu—O = 2.494 (5)–2.442 (5) Å (Cunningham & Siever, 1980). Calculations with the SHAPE software (Alvarez et al., 2005) indicate that the of EuIII is a slightly distorted dodecahedron approaching molecular D2d symmetry (Casanova et al., 2005).
3. Supramolecular features
The . In the of (I), each [Eu(DMF)8]3+ cation is linked to four neighbouring α-Keggin-type [PMo12O40]3− anions through C—H⋯O hydrogen-bonding interactions between the methyl groups of the DMF ligands and the terminal-oxygen (Od) and the bridging-oxygen atoms (Ob,c) of the [PMo12O40]3− anions (Fig. 3, Table 1). The C(donor)⋯Od(acceptor) distances are between 3.174 (10) and 3.541 (11) Å while the C⋯O(b,c) distances are between 3.289 (11) and 3.473 (12) Å. In the crystal packing, the POM anions are packed into hexagonally arranged rows extending parallel to [001] with the [Eu(DMF)8]3+ cations located between the rows (Fig. 4).
content of the title compound is illustrated in Fig. 24. Synthesis and crystallization
The starting material [(C4H9)4N)4H3][PMo11O39] was prepared using a literature method (Combs-Walker & Hill, 1998). EuCl3·6H2O (361.41 mg, 1 mmol) and isonicotinic acid (C6H5NO2) (123.11 mg, 1 mmol) were dissolved in 10 ml of dimethylformamide. This solution was added dropwise to a yellow dimethylformamide solution of [(C4H9)4N)4H3][PMo11O39] (0.33 mmol in 10 ml). The mixture was heated under stirring for 1 h at 333 K. Single crystals of the title compounds were obtained by slow diffusion of 2-propanol through the dimethylformamide solution. UV–vis spectrum in dimethylformamide: λmax (nm) 315 and 205.
5. FT–IR spectroscopy
The FT–IR spectrum was recorded in the range 4000–400 cm−1 on a Nicolet 470 FT–IR spectrophotometer with pressed KBr pellets.
The FT–IR spectrum of (I) (Fig. 5) exhibits characteristic bands attributed to the stretching and deformation modes of the Mo—O bond vibration of the [PMo12O40]3− anion in the region 1100–400 cm−1. Thus, the asymmetric vibration νas(P—Oa), νas(Mo=Od), νas(Mo—Ob—Mo) and νas(Mo—Oc—Mo) appear at 1065, 951, 885 and 974 cm−1, respectively (Masteri-Farahani & Shahbazi, 2012). The absorption bands at 1265 and 1657 cm−1 are characteristic of the asymmetric vibration of the C—N and the C=O bonds, respectively. The vibration bands at 1115, 1440, 1385 and 2964 cm−1 are attributed to the vibration ρ(CH3) (rocking vibration), δa(CH3), δs(CH3) and ν(C-H) of the dimethylformamide ligand (Durgaprasad et al., 1971).
6. Refinement
Crystal data, data collection and structure . Hydrogen atoms were placed in calculated positions and refined as riding atoms: C—H = 0.93 Å and Uiso(H) = 1.2Ueq(C) for methine groups and C—H = 0.96 Å and Uiso(H) = 1.5Ueq(C) for methyl groups. The refined (Parsons et al., 2013) of −0.015 (7) indicates the correct determination of the absolute structure.
details are summarized in Table 2
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Supporting information
CCDC reference: 1456619
https://doi.org/10.1107/S2056989016003546/wm5274sup1.cif
contains datablock I. DOI:Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989016003546/wm5274Isup2.hkl
Data collection: APEX2 (Bruker, 2006); cell
SAINT (Bruker, 2006); data reduction: SAINT (Bruker, 2006); program(s) used to solve structure: SIR2004 (Burla et al., 2005); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012) and DIAMOND (Putz & Brandenburg, 2014); software used to prepare material for publication: WinGX (Farrugia, 2012).[Eu(C3H7NO)8][PMo12O40] | Dx = 2.559 Mg m−3 |
Mr = 2558.97 | Mo Kα radiation, λ = 0.71073 Å |
Orthorhombic, Pna21 | Cell parameters from 9528 reflections |
a = 26.9108 (10) Å | θ = 3.0–32.3° |
b = 18.3506 (6) Å | µ = 3.24 mm−1 |
c = 13.4494 (4) Å | T = 296 K |
V = 6641.7 (4) Å3 | Prism, yellow |
Z = 4 | 0.20 × 0.18 × 0.17 mm |
F(000) = 4888 |
Bruker APEXII CCD diffractometer | 19583 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.075 |
φ and ω scans | θmax = 37.1°, θmin = 2.2° |
Absorption correction: multi-scan (SADABS; Bruker, 2006) | h = −41→45 |
Tmin = 0.667, Tmax = 0.747 | k = −31→31 |
88354 measured reflections | l = −21→22 |
33285 independent reflections |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.047 | H-atom parameters constrained |
wR(F2) = 0.095 | w = 1/[σ2(Fo2) + (0.035P)2] where P = (Fo2 + 2Fc2)/3 |
S = 0.98 | (Δ/σ)max = 0.001 |
33285 reflections | Δρmax = 2.08 e Å−3 |
863 parameters | Δρmin = −1.80 e Å−3 |
1 restraint | Absolute structure: Flack x determined using 6924 quotients [(I+)-(I-)]/[(I+)+(I-)] |
Primary atom site location: structure-invariant direct methods | Absolute structure parameter: −0.015 (7) |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Eu1 | 0.62226 (2) | 0.24667 (2) | 0.27301 (3) | 0.03117 (7) | |
Mo1 | 0.26680 (2) | 0.18597 (3) | 0.63650 (5) | 0.03332 (13) | |
Mo2 | 0.30169 (2) | 0.35458 (3) | 0.55755 (5) | 0.03366 (13) | |
Mo3 | 0.41829 (3) | 0.43690 (3) | 0.64996 (5) | 0.03387 (13) | |
Mo4 | 0.47559 (2) | 0.36195 (3) | 0.85122 (5) | 0.03004 (12) | |
Mo5 | 0.49335 (2) | 0.20234 (3) | 0.68682 (5) | 0.03324 (13) | |
Mo6 | 0.39245 (3) | 0.10613 (3) | 0.60967 (5) | 0.03505 (14) | |
