Crystal structure of BaMnB2O5 containing structurally isolated manganese oxide sheets

Maschmeyer, E.M.; Sanjeewa, L.D.; Ranmohotti, K.G.S.

doi:10.1107/S2056989016013074

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 4
(a) Extended structure of BaMnB₂O₅ viewed approximately along the [101] direction. The connectivity of the barium atoms is not shown for clarity. (b) Partial structure of [MnB₂O₅]²⁻ slab viewed along [100] where the polyhedral drawing represents MnO₅ square pyramids and B₂O₅ units are represented by ball-and-stick drawing. (c) Edge-sharing and corner-sharing MnO₅ units corner-share with B₂O₅ pyroborate groups (polyhedral drawing) to create a cage. (d) Stick drawing of one cage with empty space in the middle.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 72| Part 9| September 2016| Pages 1315-1320

https://doi.org/10.1107/S2056989016013074

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