Figure 1
The asymmetric unit of (I), solvent molecules being shown in different positions relative to the peptide molecules than they have in the unit cell to avoid extensive overlap. The minor disorder orientation for TFE molecule D is shown in wireframe representation. The amino group of molecule A has an unusual eclipsed conformation (blue shade) resulting from formation of an intramolecular hydrogen bond to O1A, while a normal staggered conformation (red shade) is observed for molecule B. Thermal displacement ellipsoids are shown at the 50% probability level. |