Mo7 | 0.32991 (3) | 0.10420 (3) | 0.85410 (5) | 0.03838 (15) | |
Mo8 | 0.43839 (3) | 0.17833 (4) | 0.93808 (5) | 0.03661 (14) | |
Mo9 | 0.32843 (3) | 0.26018 (4) | 0.99282 (5) | 0.04260 (17) | |
Mo10 | 0.36044 (2) | 0.43617 (3) | 0.87490 (5) | 0.03517 (14) | |
Mo11 | 0.25072 (2) | 0.33286 (4) | 0.78760 (5) | 0.03541 (14) | |
Mo12 | 0.42166 (3) | 0.26738 (4) | 0.49994 (5) | 0.03432 (13) | |
P1 | 0.37299 (6) | 0.26883 (8) | 0.74508 (12) | 0.0207 (3) | |
O1 | 0.6764 (2) | 0.1551 (4) | 0.2093 (5) | 0.0526 (16) | |
O2 | 0.2228 (2) | 0.1295 (3) | 0.5946 (5) | 0.0453 (14) | |
O3 | 0.26515 (19) | 0.2607 (3) | 0.5440 (4) | 0.0350 (11) | |
O4 | 0.34964 (18) | 0.4169 (3) | 0.6033 (4) | 0.0320 (10) | |
O5 | 0.47195 (19) | 0.4273 (3) | 0.7347 (4) | 0.0325 (11) | |
O6 | 0.5310 (2) | 0.3873 (3) | 0.8969 (4) | 0.0420 (13) | |
O7 | 0.49746 (19) | 0.2908 (3) | 0.7483 (4) | 0.0330 (11) | |
O8 | 0.45951 (19) | 0.1127 (2) | 0.6394 (4) | 0.0355 (11) | |
O9 | 0.32412 (19) | 0.1439 (3) | 0.5897 (4) | 0.0333 (11) | |
O10 | 0.3722 (2) | 0.0854 (3) | 0.7370 (4) | 0.0372 (12) | |
O11 | 0.3952 (2) | 0.1009 (3) | 0.9240 (4) | 0.0407 (13) | |
O12 | 0.45956 (19) | 0.2814 (3) | 0.9252 (4) | 0.0349 (11) | |
O13 | 0.3888 (2) | 0.2209 (3) | 1.0310 (4) | 0.0420 (13) | |
O14 | 0.3515 (2) | 0.3523 (3) | 0.9652 (4) | 0.0374 (12) | |
O15 | 0.30057 (19) | 0.4081 (3) | 0.8207 (4) | 0.0337 (11) | |
O16 | 0.1992 (2) | 0.3743 (4) | 0.8289 (5) | 0.0527 (16) | |
O17 | 0.25496 (19) | 0.3787 (3) | 0.6547 (4) | 0.0363 (11) | |
O18 | 0.22650 (19) | 0.2506 (3) | 0.7233 (4) | 0.0377 (12) | |
O19 | 0.32137 (16) | 0.2804 (2) | 0.7018 (3) | 0.0231 (9) | |
O20 | 0.36948 (17) | 0.2233 (2) | 0.8397 (3) | 0.0257 (9) | |
O21 | 0.39628 (16) | 0.3431 (2) | 0.7695 (3) | 0.0241 (8) | |
O22 | 0.40539 (17) | 0.2288 (2) | 0.6696 (3) | 0.0248 (9) | |
O23 | 0.35674 (19) | 0.2989 (3) | 0.5004 (4) | 0.0344 (11) | |
O24 | 0.4401 (3) | 0.2850 (4) | 0.3828 (4) | 0.0512 (15) | |
O25 | 0.43539 (19) | 0.3610 (3) | 0.5671 (4) | 0.0342 (11) | |
O26 | 0.48598 (18) | 0.2386 (3) | 0.5597 (4) | 0.0340 (11) | |
O27 | 0.4063 (2) | 0.1693 (3) | 0.4917 (4) | 0.0349 (11) | |
O28 | 0.3447 (2) | 0.5055 (3) | 0.9514 (5) | 0.0499 (15) | |
O29 | 0.38277 (19) | 0.4838 (2) | 0.7624 (4) | 0.0361 (11) | |
O30 | 0.43123 (19) | 0.4244 (3) | 0.9129 (4) | 0.0344 (11) | |
O31 | 0.3075 (2) | 0.1592 (3) | 0.9607 (4) | 0.0440 (14) | |
O32 | 0.4708 (2) | 0.1659 (3) | 0.8178 (4) | 0.0341 (11) | |
O33 | 0.4791 (3) | 0.1462 (4) | 1.0216 (5) | 0.0547 (16) | |
O34 | 0.2843 (2) | 0.1389 (3) | 0.7637 (4) | 0.0367 (11) | |
O35 | 0.4338 (2) | 0.5098 (3) | 0.5822 (5) | 0.0488 (15) | |
O36 | 0.2790 (2) | 0.3974 (3) | 0.4560 (4) | 0.0446 (14) | |
N1 | 0.6761 (3) | 0.4097 (4) | 0.0486 (6) | 0.0457 (17) | |
N2 | 0.5963 (3) | 0.3569 (4) | 0.5746 (5) | 0.0438 (16) | |
N3 | 0.7647 (3) | 0.3614 (4) | 0.3484 (6) | 0.0437 (16) | |
N4 | 0.5971 (3) | 0.1673 (3) | −0.0459 (5) | 0.0390 (15) | |
N5 | 0.4821 (3) | 0.3901 (4) | 0.2356 (6) | 0.0476 (18) | |
O47 | 0.6329 (3) | 0.1665 (4) | 0.4103 (5) | 0.0617 (19) | |
N7 | 0.6224 (3) | 0.0801 (4) | 0.5252 (5) | 0.0400 (15) | |
N8 | 0.4832 (3) | 0.1029 (4) | 0.2582 (6) | 0.0474 (17) | |
N9 | 0.7415 (3) | 0.0838 (4) | 0.1778 (6) | 0.0471 (17) | |
O37 | 0.2743 (2) | 0.2842 (3) | 0.8971 (4) | 0.0382 (12) | |
O38 | 0.2989 (3) | 0.2710 (4) | 1.1019 (4) | 0.0632 (19) | |
O39 | 0.3086 (3) | 0.0201 (3) | 0.8810 (5) | 0.0559 (17) | |
O55 | 0.5523 (2) | 0.1732 (3) | 0.6856 (5) | 0.0459 (14) | |
O40 | 0.6550 (2) | 0.3481 (3) | 0.1859 (5) | 0.0490 (14) | |
C2 | 0.6452 (3) | 0.3714 (4) | 0.1012 (7) | 0.046 (2) | |
H8 | 0.6142 | 0.3609 | 0.0743 | 0.055* | |
C3 | 0.7237 (4) | 0.4299 (5) | 0.0907 (9) | 0.061 (3) | |
H2 | 0.7185 | 0.4556 | 0.1520 | 0.092* | |
H3 | 0.7412 | 0.4606 | 0.0448 | 0.092* | |
H4 | 0.7429 | 0.3867 | 0.1032 | 0.092* | |
C4 | 0.6638 (5) | 0.4329 (6) | −0.0517 (7) | 0.067 (3) | |
H6 | 0.6861 | 0.4101 | −0.0980 | 0.101* | |
H7 | 0.6670 | 0.4849 | −0.0564 | 0.101* | |
H5 | 0.6303 | 0.4191 | −0.0668 | 0.101* | |
O41 | 0.6001 (3) | 0.3175 (4) | 0.4158 (5) | 0.0580 (17) | |
C6 | 0.6147 (3) | 0.3158 (5) | 0.5037 (7) | 0.051 (2) | |
H10 | 0.6400 | 0.2836 | 0.5200 | 0.062* | |
C7 | 0.6139 (4) | 0.3522 (7) | 0.6749 (7) | 0.067 (3) | |
H12 | 0.6340 | 0.3092 | 0.6823 | 0.100* | |
H13 | 0.5861 | 0.3496 | 0.7195 | 0.100* | |
H11 | 0.6335 | 0.3945 | 0.6902 | 0.100* | |
C8 | 0.5581 (4) | 0.4096 (6) | 0.5489 (8) | 0.068 (3) | |
H15 | 0.5724 | 0.4481 | 0.5099 | 0.102* | |
H16 | 0.5441 | 0.4297 | 0.6086 | 0.102* | |
H14 | 0.5324 | 0.3860 | 0.5112 | 0.102* | |
O42 | 0.7020 (2) | 0.2798 (3) | 0.3417 (5) | 0.0472 (14) | |
C10 | 0.7180 (3) | 0.3417 (4) | 0.3558 (6) | 0.0430 (18) | |
H18 | 0.6951 | 0.3774 | 0.3731 | 0.052* | |
C11 | 0.8025 (4) | 0.3079 (6) | 0.3206 (8) | 0.062 (3) | |
H19 | 0.7881 | 0.2600 | 0.3203 | 0.093* | |
H20 | 0.8293 | 0.3093 | 0.3678 | 0.093* | |
H21 | 0.8151 | 0.3190 | 0.2555 | 0.093* | |
C12 | 0.7807 (4) | 0.4351 (6) | 0.3660 (9) | 0.067 (3) | |
H22 | 0.7522 | 0.4657 | 0.3761 | 0.100* | |
H23 | 0.7992 | 0.4523 | 0.3096 | 0.100* | |
H24 | 0.8014 | 0.4365 | 0.4241 | 0.100* | |
O43 | 0.6047 (3) | 0.2262 (3) | 0.0990 (4) | 0.0514 (15) | |
