Figure 1
The asymmetric unit of (I) , solvent molecules being shown in different positions relative to the peptide molecules than they have in the unit cell to avoid extensive overlap. The minor disorder orientation for TFE molecule D is shown in wireframe representation. The amino group of molecule A has an unusual eclipsed conformation (blue shade) resulting from formation of an intramolecular hydrogen bond to O1A, while a normal staggered conformation (red shade) is observed for molecule B. Thermal displacement ellipsoids are shown at the 50% probability level. |