Figure 8
Scatter plot of the folding angles about Na—M versus Npy—M—Npy bite angles for all transition metal complexes reported to the CSD with dpa in coordination mode VI. Blue dots represent all complexes with dpa coordinating in bonding mode VI to a transition metal. Red dots represent compounds where the metal has a coordination environment similar to the title compound: two dpa in bonding mode VI and two terminal azide anions. Black dots represent the title compound. |