C14 | 0.5960 (3) | 0.1715 (4) | 0.0515 (6) | 0.0422 (18) | |
H26 | 0.5881 | 0.1294 | 0.0866 | 0.051* | |
C15 | 0.5833 (4) | 0.1013 (4) | −0.0986 (6) | 0.046 (2) | |
H28 | 0.5798 | 0.0620 | −0.0519 | 0.069* | |
H29 | 0.6087 | 0.0894 | −0.1461 | 0.069* | |
H27 | 0.5523 | 0.1088 | −0.1325 | 0.069* | |
C16 | 0.6085 (4) | 0.2314 (5) | −0.1036 (7) | 0.055 (2) | |
H31 | 0.5807 | 0.2641 | −0.1021 | 0.082* | |
H30 | 0.6153 | 0.2175 | −0.1710 | 0.082* | |
H32 | 0.6372 | 0.2551 | −0.0759 | 0.082* | |
O44 | 0.5498 (2) | 0.3180 (4) | 0.2319 (5) | 0.0528 (16) | |
C18 | 0.5248 (3) | 0.3674 (4) | 0.2680 (8) | 0.0468 (19) | |
H34 | 0.5377 | 0.3907 | 0.3237 | 0.056* | |
C19 | 0.4532 (4) | 0.4425 (5) | 0.2893 (9) | 0.065 (3) | |
H35 | 0.4220 | 0.4211 | 0.3081 | 0.098* | |
H36 | 0.4472 | 0.4842 | 0.2479 | 0.098* | |
H37 | 0.4709 | 0.4573 | 0.3478 | 0.098* | |
C20 | 0.4613 (6) | 0.3597 (9) | 0.1481 (9) | 0.114 (6) | |
H39 | 0.4498 | 0.3982 | 0.1055 | 0.171* | |
H40 | 0.4338 | 0.3289 | 0.1656 | 0.171* | |
H38 | 0.4861 | 0.3316 | 0.1140 | 0.171* | |
C21 | 0.6486 (4) | 0.1287 (5) | 0.4775 (6) | 0.0453 (19) | |
H47 | 0.6816 | 0.1349 | 0.4962 | 0.054* | |
C22 | 0.5722 (3) | 0.0645 (5) | 0.4960 (9) | 0.058 (2) | |
H41 | 0.5499 | 0.0791 | 0.5481 | 0.087* | |
H42 | 0.5687 | 0.0132 | 0.4841 | 0.087* | |
H43 | 0.5645 | 0.0909 | 0.4364 | 0.087* | |
C23 | 0.6432 (4) | 0.0379 (6) | 0.6040 (8) | 0.064 (3) | |
H44 | 0.6776 | 0.0503 | 0.6120 | 0.096* | |
H46 | 0.6403 | −0.0130 | 0.5884 | 0.096* | |
H45 | 0.6257 | 0.0480 | 0.6646 | 0.096* | |
O45 | 0.5562 (2) | 0.1600 (3) | 0.2673 (5) | 0.0503 (14) | |
C25 | 0.5106 (3) | 0.1617 (4) | 0.2671 (7) | 0.0449 (19) | |
H55 | 0.4948 | 0.2066 | 0.2735 | 0.054* | |
C26 | 0.5044 (5) | 0.0336 (5) | 0.2361 (11) | 0.088 (4) | |
H49 | 0.5385 | 0.0398 | 0.2165 | 0.133* | |
H51 | 0.4862 | 0.0111 | 0.1830 | 0.133* | |
H50 | 0.5029 | 0.0031 | 0.2941 | 0.133* | |
C27 | 0.4286 (4) | 0.1112 (7) | 0.2546 (9) | 0.080 (4) | |
H52 | 0.4201 | 0.1618 | 0.2609 | 0.120* | |
H53 | 0.4139 | 0.0842 | 0.3081 | 0.120* | |
H54 | 0.4164 | 0.0930 | 0.1923 | 0.120* | |
C28 | 0.7155 (4) | 0.1265 (5) | 0.2333 (7) | 0.050 (2) | |
H56 | 0.7275 | 0.1363 | 0.2968 | 0.060* | |
C29 | 0.7248 (4) | 0.0661 (8) | 0.0795 (9) | 0.084 (4) | |
H58 | 0.7093 | 0.1081 | 0.0501 | 0.126* | |
H59 | 0.7012 | 0.0270 | 0.0829 | 0.126* | |
H57 | 0.7526 | 0.0514 | 0.0396 | 0.126* | |
C30 | 0.7896 (5) | 0.0544 (8) | 0.2084 (9) | 0.088 (4) | |
H61 | 0.8144 | 0.0676 | 0.1603 | 0.132* | |
H62 | 0.7875 | 0.0023 | 0.2129 | 0.132* | |
H60 | 0.7985 | 0.0741 | 0.2721 | 0.132* | |
O52 | 0.3886 (3) | 0.0253 (3) | 0.5521 (5) | 0.0571 (17) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Eu1 | 0.03342 (16) | 0.02974 (14) | 0.03036 (15) | −0.00241 (13) | −0.00034 (15) | −0.00084 (15) |
Mo1 | 0.0306 (3) | 0.0302 (3) | 0.0392 (3) | −0.0058 (2) | −0.0060 (3) | −0.0007 (3) |
Mo2 | 0.0306 (3) | 0.0352 (3) | 0.0352 (3) | 0.0008 (2) | −0.0079 (3) | 0.0104 (3) |
Mo3 | 0.0381 (3) | 0.0250 (3) | 0.0385 (3) | −0.0063 (2) | −0.0028 (3) | 0.0059 (3) |
Mo4 | 0.0258 (3) | 0.0310 (3) | 0.0333 (3) | 0.0000 (2) | −0.0034 (2) | −0.0058 (3) |
Mo5 | 0.0281 (3) | 0.0369 (3) | 0.0347 (3) | 0.0098 (2) | −0.0026 (3) | −0.0085 (3) |
Mo6 | 0.0397 (3) | 0.0252 (3) | 0.0403 (3) | 0.0005 (2) | 0.0023 (3) | −0.0095 (3) |
Mo7 | 0.0455 (4) | 0.0297 (3) | 0.0399 (4) | −0.0055 (3) | 0.0003 (3) | 0.0121 (3) |
Mo8 | 0.0409 (4) | 0.0384 (3) | 0.0306 (3) | 0.0043 (3) | −0.0081 (3) | 0.0091 (3) |
Mo9 | 0.0560 (4) | 0.0450 (4) | 0.0268 (3) | 0.0115 (3) | 0.0128 (3) | 0.0052 (3) |
Mo10 | 0.0317 (3) | 0.0291 (3) | 0.0447 (4) | 0.0035 (2) | 0.0021 (3) | −0.0131 (3) |
Mo11 | 0.0238 (3) | 0.0406 (3) | 0.0419 (4) | 0.0031 (2) | 0.0032 (3) | −0.0048 (3) |
Mo12 | 0.0406 (3) | 0.0386 (3) | 0.0238 (3) | 0.0044 (3) | 0.0064 (3) | 0.0030 (3) |
P1 | 0.0222 (7) | 0.0199 (6) | 0.0198 (7) | 0.0017 (5) | −0.0004 (5) | 0.0009 (5) |
O1 | 0.050 (4) | 0.057 (4) | 0.051 (4) | 0.014 (3) | −0.006 (3) | −0.014 (3) |
O2 | 0.040 (3) | 0.040 (3) | 0.056 (4) | −0.009 (2) | −0.007 (3) | −0.006 (3) |
O3 | 0.034 (3) | 0.036 (3) | 0.035 (3) | 0.000 (2) | −0.009 (2) | 0.001 (2) |
O4 | 0.034 (3) | 0.027 (2) | 0.035 (3) | 0.0005 (19) | −0.003 (2) | 0.005 (2) |
O5 | 0.032 (3) | 0.029 (2) | 0.037 (3) | −0.0049 (19) | 0.000 (2) | −0.002 (2) |
O6 | 0.031 (3) | 0.043 (3) | 0.052 (3) | −0.004 (2) | −0.013 (2) | −0.009 (3) |
O7 | 0.030 (3) | 0.032 (2) | 0.037 (3) | 0.0019 (19) | 0.002 (2) | −0.004 (2) |
O8 | 0.038 (3) | 0.027 (2) | 0.042 (3) | 0.008 (2) | 0.002 (2) | −0.007 (2) |
O9 | 0.035 (3) | 0.031 (2) | 0.033 (3) | 0.001 (2) | −0.005 (2) | −0.006 (2) |
O10 | 0.044 (3) | 0.029 (2) | 0.039 (3) | 0.004 (2) | 0.000 (2) | 0.001 (2) |
O11 | 0.051 (3) | 0.032 (3) | 0.040 (3) | 0.004 (2) | −0.005 (3) | 0.009 (2) |
O12 | 0.037 (3) | 0.035 (3) | 0.032 (3) | 0.004 (2) | 0.001 (2) | 0.000 (2) |
O13 | 0.054 (3) | 0.051 (3) | 0.021 (2) | 0.007 (3) | −0.003 (2) | 0.004 (2) |
O14 | 0.043 (3) | 0.040 (3) | 0.030 (3) | 0.006 (2) | 0.002 (2) | −0.003 (2) |
O15 | 0.029 (3) | 0.032 (2) | 0.040 (3) | 0.003 (2) | 0.002 (2) | −0.003 (2) |
