view article
Figure 6
The two-dimensional supra­molecular sheets that lie parallel to the ab plane are linked via O—H⋯N inter­actions, represented by dashed blue lines, between the water mol­ecules of one sheet and azide anions of another sheet to form a three-dimensional supra­molecular framework. The discussed C—H⋯N hydrogen bonds between neighboring dpa ligands and azide anions within the coordination sphere of the CoIII cation are represented by dashed yellow lines, and the C—H⋯O, N—H⋯O, and O—H⋯O hydrogen bonds linking the anions, complex cations, and water mol­ecules into sheets are represented by dashed red lines. For clarity hydrogen atoms not involved in hydrogen-bonding inter­actions have been omitted.

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 72| Part 4| April 2016| Pages 470-476
https://doi.org/10.1107/S2056989016003662
Follow Acta Cryst. E
Sign up for e-alerts
E-alerts
Follow Acta Cryst. on Twitter
Twitter
Follow us on facebook
Facebook
Sign up for RSS feeds
RSS