Bis{bis­(azido-κN)bis­[bis­(pyridin-2-yl-κN)amine]cobalt(III)} sulfate dihydrate

Setifi, F.; Knaust, J.M.; Setifi, Z.; Touzani, R.

doi:10.1107/S2056989016003662

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 5
Extensive C—H⋯O, N—H⋯O, and O—H⋯O hydrogen bonding, represented by dashed red lines, links the anions, complex cations, and water molecules into sheets parallel to the ab plane. For clarity, the pyridine C and H atoms not involved in hydrogen-bonding interactions have been omitted, and only the N atom coordinating to the Co^III cation is shown for the azide anions. [Symmetry codes: (iv) −x + 1, y, −z + $[{1\over 2}]$ ; (v) −x + $[{3\over 2}]$ , y + $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (vi) −x + 1, y + 1, −z + $[{1\over 2}]$ .]

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 72| Part 4| April 2016| Pages 470-476

https://doi.org/10.1107/S2056989016003662

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