O16 | 0.032 (3) | 0.061 (4) | 0.065 (4) | 0.007 (3) | 0.011 (3) | −0.009 (3) |
O17 | 0.031 (3) | 0.034 (2) | 0.044 (3) | 0.007 (2) | −0.002 (2) | 0.005 (2) |
O18 | 0.026 (3) | 0.040 (3) | 0.047 (3) | −0.004 (2) | 0.003 (2) | 0.000 (2) |
O19 | 0.025 (2) | 0.0205 (19) | 0.024 (2) | 0.0017 (16) | −0.0012 (17) | 0.0037 (17) |
O20 | 0.031 (2) | 0.023 (2) | 0.023 (2) | 0.0016 (17) | 0.0007 (18) | 0.0042 (18) |
O21 | 0.027 (2) | 0.0232 (18) | 0.022 (2) | 0.0028 (16) | 0.0001 (19) | −0.0043 (18) |
O22 | 0.030 (2) | 0.0222 (19) | 0.022 (2) | 0.0018 (17) | −0.0004 (18) | −0.0021 (17) |
O23 | 0.035 (3) | 0.038 (3) | 0.031 (3) | 0.002 (2) | −0.003 (2) | −0.001 (2) |
O24 | 0.064 (4) | 0.061 (4) | 0.028 (3) | 0.005 (3) | 0.016 (3) | 0.006 (3) |
O25 | 0.032 (3) | 0.035 (2) | 0.036 (3) | −0.001 (2) | 0.000 (2) | −0.003 (2) |
O26 | 0.029 (2) | 0.039 (3) | 0.033 (3) | 0.006 (2) | 0.007 (2) | −0.004 (2) |
O27 | 0.042 (3) | 0.038 (3) | 0.025 (2) | 0.006 (2) | −0.002 (2) | −0.008 (2) |
O28 | 0.050 (4) | 0.038 (3) | 0.062 (4) | 0.006 (3) | 0.004 (3) | −0.024 (3) |
O29 | 0.038 (3) | 0.0220 (19) | 0.048 (3) | 0.0043 (19) | −0.001 (2) | −0.002 (2) |
O30 | 0.032 (3) | 0.035 (2) | 0.036 (3) | 0.005 (2) | −0.003 (2) | −0.013 (2) |
O31 | 0.051 (4) | 0.039 (3) | 0.042 (3) | −0.002 (2) | 0.014 (3) | 0.013 (2) |
O32 | 0.042 (3) | 0.030 (2) | 0.030 (2) | 0.011 (2) | −0.002 (2) | 0.001 (2) |
O33 | 0.060 (4) | 0.061 (4) | 0.043 (3) | 0.013 (3) | −0.018 (3) | 0.010 (3) |
O34 | 0.041 (3) | 0.029 (2) | 0.039 (3) | −0.005 (2) | 0.005 (2) | 0.006 (2) |
O35 | 0.054 (4) | 0.038 (3) | 0.055 (4) | −0.012 (3) | −0.002 (3) | 0.014 (3) |
O36 | 0.047 (3) | 0.047 (3) | 0.040 (3) | 0.001 (3) | −0.016 (3) | 0.015 (3) |
N1 | 0.060 (5) | 0.033 (3) | 0.044 (4) | −0.002 (3) | 0.008 (4) | 0.000 (3) |
N2 | 0.040 (4) | 0.056 (4) | 0.035 (3) | 0.000 (3) | 0.004 (3) | −0.007 (3) |
N3 | 0.040 (4) | 0.041 (3) | 0.050 (4) | −0.002 (3) | −0.010 (3) | −0.007 (3) |
N4 | 0.041 (4) | 0.034 (3) | 0.043 (4) | 0.005 (3) | −0.008 (3) | −0.001 (3) |
N5 | 0.049 (4) | 0.039 (3) | 0.054 (4) | 0.007 (3) | 0.000 (3) | 0.012 (3) |
O47 | 0.072 (5) | 0.053 (4) | 0.060 (4) | −0.010 (3) | −0.008 (4) | 0.023 (3) |
N7 | 0.043 (4) | 0.037 (3) | 0.040 (4) | −0.005 (3) | 0.004 (3) | −0.002 (3) |
N8 | 0.045 (4) | 0.047 (4) | 0.050 (4) | −0.016 (3) | 0.006 (3) | −0.013 (3) |
N9 | 0.052 (4) | 0.043 (4) | 0.047 (4) | 0.005 (3) | 0.002 (3) | 0.001 (3) |
O37 | 0.040 (3) | 0.038 (3) | 0.036 (3) | 0.003 (2) | 0.011 (2) | 0.003 (2) |
O38 | 0.075 (5) | 0.085 (5) | 0.030 (3) | 0.017 (4) | 0.026 (3) | 0.003 (3) |
O39 | 0.072 (4) | 0.034 (3) | 0.061 (4) | −0.017 (3) | −0.003 (3) | 0.017 (3) |
O55 | 0.036 (3) | 0.054 (3) | 0.048 (3) | 0.017 (3) | −0.003 (3) | −0.015 (3) |
O40 | 0.059 (4) | 0.041 (3) | 0.047 (3) | −0.016 (3) | −0.004 (3) | 0.011 (3) |
C2 | 0.049 (5) | 0.029 (3) | 0.060 (6) | −0.006 (3) | −0.002 (4) | −0.003 (4) |
C3 | 0.051 (6) | 0.053 (5) | 0.079 (7) | −0.004 (4) | 0.017 (5) | 0.007 (5) |
C4 | 0.105 (9) | 0.059 (6) | 0.037 (5) | −0.012 (6) | 0.002 (5) | 0.008 (5) |
O41 | 0.057 (4) | 0.077 (4) | 0.040 (3) | 0.019 (4) | −0.004 (3) | −0.016 (3) |
C6 | 0.050 (5) | 0.058 (5) | 0.046 (5) | 0.014 (4) | −0.006 (4) | −0.009 (4) |
C7 | 0.062 (7) | 0.103 (9) | 0.036 (5) | −0.012 (6) | 0.012 (5) | −0.015 (5) |
C8 | 0.067 (7) | 0.080 (7) | 0.056 (6) | 0.019 (6) | 0.018 (5) | −0.007 (6) |
O42 | 0.041 (3) | 0.045 (3) | 0.056 (4) | −0.006 (3) | −0.012 (3) | −0.001 (3) |
C10 | 0.040 (4) | 0.042 (4) | 0.046 (5) | 0.000 (3) | −0.003 (4) | −0.005 (4) |
C11 | 0.047 (6) | 0.074 (7) | 0.066 (6) | 0.006 (5) | −0.002 (5) | −0.018 (5) |
C12 | 0.057 (6) | 0.065 (6) | 0.078 (7) | −0.023 (5) | −0.004 (6) | −0.009 (6) |
O43 | 0.073 (4) | 0.047 (3) | 0.033 (3) | 0.003 (3) | −0.010 (3) | −0.007 (3) |
C14 | 0.053 (5) | 0.039 (4) | 0.034 (4) | 0.003 (4) | −0.010 (4) | 0.000 (4) |
C15 | 0.061 (6) | 0.040 (4) | 0.038 (4) | 0.011 (4) | −0.013 (4) | −0.003 (3) |
C16 | 0.078 (7) | 0.042 (4) | 0.045 (5) | 0.005 (5) | −0.003 (5) | 0.004 (4) |
O44 | 0.052 (4) | 0.058 (4) | 0.049 (4) | 0.019 (3) | −0.002 (3) | 0.000 (3) |
C18 | 0.045 (5) | 0.042 (4) | 0.053 (5) | −0.003 (3) | −0.008 (4) | 0.000 (4) |
C19 | 0.058 (6) | 0.044 (5) | 0.093 (8) | 0.007 (4) | 0.007 (6) | 0.016 (5) |
C20 | 0.128 (13) | 0.149 (14) | 0.064 (8) | 0.055 (11) | −0.058 (9) | −0.021 (9) |
C21 | 0.049 (5) | 0.045 (4) | 0.042 (5) | −0.010 (4) | 0.001 (4) | 0.007 (4) |
C22 | 0.050 (5) | 0.044 (5) | 0.081 (7) | −0.011 (4) | 0.005 (5) | −0.006 (5) |
C23 | 0.075 (7) | 0.065 (6) | 0.051 (6) | −0.018 (5) | −0.011 (5) | 0.023 (5) |
O45 | 0.041 (3) | 0.046 (3) | 0.064 (4) | −0.013 (3) | −0.001 (3) | 0.008 (3) |
C25 | 0.050 (5) | 0.039 (4) | 0.046 (5) | −0.014 (3) | 0.003 (4) | −0.007 (4) |
C26 | 0.084 (9) | 0.041 (5) | 0.140 (13) | −0.009 (6) | 0.007 (8) | −0.008 (6) |
C27 | 0.052 (6) | 0.106 (9) | 0.083 (9) | −0.023 (6) | 0.014 (6) | −0.027 (7) |
C28 | 0.065 (6) | 0.044 (4) | 0.042 (5) | 0.009 (4) | 0.001 (4) | −0.013 (4) |
C29 | 0.070 (8) | 0.119 (10) | 0.063 (7) | 0.003 (7) | 0.001 (6) | −0.047 (7) |
C30 | 0.095 (10) | 0.100 (9) | 0.069 (8) | 0.057 (8) | −0.008 (7) | −0.006 (7) |
O52 | 0.069 (4) | 0.035 (3) | 0.067 (4) | −0.004 (3) | 0.007 (4) | −0.025 (3) |
Eu1—O40 | 2.369 (5) | N1—C3 | 1.450 (12) |
Eu1—O47 | 2.378 (6) | N1—C4 | 1.452 (12) |
Eu1—O1 | 2.383 (6) | N2—C6 | 1.311 (11) |
Eu1—O45 | 2.387 (5) | N2—C7 | 1.433 (12) |
Eu1—O41 | 2.395 (6) | N2—C8 | 1.455 (12) |
Eu1—O44 | 2.413 (6) | N3—C10 | 1.312 (11) |
Eu1—O42 | 2.415 (6) | N3—C12 | 1.438 (11) |
Eu1—O43 | 2.416 (6) | N3—C11 | 1.463 (12) |
Mo1—O2 | 1.672 (5) | N4—C14 | 1.313 (10) |
Mo1—O9 | 1.836 (5) | N4—C16 | 1.441 (11) |
Mo1—O3 | 1.852 (5) | N4—C15 | 1.452 (10) |
Mo1—O34 | 1.973 (5) | N5—C18 | 1.297 (11) |
Mo1—O18 | 1.986 (5) | N5—C20 | 1.417 (14) |
Mo1—O19 | 2.436 (4) | N5—C19 | 1.433 (12) |
Mo2—O36 | 1.690 (5) | O47—C21 | 1.214 (11) |
Mo2—O4 | 1.831 (5) | N7—C21 | 1.307 (10) |
Mo2—O17 | 1.866 (5) | N7—C23 | 1.427 (12) |
Mo2—O23 | 1.957 (5) | N7—C22 | 1.435 (11) |
Mo2—O3 | 1.993 (5) | N8—C25 | 1.313 (10) |
Mo2—O19 | 2.429 (4) | N8—C26 | 1.427 (13) |
Mo3—O35 | 1.672 (5) | N8—C27 | 1.477 (13) |
Mo3—O25 | 1.842 (5) | N9—C28 | 1.290 (11) |
Mo3—O5 | 1.848 (5) | N9—C29 | 1.435 (13) |
Mo3—O4 | 1.985 (5) | N9—C30 | 1.461 (14) |
Mo3—O29 | 1.985 (5) | O40—C2 | 1.245 (11) |
Mo3—O21 | 2.428 (4) | C2—H8 | 0.9300 |
Mo4—O6 | 1.677 (5) | C3—H2 | 0.9600 |
Mo4—O12 | 1.834 (5) | C3—H3 | 0.9600 |
Mo4—O30 | 1.851 (5) | C3—H4 | 0.9600 |
Mo4—O5 | 1.976 (5) | C4—H6 | 0.9600 |
Mo4—O7 | 1.992 (5) | C4—H7 | 0.9600 |
Mo4—O21 | 2.426 (4) | C4—H5 | 0.9600 |
Mo5—O55 | 1.675 (5) | O41—C6 | 1.245 (11) |
Mo5—O7 | 1.825 (5) | C6—H10 | 0.9300 |
Mo5—O26 | 1.845 (5) | C7—H12 | 0.9600 |
Mo5—O32 | 1.979 (5) | C7—H13 | 0.9600 |
Mo5—O8 | 1.985 (5) | C7—H11 | 0.9600 |
Mo5—O22 | 2.428 (5) | C8—H15 | 0.9600 |
Mo6—O52 | 1.676 (5) | C8—H16 | 0.9600 |
Mo6—O10 | 1.837 (5) | C8—H14 | 0.9600 |
Mo6—O8 | 1.852 (5) | O42—C10 | 1.228 (9) |
Mo6—O9 | 1.983 (5) | C10—H18 | 0.9300 |
Mo6—O27 | 2.000 (5) | C11—H19 | 0.9600 |
Mo6—O22 | 2.416 (4) | C11—H20 | 0.9600 |
Mo7—O39 | 1.686 (5) | C11—H21 | 0.9600 |
Mo7—O34 | 1.842 (6) | C12—H22 | 0.9600 |
Mo7—O31 | 1.854 (6) | C12—H23 | 0.9600 |
Mo7—O10 | 1.973 (6) | C12—H24 | 0.9600 |
Mo7—O11 | 1.994 (6) | O43—C14 | 1.214 (10) |
Mo7—O20 | 2.438 (4) | C14—H26 | 0.9300 |
Mo8—O33 | 1.675 (6) | C15—H28 | 0.9600 |
Mo8—O11 | 1.844 (6) | C15—H29 | 0.9600 |
Mo8—O32 | 1.853 (5) | C15—H27 | 0.9600 |
Mo8—O12 | 1.983 (5) | C16—H31 | 0.9600 |
Mo8—O13 | 1.987 (6) | C16—H30 | 0.9600 |
Mo8—O20 | 2.423 (4) | C16—H32 | 0.9600 |
Mo9—O38 | 1.680 (6) | O44—C18 | 1.229 (10) |
Mo9—O14 | 1.838 (6) | C18—H34 | 0.9300 |
Mo9—O13 | 1.851 (6) | C19—H35 | 0.9600 |
Mo9—O31 | 1.984 (6) | C19—H36 | 0.9600 |
Mo9—O37 | 1.993 (6) | C19—H37 | 0.9600 |
Mo9—O20 | 2.433 (5) | C20—H39 | 0.9600 |
Mo10—O28 | 1.690 (5) | C20—H40 | 0.9600 |
Mo10—O15 | 1.842 (5) | C20—H38 | 0.9600 |
Mo10—O29 | 1.847 (6) | C21—H47 | 0.9300 |
Mo10—O14 | 1.976 (5) | C22—H41 | 0.9600 |
Mo10—O30 | 1.984 (5) | C22—H42 | 0.9600 |
Mo10—O21 | 2.420 (4) | C22—H43 | 0.9600 |
Mo11—O16 | 1.676 (6) | C23—H44 | 0.9600 |
Mo11—O37 | 1.836 (5) | C23—H46 | 0.9600 |
Mo11—O18 | 1.857 (5) | C23—H45 | 0.9600 |
Mo11—O15 | 1.976 (5) | O45—C25 | 1.227 (10) |
Mo11—O17 | 1.979 (5) | C25—H55 | 0.9300 |
Mo11—O19 | 2.423 (4) | C26—H49 | 0.9600 |
Mo12—O24 | 1.684 (5) | C26—H51 | 0.9600 |
Mo12—O23 | 1.840 (5) | C26—H50 | 0.9600 |
Mo12—O27 | 1.850 (5) | C27—H52 | 0.9600 |
Mo12—O25 | 1.976 (5) | C27—H53 | 0.9600 |
Mo12—O26 | 1.980 (5) | C27—H54 | 0.9600 |
Mo12—O22 | 2.428 (4) | C28—H56 | 0.9300 |
P1—O19 | 1.521 (5) | C29—H58 | 0.9600 |
P1—O20 | 1.526 (5) | C29—H59 | 0.9600 |
P1—O22 | 1.527 (5) | C29—H57 | 0.9600 |
P1—O21 | 1.536 (4) | C30—H61 | 0.9600 |
O1—C28 | 1.219 (11) | C30—H62 | 0.9600 |
N1—C2 | 1.297 (11) | C30—H60 | 0.9600 |
O40—Eu1—O47 | 145.6 (2) | O26—Mo12—O22 | 72.45 (18) |
O40—Eu1—O1 | 98.6 (2) | O19—P1—O20 | 109.8 (3) |
O47—Eu1—O1 | 76.7 (2) | O19—P1—O22 | 109.5 (3) |
O40—Eu1—O45 | 141.7 (2) | O20—P1—O22 | 109.1 (2) |
O47—Eu1—O45 | 72.7 (2) | O19—P1—O21 | 109.3 (2) |
O1—Eu1—O45 | 88.5 (2) | O20—P1—O21 | 109.5 (3) |
O40—Eu1—O41 | 93.6 (2) | O22—P1—O21 | 109.6 (3) |
O47—Eu1—O41 | 75.1 (3) | C28—O1—Eu1 | 137.4 (6) |
O1—Eu1—O41 | 145.4 (2) | Mo1—O3—Mo2 | 124.5 (3) |
O45—Eu1—O41 | 101.7 (2) | Mo2—O4—Mo3 | 151.4 (3) |
O40—Eu1—O44 | 76.2 (2) | Mo3—O5—Mo4 | 125.8 (3) |
O47—Eu1—O44 | 127.6 (2) | Mo5—O7—Mo4 | 151.7 (3) |
O1—Eu1—O44 | 142.6 (2) | Mo6—O8—Mo5 | 124.8 (2) |
O45—Eu1—O44 | 75.6 (2) | Mo1—O9—Mo6 | 151.6 (3) |
O41—Eu1—O44 | 71.8 (2) | Mo6—O10—Mo7 | 151.5 (3) |
O40—Eu1—O42 | 70.2 (2) | Mo8—O11—Mo7 | 125.5 (3) |
O47—Eu1—O42 | 75.6 (2) | Mo4—O12—Mo8 | 152.1 (3) |
O1—Eu1—O42 | 76.8 (2) | Mo9—O13—Mo8 | 124.6 (3) |
O45—Eu1—O42 | 147.4 (2) | Mo9—O14—Mo10 | 151.8 (3) |
O41—Eu1—O42 | 77.2 (2) | Mo10—O15—Mo11 | 151.4 (3) |
O44—Eu1—O42 | 132.0 (2) | Mo2—O17—Mo11 | 124.8 (3) |
O40—Eu1—O43 | 73.5 (2) | Mo11—O18—Mo1 | 124.6 (3) |
O47—Eu1—O43 | 132.8 (2) | P1—O19—Mo11 | 126.2 (2) |
O1—Eu1—O43 | 70.2 (2) | P1—O19—Mo2 | 125.7 (2) |
O45—Eu1—O43 | 73.7 (2) | Mo11—O19—Mo2 | 89.23 (14) |
O41—Eu1—O43 | 144.3 (2) | P1—O19—Mo1 | 126.1 (2) |
O44—Eu1—O43 | 72.8 (2) | Mo11—O19—Mo1 | 88.93 (15) |
O42—Eu1—O43 | 125.7 (2) | Mo2—O19—Mo1 | 88.80 (15) |
O2—Mo1—O9 | 102.7 (3) | P1—O20—Mo8 | 126.5 (3) |
O2—Mo1—O3 | 102.4 (3) | P1—O20—Mo9 | 125.6 (2) |
O9—Mo1—O3 | 95.8 (2) | Mo8—O20—Mo9 | 88.87 (15) |
O2—Mo1—O34 | 101.0 (3) | P1—O20—Mo7 | 125.7 (3) |
O9—Mo1—O34 | 85.0 (2) | Mo8—O20—Mo7 | 89.20 (14) |
O3—Mo1—O34 | 155.8 (2) | Mo9—O20—Mo7 | 89.09 (15) |
O2—Mo1—O18 | 100.5 (3) | P1—O21—Mo10 | 126.1 (3) |
O9—Mo1—O18 | 155.7 (2) | P1—O21—Mo4 | 125.6 (2) |
O3—Mo1—O18 | 86.5 (2) | Mo10—O21—Mo4 | 89.12 (14) |
O34—Mo1—O18 | 83.2 (2) | P1—O21—Mo3 | 126.0 (3) |
O2—Mo1—O19 | 171.9 (2) | Mo10—O21—Mo3 | 89.13 (13) |
O9—Mo1—O19 | 85.20 (18) | Mo4—O21—Mo3 | 89.11 (14) |
O3—Mo1—O19 | 74.36 (18) | P1—O22—Mo6 | 126.0 (3) |
O34—Mo1—O19 | 81.65 (18) | P1—O22—Mo5 | 126.1 (3) |
O18—Mo1—O19 | 72.08 (18) | Mo6—O22—Mo5 | 89.19 (14) |
O36—Mo2—O4 | 103.7 (2) | P1—O22—Mo12 | 126.0 (2) |
O36—Mo2—O17 | 102.2 (3) | Mo6—O22—Mo12 | 89.10 (14) |
O4—Mo2—O17 | 95.3 (2) | Mo5—O22—Mo12 | 88.42 (15) |
O36—Mo2—O23 | 101.5 (3) | Mo12—O23—Mo2 | 152.1 (3) |
O4—Mo2—O23 | 85.7 (2) | Mo3—O25—Mo12 | 152.5 (3) |
O17—Mo2—O23 | 155.4 (2) | Mo5—O26—Mo12 | 124.5 (3) |
O36—Mo2—O3 | 98.6 (3) | Mo12—O27—Mo6 | 123.9 (3) |
O4—Mo2—O3 | 156.8 (2) | Mo10—O29—Mo3 | 125.1 (2) |
O17—Mo2—O3 | 86.4 (2) | Mo4—O30—Mo10 | 124.8 (3) |
O23—Mo2—O3 | 83.5 (2) | Mo7—O31—Mo9 | 125.8 (3) |
O36—Mo2—O19 | 170.1 (2) | Mo8—O32—Mo5 | 151.7 (3) |
O4—Mo2—O19 | 85.87 (18) | Mo7—O34—Mo1 | 152.0 (3) |
O17—Mo2—O19 | 73.79 (19) | C2—N1—C3 | 119.4 (8) |
O23—Mo2—O19 | 81.74 (18) | C2—N1—C4 | 121.4 (9) |
O3—Mo2—O19 | 72.30 (18) | C3—N1—C4 | 119.2 (8) |
O35—Mo3—O25 | 102.3 (3) | C6—N2—C7 | 121.7 (8) |
O35—Mo3—O5 | 102.5 (3) | C6—N2—C8 | 118.4 (8) |
O25—Mo3—O5 | 96.1 (2) | C7—N2—C8 | 119.9 (8) |
O35—Mo3—O4 | 102.0 (3) | C10—N3—C12 | 122.2 (8) |
O25—Mo3—O4 | 84.4 (2) | C10—N3—C11 | 120.0 (7) |
O5—Mo3—O4 | 154.8 (2) | C12—N3—C11 | 117.8 (8) |
O35—Mo3—O29 | 100.9 (3) | C14—N4—C16 | 119.6 (7) |
O25—Mo3—O29 | 155.3 (2) | C14—N4—C15 | 122.0 (7) |
O5—Mo3—O29 | 87.0 (2) | C16—N4—C15 | 118.2 (7) |
O4—Mo3—O29 | 82.7 (2) | C18—N5—C20 | 120.2 (9) |
O35—Mo3—O21 | 171.5 (2) | C18—N5—C19 | 121.8 (9) |
O25—Mo3—O21 | 85.71 (19) | C20—N5—C19 | 117.9 (10) |
O5—Mo3—O21 | 73.44 (19) | C21—O47—Eu1 | 166.5 (7) |
O4—Mo3—O21 | 81.45 (17) | C21—N7—C23 | 121.6 (8) |
O29—Mo3—O21 | 71.66 (17) | C21—N7—C22 | 120.6 (8) |
O6—Mo4—O12 | 103.5 (3) | C23—N7—C22 | 117.7 (8) |
O6—Mo4—O30 | 103.7 (2) | C25—N8—C26 | 121.7 (9) |
O12—Mo4—O30 | 96.0 (2) | C25—N8—C27 | 118.5 (9) |
O6—Mo4—O5 | 99.6 (2) | C26—N8—C27 | 118.9 (9) |
O12—Mo4—O5 | 155.3 (2) | C28—N9—C29 | 120.0 (9) |
O30—Mo4—O5 | 87.0 (2) | C28—N9—C30 | 122.9 (9) |
O6—Mo4—O7 | 100.0 (2) | C29—N9—C30 | 117.0 (9) |
O12—Mo4—O7 | 85.3 (2) | Mo11—O37—Mo9 | 151.5 (3) |
O30—Mo4—O7 | 155.2 (2) | C2—O40—Eu1 | 130.2 (5) |
O5—Mo4—O7 | 82.0 (2) | O40—C2—N1 | 123.4 (9) |
O6—Mo4—O21 | 170.8 (2) | O40—C2—H8 | 118.3 |
O12—Mo4—O21 | 85.6 (2) | N1—C2—H8 | 118.3 |
O30—Mo4—O21 | 73.97 (19) | N1—C3—H2 | 109.5 |
O5—Mo4—O21 | 71.54 (18) | N1—C3—H3 | 109.5 |
O7—Mo4—O21 | 81.47 (18) | H2—C3—H3 | 109.5 |
O55—Mo5—O7 | 103.4 (3) | N1—C3—H4 | 109.5 |
O55—Mo5—O26 | 102.0 (3) | H2—C3—H4 | 109.5 |
O7—Mo5—O26 | 96.1 (2) | H3—C3—H4 | 109.5 |
O55—Mo5—O32 | 101.0 (3) | N1—C4—H6 | 109.5 |
O7—Mo5—O32 | 85.1 (2) | N1—C4—H7 | 109.5 |
O26—Mo5—O32 | 156.0 (2) | H6—C4—H7 | 109.5 |
O55—Mo5—O8 | 99.6 (3) | N1—C4—H5 | 109.5 |
O7—Mo5—O8 | 155.5 (2) | H6—C4—H5 | 109.5 |
O26—Mo5—O8 | 87.2 (2) | H7—C4—H5 | 109.5 |
O32—Mo5—O8 | 82.3 (2) | C6—O41—Eu1 | 132.0 (6) |
O55—Mo5—O22 | 170.7 (2) | O41—C6—N2 | 123.9 (9) |
O7—Mo5—O22 | 85.67 (19) | O41—C6—H10 | 118.1 |
O26—Mo5—O22 | 74.59 (18) | N2—C6—H10 | 118.1 |
O32—Mo5—O22 | 81.61 (18) | N2—C7—H12 | 109.5 |
O8—Mo5—O22 | 71.80 (17) | N2—C7—H13 | 109.5 |
O52—Mo6—O10 | 103.3 (3) | H12—C7—H13 | 109.5 |
O52—Mo6—O8 | 102.5 (3) | N2—C7—H11 | 109.5 |
O10—Mo6—O8 | 95.8 (2) | H12—C7—H11 | 109.5 |
O52—Mo6—O9 | 100.9 (3) | H13—C7—H11 | 109.5 |
O10—Mo6—O9 | 85.6 (2) | N2—C8—H15 | 109.5 |
O8—Mo6—O9 | 155.5 (2) | N2—C8—H16 | 109.5 |
O52—Mo6—O27 | 99.1 (3) | H15—C8—H16 | 109.5 |
O10—Mo6—O27 | 156.2 (2) | N2—C8—H14 | 109.5 |
O8—Mo6—O27 | 87.2 (2) | H15—C8—H14 | 109.5 |
O9—Mo6—O27 | 82.1 (2) | H16—C8—H14 | 109.5 |
O52—Mo6—O22 | 170.8 (3) | C10—O42—Eu1 | 127.1 (5) |
O10—Mo6—O22 | 85.69 (19) | O42—C10—N3 | 125.4 (8) |
O8—Mo6—O22 | 74.14 (18) | O42—C10—H18 | 117.3 |
O9—Mo6—O22 | 81.56 (18) | N3—C10—H18 | 117.3 |
O27—Mo6—O22 | 72.40 (17) | N3—C11—H19 | 109.5 |
O39—Mo7—O34 | 103.4 (3) | N3—C11—H20 | 109.5 |
O39—Mo7—O31 | 102.8 (3) | H19—C11—H20 | 109.5 |
O34—Mo7—O31 | 96.1 (3) | N3—C11—H21 | 109.5 |
O39—Mo7—O10 | 102.0 (3) | H19—C11—H21 | 109.5 |
O34—Mo7—O10 | 85.3 (2) | H20—C11—H21 | 109.5 |
O31—Mo7—O10 | 154.1 (2) | N3—C12—H22 | 109.5 |
O39—Mo7—O11 | 99.8 (3) | N3—C12—H23 | 109.5 |
O34—Mo7—O11 | 155.4 (2) | H22—C12—H23 | 109.5 |
O31—Mo7—O11 | 86.4 (3) | N3—C12—H24 | 109.5 |
O10—Mo7—O11 | 82.1 (2) | H22—C12—H24 | 109.5 |
O39—Mo7—O20 | 170.4 (3) | H23—C12—H24 | 109.5 |
O34—Mo7—O20 | 85.93 (18) | C14—O43—Eu1 | 132.6 (5) |
O31—Mo7—O20 | 73.5 (2) | O43—C14—N4 | 124.7 (8) |
O10—Mo7—O20 | 80.88 (19) | O43—C14—H26 | 117.6 |
O11—Mo7—O20 | 71.30 (18) | N4—C14—H26 | 117.6 |
O33—Mo8—O11 | 102.1 (3) | N4—C15—H28 | 109.5 |
O33—Mo8—O32 | 103.5 (3) | N4—C15—H29 | 109.5 |
O11—Mo8—O32 | 96.5 (2) | H28—C15—H29 | 109.5 |
O33—Mo8—O12 | 101.9 (3) | N4—C15—H27 | 109.5 |
O11—Mo8—O12 | 155.0 (2) | H28—C15—H27 | 109.5 |
O32—Mo8—O12 | 84.6 (2) | H29—C15—H27 | 109.5 |
O33—Mo8—O13 | 98.9 (3) | N4—C16—H31 | 109.5 |
O11—Mo8—O13 | 86.8 (3) | N4—C16—H30 | 109.5 |
O32—Mo8—O13 | 156.0 (2) | H31—C16—H30 | 109.5 |
O12—Mo8—O13 | 82.7 (2) | N4—C16—H32 | 109.5 |
O33—Mo8—O20 | 170.4 (3) | H31—C16—H32 | 109.5 |
O11—Mo8—O20 | 74.0 (2) | H30—C16—H32 | 109.5 |
O32—Mo8—O20 | 85.74 (19) | C18—O44—Eu1 | 138.8 (6) |
O12—Mo8—O20 | 81.23 (18) | O44—C18—N5 | 126.1 (9) |
O13—Mo8—O20 | 72.31 (19) | O44—C18—H34 | 117.0 |
O38—Mo9—O14 | 103.1 (3) | N5—C18—H34 | 117.0 |
O38—Mo9—O13 | 102.6 (3) | N5—C19—H35 | 109.5 |
O14—Mo9—O13 | 96.7 (3) | N5—C19—H36 | 109.5 |
O38—Mo9—O31 | 99.6 (3) | H35—C19—H36 | 109.5 |
O14—Mo9—O31 | 155.6 (2) | N5—C19—H37 | 109.5 |
O13—Mo9—O31 | 86.9 (3) | H35—C19—H37 | 109.5 |
O38—Mo9—O37 | 101.1 (3) | H36—C19—H37 | 109.5 |
O14—Mo9—O37 | 85.0 (2) | N5—C20—H39 | 109.5 |
O13—Mo9—O37 | 155.1 (2) | N5—C20—H40 | 109.5 |
O31—Mo9—O37 | 81.9 (2) | H39—C20—H40 | 109.5 |
O38—Mo9—O20 | 170.6 (3) | N5—C20—H38 | 109.5 |
O14—Mo9—O20 | 86.07 (19) | H39—C20—H38 | 109.5 |
O13—Mo9—O20 | 74.19 (19) | H40—C20—H38 | 109.5 |
O31—Mo9—O20 | 71.60 (19) | O47—C21—N7 | 124.6 (9) |
O37—Mo9—O20 | 81.18 (18) | O47—C21—H47 | 117.7 |
O28—Mo10—O15 | 103.4 (3) | N7—C21—H47 | 117.7 |
O28—Mo10—O29 | 103.0 (3) | N7—C22—H41 | 109.5 |
O15—Mo10—O29 | 95.3 (2) | N7—C22—H42 | 109.5 |
O28—Mo10—O14 | 100.5 (3) | H41—C22—H42 | 109.5 |
O15—Mo10—O14 | 85.4 (2) | N7—C22—H43 | 109.5 |
O29—Mo10—O14 | 155.7 (2) | H41—C22—H43 | 109.5 |
O28—Mo10—O30 | 99.6 (3) | H42—C22—H43 | 109.5 |
O15—Mo10—O30 | 155.7 (2) | N7—C23—H44 | 109.5 |
O29—Mo10—O30 | 87.1 (2) | N7—C23—H46 | 109.5 |
O14—Mo10—O30 | 82.7 (2) | H44—C23—H46 | 109.5 |
O28—Mo10—O21 | 171.0 (2) | N7—C23—H45 | 109.5 |
O15—Mo10—O21 | 85.38 (19) | H44—C23—H45 | 109.5 |
O29—Mo10—O21 | 74.00 (18) | H46—C23—H45 | 109.5 |
O14—Mo10—O21 | 81.87 (18) | C25—O45—Eu1 | 136.7 (6) |
O30—Mo10—O21 | 72.04 (17) | O45—C25—N8 | 122.8 (8) |
O16—Mo11—O37 | 104.0 (3) | O45—C25—H55 | 118.6 |
O16—Mo11—O18 | 103.5 (3) | N8—C25—H55 | 118.6 |
O37—Mo11—O18 | 95.7 (2) | N8—C26—H49 | 109.5 |
O16—Mo11—O15 | 99.8 (3) | N8—C26—H51 | 109.5 |
O37—Mo11—O15 | 85.6 (2) | H49—C26—H51 | 109.5 |
O18—Mo11—O15 | 155.6 (2) | N8—C26—H50 | 109.5 |
O16—Mo11—O17 | 98.8 (3) | H49—C26—H50 | 109.5 |
O37—Mo11—O17 | 155.7 (2) | H51—C26—H50 | 109.5 |
O18—Mo11—O17 | 86.8 (2) | N8—C27—H52 | 109.5 |
O15—Mo11—O17 | 82.4 (2) | N8—C27—H53 | 109.5 |
O16—Mo11—O19 | 170.7 (3) | H52—C27—H53 | 109.5 |
O37—Mo11—O19 | 85.24 (19) | N8—C27—H54 | 109.5 |
O18—Mo11—O19 | 74.38 (19) | H52—C27—H54 | 109.5 |
O15—Mo11—O19 | 81.50 (18) | H53—C27—H54 | 109.5 |
O17—Mo11—O19 | 72.16 (18) | O1—C28—N9 | 125.3 (9) |
O24—Mo12—O23 | 102.9 (3) | O1—C28—H56 | 117.4 |
O24—Mo12—O27 | 101.4 (3) | N9—C28—H56 | 117.4 |
O23—Mo12—O27 | 95.4 (2) | N9—C29—H58 | 109.5 |
O24—Mo12—O25 | 101.9 (3) | N9—C29—H59 | 109.5 |
O23—Mo12—O25 | 84.4 (2) | H58—C29—H59 | 109.5 |
O27—Mo12—O25 | 156.2 (2) | N9—C29—H57 | 109.5 |
O24—Mo12—O26 | 100.0 (3) | H58—C29—H57 | 109.5 |
O23—Mo12—O26 | 155.8 (2) | H59—C29—H57 | 109.5 |
O27—Mo12—O26 | 87.7 (2) | N9—C30—H61 | 109.5 |
O25—Mo12—O26 | 83.2 (2) | N9—C30—H62 | 109.5 |
O24—Mo12—O22 | 171.3 (3) | H61—C30—H62 | 109.5 |
O23—Mo12—O22 | 85.27 (19) | N9—C30—H60 | 109.5 |
O27—Mo12—O22 | 74.48 (18) | H61—C30—H60 | 109.5 |
O25—Mo12—O22 | 81.80 (18) | H62—C30—H60 | 109.5 |
O2—Mo1—O3—Mo2 | 171.0 (3) | O22—P1—O21—Mo10 | 175.5 (3) |
O9—Mo1—O3—Mo2 | −84.6 (3) | O19—P1—O21—Mo4 | 175.3 (3) |
O34—Mo1—O3—Mo2 | 6.0 (8) | O20—P1—O21—Mo4 | 55.0 (4) |
O18—Mo1—O3—Mo2 | 71.1 (3) | O22—P1—O21—Mo4 | −64.6 (4) |
O19—Mo1—O3—Mo2 | −1.3 (3) | O19—P1—O21—Mo3 | −64.9 (3) |
O36—Mo2—O4—Mo3 | −129.9 (6) | O20—P1—O21—Mo3 | 174.7 (3) |
O17—Mo2—O4—Mo3 | 126.1 (6) | O22—P1—O21—Mo3 | 55.1 (3) |
O23—Mo2—O4—Mo3 | −29.1 (6) | O19—P1—O22—Mo6 | −64.7 (3) |
O3—Mo2—O4—Mo3 | 33.1 (10) | O20—P1—O22—Mo6 | 55.5 (4) |
O19—Mo2—O4—Mo3 | 52.9 (6) | O21—P1—O22—Mo6 | 175.3 (3) |
O35—Mo3—O5—Mo4 | 169.8 (3) | O19—P1—O22—Mo5 | 174.7 (3) |
O25—Mo3—O5—Mo4 | −86.2 (3) | O20—P1—O22—Mo5 | −65.1 (3) |
O4—Mo3—O5—Mo4 | 3.4 (7) | O21—P1—O22—Mo5 | 54.8 (4) |
O29—Mo3—O5—Mo4 | 69.3 (3) | O19—P1—O22—Mo12 | 55.5 (4) |
O21—Mo3—O5—Mo4 | −2.5 (3) | O20—P1—O22—Mo12 | 175.7 (3) |
O55—Mo5—O7—Mo4 | −129.4 (6) | O21—P1—O22—Mo12 | −64.4 (4) |
O26—Mo5—O7—Mo4 | 126.7 (6) | O24—Mo12—O23—Mo2 | −130.2 (6) |
O32—Mo5—O7—Mo4 | −29.2 (6) | O27—Mo12—O23—Mo2 | 126.8 (6) |
O8—Mo5—O7—Mo4 | 30.1 (10) | O25—Mo12—O23—Mo2 | −29.3 (6) |
O22—Mo5—O7—Mo4 | 52.8 (6) | O26—Mo12—O23—Mo2 | 30.3 (10) |
O52—Mo6—O8—Mo5 | 168.5 (4) | O22—Mo12—O23—Mo2 | 52.9 (6) |
O10—Mo6—O8—Mo5 | −86.5 (3) | O35—Mo3—O25—Mo12 | −132.4 (7) |
O9—Mo6—O8—Mo5 | 5.7 (8) | O5—Mo3—O25—Mo12 | 123.3 (7) |
O27—Mo6—O8—Mo5 | 69.8 (3) | O4—Mo3—O25—Mo12 | −31.3 (6) |
O22—Mo6—O8—Mo5 | −2.7 (3) | O29—Mo3—O25—Mo12 | 27.3 (10) |
O2—Mo1—O9—Mo6 | −129.2 (6) | O21—Mo3—O25—Mo12 | 50.5 (6) |
O3—Mo1—O9—Mo6 | 126.6 (6) | O55—Mo5—O26—Mo12 | 169.1 (3) |
O34—Mo1—O9—Mo6 | −29.1 (6) | O7—Mo5—O26—Mo12 | −85.8 (3) |
O18—Mo1—O9—Mo6 | 32.2 (10) | O32—Mo5—O26—Mo12 | 5.8 (7) |
O19—Mo1—O9—Mo6 | 52.9 (6) | O8—Mo5—O26—Mo12 | 69.8 (3) |
O52—Mo6—O10—Mo7 | −128.1 (7) | O22—Mo5—O26—Mo12 | −2.0 (3) |
O8—Mo6—O10—Mo7 | 127.5 (7) | O24—Mo12—O27—Mo6 | 169.1 (3) |
O9—Mo6—O10—Mo7 | −27.9 (7) | O23—Mo12—O27—Mo6 | −86.6 (3) |
O27—Mo6—O10—Mo7 | 31.2 (11) | O25—Mo12—O27—Mo6 | 1.8 (8) |
O22—Mo6—O10—Mo7 | 54.0 (7) | O26—Mo12—O27—Mo6 | 69.4 (3) |
O33—Mo8—O11—Mo7 | 168.8 (4) | O22—Mo12—O27—Mo6 | −3.0 (3) |
O32—Mo8—O11—Mo7 | −85.8 (4) | O28—Mo10—O29—Mo3 | 168.8 (3) |
O12—Mo8—O11—Mo7 | 5.2 (8) | O15—Mo10—O29—Mo3 | −86.1 (3) |
O13—Mo8—O11—Mo7 | 70.3 (4) | O14—Mo10—O29—Mo3 | 4.4 (8) |
O20—Mo8—O11—Mo7 | −2.2 (3) | O30—Mo10—O29—Mo3 | 69.6 (3) |
O6—Mo4—O12—Mo8 | −128.2 (6) | O21—Mo10—O29—Mo3 | −2.5 (3) |
O30—Mo4—O12—Mo8 | 126.1 (6) | O6—Mo4—O30—Mo10 | 168.6 (3) |
O5—Mo4—O12—Mo8 | 30.3 (10) | O12—Mo4—O30—Mo10 | −85.9 (4) |
O7—Mo4—O12—Mo8 | −29.0 (6) | O5—Mo4—O30—Mo10 | 69.4 (3) |
O21—Mo4—O12—Mo8 | 52.8 (6) | O7—Mo4—O30—Mo10 | 5.8 (8) |
O38—Mo9—O13—Mo8 | 169.0 (4) | O21—Mo4—O30—Mo10 | −2.2 (3) |
O14—Mo9—O13—Mo8 | −85.8 (4) | O39—Mo7—O31—Mo9 | 168.4 (4) |
O31—Mo9—O13—Mo8 | 69.9 (4) | O34—Mo7—O31—Mo9 | −86.3 (4) |
O37—Mo9—O13—Mo8 | 6.8 (9) | O10—Mo7—O31—Mo9 | 5.5 (8) |
O20—Mo9—O13—Mo8 | −1.9 (3) | O11—Mo7—O31—Mo9 | 69.2 (4) |
O38—Mo9—O14—Mo10 | −131.0 (7) | O20—Mo7—O31—Mo9 | −2.4 (3) |
O13—Mo9—O14—Mo10 | 124.3 (7) | O33—Mo8—O32—Mo5 | −132.1 (7) |
O31—Mo9—O14—Mo10 | 27.0 (11) | O11—Mo8—O32—Mo5 | 123.8 (7) |
O37—Mo9—O14—Mo10 | −30.7 (6) | O12—Mo8—O32—Mo5 | −31.1 (7) |
O20—Mo9—O14—Mo10 | 50.8 (6) | O13—Mo8—O32—Mo5 | 27.1 (11) |
O28—Mo10—O15—Mo11 | −128.4 (6) | O20—Mo8—O32—Mo5 | 50.5 (6) |
O29—Mo10—O15—Mo11 | 126.9 (6) | O39—Mo7—O34—Mo1 | −131.2 (6) |
O14—Mo10—O15—Mo11 | −28.7 (6) | O31—Mo7—O34—Mo1 | 124.0 (6) |
O30—Mo10—O15—Mo11 | 32.1 (10) | O10—Mo7—O34—Mo1 | −30.0 (6) |
O21—Mo10—O15—Mo11 | 53.5 (6) | O11—Mo7—O34—Mo1 | 29.3 (10) |
O36—Mo2—O17—Mo11 | 168.2 (3) | O20—Mo7—O34—Mo1 | 51.1 (6) |
O4—Mo2—O17—Mo11 | −86.5 (3) | O16—Mo11—O37—Mo9 | −127.0 (6) |
O23—Mo2—O17—Mo11 | 4.5 (7) | O18—Mo11—O37—Mo9 | 127.6 (6) |
O3—Mo2—O17—Mo11 | 70.2 (3) | O15—Mo11—O37—Mo9 | −28.0 (6) |
O19—Mo2—O17—Mo11 | −2.4 (3) | O17—Mo11—O37—Mo9 | 32.5 (10) |
O16—Mo11—O18—Mo1 | 168.6 (4) | O19—Mo11—O37—Mo9 | 53.8 (6) |
O37—Mo11—O18—Mo1 | −85.5 (4) | Eu1—O40—C2—N1 | −154.9 (6) |
O15—Mo11—O18—Mo1 | 6.6 (8) | C3—N1—C2—O40 | −3.1 (13) |
O17—Mo11—O18—Mo1 | 70.3 (3) | C4—N1—C2—O40 | 177.2 (8) |
O19—Mo11—O18—Mo1 | −2.1 (3) | Eu1—O41—C6—N2 | −176.3 (7) |
O20—P1—O19—Mo11 | 55.7 (3) | C7—N2—C6—O41 | 179.1 (10) |
O22—P1—O19—Mo11 | 175.5 (3) | C8—N2—C6—O41 | −2.5 (15) |
O21—P1—O19—Mo11 | −64.4 (3) | Eu1—O42—C10—N3 | −146.6 (7) |
O20—P1—O19—Mo2 | 175.9 (3) | C12—N3—C10—O42 | 180.0 (9) |
O22—P1—O19—Mo2 | −64.3 (3) | C11—N3—C10—O42 | 0.5 (14) |
O21—P1—O19—Mo2 | 55.8 (4) | Eu1—O43—C14—N4 | −165.4 (6) |
O20—P1—O19—Mo1 | −64.6 (3) | C16—N4—C14—O43 | −0.9 (14) |
O22—P1—O19—Mo1 | 55.2 (3) | C15—N4—C14—O43 | −176.1 (8) |
O21—P1—O19—Mo1 | 175.3 (3) | Eu1—O44—C18—N5 | −169.7 (7) |
O19—P1—O20—Mo8 | 175.4 (3) | C20—N5—C18—O44 | −3.2 (16) |
O22—P1—O20—Mo8 | 55.4 (4) | C19—N5—C18—O44 | 172.7 (9) |
O21—P1—O20—Mo8 | −64.6 (4) | Eu1—O47—C21—N7 | −167 (2) |
O19—P1—O20—Mo9 | −64.7 (4) | C23—N7—C21—O47 | −179.5 (9) |
O22—P1—O20—Mo9 | 175.3 (3) | C22—N7—C21—O47 | 4.0 (14) |
O21—P1—O20—Mo9 | 55.3 (4) | Eu1—O45—C25—N8 | 176.5 (6) |
O19—P1—O20—Mo7 | 54.7 (4) | C26—N8—C25—O45 | −7.7 (16) |
O22—P1—O20—Mo7 | −65.4 (4) | C27—N8—C25—O45 | −177.4 (9) |
O21—P1—O20—Mo7 | 174.7 (3) | Eu1—O1—C28—N9 | −169.7 (7) |
O19—P1—O21—Mo10 | 55.4 (4) | C29—N9—C28—O1 | −0.5 (16) |
O20—P1—O21—Mo10 | −64.9 (3) | C30—N9—C28—O1 | 176.3 (11) |
D—H···A | D—H | H···A | D···A | D—H···A |
C3—H4···O31i | 0.96 | 2.72 | 3.289 (11) | 118 |
C4—H7···O36ii | 0.96 | 2.61 | 3.476 (12) | 150 |
C7—H13···O7 | 0.96 | 2.65 | 3.473 (12) | 145 |
C8—H15···O28ii | 0.96 | 2.51 | 3.316 (13) | 141 |
C8—H16···O5 | 0.96 | 2.58 | 3.424 (11) | 147 |
C10—H18···O28ii | 0.93 | 2.62 | 3.516 (10) | 162 |
C15—H29···O16i | 0.96 | 2.55 | 3.299 (12) | 135 |
C15—H27···O32iii | 0.96 | 2.52 | 3.440 (10) | 160 |
C15—H28···O52iv | 0.96 | 2.29 | 3.174 (10) | 153 |
C16—H31···O6iii | 0.96 | 2.63 | 3.541 (11) | 159 |
C22—H41···O55 | 0.96 | 2.53 | 3.280 (12) | 135 |
C22—H42···O11iv | 0.96 | 2.45 | 3.305 (11) | 149 |
C22—H43···O45 | 0.96 | 2.61 | 3.567 (13) | 172 |
C23—H44···O17v | 0.96 | 2.52 | 3.443 (11) | 161 |
C25—H55···O24 | 0.93 | 2.53 | 3.337 (11) | 145 |
C25—H55···O44 | 0.93 | 2.58 | 3.091 (10) | 115 |
C28—H56···O36v | 0.93 | 2.62 | 3.476 (11) | 153 |
C30—H60···O36v | 0.96 | 2.58 | 3.458 (14) | 152 |
Symmetry codes: (i) x+1/2, −y+1/2, z−1; (ii) −x+1, −y+1, z−1/2; (iii) x, y, z−1; (iv) −x+1, −y, z−1/2; (v) x+1/2, −y+1/2, z. |
Acknowledgements
The authors gratefully acknowledge financial support from the Ministry of Higher Education and Scientific Research of Tunisia. The authors are grateful to the Portuguese Fundacão para a Ciencias e Tecnologia (FCT) for support through projects SFRH/BPD/24889/2005 and PTDC/BIAPRO/ 103980/2008 and for funding the purchase of the single-crystal diffractometer.
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